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By K. Vanbroekhoven

An industrial site near the centre of a historical town in Flanders is characterized by chromium(VI) contamination of the groundwater. Since the potential for natural attenuation was not sufficient to control the groundwater plume as observed from different analyses like pH, Eh, soil oxidation and reduction capacity, the feasibility of site remediation based on in-situ bioprecipitation of chromium was examined in lab microcosm studies. By creating reducing conditions by addition of a carbon source in the groundwater, chromium(VI) can be biologically reduced to chromium(III), which can form an insoluble precipitate of chromium(III) hydroxide. Microcosms contained contaminated groundwater and aquifer samples that were collected and manipulated under anaerobic conditions. Three different carbon sources were screened for their effectiveness: molasses from sugar beet production, molasses form starch production (protamylasses) based on potato juice and lactate. The different concentrations of sugar molasses were used to determine the optimal conditions. A range of parameters was monitored at regular time intervals for a period of six months such as chromium(VI) and chromium(III), DOC, methane, pH, Eh. A rapid conversion of chromium(VI) to chromium(III) was observed for all conditions tested. However, extensive removal of chromium from the groundwater by precipitation was only achieved for a limited number of conditions. In general, lactate was found to be the most effective carbon source, slightly better than the lowest concentration of sugar molasses that was tested, which itself was more effective than molasses based on potato. Higher concentrations of molasses, although causing a steeper decline in redox potential, resulted in less effective Cr removal. Typically, the fermentation of molasses results in acidification and this drop in pH may hinder the formation of insoluble chromium(III)hydroxides. It may also be possible that certain components of the molasses form soluble complexes with chromium(III). For lactate, no significant drop in pH was observed. Following the laboratory microcosm tests, the stability of the chromium precipitates was examined by performing a sequential extraction on the microcosm materials. These were performed under redox conditions which were similar to the ones observed in the field. Since the outcome of these tests was positive, a pilot scale test was implemented in the field in April 2005. Two different substrates, the cheap waste product sugar molasses and lactate are being injected creating two different impact zones and typical parameters are monitored. Frequent re-injections were important to maintain reduced conditions and are carried out three-weekly up to now. To study the stability of precipitates formed, mesocosm socks containing aquifer material were installed in the monitoring wells and harvested at regular intervals. Results of this pilot test will be presented and compared to the laboratory results. Based on the success of this field test, a full scale process will be designed and implemented as remediation strategy.

Jan 1, 2006

By D. Panias

Alumina hydroxides such as gibbsite (Al(OH)3) and boehmite (AlOOH) are precursors of many types of alumina that find important industrial applications. The thermal decomposition of AlOOH, which is a more energy saving precursor compared to gibbsite, gives rise to the formation of ?-, d-, ?- and a-aluminas that are used for the production of catalysts. The applications of the aluminas are governed by their properties that are a function of the precursor material and its microstructure. The microstructure in turn is a factor of the method and conditions applied, as well as, in the case of soft chemical processes, on the anions present. Towards these ends, this study was focused on the effect of different anions on the physicochemical characteristics of the alumina hydroxides precipitated in the first 5 minutes after the perturbation of the stability of a supersaturated sodium aluminate solution (Bayer liquor).

Jan 1, 2006

By P. Mills

More than 95 percent of all the barite mined and produced is used in the petroleum industry as “drillers mud.” The remaining barite is used in the industrial and medical markets. Therefore, the amount of drilling activity is a good indicator of the health and growth of the barite industry. The four major barite-producing countries in the world are China, the United States, India and Morocco. In 2005, the average number of drilling rigs exploring for oil and gas increased by about 15 percent over the average number in 2004. This increase in oil and gas exploration has resulted in a higher demand for barite and an increase in barite production.

Jan 1, 2006

By Steve Kral

In 2002, many in the mining industry — companies, academia and government — realized that the industry would soon be facing a serious shortfall in salaried and hourly employees. Depending on whose numbers are to be believed, 20 percent to 50 percent of current mining professionals are expected to retire within five to 10 years. And there are not enough students currently enrolled in mineral-related programs to the fill the need. Part of the impending shortage in professionals was brought on by the industry’s negative image, which discouraged students from enrolling in mining engineering programs. Another part was that the industry was in the doldrums and was seen by the public as a dying industry.

Jan 1, 2006

By V. Saltas

In the present work, dielectric spectroscopy experiments were conducted on bentonite samples collected from Milos Island, in order to study their electrokinetic behavior in correlation with water content and mild heat treatment. Low-frequency dielectric spectroscopy has proved to be a power tool in the study of the electrical behavior of clay-water systems, because polarization and relaxation processes typically affect response at frequencies below 100 kHz. Therefore, dielectric and conductivity measurements in the frequency range of 10mHz to 1MHz were carried out by means of a high-resolution broadband spectrometer on bentonite samples, at various levels of hydration. The evolution of dielectric response was also examined after annealing of the samples. Experimental data were computer fitted with the empirical Havrilliak?Negami dielectric relaxation function on which a conductivity term was superimposed. The evaluated parameters of the fitting function are shown to be strongly affected by the water content of the measured samples.

Jan 1, 2006

By William R. Yernberg

The Society of Economic Geologists (SEG) held its biennial conference May 14 through 16, 2006, in Keystone, CO. SEG is an international organization with about 3,500 individual members with interests in economic geology. The 2006 SEG conference theme was “Wealth creation in the minerals industry — integrating science, business and education.” The conference exceeded expectations with 705 participants, including 102 students, from 44 countries. The conference featured 30 oral presentations, 24 professional posters and more than 70 student posters. The conference also included a trade show with 50 vendors, numerous field trips, workshops and social activities.

Jan 1, 2006

By L. Stas

The authors have been interested in stress measurements in the rock mass for a long time. This paper describes the development of new apparatus for stress measurements in a rock mass. The principle of stress measurement by this device is based on the relief method as applied on the conical shaped surface of the bottom of a borehole. The design started based on the experience of K. Sugawara and Y. Obara who have been using the compact conical borehole over-coring system (CCBO). The conical shape of the strain gauge probe CCBO makes the fixation of the probe in borehole easy and, also, makes the measurement of stress in independent directions possible. The principle of the measuring method, the preparation of the borehole, the design of the probe for continuous measurement of stress during the course of overcoring are described. Also, a simplified version of the probe for long term monitoring of stress variations in the rock mass by means of the inserted body method and the initial laboratory results and in-situ testing of the development sample are described. Additionally, testing was done regarding the possible glues in relationship to the creep effect for this case.

Jan 1, 2006

By R. Frim, S. D. Ukeles

The present U.S. production of bromine is from inland brines located in Arkansas and Michigan. The most concentrated domestic brines (up to 5,000 ppm bromide) are situated in Arkansas. Less concentrated brines (about 2,500 ppm bromide) are located in Michigan. The amount of bromine sold or used in the United States came from three companies operating in Arkansas and Michigan. Arkansas, with its six plants, was the leading U.S. state in bromine production. Bromine being the leading mineral commodity valuewise produced in the state. The Michigan bromine production was a byproduct of magnesium compounds production.

Jan 1, 2006

By S. Di Muzio

Sulphate Reducing Bacteria (SRB) are hetero-trophic anaerobic micro-organisms that can be used to remove sulphates and heavy metals from Acid Mine Drainage (AMD), heavy metal-bearing streams with high iron and sulphate contents and low pH, generated by sulphur bio-oxidation in abandoned mine districts. After the preliminary chemical precipitation of iron with carbonate stones (I step, chemical precipitation) SRB can be used to reduce sulphates to sulphurs then favouring heavy metal removal as sulphur precipitates (II step, biologically mediated precipitation). In this work the experimental results of heavy metal and sulphate removal from column tests were reported. Sulphate and heavy metal abatement in fixed bed column was performed using chemically pre-treated samples of synthetic AMD. Attenuation of toxic effects of treated samples was also ascertained by toxicological tests of germination and radical growth with Lepidium sativum.

Jan 1, 2006

By Steve Kral

The mining industry in northern Ontario is known mostly for its huge nickel deposits. Inco’s and Falconbridge’s nickel mines in the Sudbury Basin are the best known. And with nickel prices being what they are, interest in the region continues. And how. Inco and Falconbridge want to merge. Teck Cominco wants Inco, but without Falconbridge. Xstrata made a hostile bid for Falconbridge, which Falconbridge rejected. And, in June, Phelps Dodge trumped them all when it made an approximately US$40-billion friendly offer for Inco and Falconbridge in a two-part deal.

Jan 1, 2006

By Steve Kral

For a state whose roots are in mining, most Colorado residents probably do not realize that the industry still contributes heavily to the state’s economy. In 2005, the industry contributed, directly and indirectly, about $8 billion to the state’s economy, according to the Colorado Mining Association (CMA). It employed nearly 10,000 people at mines and support businesses. And the mining industry in Colorado is one of the highest paying occupations in the state, averaging about $80,000 a year in wages and benefits. The state’s coal mining industry produced nearly 36 Mt (40 million st) of coal in 2005, valued at $800 million, the CMA said. That was seventh in the nation. And Colorado’s only major gold mine produced 10.2 t (329,000 oz) last year, valued at $124 million. That was third in the nation. And Phelps Dodge’s Henderson Mine produced about 12.7 kt (28 million lbs) of molybdenum, valued at $350 million. Colorado is the largest molybdenum producing state in the nation.

Jan 1, 2006

By G. Gaidajis

Sea water samples collected from coastal waters in the vicinity of the Stratoni mining operations, in North-Aegean Sea were analysed for dissolved metals and elements. The maximum concentrations observed were one to three orders of magnitude lower than the environmental limit which coincides with the quality of sea waters suitable for swimming purposes. The quality of the coastal sea waters are affected by the natural mineralization of the area and the urban activities drained through local small rivers, the past mining activities present in the sea bottom sediments in the form of disposed tailings, and finally by the presence of the adjacent Mill-Flotation Plant. The relative importance of the treated final effluents discharged from the mining operations is considered to be insignificant.

Jan 1, 2006

By Georgene Renner, William R. Yernberg, Steve Kral

Agapito Associates (AAI) provides consulting services in geo-engineering, mining engineering and related disciplines. Founded in 1978, the firm operates out of offices in Grand Junction, CO, Golden, CO and Lombard, IL. Members of the staff include mining, civil and geological engineers, physicists, geologists, numerical analysts, computer specialists, instrumentation specialists, plus administration and technical support personnel. AAI has provided consulting and engineering services to mining companies producing base metals, precious metals, coal, potash, trona, limestone, oil shale and salt, and to defense and nuclear-waste disposal industries. AAI also provides services for measuring in situ horizontal stresses using an advanced biaxial overcore stress downhole measurement system developed by Sigra of Australia. Since 1978, AAI has measured in situ stress in copper, oil shale, molybdenum, trona, limestone and coal mines, and in tunnels and concrete structures. Since 1994, the staff has completed 527 overcore stress determinations. AAI has the equipment and personnel for overcoring, sample coring and instrumentation installation in limited access, surface and underground mines. Portable Longyear CP-65 drills, borehole deformation gauges and strain indicators are used for difficult-access overcoring and are permissible for use in gassy mines.

Jan 1, 2006

By C. Sachanidis

From the surface mines of Ptolemais basin 48 samples of Pliocene lignite were collected. The samples were analysed using Instrumental Neutron Activation Analysis (INNA) and Inductively Coupled Plasma (ICP) for determining the concentrations of 39 trace elements. The contents of sulphur and ash and the loss of ignition were also determined. The chemical affinity of these trace elements was estimated based on 40 correlation diagrams between the elements concentrations and the ash content of the collected lignite samples. According to the obtained results, 18 elements have inorganic affinity (Co, Cr, Cs, Hf, Sc, Th, La, Ce, Nd, Sm, Eu, Yb, Lu, ?n, Ba, ?, Sn, ?r) and 10 elements have inter-mediate affinity (As, U, ?r, Pb, Cu, Sb, Sr, S, Ni, V). The remaining 12 elements (Au, Ir, ??, Rb, Se, Ta, W, Tb, Ag, Cd, Bi, Be) exhibited concentrations below the detection limit. Thus, they were impossible to be classified in a specific affinity group. Based on the classification of these trace elements and sulphur in inorganic and intermediate affinity groups some useful conclusions are drawn regarding their behaviour during lignite combustion and lignite ash utilization and disposal processes.

Jan 1, 2006

Coal fly ash and flue gas desulfurization (FGD) sludges can be returned to mine pits, fills and revegetation zones in Virginia by regulation if (and only if) a positive beneficial use can be shown. Utilization of alkaline fly ash for control of acid drainage from pyritic coal processing waste piles, and use as a soil amendment for revegetation, are the two dominant beneficial uses proposed over time. Both applications must be controlled by the basic chemical properties of the ash proposed for utilization. Currently, public concerns over long-term As and Se leaching from various applications are increasingly driving regulatory options for mine site utilization. Many fly ash materials are relatively low in inherent alkalinity or neutralizing ability, and certain ashes are actually acidic. Failure to add sufficient total alkalinity will result in strong acidification of the ash utilization zones, stripping heavy metals like Mn, Zn and Cu from the fly ash matrix. Similarly, if alkaline ash is loaded into non-acid forming coal wastes at high rates such that leachate pH is > 9.5, significant leaching of As and Se has been documented in large scale laboratory leaching columns. Utilization of fly ash and FGD as a mine soil amendment for revegetation is based upon combined liming and water holding capacity benefits, however, levels of soluble salts (primarily sulfate and borates) limit one-time application rates to 100 Mg/ha or less.

Jan 1, 2006

By M. Pantazidou

The wide use of chemical grouts, in combination with increasing environmental awareness, necessitates the evaluation of possible adverse effects if grout constituents may leak in groundwater. Acrylamide-based grouts are of particular interest, since the engineer has to balance the superior properties of these grouts and the known human health impacts of acrylamide. This paper identifies the properties of acrylamide that are required for the evaluation of its fate and transport in the subsurface and presents results of numerical simulations of acrylamide transport for a hypothetical tunneling application.

Jan 1, 2006

By Joseph J. Feiler

Historical mining operations in Colorado and other western states have resulted in thousands of remnant mine openings. Many are sources of metals loading and acid water generation in surface and ground waters. It is estimated that more than 965 km (600 miles) of streams in Colorado have been impacted by past mining activities. The Animas River watershed in southwestern Colorado is one of the most heavily affected areas in the state. Abandoned mine features pose significant safety hazards to those who enter them. These hazards can include bad air, unstable rock or falls into open shafts, stopes and winzes. Backcountry skiers and snowmobile enthusiasts are particularly vulnerable to falls into snow covered mine openings.

Jan 1, 2006

By P. A. Plunkert, D. E. Morse, L. McCartan, J. F. Papp

The mineral sector is a fundamental part of the U.S. economy. It contributes to the real gross domestic product (GDP) at several stages —basic (mining), intermediate processing, manufacturing of finished goods and construction. The real GDP increased by 3.5 percent from 2004 to 2005. The nominal GDP was $12.5 trillion at the end of 2005. Housing starts were up by more than 5 percent for the year, and the unemployment rate decreased to 5.1 percent in 2005 from 5.5 percent in 2004. The prime interest rate increased from 5.25 percent at the beginning of the year to 7.25 percent at the end of the year. The value of minerals mined in the United States in 2005 rose significantly because of increased unit prices for some metals —particularly molybdenum — and significantly increased production for some industrial minerals, mainly cement, construction sand and gravel, and crushed stone.

Jan 1, 2006

By J. MacFadyen

The U.S. cement industry, including Puerto Rico, again set a record in terms of production and shipments. The increase in shipments came primarily from imports of portland cement as domestic production from produced and imported clinker gained only 1.9 Mt (2.1 million st). Clinker production as reported to the U.S. Geological Survey (USGS) was 88.6 Mt (97.6 million st), an increase of 1 percent. Gray and white portland cement production from domestic and imported clinker, estimated at 93.5 Mt (103 million st), was up 1.9 Mt (2.1 million st). Masonry cement shipments of 5.5 Mt (6 million st), which equates closely to production, was up 6.3 percent. Blended ce-ment shipments were up 35.9 percent from 2004 at 2.35 Mt (2.6 million st).

Jan 1, 2006

By J. Loredo

In some rural regions of Peru, artisanal gold mining is currently an essential activity as it provides an important source of income. In the Huanca region (Ayacucho Department) gold deposits are not attractive for mining companies due to their reduced size, but they have enough interest for artisanal mining because of the ease and low cost of mining operations. Artisanal gold mining represents an important damage for the environment, because operations related to amalgamation processes using Hg result in special environmental problems besides the typical ones commonly associated to all mining activities. A preliminary sampling has been made in soils, materials from tailing ponds and surface water of the Acarí River, at the site of the Huanca village, according to networks specially designed for the particular conditions of the area. Studies accomplished revealed high mercury concentrations in soils and tailings. Chemical analyses of soils directly collected in the area of the active or abandoned ?quimbaletes? show mercury concentrations ranging from 15.3 mg?kg-1 to 44.2 mg.kg-1. Mercury concentrations in soils decrease as a function of distance from the before mentioned sources. Water quality of the Acarí River that flows through the area does not present important changes as a consequence of the mining and processing operations.

Jan 1, 2006