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By S. Lohmeier, D. Gallhofer, B. G. Lottermoser, T. Schirmer

At a time of resource consumption, it is important to study the chemical composition of mining and metallurgical wastes to prevent the dissipative loss of metals and metalloids from the mining value chain. In particular, the recovery of critical elements from wastes is an option to increase the resources of such materials that are economically significant and have an overall supply risk. In this paper we report on the chemical composition, in particular the critical element content, of granulated slag originating from historical smelting activities in the Tsumeb area, Namibia. Laboratory-based inductively coupled plasma–mass spectrometry (ICP-MS) and X-ray fluorescence (XRF) analyses as well as portable X-ray fluorescence (pXRF) demonstrate that the slags are on average enriched in base metals (Cu 0.7 wt%, Pb 2.7 wt%, Zn 4.7 wt%), trace metals and metalloids (Cd approx. 50 mg/kg, Mo approx. 910 mg/kg) as well as critical elements (As approx. 6300 mg/kg, Bi approx. 3 mg/kg, Co approx. 200 mg/kg, Ga approx. 100 mg/kg, In approx. 9 mg/kg, Sb approx. 470 mg/kg). While metals and metalloids such as As, Mo and Pb can be determined reliably using pXRF instruments, the technique has inherent limitations in evaluating the contents of certain critical elements (Ga, Sb). However, there are positive correlations between the As, Mo, and Pb contents determined by pXRF and the Ga and Sb contents obtained through ICP-MS and XRF. Thus, quantitative pXRF analysis for As, Mo, and Pb allows calculation of Ga and Sb abundances in the slags. This work demonstrates that pXRF analysers are a valuable tool to screen smelting slags for their chemical composition and to predict the likely contents of critical elements.

Mar 1, 2021

By M. Kumral, Y. A. Sari

Underground mining operations tend to have higher operating costs than surface mines. When metal prices decrease, profitability is jeopardized due to the high costs. Therefore, mining management harnesses new practices that increase operational efficiency. One way to manage this challenge is to invest in new mine planning practices. Stope layout optimization as a part of underground mine planning aims to identify a portion of the orebody in the form of production volumes (stopes) to maximize profit under roadway and stope dimension constraints. In this paper we propose a novel approach based on identifying ore-rich areas of the deposit and prioritizing their extraction through an iterative heuristic clustering approach. The proposed approach is compared with and validated by an exact method through a small mining example. The heuristics produced nearly identical results in a very short time. Finally, a case study was carried out using a larger data-set. The cluster-based iterative approach generated nearoptimal stope layouts in a computationally effective manner.

Mar 1, 2021

By H. W. J. P. Neomagus, J. R. Bunt, D. L. Botha, N. T. Leokaoke

Coal briquetting traditionally makes use of high-dosage, nonpolymeric binders (such as coal tar pitch or molasses) or polyvinyl alcohol (PVA) at low dosages for the binding of fine and ultrafine coal. Due to constraints associated with the manufacturing and cost of PVA-bound briquettes, a novel polyacrylic binder was developed that could possibly be added in low dosages at room temperature. A set of formulations of two polyacrylic components (components A and B) was developed, from which an optimal binder mixture was determined. This formulation comprises 40wt.% component A and 10wt.% component B with a 0.04wt.% cross-linking additive, and the balance water. The uniaxial briquette compressive strength was used to obtain the optimal binder mixture. The binder mixture was added to the coal powder in dosages from 0.1 to 1.2wt.%. Mechanical tests and thermogravimetric analysis in an oxidized environment at a maximum temperature of 930°C were conducted. Binder-bound briquettes were compared to binderless briquettes and PVA-bound briquettes. Briquettes made from the polyacrylic formulation had uniaxial compressive strengths double that of the binderless briquette yield strength, as well as the minimum recommended compressive strength of 0.375 MPa. The organic binders did not affect the combustion of the briquettes, since the results compared well with the binderless briquettes. The polyacrylic formulation is considered to be a possible substitute for PVA in terms of mechanical and thermal properties and raw material cost.

Mar 1, 2021

By J. Zhang, A. J. S. Spearing, L. Ma

Ore deposits are becoming more complex to mine as a result of the exhaustion of surface and other easily mined deposits. There is also increasing socio-political pressure to design more environmentally sound, sustainable, and safe mining practices. Wang and Ma designed a mining method for coal, similar to a modified drift and fill using a continuous miner to take sequential cuts (rooms) that are subsequently backfilled. The authors have modified the concept to make it more autonomous, safer, and less costly using highwall coal mining techniques, modified and adapted for underground applications. The method is more flexible than longwall mining and the percentage extraction would seem to be in the same range. In addition because of the backfilling, surface subsidence would not be a major issue and could be more effectively managed.

Feb 2, 2021

By J. S. Contreras, E. Córdova, I. Gottreux, A. Anani, A. Ferrada

Cave mining is an underground mass mining technique. The largest projects, which are known as ‘super caves’, produce hundreds of thousands of tons of ore per day, which involves large footprints with considerable column height, and have a life of mine of over 20-40 years. These operations are typically located deep, under high stresses and in competent rock masses, making initiation and propagation of the caving process harder to manage. These challenges must be confronted by optimizing the fragmentation of the orebody to achieve smaller size blocks that will result in consistent caving and improved flow of the ore from the drawpoints. To achieve better performance from the drawpoints, preconditioning is applied to fragment and damage the material required to cave. We present a proposed design for preconditioning in underground mines, considering the challenges that these large-scale mines are already facing, based on a comprehensive analysis of current design parameters, case studies, and sensitivity analyses using numerical models.

Feb 2, 2021

By S. Schutte, J. Pelders

Worker participation in equipment development can result in improved user acceptance and product quality. This paper focuses on worker engagement in equipment development processes in the South African minerals sector. Qualitative data was gathered during interviews with original equipment manufacturers (OEMs) and industry experts. A lack of inclusion in equipment design from workers from all organizational levels in mines was reported. Meanwhile, the historical context and workplace culture of the mining industry (including leadership, trust, training, performance, and remuneration factors) were evident barriers to the implementation of new technology. Worker engagement processes should include securing management commitment, creating multidisciplinary teams, effective facilitation, shared understanding of needs, training and development, and iterative design. Human-centred design approaches and independent platforms for engagement on equipment design requirements are recommended.

Feb 2, 2021

By A. M. Garbers-Craig, T. Coetsee, T. M. Nemavhola

Accretions often form in furnaces when slag and charge materials attach to the refractory wall and build up over time. Accretion formation is usually unwanted because it reduces the working volume of the reactor and hinders material flow through the reactor. However, in some instances a thin, stable accretion layer may be desirable to protect the underlying refractory material. In order to prevent and/or manage accretion formation, it is important to understand the underlying principles of this phenomenon in the particular reactor. Excessive accretion formation hampered production at the Exxaro FerroAlloys ferrosilicon melting and atomization plant. This plant uses induction furnaces in which a 15% silicon-iron alloy is produced by batch smelting a mixture of ferrosilicon of 75%Si grade and low-carbon steel. The molten ferrosilicon alloy is then gas-atomized to a powdered product for use as a dense medium in mineral processing plants. The objective of this study was to investigate the effect of different impurity levels in the ferrosilicon feed material on the extent of accretion formation as well as the effect on the accretion properties, which influence the ease of accretion removal upon furnace shut-down. Refractory and accretion samples were collected after a furnace shut-down and characterized using X-ray diffraction and scanning electron microscopy–energy dispersive spectroscopy. It was concluded that the trace elements in the FeSi-75 feed material (Al, Ca, Mn) were mostly responsible for accretion formation, but that rust on the low-carbon steel and oxidation of the steel contributed to accretion attachment to the lining. The total contaminant content, calcium to aluminium ratio in the FeSi-75 feed material, and thereby the liquid to solids ratio in the accretion at temperature determine the strength of attachment as well as growth of the accretion.

Feb 2, 2021

By L. Scott, M. A. Goncalves

Effective communication is a sought-after non-technical skill in the health, safety, and environmental (HSE) function and is fundamental in achieving an organization’s safety objectives. While different channels are used to communicate HSE matters, many organizations employ posters, videos, and/ or signs containing images to convey information. Communication through signage and graphical hazard symbols has been regulated in standards, but vast sections of HSE communication are bespoke communications and exist outside the sphere of standards. Effective HSE communication through images requires an understanding of the organizational culture in which the images will be used, as well as an understanding of the semiotics of the images themselves. Creative interpretation within HSE communication can create situations where the message that was received is not the message that was intended, leading to confusion and misinterpretation. This paper is aimed at elucidating the semiotics of South African HSE visual content. It was found that the indexical mode of images was most preferred in visual communication, and text-only designs the least preferred. Senders and receivers of messages differ in their opinions on the complexity of HSE communication.

Feb 2, 2021

By S. Michael, T. E. Moongo

Electrowinning consumes a substantial amount of electrical energy, and owing to the ever-increasing unit cost of electrical power there is a need to improve current efficiency in the process. This research was carried out to design a continuous quality improvement framework for improving electrowinning current efficiency by applying statistical process control (SPC) on an online industrial copper electrowinning operation. A sequential mixed research methodology was applied and a statistical software package utilized for analysing data. It was concluded that metallurgical short-circuits (hotspots) had the most significant effect on current efficiency. Bringing hotspots under statistical control resulted in a 5.40% improvement in current efficiency, which is equivalent to approximately 74 t of 99.999% pure grade A copper cathode production over a period of 1.5 months.

Jan 1, 2021

By K. Gharibi, A. Dehghani, S. Farrokhpay, M. Aghajanloo, M. Ostadrahimi

The effect of flotation operational parameters on froth stability and froth recovery was studied. Froth stability was measured using a special column. To determine the froth recovery, the froth height change model and froth height exponential model were used. It was found that since the interactions between the pulp and froth zones affect the time of froth formation, the exponential model is more suitable than the froth height change method for determining the froth recovery. The results showed that superficial air velocity and collector dosage have, respectively, the highest and lowest effect on the froth recovery, while froth recovery decreases sharply with increasing froth height.

Jan 1, 2021

By B. P. Watson, D. Hoffmann, D. P. Roberts

Potholes on the Merensky and UG2 reefs in the Bushveld Complex occur as near-circular to elliptical depressions or slumps on the reef horizon, normally presenting as severe disruptions which prevent economic extraction. Within the pothole, the reef and other strata may either be attenuated, absent, or highly deformed, this being the result of the overlying hangingwall strata having slumped down. The hypotheses for pothole formation involve several mechanisms, including downward erosion, upward fluid movement, or synmagmatic deformation. When potholes are exposed in mine workings, significant fracturing is often observed. This fracturing is particularly evident in anorthosite rock types. Stress measurements were conducted in a pothole on the Merensky Reef to determine if the fracturing was due to high stress conditions. The paper describes the measurement results and numerical modelling that was done to determine the influence of depth and mining on the stress condition at the site. The results show that high stresses do exist in at least some potholes, and that current formation theories do not adequately explain the measured stresses. In support of understanding the high local stress associated with the pothole, the study explored several rock engineering modelling processes to validate the conditions of the study site and enclosing excavations. A better understanding of the stress conditions in potholes with additional data could lead to more appropriate support design and avoidance of potential rockbursts in these structures.

Jan 1, 2021

By T. Nghipulile, M. Moys, M. Bwalya, H. Simonsen

The quest for efficiency in comminution is an ongoing concern as comminution usually constitutes a major cost component in the metal production industry. Such improvements can be made by circuit optimization or development of more efficient equipment. A novel crusher, known as the rotary offset crusher (ROC), promises to deliver in this space. The ROC was invented in 2002 by Michael Hunt, Henry Simonsen, and Ian Sinclair, but failed to garner enough support to progress to production. The original design concept was recently rekindled, and a laboratory version of the crusher has been built and commissioned at the University of the Witwatersrand. The crusher is simple in design, with two cylindrical discs that are parallel to each other, and, as the name implies, there is an offset between the vertical axes of the discs. The top disc has a conical section on its lower face, and this creates a crushing zone between the opposite faces of the two spinning discs. Centrifugal motion transports particles through the crushing zone. Batch experiments have been conducted with quartz at various crusher settings (discs offset, rotational speed, and vertical exit gap) for various feed size distributions. The indications so far suggest that the disc speed is a key factor affecting the performance. Size reduction ratios as high as 11 were recorded from experiments with quartz at a speed of 830 r/min.

Jan 1, 2021

By E. P. Preis, R. C. W. Webber-Youngman

The real cost of any mining incident has, empirically, proven to be estimation-driven, rather than factdriven. One of the main reasons for this lies with the complexity of the cost composition of any given mining incident. Incident costs comprise both direct and indirect cost factors, and in many cases the costs associated with these factors are incurred during different time periods following the incident. In this paper we aim to identify the various cost factors arising from mining incidents, provide a thorough understanding of all the potential cost factors identified, and draw general conclusions on the knowledge obtained. Furthermore, recommendations are made on how mining companies could use the results, in order to assist them in calculating the costs of mining incidents. The paper also provides suggestions for further research, with the emphasis on the most significant immeasurable cost factors, namely the costs of implementing job accommodations following an incident, the harm to company reputation, and the decreased productivity due to low worker morale/psychological factors following an incident. If mining companies are aware of and understand which factors could contribute to the cost of any given incident, future planning and incident cost estimations could be easier. It should, however, be noted that although this study provides a comprehensive list of cost factors (and detailed explanations), other unknown cost factors relating to mine incidents could prevail in extreme cases.

Jan 1, 2021

By M. Mpofu, B. Maphalala, S. Khan, S. Ngobese, D. Roberts

This paper details an assessment of stemming practices at a South African opencast coal mine and their influence on ground vibration and air blast. Quantitative and qualitative analysis methods were used for the study. The parameters assessed for the quantitative analyses included stemming length, stemming material type, blast-hole depth, burden, and spacing. Pre-blast data from the mine was analysed to determine the deviation between actual and mine design stemming parameters. Mine design stemming length was also compared to the rule-of-thumb stemming lengths. Peak particle velocity (ground vibration) and air blast data from seismograph stations around the mine was analysed to determine the correlation between stemming length and excessive ground vibration and air blast. The qualitative analysis involved observations of blasting procedures at the mine to determine compliance with mine procedures. Some level of non-compliance of actual stemming parameters to design stemming parameters was found, which initially suggested that non-compliance may have contributed to excessive air blast. However, further analysis of the seismograph results indicated no direct correlation between stemming length and excessive air blast and ground vibration. Since stemming parameters are interrelated, it is crucial that all blasting procedures, including stemming, are executed in accordance with best practice, and recorded accurately. There is a need for digital systems for capturing on-bench blasting parameters, as the currently used manual data recording and reporting systems are inefficient and prone to error. Improvements to blast designs are possible through efficient and accurate data recording and reporting systems.

Jan 1, 2021

By J Taguta, B. McFadzean, P. E. Ngoepe, M. G. Mulaudzi

Computational modelling methods and isothermal titration calorimetry (ITC) were employed to investigate the interaction of a pyrite surface with thiol collectors. Modelling work was conducted in the presence and absence of water. Microcalorimetry was employed to investigate the resultant energy of interaction pyrite as a result of mineral-collector interactions. Sodium ethyl xanthate (SEX), diethyldithiocarbamate (DTC) and diethyl dithiophosphate (DTP) were investigated in this study. The results showed that the calculated surface energies and morphologies for FeS2 showed that (100) and (111) are the most stable surfaces. The morphology also indicated the appearance of the (100) and (111) surface facets and no presence of others. The calculated adsorption energies between thiol collectors and the pyrite surface were always more exothermic than the experimentally determined ones. When comparing different ligand types with the same alkyl chain length, the heat of adsorption of diethyl-DTC was greater than that of ethyl xanthate and diethyl-DTP for pyrite. Experimentally, the diethyl DTP barely adsorbed onto the pyrite surface and this may be due to a different mechanism of action. In computational calculations, water adsorption was found to reduce the reactivity of the Fe atom for the interaction with thiol collectors, and bring the adsorption energies closer to the magnitude of the experimental values. Keywords: Computational modelling, microcalorimetry, experimental and thiol collectors, adsorption energies

Jan 1, 2020

By B. Friedrich, A. Birich

Gold has been a metal of special importance for mankind for several thousand years. Its outstanding chemical resistance is an important property of this noble metal, but becomes a disadvantage when it comes to gold recovery. The established processes are based on highly aggressive and toxic reagents. Different alternative leaching reagents with a significantly lower toxicity proved to be promising alternatives in the last decades. Major research activities in this field focused on gold ores, so that leaching of secondary resources were not described sufficiently. Based on literature research and extensive experimental investigations, a reagent assessment was conducted for hydrometallurgical gold recovery from electronic waste. It was found that besides thiourea and halides, thiosulfate in particular represents an alternative of major relevance. A variety of different electronic waste (e-waste) specimens were investigated to identify suitable leaching conditions. As a result, an almost complete and selective gold recovery in less than 48 hours from different electronic waste types and components was achieved by thiosulfate leaching. Within the experiments conducted, it was found that the leaching behaviour of cyanide alternative lixiviants differ strongly from leaching of primary ores. Keywords: Gold leaching, cyanide alternative, thiosulfate, electronic waste

Jan 1, 2020

By F. Nakhaei, Z. Pourkarimi

Tailings produced from the iron ore industry present many challenges due to the high economic and environmental impacts involved with their disposal. However, the relative scarcity of high-grade iron ores has driven manufacturers to recover and recycle these valuable tailings (secondary sources). This study aimed at the purification of ultrafine tailings with high sulphur content from an iron ore concentrator via reverse flotation to produce pellet feed fines. A specially designed flotation column featured with a nano bubble generator and a conventional bubble generator were employed to assess the effects of nano bubbles on the desulfurisation performance of iron ore concentrate under different operating conditions. Results obtained from this study indicated that the sulphur content of iron concentrate could be reduced from 1.2% to 0.22% in the presence of nano bubbles. Also, the results showed that use of nano-micro bubbles increased sulphur recovery 20% more, in comparison to micro bubbles. Keywords: Column flotation, iron ore, tailings, slime, nano bubbles, desulphurisation

Jan 1, 2020

By S. M. H. Haddad, M. Saghaeian, R. Hejazi, V. Sheikhzadeha, A. H. Baladastian, A. Dehghani Ahmadabadi

Sulfide impurities in iron ore concentrates play an important role in designing pelletising and steel making plants. Therefore attempts are made to keep the sulfur content of the final concentrate produced by the plants as low as possible. Generally, in the beneficiation process of iron ore concentrate, the removal of sulfur is performed through magnetic separation systems, followed by reverse flotation. The sulfide content of the iron ore concentrates originated from two main sources, including pyrite and pyrrhotite. In this research, in order to compare the floating capability of these two types of sulfide minerals, two iron ore concentrates with different sulfide constituents, pyrite or pyrrhotite, were selected. Reverse flotation tests were done separately on these samples under similar conditions. Process parameters considered for the tests included pH (2, 4, 6, 8 and 10), collector consumption (150, 200, 250, 300 and 350 g/t) and frother consumption (40, 50, 60, 70 and 80 g/t). Potassium Amyl Xanthate (PAX) and Methyl Isobutyl Carbinol (MIBC) were the collector and frother used in the tests, respectively. For modelling and optimising process parameters, the Central Composite Design (CCD) method was applied to the test results. Empirical coded equations were obtained for responses involving weight recovery, Fe recovery, Fe grade and S grade. Finally, comparison of test results revealed that the elimination recovery of pyrite sulfides was far greater than pyrrhotite sulfides, and it was possible to remove 84% sulfur content of the pyrite sample compared to minus 30% for the pyrrhotite sample. Keywords: Reverse flotation, pyrite and pyrrhotite, sulfur removal, iron ore concentrate, beneficiation plant

Jan 1, 2020

By O. I. Rychkova, M. N. Sycheva, E. V. Poryadochnova, G. V. Sedelnikova

Deposits of copper-porphyry type occupy a leading position in the mineral resource base of the world copper industry. They are characterized by large and gigantic scales, often complex composition, their development is carried out in an open way. The raw material base of the Russian copper industry is mainly sulfide copper-Nickel and copper-pyrite ores. Exploration of copper-porphyry deposits and the creation of long-term large mining facilities on their basis is one of the most promising and priority tasks for the Russian industry. This task is especially acute for the copper enterprises of the Urals in connection with the depletion of copper - pyrite ore reserves. In recent years, Russia has carried out a large complex of studies on the composition and technology of processing of copper-porphyry ores of different subtypes. In this work the complex poor copper-molybdenum-gold ore of one of the deposits is investigated. The chemical and mineral composition of the ore containing 0.49% copper, 0.020% molybdenum, 0.39 g/t gold, 5.85 g/t silver was determined. The forms of finding metals and their distribution by size classes are established. The dependence of extraction of metals into concentrates of collective-selective flotation on the size of ore grinding, pH of the medium, reagent consumption is shown. Under optimal flotation conditions, copper concentrate with 18.6% copper content and 92.32% extraction and molybdenum concentrate with 21.5% molybdenum content and 73.4% extraction were obtained. With a high concentration of molybdenum in selective flotation products, it is possible to conclude about the expected molybdenum concentrate with a content of 45% and a recovery of 70%. The associated extraction of gold and silver into copper concentrate is 76.8 % and 73.4%. Keywords: Collective-selective flotation, copper, molybdenum, porphyry ore, grinding, pH, reagents

Jan 1, 2020

By N. V. Nemchinova, A. A. Kozlov, A. V. Epiforov

The gold dissolution in sulfuric acid media during industrial oxidative leaching test of sulfide gold-copper flotation concentrates has been achieved. The reason for this was using technological water containing thiocyanates and cyanides, which can dissolve gold under these conditions. The carbon in column (CIC) process for gold recovery from these solutions was proposed. However, significant amounts of copper and iron were adsorbed onto the carbon during CIC technology industrial tests. This resulted in a decrease of the gold content in the loaded carbon up to 0.5 kg/t. Further development of the technology was conducted by optimisation of gold and impurities stripping and implementation of carbon reactivation. It was shown, that the copper extraction from the loaded carbon during cyanide treatment was about 95%. The copper content in the stripped carbon after cyanide treatment was 1.76 kg/t. The gold recovery during high-pressure elution by caustic solution was 98%. The hydrochloric acidic treatment with thermal pre-treatment (reactivation) for removing iron and calcium from gold-free carbon was proposed. In this case, the iron and calcium extractions from carbon were 40-45 and 50-55% respectively. These tests showed that for carbon recycling the sequence operations of ‘cyanide treatment, gold elution, thermal pre-treatment, hydrochloric acidic treatment’ can be used. Keywords: Thiocyanate leaching, recovery of gold, carbon adsorption, gold elution, copper stripping, thermal reactivation of carbon, activated carbon, carbon-in-column

Jan 1, 2020