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By L. Runqing, H. Yuehua, S. Lei, S. Wei

"Tin ore from the southeast of Yunnan in China is a complex polymetallic low-grade ore. Because of the highly disseminated extent ore, cassiterite flotation was applied in industrial production instead of the low efficient gravitational separation. Benzohydroxamic acid (BHA) was widely used as a collector in cassiterite flotation, but the consumption of BHA was large. In this study, the influence of octanol in cassiterite flotation from the southeast of Yunnan using BHA as the collector was investigated. The results indicated that single octanol showed almost no flotation capability to cassiterite without BHA. However a small amount addition of octanol as the auxiliary collector can decrease the consumption of BHA significantly, while did not reduced the recovery of cassiterite obviously. Infrared spectra analysis indicated that the single octanol adsorbed on the surface of cassiterite was unsteady adsorption, and a new entity assembled of BHA and octanol in a well manner was able to adsorb on the surface of cassiterite steadily. The probable self-assembly structure model of BHA and octanol existing on the surface of cassiterite was analyzed. INTRODUCTION Cassiterite is the prime and economic mineral from which tin metal is extracted economically (Qin et al., 2011). The estimated tin metal resources in the world is about 4.9 million tonnes, about 30.5% of which is distributed in China (Mineral commodity summaries, 2013). Cassiterite has many characteristics such as including heavy, hard, and extremely brittle in nature. Hence cassiterite is preferentially concentrated by gravity separators. However, the influence of particle size on gravity concentration is obviously. The separation efficiency is very high for coarse particles while it drops down considerably for fine sizes. (Turner and Hallewell, 1993). Application of flotation and development of selective surfactants have made it possible to recover fine and ultrafine cassiterite from the gravity tailings. A substantial amount of research work on cassiterite flotation has been reported in the past years. The outcome of such research has helped to develop various collector reagents such as cupferron (Vivian, 1927), sodium dodecyl sulfate (Edwards and Ewers, 1951), sodium oleate (Collins et al., 1968), salicyaldehyde (Marabini, 1978), alkyl and aryl arsonic acids (Senior and Poling, 1986), alkyl and aryl phosphonic acids (Gruner and Bilsing, 1992), alkyl sulfosuccinamates (Khangaonkar and Kamarudin, 1994), and alkyl hydroxamates (Sreenivas and Padmanabhan, 2002)."

Jan 1, 2016

By Yu. A. Polozov, V. A. Lagunov, O. Yu. Lushinkova, Yu. I. Svirskiy, Eh. Ya. Kipko, Roy A. Williams

The reliable quality assessment of grouting operations is one of the key issues in establishing impermeable grout curtains around shafts, drifts and tunnels. Reliable opera¬tional information on the decrease in the permeability of rock during the grouting process facilitates the assessment of the effectiveness of the completed curtain and assures production quality. Quality control and assurance also fa¬cilitates the early detection and elimination of possible de¬fects in the grout curtain. Thorough control of the grouting process provides the capability to evaluate decreases in the permeability of water-producing fracture zones prior to the beginning or the continuation of excavation of the shaft, tunnel or drift. In order to achieve this objective, post¬grouting hydrodynamic investigations are conducted prior to the initiation or re-initiation of work on the underground workings to measure the decrease in the permeability coef¬ficient of aquifers during grouting operations. 8.1 QUALITY ASSURANCE AND CONTROL OF THE ISOLATION OF ROCK BY GROUTING THROUGH HOLES DRILLED FROM THE SURFACE Quality assurance and control are based on measuring the decrease in the permeability coefficient of water-pro¬ducing horizons as a result of injecting grout into the drill¬holes. For this purpose, the value of the acceptable residual permeability coefficient is calculated beforehand based on the acceptable value of ground water inflow into the shaft, drift or tunnel as specified by the "construction norm and integrated practice (SNIP)" (Anon., 1976). Having ob¬tained the values of aquifer thickness, permeability, and head distribution for each aquifer from flowmetric data (dis¬cussed in Chapter 3), the average value of the permeability coefficient of all aquifers intersected by the shaft is calcu¬lated as [ ] where Ki is the permeability coefficient of the "ith" aqui¬fer; Pi is the pressure of the "ith" aquifer; and M; is the thickness of the "ith" aquifer. The total expected inflow of ground water into the shaft is [ ] where RK is the radius of the contour of influence; RCFB is the radius of the shaft; and p is the coefficient of dynamic viscosity of the ground water. The necessary reduction of the coefficient of permeabil¬ity of the aquifer [ ] where Q is the expected inflow of ground water into the shaft from eq. 8.2; Q.-fin is the acceptable inflow of ground water; and a is the safety factor. By knowing the average permeability value of the rock and the permeability reduction coefficient, it is possible to determine the value of the acceptable residual permeability coefficient for all the aquifers [ ] The values of the permeability coefficient, pressure, and thickness for each aquifer are determined from the data gathered during the hydrodynamic investigations conducted in grout holes prior to beginning the grouting operations as discussed in Chapter 3. After injecting the grout into the first of the holes, the injection into each of the following grout holes is preceded by repeated hydrodynamic investi¬gations. Using the data obtained for each water-producing zone, a graph is constructed where the numbers representing the grout holes in their order of grouting are placed on the abscissa, and the values of the aquifer permeability coeffi¬cient are placed on the ordinate (Fig. 103). This curve char¬acterizes the change in permeability of the given hydro¬stratigraphic unit as grouting operations are completed, one hole at a time. The results of grouting operations are considered to be positive when each sequential observation records a steady decrease in the permeability of the aquifer. The permeabil¬ity measured prior to the injection of the grout into the last hole must be lower than or equal to the acceptable perme¬ability as determined by the application of eqs. 8.1 through 8.4. Table 8.1 presents illustrative data on the hydrogeo¬logic properties of aquifers at a mine shaft prior to the initiation of grouting operations. Data also are presented on the reduction in the permeability coefficient during the in¬jection of the grout. The shaft in question intersects eleven aquifers. Based on data concerning aquifer pressure, thick¬ness, permeability, and the expected inflow rate of water for each of the strata, the average permeability coefficient is calculated according to eq. 8.1 as K = 0.2 x 10-12 m2. The

Jan 1, 1993

By C. P. Boddy

One of the most difficult tasks a project manager will have in pre-mine planning is dealing with the mine site's hydrologic regime. Numerous federal statutes passed by Congress in the last decade have made the coal mining industry more responsive to the environmental impact during all phases of the mining process. Permitting these mines has dictated a cradle to grave approach in dealing with water related issues. This paper will attempt to explore the application of these technology- based laws and their direct application to the unique environment found in Alaska's interior regions.

Jan 1, 1985

By M. F. Werneke

Flotation of the carbonate, oxide and silicate minerals of copper (malachite, azurite, chrysocolla) has been the subject of much research in recent years, but few effective solutions to this problem have been found. With decreasing reserves of sulfide minerals, the economic recovery of these "oxides" appears to be an important source of copper for the future. Xanthates have been known for many years to be malachite collectors (1), but only at very high dosages, or at lower dosages following activation of the mineral by sulfide ion. Dewitt and Batchelder (2, 3) found that chelating agents such as certain oximes were collectors for malachite and azurite, but also required high reagent dosages. Fuerstenau (4) has suggested, for example, that potassium octylhydroxamate may be an effective collector for malachite, On the other hand, Balberyszski (5) has found that oxide minerals may be completely sulfidized at high temperatures with gaseous sulfur or H2S, and then floated with conventional collectors. None of the above approaches appear to offer an economically effective method for the direct flotation of these oxide minerals.

Jan 1, 1977

By WILLIAM M. CROSS, ALBERT ROMKES, BERNARDO MORENO BAQUEIRO SANSAO, Jon J. Kellar

The mineral industry uses significant amounts of water in processing. Thus, sustainable practices with the processing of ores are of critical importance. An impact tester was used to measure the adhesion force between particles and a glass disk [1,2]. A removal force was caused by the impact of the disk/particle containing a puck with a stopper. Johnson-Kendall-Roberts (JKR) theory [3] was used to determine the interfacial energy between the particles and the substrate. Capillary condensation of water can occur between the particle and surfaces in humid environments. The adhesion of particles on rough surfaces has been studied previously [4-10]. The research presented herein combines both variables to separate particle types with minimal water usage.

By Phil Pennington, D. Jack Adams

Mining and processing of minerals, metals, and fossil fuels can release selenium and arsenic into wastewaters. Both selenium and arsenic are difficult to remove to levels that meet current drinking water and discharge criteria. These metalloids can be used as electron acceptors by microorganisms transforming them back to reduced states, thus removing or stabilizing them. Bioremediation cost effectiveness will be discussed in terms of site information required, microbial populations, co-contaminants, pH, redox, and nutrients. Full-scale, economical ex situ and in situ biotreatments are possible and can produce 1,000’s of times less sludge than conventional precipitation technologies.

Jan 1, 2005

By Michael Gilbert

In the world of tunneling the glamour is in the large diameter, long tunnels, but perhaps the number of projects for small diameter and short length tunnels are greater and generally have higher risk factors. Reasons for these higher risks include both the ?boiler plate? contract provisions used on these types of contracts, the technical specifications related to the tunnel work (versus the pipeline construction), the bid practices including measurement and payment and the construction. This paper reviews and comments on some of the key issues the authors have observed in recent major pipe-line projects that involve a small percentage of tunneling footage of the total contract.

By Laura L. Damon, Alastair McNeillie

The use of calcium peroxide for enhanced heap detoxification has been investigated on the laboratory scale using heap leach columns. The addition of calcium peroxide to the ore prior to leaching resulted in a significant increase in the rate at which the leached ore was detoxified and this led to an overall decrease in the total heap leach cycle time. This decrease could allow a minesite to increase the ore throughput or gold leaching time and generate additional revenue. The process is of particular relevance to reuseable leach pad operating though pennanent pad systems could also benefit.

Jan 1, 1992

By Ernest Y. Baafi

The technique of linear kriging as a grade estimation method of mining blocks is reasonably established in the mining industry. Because of the nonbias condition imposed in kriging which requires that the kriging weights (?i) add up to one, negative weights are sometimes used in kriging. The use of negative weights is not justifiable from the practical standpoint. Also, negative block grades can be obtained in some extreme situations which makes no practical sense. To guarantee non-negative weights an additional constraint is required in the kriging system of equations. Unfortunately, the nonnegative weight constraint results in a set of non- linear system of equations. In this paper, a derivation of the resulting set of nonlinear equations is presented and a numerical algorithm is developed for the solution of the equations. Because the algorithm developed does not remove negative weights arbitrarily, optimal nonnegative weights are always guaranteed. Results obtained using the developed algorithm were compared with those using the standard linear kriging, in terms of computer time and the estimation results. Both the computer time and the kriging variance were found to be higher with nonnegative constraint, as expected. However, some systematic pattern was observed in the kriged values (i.e., over or under estimation) with or without the nonnegative constraint. The study also demonstrated when one should generally expect negative kriging weights in practice, and what practical impact the negative weights can have on the kriging estimates.

Jan 1, 1984

By Steve Polegato, J. Coady Marsh, Gary Landry

The Donkin-Morien Mine in Cape Breton, Nova Scotia, has successfully completed the excavation of a 7.6m (25-ft) diameter access decline over a distance of 3.5km out under the Atlantic Ocean. The tunnel, completed in December 1984, was driven through a sedimentary sequence of sandstone, siltstone, mudstone and various gassy coal seams prior to intersecting the Harbour Coal Seam where development work will commence. The tunnel was driven by a Canadian prototype tunnel boring machine (TBM) manufactured by Lovat Tunnel Equipment, Inc., Toronto, Ontario. The 7.6m (25-ft) diameter full-face shielded TBM operated at various grades from 0-20%. This paper outlines the TBM design, excavation, support and backup system utilized in the drivage. Problems encountered and drivage rates will be addressed.

Jan 1, 1985

By Bruce T. Stanley

Though most porphyry-molybdenum deposits lend themselves to various reserve estimating techniques, still there must exist the constant effort to not merely obtain an estimate but rather to obtain the best estimate. To answer the challenge of a complete ore reserve estimation, one must attack the problem with the purpose of obtaining the results closest to reality. What we wish to determine is simple: metric tons (short tons), grade, and kilograms (pounds) of molybdenum contained. In order to effectively accomplish this task, further consideration must be given to the ease of using the information obtained and its inherent reliability. The only known method for ore reserve estimation that supplies the needed results along with its distribution and a measure of confidence provided by sound mathematical backup is geostatistics. The following review is an example of geostatistical application of an ore reserve estimate at the AMAX Henderson mine demonstrating technique, viability, and usefulness of results.

Jan 1, 1979

By Allen H. Gipson

Innovative thinking has led to the development of safe, environmentally sound, and cost effective methods for expanding existing tailings storage facilities (TSF). Three case histories are discussed here to demonstrate methods that have recently been used or are being considered for such expansions. Maintaining the integrity of the structure and reducing costs were primary goals in each case.

Jan 1, 1997

By D. Erik Spiller

A commercialized dry gravity concentrator is operating on an alluvial gold deposit in the Boludo Mining District, State of Sonora, Mexico. The technology base of the process is the Rotary Air Concentrator (a dry circular air jig) that recovers gold from the desert sand resource. An overview of the Mexican operation and the dry concentration technology is presented. Application of the dry technology to pretreat­ment of heap leach feeds and other heavy minerals is a pos­sibility.

Jan 1, 2000

By E. A. Devuyst, G. Robbins

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by G.J. Borberly et al. (1984). The process uses SO2 (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst which can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops wastewaters. The SO.jAir process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful by-products species exist. Consequently final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By A. Juganda, Jr. Bogin, J. Brune, J. Grubb, S. Lolon

"Face ignitions at the longwall face are a serious hazard in underground coal operation that can lead to a major mine explosion. Despite having methane monitoring system mounted on the shearer and at various locations on the longwall face, undetected accumulations of methane can still occur and result in face ignitions. With the use of Computational Fluid Dynamics (CFD), the interaction between the air flow at the longwall face and factors that contribute to the accumulation of methane around the longwall face can be modeled and visualized in great detail. The results confirm that the tailgate corner of longwall face is a critical area that is prone to face ignitions and needs to be properly monitored. The occurrence of roof falls on the tailgate entry inby the face and/or poor caving conditions behind the shields can pose a safety risk in the longwall operation. Poor gob caving can lead to insufficient face air quantity to dilute methane at the tailgate corner, while blocking of tailgate by a roof fall can carry methane contaminated air from behind the shields back into the face near the tailgate corner and pull the explosive gas zones (EGZs) inside the gob closer to the face. INTRODUCTION Ignitions of accumulated methane gas at longwall faces are well known to be among the major causes of methane explosion in underground coal longwall mining operations. Some of these ignitions can lead to major mine explosions, such as the Upper Big Branch mine disaster in 2010, in which methane migrated from the gob to the shearer cutting drum where it was ignited, resulting in a major mine disaster (Phillips, 2012). History has shown that, despite having methane monitoring systems mounted on the shearer and various locations at the longwall face and alarms set to 1% CH4 (Mine Safety & Health Administration, 2012), undetected accumulations of explosive methane-air-mixtures can still occur and result in face ignitions. Recent study by Verma and Brune (2016) state that frictional ignitions on longwall faces contributed to 379 incidents or 23% of the total 1,637 cases of face ignitions recorded from 1983 to 2014. The common cause of mine explosions usually involves poorly designed ventilation systems, insufficient ventilation, and inadequate monitoring in critical areas that are prone to methane accumulations. In longwall operation, the tailgate corner of the longwall face can be considered as one such critical area. On-site studies by Krog et al (2006) and Thakur (2008) show that increasing the longwall panel width may also increase cumulative methane emissions at the tailgate. There are also indications that increasing longwall face lengths can result in an increase of the void space behind the face under certain roof conditions (Schatzel et al, 2006). This may cause higher leakage rates from the face to the gob, thus reducing the amount of fresh air available at the tailgate."

Jan 1, 2017

By J. H. Canterford

To date, large-scale solution mining has received little attention in Australia, although the potential of this technique has not gone unnoticed. The possibility of long-term damage to the local environment has also been recognized. Because no two orebodies are the same, it is clear that the application of solution mining techniques and the assessment of environ- mental damage will be somewhat different for different orebodies, even though the general principles will be the same. At present the most significant copper solution mining operation in Australia is at the Mammoth (Gun- powder) Mine in northern Queensland. This mine currently produces more than 3 000 t of cement copper a year.1

Jan 1, 1981

By J. A. Organiscak

This paper examines methods for limiting occupational silica exposures for roof-bolting personnel in underground coal mining. A canopy air curtain and an air tube were evaluated as means to provide filtered air over the breathing zone of these personnel. Laboratory testing showed that dust reductions beneath the air curtain and air tube approached 60% and 40%, respectively, with low interference air velocities. The data also showed that dust reductions were highest for positions closest to the device and that these levels decreased with distance. This paper also evaluates a metal rake, a flexible insert and a rigid insert for cleaning the roof-bolter dust collector box. Less dust was produced when using the rigid insert. Surprisingly, the flexible insert was sometimes no better than scraping or raking the dust onto the mine floor. However, little dust got on the workers coveralls when using either of the inserts.

Jan 1, 2003

By Gill G. Geesey, Michael R. Hankins, Paul L. Wichlacz, Anita Gianotto, John G. Jolley, Randy B. Wright

Thin films of copper [2.0 nm on germanium internal reflection elements (IREs) and 3.4 nm on germanium discs] were exposed to 10% gum arabic (aqueous solution) , 2% alginic acid (aqueous solution), 1% bacterial culture supernatant (BCS, simulated seawater solution) and 0.5% Pseudomonas atlantica exopolymer (simulated seawater solution). The IRES were monitored in situ, in real time using fourier transform infrared/cylindrical internal reflection/attenuated total reflection spectroscopy as a function of time at ambient conditions. The discs were characterized (pre- and post-exposure) by X-ray photoelectron and Auger electron spectroscopies. Ancillary graphite furnace atomic absorption spectroscopy was used to monitor the removal process of the copper thin film from the germanium substrates. Results indicate that Cu was oxidized by gum arabic, alginic acid and BCS. Furthermore, Cu was removed from the Cu/Ge interface by all four polymers. The Cu was found associated with the polymer solutions.

Jan 1, 1989

By J. A. Organiscak

This paper examines methods for limiting occupational silica exposures for roof bolting personnel in underground coal mining. A canopy air curtain and an air tube were evaluated as means to provide filtered air over the breathing zone of these personnel. Laboratory testing showed that dust reductions beneath the air curtain and air tube approached 60 percent and 40 percent, respectively, with low interference air velocities. The data also showed that dust reductions were highest for positions closest to the device and that these levels decreased with distance. This paper also evaluates a metal rake, a flexible insert, and a rigid insert for cleaning the roof bolter dust collector box. Less dust was produced when using the rigid insert. Surprisingly, the flexible insert was sometimes no better than scraping or raking the dust onto the mine floor. However, little dust got on the coveralls when using either of the inserts.

Jan 1, 2002

By Charles E. Mongan

The problem of roof control in the coal-mining industry is of major importance inasmuch as 65 percent of all coal-mine fatalities result from falls of roof, face, or ribs. The Health and Safety Research and Testing Center of the Federal Bureau of Mines at Pittsburgh, Pa., is engaged in several programs directed toward increasing safety in coal mining. The Roof Control Research Group has 4 programs aimed at reducing roof fall accidents. One of these programs is the use of sonic techniques to explore mine roof strata.

Jan 1, 1961