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By J. B. Moritz

From the beginning, man has concerned himself with the task of controlling the elements and forces about him so as to provide a better and easier life. In the accomplishment of this task, he is required to utilize in the best way possible the resources which are available to him. In many cases, the available resources must bee refined before they are in a useable form. Many products in the mining industry fall into this category, as some form of refinement is generally needed to produce a saleable product. Over the years man developed more efficient ways of extracting the resources from earth through the use of electrical and mechanical devices. A reduction in manual labor, which is a by-product of increased efficiency through machines, has also been enjoyed. The combination of man's senses and new devices has also enabled man to reach a high level of control in the refinement process. Control of a process through machinery and man's senses has been termed an "art." Until recently man's senses (sight, feel) were the only method available for making measurements simply because suitable measurement devices (instruments) were not available. Even today some items cannot be measured and man's senses must be used. However, the development in our instrument laboratories tends to indicate that time will eliminate this. In recent years, control of many processes has been reduced to a science and part or all of the art eliminated. This does not imply that process art should be degraded; however, when a process is reduced to a science, uniformity of the product from day to day is attained. Decreased processing time and more efficient use of additives and raw materials are other benefits that result from control of a process when it is reduced to a science.

Jan 1, 1965

By L. B. Phelps

The nation is confronted with thousands of acres of abandoned coal lands. In Pennsylvania alone, these lands have been estimated to cost $15 billion to reclaim (Pennsylvania Bulletin, 1985). One way to deal with this problem is to provide a mechanism by which the active mining industry can undertake to remine certain of these abandoned mine areas. Remining is classified as reaffecting previously mined areas in order td extract the remaining coal reserves while improving the environmental quality of these lands through land restogation and abatement of pollutional discharges. However, there currently is a disincentive for operators to plan to extract reserves on these abandoned mine lands which have preexisting pollutional discharges. Therefore, they presently avoid them. This is because of the "potentially unlimited liability of post- mining treatment for any discharges that would remain after mining? (Pennsylvania Bulletin, 1985).

Jan 1, 1987

By M. R. Peterson

The U.S. Bureau of Mines has investigated new methods for increasing the selectivity in flotation by creating and regulating reagent concentration gradients within flotation columns at steady-state operation. Gradients were generated and traced in a water-only system with the use of fluorescent dyes, and the effects of various operating parameters on these gradients were investigated. From this investigation, it was found that both gradual and steep gradients could be generated in the froth cleaning zone, and that these gradients could be changed through the manipulation of both physical and chemical operating parameters. The application of reagent-gradient control to mineral systems could improve both flotation grade and recovery in commercial flotation operations without the use of additional flotation circuitry.

Jan 1, 1992

By C. E. Jordan

The Bureau of Mines has investigated the fundamentals of fatty acid/fuel oil conditioning for improved flotation selectivity. Both conditioning time and intensity can provide optimum flotation selectivity as well as good recovery. Traditional conditioning seeks to optimize conditioning parameters with subsequent recovery of the hydrophobic mineral. In the fatty acid/fuel oil system many silica gangue particles are also rendered hydrophobic by the flotation collector. Fundamental studies have shown that particle-particle collisions transfer the collector reagents selectively to the mineral surfaces with the highest affinity for the reagent. This mechanism deactivates the gangue particles while increasing the collector reagent loading on the selected mineral. The degree of this transformation is directly related to the number of particle-particle collisions which can be controlled through conditioning time or conditioning mixing intensity.

Jan 1, 1995

By M. J. Virnig, G. A. Kordosky

Throughout time, the mining industry has been very successful in meeting the world's requirements for metals and materials while meeting the challenges of decreasing ore grades and increased emphasis on protection of the environment. This success has been due to the development and implementation of new technologies. A clear example of such a development over the past 25 years is the increasing use of leaching/solvent extraction/electrowinning for the recovery of copper from oxide and sulfide ores. The key to the successful introduction of this technology was the discovery and development of the hydroxyoxime liquid ion exchange reagents by General Mills Chemicals (now Henkel Corporation). An important role was also played by the close working relationships between General Mills Chemicals and Ranchers Exploration which resulted in startup of the first plant in 1968 and between General Mills Chemicals and Bagdad Copper which resulted in the startup of the second copper SX-EW plant in August of 1970. Following on the heels of the hydroxyoxime development came the commercialization of other new chelating reagents based on different chemical functionalities, i.e., beta-diketones, alkylated 8- hydroxyquinolines and sulfonamidoquinolines. This initial spurt of activity was then followed by a slowing of development in terms of new reagent functionalities. Activity has continued in terms of further optimization/improvement of existing reagent functionalities but the commercialization of new reagent functionalities has slackened. This observation reflects the fact that the development of new reagent functionalities for metal recovery has become increasingly more expensive such that the right combination of price and sales volume must exist in order to justify the investment required to bring a new reagent to the market place. Given the dependence of the mining industry on innovation to meet the needs of the future, one can ask how these new developments, particularly in new reagents, will occur. To arrive at an estimate of the costs involved in commercializing a new metal extractant functionality, particularly a chelating type functionality, a case study of the development of LIX ®* 34

Jan 1, 1994

By Deepak Malhotra

Following a severe recession in the early 1980's, mining companies have taken significant steps to improve metallurgy and reduce operating costs. They do not view chemical reagents and the long-term relationship with reagent producers the same way they did two decades ago. This paper discusses the general perspective of changes that have taken place over the years, especially with respect to cost of production, selling price and environmental constraints. A cooperative program between the consumers and producers of chemical reagents is recommended to understand each other's problems and identify the present and future needs of the mining industry. This approach will be beneficial to the long-term survival of both parties.

Jan 1, 1994

By William F. Riggs

In the fresh application of a frother, collector, or the change of any particular reagent, the interaction caused by this change is often overlooked since we attempt to solve a problem or improve a situation with use of a particular reagent without regard for the Interactions or side effects. When a particular reagent is added to a flotation circuit or substituted for another reagent, a series of chemical reactions occurs which. In turn, will create different physical responses. This discussion will provide a series of examples which have actually been experienced by the author.

Jan 1, 1994

By J. J. Harrington

Manufacture and mixing of flotation reagents at the mill site provides an economic and convenient method of maintaining a continuous and fresh supply of reagents for concentrator operations. Kennecott Copper Corporation has designed and built a Reagent Mixing Facility which incorporates new ideas in construction and fail-safe operation at its Nevada Mines Division concentrator. Highly sophisticated automation and instrumentation techniques are combined with safety procedures and equipment that meet and exceed all Federal and State safety requirements. Installation of the facility has minimized hazardous working conditions for the operator, isolated reagent preparation from production personnel and equipment, and reduced the time required for reagent preparation from three shifts to one shift per day.

Jan 1, 1976

By Charles U. Keranen

The Tilden Mine is an iron ore mining, processing and pelletizing facility located on the Marquette Iron Range in Michigan's Upper Peninsula. It has a designed capacity to produce 8 million long tons of pellets annually from 21 million long tons of crude. It is a partnership owned by The Cleveland-Cliffs Iron Company, Algoma Steel Corporation, LTV Steel Corporation, the Steel Company of Canada, Wheeling Pitts- burgh Steel Corporation and the Sharon Steel Corporation. Cleveland- Cliffs manages and operates the Tilden. The crude ore averages 35% iron and is primarily non-magnetic iron oxide and silica. The major ore mineral is martite. Hematite, earthy hematite, goethite and magnetite are also present. The principal gangue mineral is chert. The ore grains are mostly in the 10 to 25 micron size range which necessitates very fine grinding for liberation. The concentrating process is the most complex one used in the iron ore industry. The unique technology for Tilden was developed in the mid and late 60's. The design and construction occurred in the early 70's and operation of the first phase which was of 4 MLTPY capacity began in October. 1974. Expansion of the facility to the current 8 MLTPY capacity was completed in 1979. Chemicals are the key to the beneficiation process at the Tilden Mine. The flowsheet utilizes selective flocculation - desliming, cationic silica flotation and concentrate dewatering by thickening and filtering. Nine different process chemcals are used. The control of the reagent feed systems is highly auto- mated. The entire concentrator is operated from a central control room. The concentrator flow diagram is presented in figure 1. The plant consists of 12 primary autogenous grinding lines, a common crushing circuit to handle an intermediate product within the primary grinding section, 24 pebble mill lines with cyclones and deslime thickeners, 12 flotation lines, 4 concentrate thickeners and slurry tanks, 8 lines of filters with six machines per line, and 2 tailings thickeners. A pumping system was installed in 1980 to permit the direct return of tailings thickener overflow water back to the reuse water pumphouse.

Jan 1, 1986

By J. M. Keating, R. L. Wiegel

Those processing plants which depend on flotation for their mineral separations are always looking for reagents which are cheaper, more selective or in some other way may provide improved economic performance. This paper describes the rationale for and some results from applying a statistically based approach to reagent testing in those flotation plants which still rely on experienced operators for manual flotation control.

Jan 1, 1986

By Harold E. Goetzman, Blair R. Benner

The U.S. iron ore industry is located primarily in Northern Minnesota and Michigan's Upper Peninsula with one additional small plant in Missouri. There are currently some 10 plants operating that produce about 48 million tons per year of pellets. The major reagent use occurs in the three general areas of: flocculation, flotation and pellet additives. Minor areas of usage are for corrosion inhibition and dust suppression. Current practice as to types of reagents, consumption, and method of application are reviewed. The interaction of reagents with other parts of the process are discussed. Also included is a discussion of future reagent needs.

Jan 1, 1994

By Pradip

The development of highly selective mineral processing reagents, which are not merely metal-ion specific, but specific to the particular mineral surface structure, is essential for the exploitation of relatively more difficult-to-process ore deposits, in particular for the separation amongst minerals having the same constituent ion. Both the choice of the functional group as well as the molecular architecture of the reagent determine its selectivity. Several examples are presented in this paper to illustrate the concepts of structure specificity and molecular recognition at mineral surfaces - the concepts crucial to the advancement of the emerging science of reagents design. Recent advances made in the understanding of molecular interactions involved in the synthesis of biomineralized materials are discussed so as to delineate the utility of this approach in the design of selective reagents for mineral separation.

Jan 1, 1994

By F. F. Aplan

Rather than reiterate what is well known about the flotation of the non-sulfide minerals, emphasis has been placed on those separations which are not so effective. These difficult separations are largely connected with problems of selectivity in the flotation of the base metal oxides, the other slightly soluble minerals, the insoluble oxides and the naturally floatable minerals. The paper discusses possible methods of improving selectivity between similar species and of improving selectivity against the gangue minerals.

Jan 1, 1994

By Richard R. Klimpel

INTRODUCTION The purpose of this paper is to summarize the current status of reagents used in the mineral industry plus present some current challenges and possible new technologies of the future. Table 1 lists the important families of reagents which, when taken together, constitute at least 95% of the current commercial reagent market. A very approximate estimate of the free world reagent market size in mineral applications is about 1.5 to 2.0 billion dollars (U.S.) using 1985 data. Obviously, to serve such a large market requires the effort of many different types of commercial supply sources. It is estimated that there are over 300 industrial firms in the free world that have a dedicated business/technical structure for supplying reagents related to the mining industry. There are a number of characteristics which are associated with the product families listed in Table 1. Understanding these characteristics helps to provide a realistic economic/technical basis for outlining future challenges in mining chemicals. 1.Essentially all of the products listed are old chemistry in the sense that the molecules have been known and manufactured for at least 25 years. This has not been a highly dynamic field of endeavor from the viewpoint of new product introduction. 2. The greater majority of the products listed can be viewed in commercial terms as "commodity" chemicals, that is, they are available from many sources and the pricing of a some- what generic product generally dominates differences in product quality or uniqueness. With commodity pricing, reagent suppliers significantly reduce research expenditures, loosen product quality somewhat if the applications of the reagents allow, etc. in order to be cost competitive.

Jan 1, 1989

By Yelloji M. K. Rao, P. Somasundaran

Reagents of biological origin are becoming more and more important in the field of metallurgy, especially in the areas of mineral processing and hydrometallurgy. The advantage of lower operating cost over physical and chemical processes and the capacity to operate with low grade ores make the microbial processes further attractive. In this paper, the role of microbes directly as a reagent and microbially produced reagents or secreted metabolites in mineral processing and hydrometallurgy will be discussed. Adhesion of microbes to surfaces is known to alter the hydrophobicity of minerals. Applications include surface modification to impart hydrophobicity or hydrophilicity on sulfide or non-sulfide minerals and dissolution of precious metals. Microbes can also perform the role of flocculating agents. Biosorption of toxic and heavy metal ions by microbes are finding application in treating tailing ponds. Mechanisms associated with the use for microbially produced reagents are discussed along with some recent results.

Jan 1, 1994

By B. J. Arnold, F. F. Aplan, S. Chander

There is a broad range of chemical reagents of potential use to the coal preparation industry: flotation frothers, flotation collectors (for coal, ash minerals or pyrite) and collector-assisting (conditioning) agents, flotation depressants (for coal, ash minerals or pyrite), pH regulating agents, acid mine drainage treatment chemicals, flocculants, filtration aids, dispersants, dust suppressants (wetting agents and car-top or pile binders), freeze conditioning agents, water treatment chemicals (corrosion and scale inhibitors) and suspension stabilizing reagents (dispersants, stabilizers, biocides). The application of each of these types is discussed with particular attention paid to those of greatest importance: flotation frothers and collectors, pH regulators and acid mine drainage treatment chemicals, flocculants and freeze conditioning agents.

Jan 1, 1986

By R. Hogg, E. Kaya, H. Cho

Investigations were performed on fine grinding of bituminous coal in a laboratory-scale pulverizer. The results indicated that the breakage behavior at relatively coarse sizes (i.e., greater than about 20 µm) is essentially "normal." However, at fine sizes (i.e., less than about 10 m), there is clear evidence of reagglomeration. A simplified population-balance model for simultaneous growth and breakage is formulated. Breakage rates and breakage distributions were assumed to follow the patterns typically observed in simple grinding systems. It is recognized, however, that solid particles and agglomerates may exhibit different breakage behaviors. Agglomeration rates are assumed to be determined by contact probability, i.e., by the relative numbers of interacting particles. Based on comparisons between model simulations and experimental data, it appears that agglomerate rebreakage rates and fragment size distributions are quite different from those for solid particles. The result is that product size passes through a minimum and then increases with time as agglomeration begins to dominate.

Jan 1, 1998

By E. Kaya

Investigations of fine grinding of bituminous coal in a laboratory-scale pulverizer are described. The results indicate essentially "normal" breakage behavior at relatively coarse sizes (greater than about 20 µm) but show clear evidence for re-agglomeration in the fine size range (less than about 10 µm). A simplified population balance model for simultaneous growth and breakage has been formulated. Breakage rates and breakage distributions are assumed to follow the patterns typically observed in simple grinding systems. It is recognized, however, that solid particles and agglomerates may exhibit different breakage behavior. Agglomeration rates are assumed to be determined by contact probability, i.e. by the relative numbers of interacting particles. Based on comparisons of model simulations and experimental data, it appears that agglomerate re-breakage rates and fragment size distributions are quite different from those for solid particles. The result is that product size passes through a minimum and then increases with time as agglomeration begins to dominate.

Jan 1, 1996

By Ehsan Alavi, Sanjeer Yogendran, Savreet Singh

The Don River & Central Waterfront Coxwell Sanitary Bypass Tunnel Project in Toronto extends approximately 10.5 km from Ashbridges Bay Treatment Plant west under Lake Shore Boulevard, north under Bayview Avenue and east through the Don River park area to the Coxwell Ravine Park. This project includes the installation of five intake shafts connected by 10.5 km of 6.3 m internal diameter tunnel and eleven drop shafts and vent shafts, connected to the tunnel by a series of adits. During the excavation of one of five intake shafts (20 m in diameter and 52 m deep), significant volumes of free phase oil and hydrocarbons were encountered. Due to the heavy inflows of the contaminants, excavation was stopped at the transition depth. The initial support of excavation needed to be redesigned, shaft had to be backfilled with CDF and installation of deeper secant piles are in progress to cut off contaminants. This paper outlines the initial plan for excavation as well as the design changes to the plan. The current status of the shaft excavation and lessons learned will be discussed.

Jun 13, 2021

By Alan E. Isaacson

Extensive gravel deposits exist within a six-county area in the mountains surrounding the Salt Lake Valley, and in the mountain ranges to the west. The six-county area includes Davis, Salt Lake, Summit, Tooele, Utah, and Wasatch Counties. The majority of these are beach deposits from prehistoric Lake Bonneville. However, real estate development associated with a projected population increase of 54 percent over the next 20 years is expected to remove most gravel deposits in Salt Lake County from consideration for mining, forcing gravel operations to relocate from eastern Salt Lake Valley to the Oquirrh and Stansbury Mountains farther west. The gravels in these ranges are of lower quality and require additional processing to manufacture asphalt and concrete. Replacing gravel resources along the Wasatch Front with resources in the Oquirrh and Stansbury Mountains over the next 20 years has the potential to increase construction costs by nearly $1 billion. The majority of this cost (82 percent) is the result of increased transportation costs due to longer distances to market. The remainder of the cost is attributable to lower quality gravels that will require additional processing in the manufacture of asphalt and concrete. The following analysis and discussion does not take into consideration the amount of crushed stone that is currently being used in the construction industry in northern Utah, its use as a substitute for lower quality gravels, or as a factor in the base case projection.

Jan 1, 2001