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By F. D. Ayhan

The aim of this study was to investigate desulfurization and de-ashing of a mixture of subbituminous coal and gangue minerals by the agglomeration method. For this purpose, experimental studies were conducted on a mixture containing subbituminous coal, pyrite, quartz and calcite. The effects of some parameters that markedly influence the effectiveness of selective oil agglomeration, such as solid concentration, pH, bridging liquid type and concentration, and depressant type and amount, were investigated. Agglomeration results showed that the usage of various depressants (Na2SiO3, FeCI3, corn starch, wheat starch) in the agglomeration medium has a positive effect on the reduction of ash and total sulfur content of agglomerates. It was found that an agglomerate product containing 3.03% total sulfur and 25.01% ash with a total sulfur reduction of 56.71% was obtained from a feed that contained 7% total sulfur and 43.58% ash when FeCI3 was used in the agglomeration medium. Key words: Desulfurization, De-ashing, Agglomeration, Coal, Gangue minerals

Jan 1, 2009

By N. Ohmura, H. Saiki, T. Nagaoka

A microbiological flotation system that facilitates the removal of pyritic sulfurfrom coal is reported. The chemoautotrophic bacterium Thiobacillus ferrooxidans is utilized as a pyrite-selective biological surfactant that augments the flotation-mediated rejection of pyritic sulfur. The bacteria were produced by continuous cultivation in 50-L tanks, where it was possible to produce 3.8 x 1012 cells/day when the dilution rate was optimal and the pH was 1.6, a condition that prevented ferric precipitation. Prior to flotation, the bacteria were mixed with coal, which allowed cells to selectively adhere to the pyrite. The adherence of bacteria made the pyrite surfaces more hydrophilic, which facilitated separation by increasing the tendency of pyrite to sink, while the hydrophobic coal floated. When a synthetic coal/pyrite mixture (10.1 % sulfur) was subjected to microbial flotation, the level of sulfur rejection was stable during the entire period of operation (i.e., one hour). In the absence of bacteria, flotation reduced the sulfur content of a coal/pyrite mixture to within the range of 6.7% to 7.4%, with the combustible recoveries ranging from 93.9% to 99.0%. In the presence of bacteria, the sulfur content of cleaned coal was in the range of 1.3% to 1.4%, with the combustible recoveries ranging from 80.8% to 86.3%. Bacterial activity accounted for 57% of the total sulfur rejected through flotation. The desulfurization capacity of the system was further confirmed by testing it with run-of-mine coal. The pyritic sulfur content was reduced from 2.9% in the feed coal to around 1.2% in the froth product, while 80% of the combustible recovery was retained. Microbial flotation removed 60% of the pyritic sulfur from the feed. These findings demonstrated that micro¬bial flotation could be utilized for the removal of pyritic sulfur from coal in a semicontinuous system.

Jan 1, 2000

By A. K. Sinha

A great potential market for the high BTU midwestern thermal coal exists if the coal is desulfurized and prepared to meet the environmental restrictions and the utility customer specifications. Because the midwestern coal is very high in pyritic sulfur, it can be adequately desulfurized by removing the pyrite with the help of such coal cleaning techniques as the froth flotation. Froth flotation cells are now commonly employed in modern coal preparation plants for recovering the fines but they are not utilized for desulfurizing the coal probably due to a lack of system operating data for such applications. A research project recently conducted at Southern Illinois University shows that the total sulfur in the midwestern coals can be successfully reduced from as high as 5.3 percent to less than 1.4 percent by single stage froth flotation. The results obtained on ten different samples of high sulfur coal obtained from different areas in the Illinois Basin are presented and discussed.

Jan 1, 1985

By E. Cho

Illinois No. 6 coals of IBC 101 and IBC 112 were treated in solution with sodium hypochlorite to remove their sulfur contents, especially organic sulfur. The lab experiments were conducted in two steps of leaching at room temperature and hydrolysis at 90oC. The removal of organic sulfur from IBC 101 was by 37.8% while that from IBC 112 was only 13.7% under their respective optimum conditions. This large difference in organic sulfur removal is considered to be due to difference in concentration of surface total acid group, 3.14 vs. 0.88 mmol/g of coal.

Jan 1, 2007

By Y. Wang, K. S. E. Forssberg, A. Johansson, X. Lu

This paper presents the desulphurisation of a fine graphite powder below 80 µm by high gradient magnetic separation. The removal of pyrite (FeS2) and pyrrhotite (Fe1-xS) from the fine graphite powder was carried out with a modified version of the Sala dry HGMS with vibration assistance. In addition, a comparative study with dry and wet HGMS systems has also been performed. In order to establish the performance of the desulphurisation, a test series of varying parameters such as magnetic induction, matrix type/configuration and vibration were performed. As an equipment/process for removing sulphurous impurities from the fine graphite powder, the dry HGMS is deemed useful and comparative with the wet HGMS.

Jan 1, 2002

By Akira Tsune, Shingo Sugimoto, Tadayuki Ishiyama, Nadao Saito, Masatsugu Okazaki

"The Deep Ocean Resources Development Co. Ltd. (DORD) of Japan signed a 15-years contract with the International Seabed Authority for exploration of polymetallic nodule in a 75,000 km2 area, consisting of West and East Areas in the Clarion and Clipperton Fracture Zone in 2001. The exploration work is now concentrated in resource estimation of the first generation of mining area, the High Abundance Area.A detail survey of the Model Area, set in the High Abundance Area, was conducted using AUV (Autonomous Underwater Vehicle) equipped with MBES (Multi-Beam Echo Sounder), SSS (Side Scan Sonar), Sub-Bottom Profiler (SBP) and still camera. The seafloor topographic map based on 1 m grid data was produced in an area of approximately 80 km2 (Figure 1). Photographs, continuously covering the seafloor taken by AUV along two west-east trending traverse lines, together with detail seafloor topographic map produced from MBES give an excellent opportunity to observe distribution manner of pollymetalic nodule related to topographic features. This helps to understand more accurate resources estimation of a whole area of the High abundance Area. Furthermore, information of micro-topography gives ideas for conducting ore collecting operation and designing ore collector."

Sep 1, 2014

By Sandeep Upadhya, Marc Morgan, Baljinder Bassi, James Fletcher, Mike Deevy, Nishant Nayan

"In order to protect public safety in the event of a deliberate fire attack, underground rail authorities are increasingly considering the need to design for arson-initiated fire scenarios. Where typical design fires for modern rolling stock mean a peak fire size is reached after 12 minutes, an arson-initiated fire reaches its peak within 2-3 minutes. We present the innovations required to successfully incorporate this requirement on a recent design-build project. In stations 3D modelling is used to optimise smoke reservoir designs, smoke chimneys, station boxes and tunnel geometry to allow coordination with structural requirements. In tunnels, novel coupling of one dimensional network modelling and 3D Computational Fluid Dynamics (CFD) is used to improve assessment of complex fire scenarios. Finally, the impact on tunnel structures is assessed through comparison with standard time-temperature curves and risk of explosive spalling. INTRODUCTION An increasing regulatory environment and the appreciable influence that terrorist incidents have had on public safety policy have motivated the need to protect against large arson fires, especially in civil structures and public transport systems. With a greater reliance of a growing urban population on underground subway systems, design of such infrastructure is continually being reassessed and developed worldwide. Underground rail authorities are paying increased consideration to the design of fires - with properties beyond the upper regions of growth and intensity - amongst arson fire studies. Use of fire hardened materials on modern rolling stock means fires caused accidentally can be expected to develop relative slowly. However, recent experiments involving large initiating fires (as would result from an arson attack) have shown rapid fire growth rates and flashover leading to greater maximum heat release rates, Hadjisophocleous (2012), White (2010), and Lönnermark, et al. (2015). This paper describes the challenges and innovations required to complete a detailed design to control smoke from such aggressive super-fast growing fires. Computational modelling is used to demonstrate the required smoke control design by configuring the mechanical exhaust system combined with careful coordination with the architectural and structural design. The design objectives are to provide tenable egress paths in accordance with NFPA 130 (2014) and fire-fighting access. Finally, analysis of the design fire is used to inform the tunnel lining design, reducing the risk of explosive spalling, protecting the asset in the event of a severe fire."

Jan 1, 2016

By Carl E. Williams

During the past two years a computer program called "COPOR," Computerized Open Pit Optimization Routine, has been developed and used for mine planning of several base metal deposits. This routine utilizes a three dimensional computerized block model of an orebody, some economic parameters and operating constraints to locate the mineable or economic limits of the deposit schedule the yearly production from the mine and produce bench by bench ore reserve summaries and maps of the yearly and ultimate pit configurations. The moving cone method is used to perform these functions with a conventional block model. This model is conventional in the sense that each block is assumed to be homogenous; i.e., either ore or waste but not a mixture of the two. Due to the nature of a seam type deposit this approach is not realistic; therefore, revisions have been made to form a new version of the COPOR program. This version has been named "COALOR," Coal Optimization Routine. COALOR contains all of the power of the COPOR program but is equipped to handle the intricacies of coal seam type deposits. The deposit can be composed of a single seam or multiple seams which are horizontal or dipping at any angle. The numerous coal quality values can be incorporated to aid the optimization of the economic pit limits and yearly scheduling.

Jan 1, 1978

By Y. H. Alghamdi, A. D. S. Gillies

"INTRODUCTION Background Diesel Particulate Matter (DPM) has been a critical issue during the last decade in underground mines. This problem is threatening the health of mine workers, as well as the mine’s productivity. It has been confirmed that the diesel engine exhaust is the main source for the diesel particulate matter (DPM), and that it has the highest impact in raising carbon monoxide, carbon dioxide, oxide of nitrogen, and hydrocarbons in the underground environment. Miners who are exposed to this kind of emission are at high risk for developing lung cancer and other lung diseases. The Mine Safety and Health Administration (MSHA) has issued standard rules to regulate diesel emissions in underground mines. The final ruling confirmed in 2008 that the total carbon should not exceed 160 µg/m3. (MISHA, 2008) Monitoring DPM in underground mines has become important to ensure compliance with the MSHA regulations. There are many different types of DPM monitoring systems that are currently being used in underground mines. Two methods are typically used for DPM sampling: the personal sampling method or the direct exhaust sampling method, which takes a direct sample from the engine’s tailpipe. Many mines do not recommend using the direct exhaust sampling method since it involves complex measuring equipment and procedures, as well as it is not regulated in the United States or Canada. Thus, the personal sampling method is the preferred method in many mines when taking DPM samples. Even this method includes many variations, such as the Respirable Combustible Dust (RCD) method and the method devolved by the National Institute for Occupational Health and Safety NIOSH 5040. The NIOSH 5040 method is the preferred method overall because it gives more accurate measurements compared to the other methods. This method does not allow organic carbon sources other than those coming from diesel engine exhausts to interfere with the measurements, which otherwise would lead to overestimating the actual amount of the DPM in the mine environment. An impactor feature in the cassette, which holds the samples in the instrument, characterizes this method. Since the diesel particles are less than 0.9 micron, this impactor does not allow particles more than 0.9 microns to be collected in the cassette filter. The cassette is then analyzed in a lab and the concentrations of organic carbon (OC), elemental carbon (EC), and total carbon (TC) are determined. Lately, the National Institute for Occupational Safety and Health (NIOSH) has developed a new instrument that can use the same concept of NIOSH 5040, but with instant measurements of elemental carbon. It utilizes laser radiation with the cassette so it can give a real time measurement. The real time measurements give instant information about the underground environment that will allow the mining engineer to take immediate action and enact plans instead of waiting for results from the laboratories where NIOSH 5040 method may take several weeks to get the measurements."

Jan 1, 2016

By Rene Padilla, Siyanda B. Mngadi, Gerrie van Aswegen, Peter Stonestreet

While many mine tunnels are developed through ground that must be riddled with the sources of small (and larger) mining induced seismic events, recorded by the mine seismic monitoring systems, we do not see planar discontinuities classified as seismic sources in the geotechnical databases. Here we list criteria that may be useful to identify discontinuities in drill core which are dynamic slip surfaces, parts of mining induced seismic sources. Such shear rupture surfaces in core would generally be powdery, cohesionless, and rough on cm scale. Finely broken rock and rock flour may be found in the core boxes at the discontinuities. Slickensides would be soft (easily destroyed) and kinematically consistent with the local stress field. In some cases, a cross fabric would be present, orthogonal to the slickensides, being the intersections of en-echelon extension fractures, within the dynamic shear zones, with the shear zone walls.

Apr 26, 2022

By F. Sime, X. Wang, J. D. Miller, T. Akinseye, S. Assemi, L. Pan

Respirable coal mine dust (RCMD) is a complex mixture of carbonaceous and mineral particles with a variation in size and shape. Accumulation of RCMD in the lungs of underground coal miners results in severe respiratory damage and ultimately progressive pneumoconiosis known as the black lung disease. The occurrence of the black lung disease dropped to a low of 2.1% in 1990s but has increased to 3.1% in 2000s [1], prompting more research on coal mine dust mitigation. In addition to surveying the impact of new mining technologies on the size of generated dust and exposure measurement, a comprehensive characterization of physico-chemical properties of RCMD particles are essential for a better understanding of the adverse health effects of coal mine dust. Such vital factors include particle size, surface charge, morphology, composition, and agglomeration state. The respirable fraction of RCMD, has been designated as particles < 10 μm in diameter, and almost all studies on the RCMD toxicity have focused on micron-sized particles. However, recent toxicological studies have shown that nanoparticles (particles with one dimension less than 100 nm) can have a magnified toxicity compared to the larger particles with the same chemistry [2]. Nanoparticles have a much higher specific surface area compared to the same mass of larger particles and are thus more reactive. Most micron-size particles can be cleared by the body’s defense mechanism. However, inhaled nanoparticles can easily deposit in all regions of the respiratory tract and can translocate to vital organs. [2].

Mar 2, 2022

By P. L. M. Wong, N. W. Johnson

Surface analysis by X-Ray Photoelectron Spectroscopy (XPS) of samples taken from the galena flotation section of the Hilton Concentrator of Mount Isa Mines Limited are presented. Flotation rate and pulp chemical data taken during the sampling period are also presented and discussed. Surface analysis suggested that, under normal operating conditions, an overlayer of precipitated calcium sulfate existed at the surface of the sulfide minerals. In particular, there was a decrease in the surface concentration of calcium sulfate for the concentrate samples relative to that occurring on the tailing samples. This suggests that the flotation process was selective against minerals which have calcium sulfate predominating at the surface. Heterocoagulation of hydrophilic calcium sulfate on to the galena surface considerably reduced galena flotation rate. Methods to control calcium sulfate precipitation, which include sodium carbonate treatment of the pulp, are also discussed. Sur- face analysis results of samples taken from the Hilton Concentrator during sodium carbonate addition to the grinding circuit are also presented. This shows clear evidence for the removal of calcium sulfate from the mineral surfaces without concomitant surface precipitation of calcium carbonate. Reasons for the apparent dispersion of precipitated calcium carbonate are discussed. Galena flotation rate was increased by the addition of sodium carbonate apparently due to the removal of interfering calcium sulfate.

Jan 1, 1995

By R. D. Hamilton, W. J. Miles

In 1987, the International Agency for Research on Cancer designated crystalline silica as a 2A probable carcinogen. As a result, crystalline silica is regulated under the Hazard Communication Standard as a probable carcinogen at a concentration of 0.1% or greater in the workplace. Crystalline silica will be listed as "reasonably anticipated to be a carcinogen" by the National Toxicological Program. This designation of crystalline silica as a probable carcinogen has created major issues for the mineral and chemical producer, including labeling, hazard communications, marketing a material with potential hazard exposure, and potential liability. The State of California also regulates crystalline silica under Proposition 65 in products as a carcinogen, based upon the IARC determination that it is a probable carcinogen. More federal and state regulations are anticipated as a result of the IARC classification of crystalline silica and its subsequent federal regulation. Respirable crystalline silica has been regulated as a hazardous dust for many years by OSHA. This regulation was initiated to prevent silicosis, another occupational disease. OSHA has established monitoring devices for determining the concentration of airborne respirable silica in order to measure exposure to this substance. The accurate determination of the crystalline silica content is critical to dealing with these health risks and regulations. In the past, crystalline silica was considered to be safe and, because of its ubiquitous nature, little effort was made to determine or quantify its presence in most materials. The Hazard Communication Standard requires that a1l products containing 0.1% or greater crystalline silica must be properly labeled for this material and its hazard. Unfortunately, the 0.1% threshold was not chosen on the basis of established analytical capabilities for crystalline silica, but results from general limits for potentially carcinogenic chemicals and substances. Numerous methods have been developed for the determination of crystalline silica in a variety of products. However, these methods are not generally applicable since they must be specific for silica in any of its crystalline states and not just for total silica content. Chemical tests for silica are not difficult and quite accurate at the 0.1% level; however, in addition to its crystalline phases, it occurs in amorphous phases and in a wide variety of crystalline and amorphous silicates. In general, there is little correlation between total silica content and crystalline silica.

Jan 1, 1991

By J. A. Herbst, C Lo. Y, Z. Rogovin

The identification and quantification of incipient overload conditions in mills have recently been found to be very significant in the design of tumbling grinding mills. To investigate these phenomena, a series of experiments was conducted in a Plexiglas mill operated in both dry and wet modes. For on-stream measurement of the mill charge weight, volumetric filling, dynamic angle of repose, and mill power, an electronic system was developed. The mill was filled to various levels with 19.1-mm (3/4-in.) ceramic balls as grinding media. As feed material, grindable limestone or 3.2-mm (1/8-in.) nongrinding ceramic balls were fed at various steady-state rates to determine the incipient overload conditions. The prediction of overload has apparently been reduced to predicting the feed rate that results in 50% mill filling.

Jan 1, 1988

By Stephen L. Chryssoulis

The detection and quantification of invisible gold by microbeam techniques is discussed. Ion probe microanalysis is used to quantify the gold content of individual sulphide, sulpharsenide and oxide particles with a detection limit of 0.2 ppmw (g/t). The proton microprobe is used to determine the gold concentration of gangue minerals with a detection limit of 2 - 4 ppm. Using these techniques complete mineralogical balances for gold are obtained to assist in the process selection and optimization. A total of twenty gold and gold-bearing ores have been examined. Selected examples are presented.

Jan 1, 1990

By D. Butler

Subsurface density changes can be detected by very precise surface gravity measurements. A feasibility study, combined with field experience using modern instruments, will indicate the probability of success. In addition to projected anomaly parameters, surface conditions that effect the survey precision must be evaluated. Examples with excavated zones at 9 m (30 ft) of depth and [+] 22 microgal error are compared to the same model at 30 m (98 ft) of depth. The figures illustrate anomaly detectability. The survey error is a function of surface topography and lateral density variation in the very near surface.

Jan 1, 1990

By D. Butler

Lateral density changes in the subsurface cause a change in the vertical pull of gravity at the surface. By very accurate measurement of gravity and the practical application of common sense, a microgravity survey can sometimes detect natural or man-made voids, bedrock profiles, and geologic structures of engineering interest. This paper will give some practical guidelines for the application of microgravity surveying. Emphasis in many papers (Blizkovsky, 1979, Fajklewicz, 1983) has been on the anomaly size: herein emphasis will be placed on detectability and signal-to-noise ratios. First, some easy to use curves for anomaly valuation are adapted from Arzi (1974). Secondly, the predictable noise sources are discussed. Thirdly, representative models of abandoned underground workings are evaluated for microgravity surveying given the probable noise in the survey results.

Jan 1, 1988

By Duk-Won Park

Since geologic anomalies are one of the governing factors of instability of underground openings, it is extremely important to know in advance the locations and extent of these anomalies such as faults and weak zones. At an underground coal mine in the Black Warrior Basin, core drilling was conducted to find a fault in an area where they were planning to locate longwall panels and possibly a shaft. Core logging did not provide sufficient information to delineate the exact location, strike, and dip of the fault. However, a high resolution reflection seismic study successfully solved this problem. This experience proved the seismic exploration technique could be used for premining coal exploration by reducing drilling costs and providing more accurate and detailed information about geologic anomalies.

Jan 1, 1988

By Joseph L. Condon

The U.S. Department of the Interior, Bureau of Mines, is doing research on methods to obtain premining information on problems such as detection of old mine workings, abandoned oil wells, channel sands, faults, and other geologic features that are undesirable from a production or safety aspect. Techniques being developed to acquire the necessary information include seismic and electromagnetic. The seismic methods include high-resolution seismic and acoustic methods applied from the surface and inseam channel waves applied under- ground. The electromagnetic, or radar, methods are applied from the surface, from boreholes, and from the working face underground. All of these methods are useful under certain site-specific conditions, but none of these methods is universally applicable for all mining conditions.

Jan 1, 1980

By R. J. Gray

Oxidation of coal can best be described as a process of deterioration, since most of the uses of coal, such as for fuel and by-product chemical and coke production, are adversely affected by coal oxidation, and the inclusion of oxidized coal in most coal products detracts from their value. There are probably many mechanisms of coal oxidation, and the ways oxygen molecules combine as complexes with coal macromolecules to form new substances have been dealt with and speculated upon by many workers1)* but are not dealt with in the present work. This study deals with tests and methods of detecting oxidized coal, with particular emphasis on the microscopically discernible changes that accompany the chemical and physical changes that affect the technological properties of coal during oxidation.

Jan 1, 1974