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By Bruce R. Sutherland, Jim B. Ramsden, Gerry L. Bolton

Conductive metal powders are important building blocks for today's micro-electronic circuitry. Formulated into inks, they provide the interconnects needed to complete a complex integrated circuit and the means to enter the world of miniaturization. Traditionally, the inks have been based upon expensive metals such as silver, palladium, platinum and gold because of their excellent electrical conductivity and resistance to corrosion and oxidation. The use of a copper based ink, as an alternative to precious metal inks, recently has received considerable attention. Instability in the prices and limited supply of certain precious metal systems have driven up production costs, making the development of a lower cost copper system more attractive to manufacturers. However, lower production costs are on1 y real ized if performance and reliability can be maintained. While the development has been driven by cost, copper does offer some significant performance advantages over noble metal systems: conductivity as good as silver and 4W better than gold; leach resistance better than silver and equal to gold; stability at high frequencies better than gold or silver; strong film bonding characteristics; and compatibility with most solders. These benefits, however, do not come without cost. The inherently reactive nature of pure copper, while providing unique performance properties, makes it difficult to process. Unl i ke precious metals which can be fired in air, copper would oxidize and so requires special furnaces and atmospheres. Despite these difficulties, the transition from precious metal thick film systems to copper is gaining momentum. Manufacturers of high density, high performance circuitry are exploring the performance advantages of copper over gold and silver and the manufacturers of consumer products are considering the potential cost savings of copper over silver-palladium. Sherritt has developed a fine copper powder for this industry. Through association with the ink manufacturers, it has been found that performance properties of the ink vary with the physical and chemical characteristics of the powder. Production Process The production of very fine copper powders at Sherritt is based upon the disproportionation of cuprous ions as outlined in Equation [1] (1).

Jan 1, 1990

By Eric Leung, Stephen G. Hardcastle, Andrew Dasys

In today's economic environment, Canadian mines can ill afford to neglect their ventilation systems as they can consume 30- 40% of the electricity used in underground mines. In addition, Canadian mines can incur significant heating costs. For mines to be their most cost efficient they must embrace existing and emerging technology to optimize the use of their air; namely, maximizing its work in diluting and removing pollutants, limiting leakage, and avoiding the unnecessary consumption of costly fan pressure all the while ensuring the health of their workforce. Furthermore, in Canadian mines which are heavily dieselized there is great interest within the industry to convert from a rigid quantitative approach to ventilation, based upon engine size, towards a more flexible qualitative approach that provides credit for Clean engine technology" and permits ventilation supply to be driven and based upon pollutant demands. In the future, there is even the possibility that ventilation will only be required to supply oxygen to diesel equipment as the underground hands-on workforce is replaced by surface workers and tele-operation. Such changes will allow mine operators to minimize their electrical usage and operating costs, for in its simplest form the cost of running a fan is proportional to the quantity3; therefore, reducing current ventilation demands or limiting increases brought on by more stringent legislation, can produce very significant cost savings. CANMET, through ventilation surveys and use of its modern 3D-CANVENT ventilation simulator, have been demonstrating to the mining industry how ventilation can be optimally delivered at reduced costs. El-Equip with their leaky-feeder communications and MultiVENT monitoring and control system have facilitated mines to control fans and hence costs, and also monitor such ventilation parameters as pollutant concentrations. These two parties are now combining their efforts to develop an integrated air management system which will be demonstrated at CANMET's Experimental Mine Val D'Or, Quebec. With such an air management system, the ventilation engineer will have: 1) a simple to use simulator to design and test ventilation scenarios; 2) remote controls of fans, doors and regulators to implement changes; and 3) real-time monitoring of airflow, pollutant concentrations, and both vehicle identity and location to show whether changes are necessary. It is only when all three are available, that a mine's ventilation system can be operated at minimum cost.

Jan 1, 1997

By Peter M. Fozzard

A review is made of the actual costs of recent foreign mineral exploration programmes in third world countries. Target identification leading to the selection of areas, or macro-targets, must follow a well planned and defined series of steps. Suggestions are made with respect to this inter-active project development work. Potential revenues in the broad sense will always determine the overall economics of exploration but clear objective philosophy, good planning and adequate financing are essential for exploration success. Considerable opportunities exist for making important foreign mineral discoveries and broad selected suggestions are made for the identification of exploration areas in relation to high-grade and precious metal mineralization.

Jan 1, 1984

Two miners were fatally injured when a pillar bump occurred during retreat mining in a southern West Virginia coal mine. The mine was operating in the Eagle seam with overmining in the No. 2 Gas and Powellton seams. A coal bump is defined as a sudden and violent failure of coal caused by the release of stored strain energy in the pillar. While significant strides have been made by academia, industry, and regulatory agencies to better understand bump conditions and mitigation techniques, coal bumps represent a long standing, highly site-specific engineering problem in which the exact failure mechanism(s) is not clearly understood.

Jan 7, 2020

By Robert F. Droullard

The U. S. Bureau of Mines (USBM) has investigated instrumentation and methods for measuring exposure to radon daughters in underground mine atmospheres. Both personal and area monitors have been studied through in-house and contract research. A field study in uranium mines identified some reliability problems that required additional work for the personal dosimeter systems. Improved versions of continuous working level detectors have been developed and tested for use as area monitors in underground mines. Test results for the personal and area monitors were satisfactory for underground mine applications.

Jan 1, 1981

By Terrence J. Stobbe

On the job injuries to the musculoskeletal system are probably the oldest of the industrial safety problems. Long before we had pinchpoints to guard, chemical vapors to ventilate, and noise to enclose, people were getting strains, sprains, and sore backs from their work activities. In spite of the age of the problem, it remains a long way from being solved. The past ten years have seen a significant commitment by the sci¬entific community to understanding the problem. Engineers, scientists, doctors, and epidemi¬ologists have been involved, and as a result, today we have a much better understanding of the problem. The first step in understanding a problem such as this is to explore its history and epidemiology. The research done by Chaffin (1977), Snook (1970), Ayoub (1978), the ILO (1962), and others, led NIOSH to publish its Work Practices Guide for Manual Lifting in 1981. The guide was based on research carried out in general industry, but subsequent research by Stobbe (1983) and Peters (1983) has suggested that the nature of the problems producing injuries in underground mining is the same as in general industry. The problems are more intense in the mining environment.

Jan 1, 1984

With the dawning of a new century came the beginning of a new era in the coal industry. Instead of the traditional practice of only buying and selling produced coal in the United States, a coal futures market was established. The New York Mercantile Exchange began trading coal futures in July 2001. But, even in this new era, many of the old is-sues that have beset the coal industry still remain, as was evident in2001. Coal production increased to are cord level during 2001, according to preliminary data from the US Energy Information Administration(EIA). Production in 2001 rose by4% to 1.01 Gt (1.12 billion st), compared with 2000 (Table 1). This barely surpassed the previous record level of 1 Gt (1.11 billion st)set in 1998. Coal consumption remained unchanged. The additional production was used to replenish the depleted stockpiles that had resulted after two years of declining coal production and increasing coal consumption.

Jan 1, 2002

By T. E. Mccandless

Detrital minerals of mantle origin have been found in the Green River Basin of Southwestern Wyoming (Figure 1). Pyrope, pyrope-almandine, and chrome-bearing clinopyroxene and orthopyroxene occur on the antmounds of Pogonomyrmex Occidentalis. These antmounds are a common sight throughout the western U.S., and were used by early paleontologists as fossil mammal collection sites. The mound is composed of two types of material; (1) soil excavated during the digging of the nest below the surface (maximum depth 3 meters) and (2) larger grains collected from the surface and placed on the mound, probably to prevent erosion. The selection of grains to armor the mound seems to be based largely on the mean diameter of the grain, with other factors such as weight, sphericity, roundness and composition in decreasing order of importance (Wheeler and Wheeler, 1963). The minerals of this study happen to fall within that mean diameter range. The garnets are found on the mounds as 3-6 mm diameter subrounded to subangular grains. The pyroxenes are also 3-6 mm in diameter and are most commonly subangular laths. The minerals themselves show evidence of abrasion, such as frosted surfaces and rounded edges. Orange peel texture is present on some of the grains, which suggests that kelyphitic rims were once present, but have been removed. Also, no similar minerals were found in sieved soil auger samples to depths of 2 to 6 meters taken near the antmounds. These observations imply a distal rather than proximal source for the minerals. Lamproitic rocks of upper mantle origin are found bordering the "Green River Basin. The best known are the Leucite Hills, a series of ultrapotassic volcanics found on the north flank of the Rock Springs Uplift (Carmichael, 1967). Minor occurrences of mica peridotite and ultrapotassic volcanics are also found on the western end of the Uinta Mountains in Utah (Best, et al, 1968). None of these rocks are known to contain minerals like those on the antmounds. The garnets are comprised of purple chrome pyrope, red chrome pyrope-almandine, and pink to orange low chrome pyrope/pyrope-almandine. Oxide statistics for these groups are summarized in Table 1. These three groups are distinct when their Cr203 values are plotted against magnesium number (Figure 2). The chrome pyropes are highest in Cr203 (1.28-2.66%) and have high, restricted Mg number values (0.781-0.826). The chrome pyrope almandines have similarly high Cr203 (1.29-2.62%) but a lower Mg number range. The low chrome pyrope/pyrope-almandines have the lowest Cr203 content (0.09-0.73) and the widest Mg number range (0.534-0.836). Using the classification scheme of Dawson and Stephens (1975) the chrome pyropes are most similar to garnets derived from kimberlite and from garnet lherzolite, websterite, and harzburgite xenoliths in kimberlite. The chrome pyrope-almandines and the low chrome pyrope/ pyrope almandines are similar to garnets derived from eclogite nodules (Figure 3).

Jan 1, 1984

By T. E. Bernard

Occupying a refuge alternative (RA) is an accepted practice in mine fires and explosions when escape is not feasible. MSHA has promulgated a final rule on refuge alternatives that includes a recognition that thermal environment is an important consideration. To this end, an environmental index was specified. The question remains about how to test a refuge shelter to demonstrate that it meets the final rule. The analysis followed five activities: A. Provide an estimate of heat generated by an individual refuge alternative occupant; B. Evaluate the Steadman Apparent Temperature criterion of 95°F; C. Discuss simulations based on body temperature or skin temperature limits; D. Suggest method of simulating human heat generation during refuge occupancy; and E. Suggest alternative methodologies/criteria for evaluating heat and humidity survivability inside a refuge alternative.

Feb 27, 2013

By A. Juganda, Jr. Bogin, S. Saki, R. Gilmore, J. Brune, J. Grubb, S. Lolon

"In longwall mines, atmospheric or barometric pressure fluctuations can disturb the pressure balance between the gob and the ventilated working area of the mine, resulting in a phenomenon known as “gob breathing”. Gob breathing triggers a gas flow across the gob and the working areas and may result in a condition where a methane accumulation in the gob flows into the face area forming an explosive mixtures. This paper discusses results of Computational Fluid Dynamics (CFD) modeling carried out to analyze this phenomenon and its impact on the explosive mixture development under a bleeder-ventilated longwall gob panel scheme. Modeling results indicate that the gas inflow and outflow across the gob and the formation of Explosive Gas Zones (EGZs) are directly affected by the barometric pressure changes. Methane gas and EGZs in the gob expand out toward the face and bleeder entries during the falling barometric pressure. Where methane zones interface with mine air, EGZ fringes may form along the face and in the bleeder entries. When the atmospheric pressure increases, an ingression of oxygen into the gob is observed that can also increase EGZs in volume. The findings from this study help assess the methane ignition and explosion risks associated with fluctuating atmospheric pressures. INTRODUCTION Methane explosions continue to be a daunting risk for underground coal miners, although the number of related fatalities and injuries in the U.S. coal mining industry has steadily decreased since the establishment of the U.S. Bureau of Mines in 1910. Still, the consequences of a methane explosion are often disastrous with multiple fatalities and property damage often leading to permanent shutdown of the mine. Methane is formed during the coalification process and is released from the coal seam to the mine atmosphere when the coalbed is disturbed by mining or natural causes such as earthquakes. If not properly diluted by appropriate mine ventilation, this methane may accumulate in the active mine workings and gob areas. Researchers at the Colorado School of Mines have developed numerical models showing how and where explosive methane may accumulate in gob areas. Historical mine explosions appear to show a connection between mine explosions and fluctuating barometric pressure as a result of stormy weather. McIntosh (1957), Boyer (1964), and Kissell et al. (1973) studied the influence of barometric drops on major coal mine disasters in the United States prior to 1970. Their statistical analyses found that a majority of these disasters occurred in the fall and winter months when the barometric pressures were influenced by unstable weather conditions and noted increased methane content in the mine workings during times of falling pressure. Studies conducted by Fauconnier (1992) and Hemp (1994) found similar connections between methane explosions and barometric pressure fluctuations in a majority of gas explosions in South African mines. Ten out of twelve major mine explosions with five or more fatalities in the U.S. after 1970 were found to have occurred during the months of November through April when barometric pressure swings were more abrupt and intense (Lolon et al., 2015)."

Jan 1, 2016

By Robert A. Haney, David J. Atchison, Kenneth G. Fields

Mining systems with greater than a 20-foot face advance (deep cut) have become popular due to their increased productivity and safety. The face dust collection system used in many of the mines employing the deep cut systems, incorporates a machine mounted dust collector with either a blowing or exhausting line brattice and a remote control operated continuous miner. In order to characterize and quantify the parameters used to control dust with these systems, the Dust Division conducted studies on four mining sections using continuous miners with deep cut mining systems. On each section, the dust control system incorporated line brattice with a machine mounted dust collector. The remote control made it possible for the continuous mining machine to advance further while permitting the operator to remain under supported roof and away from dust generated during mining. The purpose of these studies was to evaluate the effectiveness of deep cut mining systems using dust collectors to control respirable dust exposure. This paper summarizes the results of the studies conducted. At each mine face workers were sampled to determine their full-shift dust exposure. Additionally, fixed point dust samples were collected at various locations to determine relative concentrations of dust generated from mining. Air quantities were measured at each working place to determine the amount of air delivered to the face area. Evaluations were made by comparing worker exposures to respirable dust samples taken at appropriate locations upstream and downstream of the coal faced being mined. An estimate of the amount of the respirable dust being generated at the face during mining and the amount of respirable dust being removed by the dust collectors was made by balancing the air quantities and the dust concentrations immediately upstream and downstream of the coal face. Results of the studies showed that the dust control systems, were effective for controlling workers exposure to respirable dust. Dust collector efficiencies were determined to be approximately 85 percent. While the dust collectors were effective in removing respirable dust, the success of the systems with line brattice greater than twenty feet from the face, was dependent on the use of the remote control which permitted the continuous miner operator to remain out of the high concentration dust cloud in the working face. Dilution from intake air, combined with the dust collector efficiency, maintained exposure of other section workers below applicable standards.

Jan 1, 1991

By David Hartley

United States Steel Corporation Minntac Mine is located at Mt. Iron, Minnesota, on the Mesabi Iron Range. The taconite pit is two miles long by a mile wide, with a maximum depth of 170 feet. This paper will deal with the radio remote control of locomotives engaged in the railroad haulage of crude ore and waste rock at this property.

Jan 1, 1970

By P. A. Plunkert, D. E. Morse, L. McCartan, J. F. Papp

The mineral sector is a fundamental part of the U.S. economy. It contributes to the real gross domestic product (GDP) at several levels — basic (mining), intermediate processing, manufacturing of finished goods and construction. The real GDP during 2004 increased by 4.4 percent. The nominal GDP was about $11.7 trillion. Housing starts were up by slightly more than 4 percent for the year. And the nation’s unemployment rate decreased to5.5 percent in 2004 from 6 percent in 2003. Interest rates continued to be low (prime rate was 5.25 percent at the end of 2004) but have risen gradually, following rising inflation.

Jan 1, 2005

By M. Radwan, S. Shimada, S. Z. El-Tawil, K. A. El-Barawy, Y. Miyamoto

This study presents the results of synthesizing monolithic siliconoxynitride, Si2N2O, ceramic from a mixture composed of reclaimed silicon and natural desert sand by using the nitriding combustion synthesis method. Single-phase Si2N2O powder was prepared by the combustion of a mixture composed of silicon and pulverized sand in 3 MPa nitrogen gas. The combustion reaction completed in 2 min and the combustion temperature reached 1577°C.The as-synthesized Si2N2O powder is agglomerate of fine particles with sizes < 5 µm and has various morphologies; rod-like and irregular crystals, irregular kinking, hollow crystals and grown pseudo-hexagonal prismatic crystals. Porous Si2N2O compacts (24.5–47.1% porosities) were fabricated from the synthesized Si2N2O powder at different calcia-alumina additives (5–20 wt%) by normal sintering at 1500°C for 1 hr in N2atmosphere.They showed superior oxidation-resistance at high temperatures up to 1500°C in an oxidizing atmosphere of Ar/O2/H2O(70/20/10 kPa).Near-full dense Si2N2O compacts were also successfully fabricated from the synthesized Si2N2O powder with 5 wt% oxide additives by using the spark plasma sintering at 1600°C.DenseSi2N2O had good mechanical properties (18.7 GPa Vickers hardness, 3.3 MPa.m1/2fracture toughness and 363 MPa strength) and excellent chemical and oxidation resistance.

Jan 1, 2004

By G. H. Lewis, C. L. Krcil, N. S. Harding, D. E. Havekotte

INTRODUCTION Limestone injection work was completed in a 440-kW (1.5-million Btu per hour) pilot-scale combustor in preparation for a 50,000-kg/h (110,000-lb per hour) industrial steam boiler limestone injection test program. The main objectives were to: (1) identify the important variables that affect sulfur capture, (2) determine the maximum SO2 removal, and (3) determine the effect of limestone addition on furnace operability and heat transfer. A more detailed report is given by Lewis et al. (1985). The test program was divided into two phases. The objectives of Phase I were to determine the important variables that affect SO2 reduction and to investigate the effect of limestone addition on combustor operation and heat transfer surfaces. The objective of Phase II was to determine, using only the important variables identified during Phase I, the conditions that resulted in the greatest sulfur dioxide reduction. Phase I Test program Using one limestone, five variables were identified as having an effect on SO2 reduction. These are noted with their respective ranges: heat release rate [103 to 166 kW/m3 (10,000 to 16,000 Btu per hour-cu ft)], Ca/S molar ratio (0 to 3), flue gas oxygen concentration (3% to 5%), additive particle size [90% -150 µm (-100 mesh) and 90% -45 µm (-325 mesh)], and burner stoichiometry (SR = 0.75 and >1.15). A 2.3% sulfur northern West Virginia coal, pulverized to a nominal grind of 70% -75 µm (-200 mesh), was burned for the tests. The limestone used was obtained from a Maysville, KY, quarry and contained 51.75% (wt) CaO. An 11-run statistically designed program (plus three duplicates) was used to screen the five variables. The effect of limestone injection on the combustor heat transfer surfaces was determined by comparing the heat transfer rates through a slag panel and fouling probes during periods with and without limestone injection. Combustor operation was determined by noting any operating problems that occurred during the tests. Test procedure After furnace wall temperatures had stabilized at operating conditions, heat transfer surfaces (slag panel and fouling probes) and the convection section were blown clean, and a four-hour test was begun. The

Jan 1, 1987

By Michael Lenz

Predictive maintenance technologies including vibration analysis, tribology, infrared thermography, ultrasonic detection, and electrical measurements have been applied to large electric mining shovels. The predictive program was initiated on the P&H Model 2300 and 4100 electric shovels. The utilization of these technologies has shown the potential for improving electric mining shovel availability and minimizing maintenance costs. Predictive technologies provide the tools to assess machinery condition. Availability is enhanced by the condition based planning of component replacement. Maintenance costs are minimized by focusing resources through condition based prioritization.

Feb 24, 1997

By M. K. Larson

"Specialized numerical modeling codes have been developed over the years to estimate ground stresses during the excavation of coal in underground mines. One of these tools, MULSIM, a displacement discontinuity boundary element code, was last developed by Zipf into a version called MULSIM/NL [USBM 1992a, 1992b]. The code was used frequently in years past, but closure of the Bureau of Mines in 1996 marked the beginning of a pause in its development. A similar tool with distinctly different treatment of overburden idealization, LaModel, was subsequently developed [Heasley 1997] and largely displaced MULSIM/NL in the literature. However, recent work modeling deep western longwall coal mines [Larson and Whyatt 2013] has demonstrated that MULSIM has distinct advantages for regions with relatively stiff and strong overburden. This work required that MULSIM be revived and updated into a version called MulsimNL/Large. Updates include larger array sizes, greater precision, greater number of materials, and the addition of a five-point, six-segment pillar load/displacement model that provides the user a more flexible coal-strength model allowing hardening and softening before a final residual strength. MulsimNL/Large has the ability to calibrate to large load transfer distances observed in some western U.S. coal mines that appear to be caused by strong, massive units in the overburden and/or floor of a coal mine. Also, it provides the ability to calibrate gob stiffness to simulate measurements or estimates of overpanel weight distribution between gob and abutment, while still maintaining load transfer distance with minor adjustments. MulsimNL/Large can easily implement material strengths calculated from various pillar strength models. The five-point model gives MulsimNL/Large the ability to easily simulate pillar behavior that is extracted from detailed pillar models, such as FLAC3D. MulsimNL/Large or similar approaches should be considered for evaluating mining layouts where stratigraphic conditions are known to cause overpanel weight to transfer to an extent significantly longer than the empirical method widely used to calculate load transfer distances in the U.S. [Peng and Chiang 1984; Mark 1987; USBM 1990]."

Jan 1, 2015

Effective gas management in coal mines, as well as proper ventilation design, is very important for maintaining the safety of underground coal miners. Advances in numerical modeling techniques have enabled evaluations of the coal mining environment using advanced grid designs and computed gas distributions through detailed mathematical models. These models help engineers to see the unseen areas of the mine through visualization of the data and ultimately help improve worker safety. This paper summarizes the modeling efforts conducted by NIOSH in the U.S. and CSIRO in Australia to address various gas management issues encountered in longwall mines. The modeling studies involved two of the most widely used grid-based techniques, namely computational fluid dynamics (CFD) and numerical reservoir modeling. This paper discusses the application of these techniques for gob inertization and gas control for spontaneous combustion, pre-mining degasification of coalbeds, gob gas venthole design and performance evaluation in longwalls, and gas management during development mining.

Jan 1, 2009

By M. Adnan Goksel

The hydrothermal agglomerating process described (U.S. Pat. 3,235,371, (1966)) is different from the conventional high temperature processes. Green pellets or briquettes made with mixtures of moist iron ore concentrates and burned or hydrated lime fines are hardened in an autoclave at 198°C and under steam pressure for 1/2 to 5 hours, with or without previous drying. Under the neutral conditions, oxidation of magnetite does not occur as in the conventional processes. The resulting agglomerates are hard and resistant to abrasion and weathering, and they do not disintegrate in the Linder test. The equipment required for the process is not complicated, and favorable operating costs are projected because of the low temperature and efficient heat recuperation. A low capital investment makes the process attractive even when the annual pellet production is below a million tons.

Jan 1, 1968

By L. "Andy" Anderson, Stephen N. Short, James E. Friant

Since the introduction of "boxhole" drilling in South Africa in 1973, the concept of a blind raise, drilled upward from below, has become an accepted mining practice. A combination machine, capable of constructing raises to a mining level below, or blind raising upward from a single setup position adds a further dimension in versatility. A machine with these dual operating modes was designated by The Robbins Company as the 53R and was introduced into the Western Deep Level Mines, South Africa in 1984. The unit is powerful (200 hp) and compact (18,000 lbs., in a 10 ft x 4 ft 5 inch x 4 ft 6 inch package). This paper describes the design considerations for the new machine, provides field data from early trials, and looks briefly at its overall market and potential.

Jan 1, 1985