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By Reinhard Gertl, Maximilian Weithaler, Harald Kammerer, Juan Pablo Muñoz, Juan-Carlos Rueda

The Guillermo Gaviria Echeverri tunnel and its access roads project in Antioquia, Colombia is a mega infrastructure project that includes a road network with the longest tunnel in Latin America and several short tunnels, the latter being the focus of this study. The design of the project required careful consideration of several special factors, such as the tunnels’ steep slopes of up to 5%, high fire load of 100 MW, bidirectional operation, and short lengths that make it difficult to place ventilation equipment. The combination of all these parameters cause a challenging design problem for the ventilation systems and smoke control of the short tunnels. To address this challenge, a risk assessment study was conducted to support the design of a new and innovative ventilation strategy that deviates from relevant guidelines and standards, like the Austrian RVS [1][5][6] or the German EABT [8] in order to provide a customized solution for this particular project. This strategy resulted a cost-effective solution, that allowed a reduction in the number of required jet fans and at the same time reaches or reduces the risk level compared to traditional ventilation strategies.

Jun 13, 2023

By Hun-Joon Sohn

Chemical metathesis and electrochemical reductive conversion of chalcopyrite in the presence of cupric ions were studied in sulfuric acid solutions for temperatures up to 90°C. The process results in the displacement of iron in the chalcopyrite lattice by copper ions with rejection of ferrous ions to the aqueous phase. The rate of reaction was found to be very slow, requiring subsieve-sized particles for extensive reaction to occur. The reaction was insensitive to copper ion concentration. Stirred ball milling of chalcopyrite introduces lattice strain. The reaction rate with strained particles was markedly higher than with annealed chalcopyrite. The reaction rate was found to be diffusion-limited, showing two distinct reaction stages corresponding to the formation of CuS (covellite) followed by Cu1.8S (digenite). The experimental activation energy for the first stage was 102 J (24.4 kcal) and the second stage 123 3 (29.4 -kcal) per mole. The rate-controlling process is diffusion of lattice ions, probably iron. The enhanced rate after milling is attributed to a recrystallization process which provides new paths for diffusion along dislocations and grain boundaries.

Jan 1, 1984

By Earle Bagley

In late 1971, the Sun Company, then known as Sun Oil Company, acquired a large surface mineable federal coal lease with the thought that those coal measures within its boundaries would provide a future feedstock of either coal or coal liquification. Our Cordero lease was one of the last Federal coal leases let before the recent decade long leasing moratorium. Because of the tremendous demand for compliance steam coal for the electric power industry, a decision was made to develop the property to serve that market. In 1974, Sunoco Energy Development Company (SUNEDCO), the non- oil and gas energy unit of the Sun Company, began engineering studies for development of the lease. The mine was originally designed at a 12.0 million ton per year capacity. The Cordero Mining Company was formed to mine and operate the property. Construction of the facilities adjacent to the lease began in January 1975. Due to the Sierra Club versus Department of Interior Secretary L. B. Morton suit, work within the lease was delayed until mid-1976 when pre-stripping of the overburden began.

Jan 1, 1982

By Michael S. Moats, John Bailey Fletcher

Wear rates of grinding media can be misrepresented by marked ball wear tests (MBWT). Galvanic interactions between dissimilar grinding media can be affected by the chromium content in the media and the presence of oxygen in the environment. Corrosion, one component of wear, can be affected by many variables. Corrosion rates and corrosion potentials for modern high chromium white iron (HCWI) and high carbon steel (HCS) grinding media samples were obtained through electrochemical testing. In this study, the impact of chromium content in the grinding media and the dissolved oxygen in a simulated mill water solution on corrosion rates and potentials was examined. Increasing chromium content in HCWI above 15 weight percent increases the corrosion potential and decreases corrosion rate. Removing most of the oxygen from the solution lowers both the corrosion potential and corrosion rate of the materials tested. The electrochemical results were examined to model possible galvanic coupling effects on corrosion rates. Galvanic coupling between HCS and HCWI could cause differences in corrosion rates for almost all scenarios modeled. Based on the galvanic coupling analysis, MBWT results could be impacted by mixing HCWI and HCS in a ball mill charge. This impact is predicted to be more significant when dissolved oxygen is present in the mill water and as the chromium content of HCWI is above 15 weight percent.

Dec 21, 2022

By Fiona M. Doyle Garner

Hydrolytic stripping is the process whereby metal ions in a loaded solvent extractant are hydrolyzed by water, typically at 130°-200°C. Equilibrium hydrolytic stripping tests were done on Versatic 10 solutions of various metals, singly and in mixtures. Single solutions of Fe, Xi, Cu, Mg, and tin precipitated aFe2O3, Ni(OH)2, Cu2O, Mg(OH) 2 and ?Mn203 respectively during hydrolytic stripping. Several mixtures containing iron precipitated magnetic spinel ferrites, MFe20k. No other combinations formed mixed oxides. It is proposed that the mechanisms for hydrolysis and precipitation of iron in loaded Versa- tic solutions are similar to those for iron hydrolysis in aqueous solutions. Infrared spec- troscopy and thin-layer chromatography of mixed iron-nickel Versatic solutions indicated that mixed Fe-Ni carboxylate complexes are present. Magnetic interactions between mixed complexes are thought to be responsible for the homogeneous nucleation of magnetic mixed oxides in preference to single oxides.

Jan 1, 1984

By J. Andres, M. Cross

"Freeport-McMoRan’s Sierrita operations has two natural gas-fired molybdenum roasters for converting molybdenum disulfide into molybdenum trioxide. When these roasters were compared to other similar units within the company during a benchmarking exercise, it showed that increased throughput from the roaster units at Sierrita was possible. A team of site metallurgists, technical experts from other sites, and engineers from the Climax Technology Center was formed to study the potential in more detail. The team investigated many parameters in the roaster, including temperature profiles, roaster chemistry profiles, rabble and drop hole patterns, and operational strategies. The results of these studies and the associated throughput improvements are described in this paper. INTRODUCTION Molybdenum, a vital component for the steel industry, is typically found in nature as molybdenum disulfide (MoS2). MoS2 is typically recovered via flotation processes and is purified through leaching processes. While molybdenum disulfide is a commercial product, it is not the form of molybdenum that the steel industry requires. They require molybdenum in the form of molybdenum trioxide, MoO3. There are multiple ways to refine molybdenum disulfide into molybdenum trioxide. The primary method is the oxidation of molybdenum disulfide in a multiple hearth roaster. The chemistry of converting molybdenum disulfide to molybdenum trioxide is very favorable at increased temperatures, oxidizing the molybdenum through a range of exothermic reactions to ultimately produce MoO3. The chemical reactions that occur in molydenum roasting occur in three zones. These three zones correspond with four different reactions."

Jan 1, 2015

By W. T. Robertson

My charge is to review briefly "Coal In The Electric Utility Industry - Present and Future." Thus, I will not dwell on the overall energy picture, other than to express what most others involved in the energy picture know - we're in trouble! Several years ago, speaking to another engineering society, I said, "Much has been and yet will be said and written about the energy situation in our Country." What an understatement! The energy question has reached crisis proportions and is a top priority item at the highest level of government, Unfortunately, it will be in that situation for some time to come. Many factors created this complex problem, and we all share some of the blame. But I am perplexed when I read in the popular press that environmental factors are unrelated to the energy crisis when I know this to be untrue. In the recent past all forms of energy have been cast in the role of villain, particularly coal with its problems of surface mining, mine safety, acid water drainage, sulfur content, and a multitude of other adverse factors relating to the environment in one way or another. As you know, the sulfur situation has led to the closing of numerous mines, resulting in the lessening of our mining capacity. Today, along the Eastern Seaboard, 60 to 70 million tons of coal are displaced by imported oil, primarily to meet air standards. Even in the Midwest, utilities sitting on enormous coal reserves are converting to other fuels or hauling low sulfur coal thousands of miles from the western Mountain States. [We will hear more about this coal from another speaker on the program this morning.]

Jan 1, 1973

By Robert L. Sandefur

Geostatistics of coal thickness and quality parameters for various coal seams in the San Juan Basin of New Mexico are reviewed. Interpretation of the histograms, variograms, and drifts of the data in the context of depositional environment and post-depositional geological history is discussed. A multivariate geostatistical technique for checking the accuracy of seam correlations is demonstrated.

Jan 1, 1982

By Verya Nasri, Heather M. Ivory, Kevin Clarke, Eric Cole

Development of the New York City Water Supply System The New York City water supply system serves a population of almost nine million, including residents in neighboring counties. Peak day demands on the system are currently running at about 70 m3/sec (about 1,600 mgd), which is significantly lower than in the 1990s. This trend of reducing demands over the past 25 years, which has been experienced in other major urban centers in the US, is mainly the result of conservation measures and increased cost consciousness on the part of water users. In the long term, demands are expected to once again follow an increasing trend with population growth, so that by the end of the planning horizon of these studies, the year2045, the peak day demand is expected to increase to about 85 m3/sec (2,000 mgd).The system is served largely by surface water sources, regulated by a system of 19reservoirs and three controlled lakes, which are connected to the City by a series of aqueducts, the longest of which is about 87 km (54 miles). The total storage in the sys-tem amounts to about 560 billion gallons, providing a system firm yield of about1300 mgd. The Delaware system provides about 50% of the City’s water, the Catskill about 40%, with the remaining 10% provided by the Croton. The system as a whole, which is shown on Figure 1, has been built up over the past 150 years, and is truly a marvel of engineering. The Catskill and Delaware aqueducts both discharge into Kensico Reservoir, which is a daily balancing reservoir located in Westchester County about 24 km(15 miles) north of the New York City line. The two aqueducts extend south for a further 14 miles to combine again at Hillview Reservoir in the Bronx, which provides hourly balancing storage for New York City system. The Croton aqueduct runs nearby as shown on Figure 2, but does not connect into the two reservoirs. From Hillview Reservoir the water is supplied to the city via three main distribution tunnels, known as City Tunnels 1, 2, and 3. City Tunnel No.1 was developed in the 1920s as part of the Catskill system. City Tunnel No. 2 followed in the 1960s as part of the Delaware system. City Tunnel No. 3 (CT3) is partly under construction and partly in operation, and is being implemented to permit the other distribution tunnels to be taken out of operation for the first time for inspection and maintenance. Presently CT3 is supplied with water from Hillview Reservoir via a large underground valve chamber, the Van

Jan 1, 2007

Worldwide minerals exploration slipped in 1992 from 1991 levels. Although industrial production figures showed the US economy emerging from recession in early 1992, it was not until February 1993 that the lagging indicator of unemployment dropped to 7%. Most other industrialized countries are still in recession. Preliminary data for 1992 showed industrial production dropping in Japan (5%), Germany (1.4%), the United Kingdom (0.5%) and France (1.4%). The slowdown in industrial production led to reduced mineral demand. This resulted in lean cash flows from mining operations, which squeezed exploration funding. Although mineral prices were steady during most of 1992, some mineral commodity prices began falling in late 1992 and early this year. Exploration 1991-1992 According to Metals Economics Group (MEG), planned 1992 exploration expenditures were down by about 5%. Geographically, the leading exploration target was the United States with 21 % of the expenditures, followed by Australia (19%), Canada (18%), Latin America (15%), South Africa (9%) and the western Pacific (7.5%). The remaining 10% was split between Europe and Africa. There were absolute increases in exploration expenditures in the United States and Latin America. Latin America showed the largest increase. The change in the Mexican mining law allowing foreign ownership of mines should result in the inflow of direct foreign investment in Mexico's mining industry.

Jan 1, 1993

"Controlling dust generation and keeping it below permissible limits at the working face of a room and pillar mine is a challenge for mine operators. With the recent changes in the respirable-dust regulation, it has become increasingly difficult. The current most effective practice of dust control at a continuous miner face in an underground mine is the use of a flooded-bed scrubber. A study carried out by the National Institute for Occupational Safety and Health (NIOSH) stated that a flooded-bed scrubber, under its optimum condition, can achieve cleaning efficiencies between 58 and 90 percent. The performance of such a system can be maintenance intensive. Other industries face similar dust control issues. The University of Kentucky partnered with Toyota Motor Manufacturing for the development of a novel wet scrubber for capturing paint overspray, with capture efficiencies in excess of 98 percent and minimal maintenance. The aim of this study is to assess the ability of this novel wet scrubber to capture respirable dust in an underground coal mine. This paper presents the conceptual design and the computational fluid dynamics (CFD) modeling of this novel wet scrubber. It discusses the results of the CFD simulation performed on the novel wet dust scrubber. INTRODUCTION Dust generation from underground coal mining is an inescapable phenomenon. No matter the practices employed, it inevitably occurs. Elevated concentrations of coal dust are potential health and safety hazards. Although dust in an underground coal mine cannot be completely avoided, its influence can be mitigated through good engineering practices. The effect of dust on the health of mining personnel has had a significant impact. The prolonged exposure of airborne respirable dust (< 5 µm) can cause coal workers’ pneumoconiosis (CWP), silicosis, emphysema, and chronic bronchitis, collectively known as black lung (U.S. Department of Labor, 2014). According to the National Institute for Occupational Safety and Health, black lung has killed more than 10,000 miners between 1995 and 2004 (NIOSH, 2008). In addition to being a health issue, coal dust is also a safety issue to the underground coal miners. The generated dust, if not captured, is dispersed into the mine air through the ventilating air and deposited downwind on the return entries’ surfaces. In the event of a methane explosion, the coal dust, if insufficiently diluted with rock dust, triggers a coal dust explosion which is much more severe than a methane explosion and causes more damage (Kenneth et al, 2006). The Jim Walters No. 5 Mine and the Upper Big Branch Mine disasters which together killed 42 people and resulted in damage worth millions of dollars in property are the examples of coal dust explosions (U.S. Department of Labor, 2001 & 2010)."

Jan 1, 2016

By Jürgen F. Brune, SAMUEL A. LOLON, ADITYA JUGANDA, Gregory E. Bogin Jr

Historically, there have been many occurrences ofmine fires and explosions recorded in the United States and other countries that have demonstrated the existence of explosivemethane–airmixtures, herein referred to as explosive gas zones (EGZs). The risk of mine explosions can increase if the EGZs migrate out from the gob into the surrounding mine entries. Fluctuating barometric pressure is the common cause for EGZs outflowing or outgassing from the gob. Numerical analysis using a 3D computational fluid dynamics method was developed to fully understand the outgassing phenomenon. A number of simulations using various magnitudes and periods of barometric pressure changes indicated that the EGZ outgassing potentially occurs due to lags in pressure, which are strongly influenced by mine conditions and ventilation systems. An early warning system with a real-time pressure monitoring and the application of gob ventilation boreholes are recommended to detect and mitigate explosion hazards from gob outgassing.

Aug 24, 2020

By H. G. Linge

Pyrrhotite (FeS1+x ,0<x<0.15) is an iron sulfide which is considered to be a pest in carbon-in-pulp/ leach (CIP/L) gold processing [l].The perceived influence of pyrrhotite on gold processing by CIP/L is a competing consumption of 02 and CN­as the pyrrhotite dissolves by oxidation [1,2]. The few studies of the oxidation chemistry, kinetics and mechanism of the oxidation ofpyrrhotite are reviewed in detail elsewhere [3].There is broad agreement that the surface of pyrrhotite is very rapidly oxidized to form a thin (e.g. 10 nm) ferric hydroxy-oxide layer which overlays an iron-deficient sulfide lattice covering the original pyrrhotite. The reaction can be summarized thus:

Jan 1, 1995

By Simón Díaz-Quezada, HUMBERTO ESTAY

The heap leaching process has been widely used for recovering different metals since its first application at the end of the 1960s. In Chile, copper production via heap leaching has accounted for between 30 and 40% of annual copper production over the past 10 years. This level of production has been achieved through and supported by the use of a mathematical relation, known as the leaching ratio (LR) or irrigation ratio (IR), which relates operational parameters with metal extraction in a heap leaching operation. This ratio has been used to develop leaching column tests, to scale up results from the laboratory to industrial operations, to design new heap leaching plants, and in metallurgical control and production estimation. In spite of the widespread industrial use of this relation, few scientific studies mention it. This is due to its simplicity and basic theoretical foundations. This disparity between industrial practice and scientific research could lead to operational decisions which lack substantial theoretical support, and to scientific studies which have limited industrial impact. Against this background, several questions arise about the use of the LR: What are the constraints on the use of the LR? Are there practical advantages with respect to reported kinetic models? What is the main reason that industry prefers the use of the LR over kinetic models, which enjoy greater theoretical support? In order to guide its future use, this paper describes the leaching ratio and its current uses and limitations, through a literature review and case studies.

May 2, 2020

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) ammines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Nov 1, 2011

By D. Weston

During recent years there has been a great deal of confusion in the North American mining industry with the introduction of new comminution terminology and claims (without substantiative evidence), for various types of equipment in this field. The authors will attempt to clarify the terminology used, and where possible, give illustrations of plant practice with actual operational and pilot plant data. This is considered necessary in order to obtain a clear picture of the comparison of such equipment to the revolutionary change that the Aerofall Mill has brought to the mining industry.

Jan 1, 1964

By K. E. Burgher

Since World War II, the need for the use of explosives in construction, mining, and quarrying near congested urban areas has increased dramatically. Often times a coal mine, once isolated from a city, finds itself surrounded by residential and commercial structures. The United States Bureau of Mines and others have researched blast design to a point where ground vibration and airblast damage can be avoided. A problem still exists, however. It is the fact that people often react to only the loud noise associated with a blast although it may not cause damage. Most often it is the concussion of a blast, less than 20 hertz and inaudible, that produces damage. Public fear from the "startle" and "fright" of loud blast noise greater than 20 hertz leads to the complaints which are generally unfounded. See Thackray, Touchstone, and Baily (1975) for a further discussion of the startle effects of loud sudden noises. When blasts are designed in accordance with U.S.B.M. specifications, management generally has little to worry about with respect to damage claims. Complaints, however, still arise when the noise is accentuated from the blast. It is meteorological conditions which dictate how the sound levels will propagate. Some mines use small pilot test shots (generally one-two lbs) to determine when atmospheric conditions favor sound travel.

Jan 1, 1987

By J. A. Lepinski

The FASTMETSM Process is a coal-based process for converting iron oxide fines into metallic iron. The end product, direct reduced iron (DRI) is used as a low residual charge material in electric arc furnace steelmaking. This paper describes the FASTMET Process and its potential application in the United States. Operating results from a 175 kg/h process simulator are presented. Characteristics of the end product are discussed. Process economics are reviewed along with plans for scaling-up the process to full commercial size.

Jan 1, 1993

By Dan Wang, Qiuju Li, Xiao Guo

The chemical states and ions interaction were significant interest to understanding columbite mineral/acid solution interface dissolution and reaction. The present research work was focus to explore the specific cations ( Nb5+, Fe2+, Fe3+) distribution near the ferrocolumbite mineral/acid solution interface, and determine these cations leaching sequence in sulfuric acid solution. X-ray photoelectron spectroscopy had the potential to provide detailed dissolution information by resolving chemical state and ion distribution of ferrocolumbite during sulfuric acid leaching process. The binding energy decreased in sequence as Nb5+- O < Fe2+- O < Fe3+- O, and increased in sequence as Fe3+- SO4 < Fe2+- SO4 < Nb5+- SO4 which revealed Nb in ferrocolumbite mineral more easily leached comparing to Fe. The ratio of Fe2+- O/Fe3+-O on leaching residue decreased, and Fe2+- SO4/Fe3+-SO4 ratio increased as sulfuric acid contraction increasing suggested that the Fe2+ oxidized to Fe3+ and released Nb from mineral and dissolved into leaching solution. The ratio of Nb/Fe was lower 0.07 with sulfuric acid contraction increasing which meant Nb dissolution promoted by oxidation of iron. The dissolution mechanism of Fe element in ferrocolumbite mineral was Fe2+- O broken and generated Fe2+. Fe2+ was oxidized to Fe3+ in concentrated sulfuric acid leaching solution. The dissolution mechanism of Nb in ferrocolumbite was that Nb5+- O was directly digested by H+, and the released Nb5+ complex with SO4 2− ion formed cation − anion pairs. The coordination of formation Nb5+- SO4 pairs and oxidation Fe2+ in mineral could promote ferrocolumbite dissolution.

Aug 5, 2023

By J. C. Purcupile

In this time of increased coal demand, a faster and safer method for roof support is needed. This report outlines the preparation and testing of a machine which we feel will help answer this need. The results of the tests are encouraging, and indicate that further exploration of the method should be continued.

Jan 1, 1975