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By A. D. Hammond

Vanadium is a transition metal, ductile, silver-gray metal. It is harder than most metals and steels and it has a good resistance to corrosion, it is stable against alkalis, sulfuric and hydrochloric acids. Vanadium is oxidized in air about 660 °C, although an oxide layer forms even at room temperature. The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2-5. In aqueous solution the colors are lilac V2+, green V3+, blue VO2+ and, at high pH, yellow VO42-. Considered to be as abundant as zinc, metallic vanadium is not found in nature, but it is known to exist in about 65 different minerals. Economically significant examples include patronite (VS4), vanadinite (Pb5(VO4)3Cl), associated to the uranium mineral carnotite (K2(UO2)2(VO4)2?3H2O) and in a vanadium mica called, roscoelite K(V3+,Al,Mg)[(Si,Al)4O10](OH)2. Other important vanadium ore oxides are montroseite (V,Fe)O(OH) and corvusite (Na,Ca,K)V8O2.4H2O. Much of the world's vanadium mine production comes from magnetite-hosted deposit and to a lesser extent, in sedimentary-hosted sandstone. Vanadium is also present in bauxite and in fossil fuel deposits such as crude oil, coal, oil shale and tar sands. In crude oil, concentrations up to 1,200 ppm have been reported. A significant vanadium production comes from the processing of petroleum residues, fly ash and recycling spent catalysts. In 2011, metallurgical applications accounted for 93% of the use of vanadium. Here, an alloy called ferrovanadium is utilized to strengthen steel to be used as rebar in the construction industry, in the manufacturing of axles, crankshafts, gears and chassis in the automotive and transportation industries and in the manufacturing of high-speed tools. In the aerospace industry, vanadium is utilized as a titanium alloy in the manufacturing of airframes and jet engines. The reason for the wide use of vanadium as alloy is its high strength-to-weight ratio, the highest of any engineered material on earth. The major non-metallurgical use of vanadium is in the production of catalysts for the chemical industry. The most commercially important compound is vanadium pentoxide (V2O5), which is used as catalyst in the production of sulfuric acid.

Feb 23, 2014

By D. Bhattacharyya

The adsorption and desorption of gold cyanide by activated carbon is significantly influenced by particle size of the activated carbon particles and the chemical environment. A series of adsorption and elution experiments have been performed with ten different particle size fractions. The tests indicate that although the ultimate adsorption capacity is independent of the activated carbon particle size, the adsorption rate is strongly affected by the particle size. Further, desorption characteristics using traditional Mintek and atmospheric Zadra procedures reveal interesting trends with variation in particle size and will be discussed in this paper.

Feb 23, 2014

By A. Iannacchione

Most legacy drift mines entered the coal reserve from outcrop and developed up-dip. The Surface Mining Control and Reclamation Act of 1977 changed this way of mining, requiring all new mines with acid- or iron-producing coal seams to be designed so as to prevent gravity water discharges from the mine. This Act requires engineered barriers to contain the mine pool. In many cases, mine layout designs focus primarily on the size and hydraulic performance of the un-mined coal barrier between the up-dip mine pool and areas where down-dip surface discharge is possible. In other cases, designs focus on preventing discharges from barriers contained within the strata surrounding the mined coalbed. This paper focuses on a detailed analysis of the factors responsible for preventing mine pool discharges to surface waters. Important factors include: mine layouts, mining methods, hydraulic head and conductivity, and geology. While the exact causes for the successes and failures could not always be determined, reasonable mechanisms are presented.

Feb 23, 2014

This paper examines the feasibility of combining network modeling and computational fluid dynamics for modeling of underground mine ventilation systems. Both simulation methods have specific advantages and disadvantages for analysis of mine systems. Network modeling is widely utilized by many operations and allows for assessment of current systems and simulation for planning purposes. Alternatively, CFD has been utilized only marginally by operations and is typically a research tool, requiring considerable computational power, complex models, and careful analysis and calibration of results. Network modeling allows for a holistic approach to the ventilation system, giving quantity, velocity and pressure in every branch, but CFD modeling can resolve the flow regime in 2-D or 3-D, which is idea when examination of an area on a more detailed basis is useful, such as dust and gas control. Integration of the two can allow for more flexible systems analysis. The feasibility of integration, along with application to limited underground mine data are examined.

Feb 23, 2014

By V. Králová

The TESCAN Integrated Mineral Analyzer (TIMA), an automated mineralogy system, enables fast and quantitative mineral analyses of rocks, ores, concentrates, tailings, leach residues or smelter products. It combines BSE and EDX analysis for identification and measurement of mineral concentrations, particle size distribution, and liberation/locking parameters. In addition, it can provide bright particle searches for PGM, gold-silver ores, and/or REE. With the newly developed Automated Loading System (AutoLoader), the TIMA has become the world?s first automated mineral analyzer which permits robust, continuous and unattended sample loading. With the AutoLoader (robotics) system, the TIMA has emerged as a powerful plant support instrument. It increases the sample throughput, minimizes manual labor and enables 24/7 operations. As such, it can be used in daily, continuous mineralogy for mine geology/ore control, concentrators, leach operations, and smelter support. It will also increase the capabilities of technical service centers for mining companies, commercial laboratories, large drilling programs or pilot test campaigns. In combination with a highly automated sample preparation lab (sizing, potting and polishing), TIMA technology can establish high-throughput and fast-turnaround automated mineralogy lab modules for mine-site production support.

Feb 23, 2014

Due to the ongoing restructuring of the mining industry in central Europe with a continuous decline of the number of large underground mines and collieries, and a simultaneous decline of staff numbers in the remaining mines, the established mine rescue schemes are endangered to collapse. With the end of the mine rehabilitation at Wismut Uranium in 2014, the last remaining major mine rescue teams in Saxony, providing basic mine rescue services for all other mines in the region, will disappear. This will leave a large number of small mines and other underground operations without capable mine rescue support. Since none of these companies is able to set up a complete mines rescue unit on its own, new ways have to be found. Among others, a central mine rescue team for central Germany as well as the assistance by special trained professional fire fighters or mine rescue teams from abroad are discussed. Problems like location of the central rescue team, financing, communication and transport have to be solved. This paper provides an overview over the complexity of the problem as an example for other mining regions worldwide and will discuss national and cross-national strategies.

Feb 23, 2014

Australian underground coal mines predominately use the longwall method for coal extraction. In longwall mining at least two parallel roadways known as gateroads are mined to delineate the sides of the longwall block, a longwall installation face is then driven connecting the gateroads to enable the longwall mining equipment to be installed. Roadway development should ideally be ahead of the longwall so that the longwall equipment can be installed into the newly developed panel with minimal delay to coal production. A discrete event model of roadway development can help assess how a particular configuration may perform with high levels of variability and uncertainty in operations. One of the major delays associated with roadway development is caused by the shuttle car due to its cyclic stop-start nature. Shuttle car travelling paths and machine interactions are normally constraint by the mine?s roadway layout and mine safety issues. This paper presents simulations of shuttle car route options which can be considered at the design stage to minimize the cycle time of a shuttle car as part of a general roadway development simulation model developed using 3D Flexsim.

Feb 23, 2014

By R. J. Sheets

In 2009 the Gold Quarry open pit mine, located 11 km northwest of Carlin, Nevada, USA, experienced multiple large-scale slope instabilities of the upper east highwall that reduced gold ore extraction for nearly 18 months. The slope instabilities occurred within a weak, consolidated sedimentary sequence that exhibits strength characteristics that are transitional between soil and rock. Instability initiated as mining exposed the lower clay-rich sub-units of the Carlin Formation (Fm.). This deformation created preferential flow paths that allowed groundwater from the upper sandy sub-units to infiltrate low permeability clay-rich sub-units, thereby enhancing deformation of the slope toe which in turn destabilized the upper portion of the highwall. The outcome was a 160 m high slope instability that had a lateral run-out of 850 m. The effort to return the pit to ore production required both the geotechnical and hydrogeological investigations and the preliminary remediation mining activity to be concurrent. This approach required the development of detailed safety procedures and a requirement to modify the remediation design as new results were obtained. An initial challenge was to mitigate a near vertical, 90 m headscarp with blast induced, localized slope failures. Back-analyses applying numerical modeling indicated that the failure surface did not coincide with initial interpretations based on field observations; drilling results eventually confirmed this alternative failure geometry. The final remediation design incorporated shallower slope geometries and an approximately 3 Mt buttress along the base of the Carlin Formation and bedrock contact to reinforce the lower clay-rich sub-units. The outcome is a stable highwall within the Carlin Fm. following nearly ten years of repeated slope instability, and an example of the necessity to conduct appropriate geotechnical and hydrogeological studies during the early stages of a new layback evaluation or new open pit development.

Feb 23, 2014

By J. Snowberger III

Rhenium is a valuable and extremely rare chemical element with unique chemical properties. It is extracted commercially as a byproduct from the processing of molybdenite associated with porphyry copper ores. There is a present interest in recovering rhenium from copper pregnant leach solutions (PLS) produced by copper heap and stockpile leaching. These solutions contain rhenium at very dilute concentrations, typically in the 1 mg/L concentration range. This paper describes laboratory column ion exchange experiments to extract rhenium from these solutions using weakly basic anion exchange resins and actual plant PLS from two operating mines. The dynamic loading and elution behavior of Re on Purolite® A170 and A172 is discussed.

Feb 23, 2014

By M. Nambiar

Due to the remote locations of the mining projects and the demand for long transmission lines to provide electrical power, mining sites often operate with poor network power quality and low short circuit capacity. In order to cope up with this situation, more and more mining projects are considering the installation of appropriately designed Synchronous Condensers(SC) together with Power Factor Correction and Harmonic Filter System(PFC&HFS). The installation of these power quality equipments is viewed as a technological advancement in the mining application. An adequate level of short circuit power is essential and has to be ensured for the safe and reliable operation of especially large cycloconverter driven gearless mill drive systems used for grinding application. Increase in plant short circuit power is generally achieved by lowering the impedance of the supplying network. The SC also provides smooth voltage control during mill starting or major load trips, thereby regulating the plant voltage within the required limits. This paper will explore the impact, technical advantage and reasoning for the selection of the advanced hybrid technology mentioned above, in order to cope with the power system challenges for future mining projects. It also highlights the potential problems and how to address them carefully.

Feb 23, 2014

By S. Hamm

Elevated total dissolved solids (TDS) content in waters downstream from surface coal mines in Central Appalachia is an increasing concern, as unnaturally high TDS and/or associated specific conductivity (SC) may contribute to deteriorated stream ecosystem health. The aim of this preliminary study was to explore the efficacy of accelerated leaching as a means of minimizing long-term TDS/SC generation by problematic overburden materials. Five spoil samples were collected and leached using simulated rainwater solutions under ambient and acidified pH conditions. SC and pH were monitored during each leach cycle, and ICP-MS was used to determine how leaching conditions affected release of specific ions. This paper highlights the results of both jar and column leaching tests. Among the most significant findings was that, for certain spoil materials, SC in leach column effluent was effectively reduced when spoil was leached first with acidic rainwater followed by ambient rainwater (vs. ambient rainwater leaching alone). This suggests that accelerated leaching might aid in long-term stabilization of some materials.

Feb 23, 2014

By D. Seneviratne

Iron transfer from the pregnant leach solution (PLS) to the electrolyte can have a major economic impact on solvent extraction (SX) operations. High iron transfer will lead to greater operational costs, due to increased reagent consumption through electrolyte bleed and make up, or increased power costs due to decreased electrowinning current efficiency. Bioleaching of low-grade copper sulfide ore from the Kennecott Utah Copper Mine was investigated in a large scale piloting program including SX and electrowinning. Plant data and lab test work conducted throughout the course of operation, show that the unique containing PLS high ferric iron with high pH can lead to lower Cu: Fe selectivity than is typically seen in traditional copper SX operations. The impact of high ferric iron on the plant operation, and methods to reduce iron transfer will be discussed. Special considerations need to be taken for plant operating conditions and selection of SX reagents (including both extractant and aromatic content of diluent) based on the feed PLS characteristics.

Feb 23, 2014

By E. Tarshizi

This research project demonstrates the application of a mine system simulation and animation model in enhancing the efficiency of a truck-shovel operation and reducing the haulage environmental impact in an open-cut coal mine. In any mine, a key objective is to have enough equipment for production and not have excess to where it is counterproductive. Due to the advent of responsible mining, environmental regulations, and eco-friendly practices, these factors must also be considered in the analysis. The over-trucked situation at a mine will be discussed, i.e. when the number of trucks exceeds the optimum number of trucks a mine should have for the most productive/profitable mining operation. When the system has an excess number of trucks, truck utilization is reduced which impacts mine operation, capital costs and the environment, through unnecessary truck purchase, energy use, air pollution etc. A hypothetical surface coal mine layout was used for the simulation model.

Feb 23, 2014

By I. Sanchez

The development of the recent generation of large mining projects in South America has been challenging in many ways, but especially in the management of water in all its aspects. As a result, a number of projects have experienced difficulties and in some cases significant delays due to a lack of a clear and approved definition of the supply, use and discharge of water from mining and processing sites. The development of the recent generation of large mining projects in South America has been challenging in many ways, but especially in the management of water in all its aspects. As a result, a number of projects have experienced difficulties and in some cases significant delays due to a lack of a clear and approved definition of the supply, use and discharge of water from mining and processing sites.

Feb 23, 2014

By C. St. J. Lowe

Weir Minerals ? Linatex has developed a new approach to the dewatering of fine solids, particularly mine and process plant tailings and wastes. The Weir process, patented in 2009, uses standard process equipment in a standard flow sheet, but applies this approach to materials previously thought to be too fine to be dewatered with this type of equipment. The process can be applied to a wide range of materials, making lower moisture products that can be re-used elsewhere or sent to disposal. It has already been tested successfully on a small scale in Australia on coal fines, zinc mine tailings, red mud, iron ore tails, and copper/gold tailings. The principal factors affecting the solids recovery have been established as: 1. The % solids in the slurry feed to the process ? a higher % solids provides a higher recovery. 2. The particle size of the feed solids ? coarser feeds provide higher recoveries. The key factors affecting the % solids in the dewatered product have been determined to be: 1. The particle size of the dewatered product - coarser materials produce a higher % solids in the dewatered product. 2. The height of the discharge weir on the dewatering screen - a higher discharge weir on the dewatering screen also yields a higher % solids. 3. The angle of the dewatering screen. Setting the screen horizontal increases the travel rate, reduces the bed depth and reduces the % solids in the dewatered product. Back-sloping the screen up to 5° reduces the travel rate and increases the % solids in product. Eight plants ranging in size from 3 t/h to 40 t/h have been sold to a range of customers in China, for coal and iron ore tailings treatment. Australia has one plant, a small unit rated at 30 t/h of sand fines, and has recently completed test work on iron ore tailings for a dewatering plant rated at 135 t/h. Additional tests are under way with clients around Australia, to demonstrate the capabilities of this process on specific applications and to provide confirmation that materials can be processed successfully, before moving on to larger scale tests or full size plants. The advantages of the Weir process include - lower moisture in products, uses proven equipment, lower capital and operating costs, lower maintenance costs, reduced power consumption, compact footprint, can be used in parallel or in series with existing equipment, modular design to facilitate redundancy or expansion, efficient water recovery and simpler water management, reduced cement in backfill mixes, smaller tailings disposal footprint, reduced earthworks requirements, much lower seepage losses, more stable tailings mass, progressive site rehabilitation, reduced impact on local wildlife, reduced risk of dam wall failure, and reduced environmental monitoring and compliance costs.

Feb 23, 2014

By E. Tarshizi

Research was conducted to develop a simulation and animation model for an aggregate (sand and gravel) mine operation. This model can assist the mine engineers to investigate and consider the various options of haulage systems which are critical for the mine operation productivity. Discrete-event system simulation studies can be used for the typical haulage issues that mining engineers are often faced with: using truck fleet haulage, conveyor belts, or a combination of both. The simulation has identified some strengths and weaknesses in the current loading and hauling fleet of the mine, and has resulted in some suggestions for improving the system. The simulation includes animation of the operation. Animation is needed to enhance the benefit of any mine simulation model. By combining the visual power of animation with a mine simulation, a complete picture of the mine system is obtained and displayed. The mine is modeled and animated using GPSS/H® and PROOF Professional®, both of which have shown great applicability in discrete mining simulation projects.

Feb 23, 2014

By L. K. Holder

The White King / Lucky Lass Superfund site consists of two former uranium mines in south-central Oregon. The remedy included consolidating two large mining overburden stockpiles that contained low levels of radioactivity and heavy metals by moving over 700,000 cubic yards of material and then capping the combined stockpile. An innovative armored cap design was used to minimize the stockpile footprint and thereby prevent disturbing existing wetlands. In addition, the stockpile was designed to merge into the surrounding topography. The remedy also included stream restoration and development of new wetlands. The stream was returned to its pre-mining channel, with the addition of hydraulic features to create new wetlands. The wetlands have greatly enhanced the ecological value of the remedy and the site.

Feb 23, 2014

By E. Farrokh

CSM and NTNU models are among the most commonly used models in TBM performance evaluation. Due to increasing application of TBM in different tunneling conditions, modification became necessary for these models. Sensitivity analyses on these two models indicate that both models are very sensitive to machine characteristics. Analyses performed on CSM database for cutter load and penetration rate prediction indicate while the r-square of the CSM model is reasonably high for the predicted cutterload, the r-square value for the penetration is low. In order to increase prediction capability of CSM model for penetration rate the model was reevaluated using non-dimensional analysis and the original database of Colorado school of mines. NTNU model is evaluated using Monte Carlo simulation and regression analysis. The results of analyses indicate that the majority of the variation of the penetration in NTNU model can be explained by only three parameters. This might indicate that the effects of other factors are overshadowed and it is worthy to reevaluate NTNU model using original database and more updated statistical methods to avoid overlapping of different parameters correlations.

Feb 23, 2014

By C. Bazin

The fundamental error associated to the sampling of heterogeneous ore particles is unavoidable and can only be minimized by an adequate selection of the sample mass and/or size reduction of the sample before division into sub samples for testing or assaying. The preparation of ore batches to carry out the mineral processing evaluation of an ore is a sampling process. The fundamental error associated with the division of the ore into batches is responsible for the differences in the composition of the batches. This paper attempts by various means to assess the reproducibility of the gold content of test batches prepared from a gold ore sample. The results of the investigation shows that for fine gold grain sizes the variability in the composition of the batches is less than that predicted by Gy?s formula and that the gold grain size is a strategic information in the assessment of the gold content variability of test batches.

Feb 23, 2014

Fundamental results obtained from research on the properties of the edge surfaces of kaolinite particles (~500 nm) are reported. Of particular significance was the development of the experimental protocol. Well-ordered kaolinite edge surfaces were prepared as an epoxy resin sandwich structure having layered kaolinite particles in the center of the epoxy resin sandwich. Images of the sectioned kaolinite edge surfaces were examined by atomic force microscopy (AFM), and the average thickness of kaolinite particles in this study was determined to be 38.3 nm ± 11.7 nm. Furthermore, the surface charge of the kaolinite edge surfaces was evaluated with a super sharp Si tip. The point of zero charge (PZC) of the kaolinite edge surface was determined to be below pH 4, in contrast to the traditional view that the edge surfaces of kaolinite particles may carry a positive charge at pH 4. This lower PZC of the kaolinite edge surface was attributed to the lack of isomorphous substitution in the silica tetrahedral layer when compared to the PZC for the muscovite edge surface. Our results are consistent with the particle aggregation and flotation behavior of kaolinite, and should provide the basis for improved flotation strategies leading to the efficient recovery and utilization of mineral and energy resources.

Feb 23, 2014