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By M. Ribeiro, P. So, P. Wong

Electrowinning is a process by which metals, such as copper or nickel, are recovered from aqueous electrolyte solutions resulting from the extraction of the metal ion from an acidic or basic leach solution. The electrolyte or “pregnant” solution is customarily forwarded to an electrowinning "tankhouse." In the tankhouse, the metal ions are deposited on cathode plates by electrodeposition and then recovered from the cathode plates. Other processes may be employed with other metals, such as nickel, zinc, among others, to produce an electrolyte from which their respective metals are obtained. During the electrowinning (electrodeposition) stage, elemental metal is plated out at the electrowinning cathode and oxygen evolves at an insoluble anode. The evolution of oxygen gas forms bubbles which entrain strong acid electrolyte, carrying it into the air above the electrowinning tank in the form of a fine mist or spray when the bubbles break. An acidic mist is generated above the electrolyte. This mist or spray then spreads throughout the electrowinning tankhouse. The acidic mist is corrosive and a health hazard and can cause extreme discomfort to the skin, eyes, and respiratory systems of tankhouse workers, especially during hot weather conditions. Polyfluoroalkyl based products (PFAS) have been widely applied as anti-misting agents in the electrowinning of metals in an acidic electrolyte. Functionalized PFAS compounds, however, have come under increased scrutiny by the EPA due to their impact on human health and the environment. There remains need for improved acid mist suppression agents for electrolysis and electrodeposition, particularly for products free of fluoroalkyl components.

Feb 1, 2023

By M. Jessop, V. O. Kofoed, R. Blanchard, A. Hughes

Willowstick has successfully employed a new Seismic Acoustic Resonance (SAR) method to improve seepage characterization through, beneath, and around dams. SAR is a passive seismic method that detects zones of higher permeability in the foundation and fill materials of a dam. Just as the ocean has tides, the earth’s crust experiences daily “Earth Tides” and is constantly in motion. Continual motion produces resonance signals that can be measured, interpreted, and modeled to identify zones of higher permeability within a dam and its foundation. The SAR results are analyzed in conjunction with the traditional Willowstick Method to better characterize seepage flow paths and patterns trough, beneath, or around a dam in three dimensions. When both methodologies, which use entirely different scientific principles, identify the same anomalous feature, a higher degree of confidence is gained in the results of the investigation. Willowstick has effectively utilized the SAR method on many successful dam seepage investigations. The two geophysical techniques when used in parallel have yielded complimentary results, with both methods providing beneficial information about seepage locations. This paper will detail seepage flow paths identified using both Willowstick and SAR methods for two case study tailings dams in Canada and the United States.

Feb 1, 2023

By David A. Collins

Red Dome Gold Mine classifies ore types within the pit by gold and copper grades. Copper grades are further distinguished by total copper and cyanide soluble copper levels. At present, Cyanide Soluble Copper samples take six hours of agitating before they can be assayed. This agitation time produces results which are a proportion of the total cyanide amenable copper. This relates to our plant's performance. Frequently the total copper result is needed before we can begin the cyanide soluble copper analysis. This caused a protracted tum around time. Mennetech Pty. Ltd has produced a catalyst proven by David Martin Menne to accelerate the cyanidation of gold. David said that the information at hand indicated that Leach WELL TM also accelerates the leaching of cyanidable copper substantially. Test work was undertaken on-site at Red Dome Gold Mine to investigate the potential of Leach WELL TM to reduce the leaching period and therefore, the overall tum around time required for cyanide soluble copper determinations.

Jan 1, 1995

By Darryl J. Butcher

The Akjoujt Project is operated by MORAK SA, a company incorporated in the Islamic Republic of Mauritania. MORAK is jointly owned by General Gold International SA (A wholly owned subsidiary of General Gold Resources NL.), SAMIN, and the International Finance Corporation. The project was devel­oped to treat approximately 2.1 million tonnes of TORCO (Treatment of Refractory Copper Ores) tailings containing an average 3.2gAu/t, and 0.75%Cu/t. The process involves the use of ammoniacal cyanidation for gold extraction, and conventional carbon adsorption, and eventual desorption, of gold values. This is believed to be only the second commercial application of this leach chemistry in the world. The other being a small vat leach operation on the Paris Mine Dumps. (This operation was described by Mr M Ruane in a paper to a previous Randol Forum.) Initial work on the process, and the Akjoujt process design assumed that the reaction involved was anaerobic. This paper describes the operating experience, plant trial, and eventual installation which has lead MORAK to the conclusion that the process is not anaerobic, but requires oxygen, or an oxidant to proceed.

Jan 1, 1995

By Marc E. Orman, Todd V. Ramey, Mark E. Smith

Heap leaching in certain parts of the world, such as Chile's Atacama Desert, brings unique design problems in the form of possible large differential settlements of the foundation soils due to the dissolution of salts. In northern Chile the soils often c?ntain very high concentrations of soluble salts (nitrates, potas­smm, magnesium, and common sodium). When a leak in the liner occurs, the escaping solution dissolves these salts and trig­gers differential settlement. If the settlement is great enough, the geomembrane tears, the leakage increases, triggering more dif­ferential settlement. The nitrate plants have experienced many occurrences of this phenomenon where a brine pond will under­go a sudden and complete loss of the impounded liquors. The authors present a simplified technique to quantify the differential settlement resulting from dissolution and provide a method which can be used to select a geomembrane with suit­able flexibility under axi-symmetric (multi-axial) load condi­tions to tolerate the predicted settlement.

Jan 1, 1996

By M. T. Errington, P. C. Miller, W. E. Hardwick

Paper discusses in general terms the techno economic merits of various types of aerated biological reaction systems. The current status of the technology leaves many questions unanswered and hence the choice of the best system to employ is open to discussion. Reasons are given for the choice of the reactor system to be built and operated by Davy McKee. The pilot plant has been designed to provide answers to a number of the questions posed by this technology.

Jan 1, 1998

By Robert S. MacPhail, Bret G. Cousins

Many copper-bearing ores with associated gold use Sodium Isopropyl Xanthate (SIPX) as a flotation agent. In general, SIPX will float to some extent other minerals that may not be desirable, such as pyrite. FLEX 31 is a chemically enhanced SIPX product with many of the same properties as SIPX. But FLEX 31 has the ability to reject more pyrite from concentrates and improves copper recovery when using up to 50% less FLEX 31 than is required if using SIPX. Copper activated minerals such as sphalerite and arsenopyrite show increased recoveries as well using FLEX 31. Tests have been performed on copper/zinc ores and an arsenopyrite/pyrite ore.

Jan 1, 1995

By Gary Jobson

The Mt Todd Gold Mine is owned and operated by Zapopan NL, and is located 300km south of Darwin near the town of Katherine. The crushing plant and heap leach facility, which has operated since November 1993, has recently been expanded to treat 6 Mtpa with 1995 budget gold production reaching 120,000 oz from a head grade of 1.12 git. The process flowsheet and equipment are described, with innovative key features including:

Jan 1, 1995

By J G. Dunn, S M. Thurgate, A C. Chamberlain, P Franzmann, M Jeffrey, L J. Warren, G E. Poinen, T Williams

Gold has always fascinated mankind. From Tutankhamen's mask to the huge nuggets that have been found in the Australian outback, gold has quickened the pulse and fevered the eye. But in recent years, governments around the western world have shown a singular lack of interest in research into gold processing, with many programs being cut. There are some notable exceptions, fortunately, and this paper summarizes a large research effort that is well supported by the Australian government and the Australian gold industry. The AJ Parker Cooperative Research Centre for Hydrometallurgy is an unincorporated joint venture between the CSIRO Division of Minerals, Murdoch University, Curtin University of Technology and the Western Australian Department of Minerals and Energy. The Australian Mineral Industry Research Association (AMIRA) is the Parker Centre's broker for generic R&D contracts with industry. Each of the partners makes available staff, students and equipment to further the work of the Parker Centre, and the Australian Government provides additional funding. The Parker Centre is nearly five years old and has grown spectacularly in that time. There are now about 30 full-time-equivalents of effort from 50 scientists and engineers, as well as about 40 postgraduate and honours students. The fundamentals of the key operations in hydrometallurgy are studied in three programs: leaching (which includes pretreatment by roasting etc), precipitation (or crystallisation), and surface processes (which includes solid/liquid separation, adsorption, solvent extraction, etc). A large part of the Parker Centre's R&D is directed towards gold processing technology. In Australia, a dramatic increase in gold production, from about 30 to nearly 300 tonnes per year (1977-1997), has been made possible largely as a result of a brilliant metallurgical innovation, the carbon-in-pulp process. However, falling head grades eg 2.56 to 1.84 g(Au)/t over the last 10 years, and environmental concerns, are squeezing profit margins. There is increasing pressure to reduce costs, and the Parker Centre program is focussed on providing the scientific understanding required to do this. A selection of research highlights will be given, to indicate the depth and breadth of the R&D at the Parker Centre.

Jan 1, 1997

By M. Moats, I. E. Paschalidou, K. Awuah-Offei

Tellurium (Te) is a rare metalloid that is predominantly produced from the treatment of anode slimes formed during copper (Cu) electrolytic refining. The US Government lists Te as one of the 50 critical minerals, partly, because of its use in thin-film photovoltaic (PV) technology. Given policy initiatives to increase Te production, it is important to evaluate the life-cycle environmental impacts of Te recovery as a by-product of Cu processing. The literature contains a few specific life cycle assessment (LCA) studies of groups of metals that include Te without proper regard to impacts per life-cycle stage of Te production or the effect of allocation on the results. This study builds an LCA model of the production system of Te from anode slimes treatment to evaluate the effect of allocation on life-cycle impacts. We build life cycle inventories using data from the Ecoinvent v3.7.1 database, literature, and engineering calculations and allocate impacts in proportion to products’ mass and economic value. The results show that economic value-based allocation yields greater impacts than mass-based allocation indicating the significant effect of the allocation approach on life-cycle impact estimates.

Feb 1, 2023

By Y. Zhang, M. Yekich, C. Zhou, C. Jobes, J. Galanko, D. Tuchman, J. Srednicki, J. Carr

The continuous personal dust monitor (CPDM) is an essential instrument for working in hazardous environments, is used to monitor real-time coal dust exposure, and is mandated by the Mine Safety and Health Administration (MSHA) for underground coal mines. Researchers from the National Institute for Occupational Safety and Health (NIOSH) found that it is possible for electromagnetic interference (EMI) between a CPDM and a proximity detection system (PDS) to occur. Various approaches have been taken by researchers and manufacturers to address this EMI issue. Administrative controls were recommended to keep the CPDM six inches away from the wearable PDS device. Shielding pouches were made to contain the electromagnetic (EM) emission from the CPDM. Metal shielding was added to major EM emitting components. EMI filtering with large capacitors was introduced to mitigate EMI. Most recently, a novel magnetic-field-cancellation-based approach was developed and achieved remarkable results. In this paper, we provide a comparison between these approaches. The pros and cons of each approach are presented and discussed, so that mining device manufacturers and operators can best evaluate the technology and controls that improve the health and safety of mine workers.

Feb 1, 2023

By E. J. Owen, S. Cherotich, V. T. McLemore

Breccia pipes are vertical pipe-like columns of rocks that provide conduits for fluid flow and open spaces for mineral precipitation, hence are focus areas for exploration. In the Gallinas Mountains, Lincoln County, New Mexico, there is recorded production of Cu, Pb, Ag, F, Fe, REE (as bastnäsite), and Au from 1902 to 1980, but no production reported from the breccia pipes. Previous studies described the occurrence of REE in breccia pipes, but their transportation and deposition controls are still unclear. The aim of this research is to characterize the magmatic-hydrothermal breccia pipes in order to understand the geochemical and physical conditions of deposition of REE and gold in the breccia pipes found in the Gallinas Mountains. There are more than 20 exposed breccia pipes that form a NE-trending belt about 3–5 kilometers, mostly gray-brown and consist of angular- to sub-rounded rock fragments, some host high concentrations of REE (80,500 ppm total REE) and Au (175 ppb). Preliminary studies suggest they are magmatic and intruded into the host rock and, subsequently, hydrothermal fluids precipitated F-REE and Au along the edges of some breccia pipes. More studies are underway to test this hypothesis.

Feb 1, 2023

By James L. Whitlock, Amy E. James

During the past twenty years, numerous advances have been made in the technologies used to pretreat sulfidic refractory gold ores. These advances have included improved equipment design, increased gold recoveries, and reduced operating and capital costs. More recently, treatment of refractory gold ores has primarily been accomplished by pressure oxidation (POX), roasting, chlorine oxidation, or biooxidation. In addition to improving the time-proven processes of pressure oxidation and roasting, new and innovative approaches to biooxidation pretreatment of both concentrates and whole ores have been developed. Selecting the appropriate biooxidation technology depends on the nature of the refractoriness in the ore, economic gold recovery, plant design operating parameters (such as desired tonnage), site climatic conditions, and operating and capital costs, as well as several other deciding factors. The objective of this paper is to outline the biooxidation processes and technologies currently available for the recovery of gold from refractory sulfidic ores, to discuss the critical factors that affect plant design and operation, and to provide the metallurgist with a practical guide to choosing the appropriate biooxidation technology for a particular ore or concentrate.

Jan 1, 1999

By G. Deschenes, M. Fulton

The New Britannia Mine processes a qumtz-carbonate gold ore containing 4.63 git Au at a rate of 2,200 tpd. The ore contains approximately 3 .0% arsenopyrite, 2. 7% pyrite and the rest is gangue minerals. Eight to ten percent of the gold is refractory to leaching. Two years ago, New Britannia Mine experienced cyanidation problems. Gold extraction was not stable and occasionally decreased significantly. Preliminary test work, at laboratory scale and in the plant, indicated that lead nitrate addition was beneficial. A laboratory study was initiated to evaluate the level of control of the parmneters (grinding size, dissolved oxygen, pH, free cyanide and lead nitrate) to optimize the efficiency of the process. It was found that lead nitrate addition is required to alleviate the effect of metallic sulphides. This addition causes a significant increase in the gold leaching kinetics and a reduction in the cyanide consumption. The optimum system appeared to be: leaching for 24-30 hours at pH 11.8, 50 git lead nitrate, 250 ppm NaCN and 8 ppm 02. The gold extraction was 89.8% with grinding at 89%-74Fm (leached tail at 0.48 git). Cyanide and lime consumption are 0.40 kglt NaCN and 1.9 kglt respectively. Following the incorporation of lead nitrate, overall gold extraction was increased from 89.2% to 91.1 % but no change was noticed in cyanide consumption. The gross profit is $CDN 988,000 per year.

Jan 1, 1999

By Denis McDermott

This paper describes the process used at three mines to devel­op safety and training programs. The mines are located in Australia, New Zealand and the United States of America. The aims of the programs were to promote and reinforce safe and healthy behaviour, increase productivity and efficiency and to provide a fair and objective basis for the payment of wages. There were common aspects to each of the projects: • mandatory legislation required employers to provide employ­ee training in work performance • employees had little previous involvement in the design and development of the training provided • training had been unstructured with employees relying on the "buddy system" to acquire new skills; the degree of skill acquired by an employee depended on the knowledge and teach­ing capacity of the worker to whom the novice was assigned • appointments and promotions had been based on judgements by supervisors and these were not generally understood by employees • employment conditions for employees were covered by an industrial agreement between management, unions and employ­ees. The degree of sophistication of the industrial agreements varied however none provided a description of work performed in each classification, nor the career or promotional path for an individual • supervisors with the responsibility to train, develop, motivate and reward employees expressed concern that there were no structured processes ( eg work standards or wage progression cri­teria) to support their role.

Jan 1, 1998

By D. L. Slyter

Coeur d'Alene Mines Corporation's Thunder Mountain project in Valley County, Idaho, is one of the most remote active mining operations in the US. High altitude, heavy snows, and proximity to wilderness complicate operations in this environmentally sensitive area. Mining is conducted by conventional open pit techniques while processing utilizes on-off heap leaching and Merrill-Crowe zinc precipitation. The project is one of a few similar operations which detoxify the leached ore prior to its removal from the leach pads. Both leaching and neutralizing ( detoxifying) circuits are closed and independent loops. After leaching, alkaline chlorine solutions destroy residual cyanide in the heaps. Calcium hypochlorite solution for the cyanide destruction is prepared by injecting chlorine gas into milk of lime solution.

Jan 1, 1998

By Norbert Patzelt, Johann Knecht, Wolfgang Baum

The principle of high-pressure interparticulate comminution has been used very successfully since the mid 1980's for grinding a wide range of different materials. A number of reports about operating experience have already been published. High-pressure grinding rolls (HPGRs) are currently making their debut in the mining industry. Experience is being gained with test machines, particularly for the comminution of hard rock. In the grinding of diamond-bearing ore, (Fig 1) interparticulate comminution has already become the standard for liberating the diamonds from the matrix. The advantages of interparticulate comminution are also recognized for the grinding of concentrates (chrome ore, iron ore). Numerous HPGRs are being used very successfully in this field. A testing plant for first-time industrial grinding of coarse, very hard and highly abrasive copper ore was built at Cyprus Amax's plant in Sieretta, Arizona (Fig. 2). The operating experience gained here showed that the grinding of very hard ores places particularly high mechanical demands on the mill. While the machine itself meets the high availability requirements, the wear-protection system proves to be the most sensitive point. Naturally, the properties of the ore to be ground exert a considerable influence on the lifetime of the grinding rolls. This paper describes the wear mechanisms and the wear­protection systems designed to combat these.

Jan 1, 1997

By Mike D. Adams

Testwork was conducted on loaded carbon samples from a small gold mine in South Africa. It was shown that a 75% saving in reagent consumption in the Zadra elution circuit could be achieved by adopting a cyanide-free elution approach, i.e. by cutting back the NaCN level from 1 % to nil, and the NaOH level from 3% to 1 %. This process change was also shown to result in a 20% improvement in the elution kinetics. Furthermore, it was also shown that a 50% enhancement in elution rate over the current situation could be achieved by use of an eluant containing 0.5% NaOH and 0.15% NaCN, corresponding to an 84% saving in reagent consumption. A further improvement in elution kinetics was found to occur by increasing the NaCN level to 3%, but this would lead to a concomitant increase in reagent consumption, due to the decomposition of cyanide at high temperatures. The presence of base metals loaded onto the carbon was also found to have a significant effect on the elution. Copper tends to adsorb as Cu(CN)2- during the adsorption stage, and acid washing converts this species to CuCN. Copper in this form is not eluted during cyanide-free elution, whereas it is eluted during a conventional cyanide elution, consuming the initial cyanide in the process. The elution data was analysed and the fit to a simple model was verified.

Jan 1, 1995

By J. O. Craig Imrie

Mine operations are being squeezed to do more with less. This is not new. But, where do mine operators turn for the next stage of improvement? Many have waged strong wars on the cost reduction front and cut back staff to the bone, yet need more improvement to remain competitive. This paper will outline an approach which a few leading operators have taken. Following the footsteps of manufacturing's view of supply chain management and basic quality management they are reaping the benefits of taking a more holistic process view of their operation. This paper presents summaries of three companies' approaches and the impact which is being felt on the bottom line.

Jan 1, 1999

By P. Ollivier

The ore-processing plant of the Soremib mine Pour a (Burkina Faso) has now been in uninterrupted operation for 3 years. Ores from the oxidized and non-oxidized zones of the deposit are processed together in one flotation unit. About 60% of the gold is free and is recovered in a gravity processing unit. The residual gold in the flotation concentrate is processed on the spot by cyanidation and carbon-in-pulp.

Jan 1, 1998