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By C. Villa Diniz, A. H. Martins, Fiona M. Doyle

It is proposed that battery grade MnO2 can be produced directly from a manganese ore from Azul Mine in Brazil, by leaching with HCI to remove heavy metals selectively. We are working to find a way of selectively separating Cu, Ni, Co, Pb and Fe from the resulting acidic manganese chloride solution, to detoxify it and produce marketable chloride solution. Chelating ion exchange resins are proving more promising for this separation than solvent extraction with commercially available reagents. Results from batch and column ion exchange tests that characterize the behavior of copper, nickel, cobalt, lead and iron are reported.

Jan 1, 1999

By D. Jacobson

There are many different machine design parameters and variables that affect the production of cone crushers in a mineral processing plant. One of these variables is the speed at which the cone gyrates. In June 2012, pilot tests were conducted to determine the production and operating conditions over a wide spectrum of speeds. mining operations will have variations in the ore characteristics and feed rates that result in non optimal use of the crushing energy and inconsistent process control. This study documents the measured variation in production and energy efficiency with two operating modes. Overall, the results match the theory, and the capacity and power fluctuated by 25% and 17%, respectively, when operated at full capacity, with an overall trend of slightly coarser discharge size distribution as the speed decreased. Using a fixed feed rate, the crushers had 4-14% higher production when operating at the optimal speed. Secondary analysis showed that the power draw consistency and magnitude of power spikes could also be improved by optimizing the cone speed. Varying the speed of the crusher can be used to tune the crusher during commissioning, adapt to changing ore conditions over long periods of time or be used as a dynamic input into an advanced control system. each action above would serve to make the crusher(s) more productive, more energy efficient, impove process control and would also have mechanical benefits for the machine

Dec 1, 2013

By R. G. L. McCready, G. Dr. Heinrich, V. I. Lakshmanan

The objective of this study was to prove repeat loading capacities of physically stabilized fungal biomass from Penicillium sp. for the removal and recovery of uranium from mine water (Denison Mines). The testwork was carried out on a bench scale in small columns and proved that it is possible to stabilize the biomass in an inorganic compound. A lifetime of 10 loading-eluting cycles of the stabilizer biomass product was obtained by additional pretreatment. Sodium carbonate proved to be an effective elution medium. Loading and elution can be controlled by the pH values of the column. The effective loading capacity until the breakthrough point is approximately 70 % of the overall loading capacity. The loading capacities of the stabilizer biomass product are comparable to that of the original biomass. Uranium recoveries of 90 to 99 % were achieved during the loading and eluting under optimized conditions. Depending on the used biomass the described process might be applicable to remove uranium or other dissolved heavy or rare metals from effluents.

Jan 1, 1989

By Lee W. Saperstein

P.L. 95-87 contains explicit demands for land-use planning in its reclamation and designation sections. Both sections require recognition of local land-use plans; however, the sections are not well integrated. Accommodations to these planning requirements may be found in suggestions based on British mineral planning practice. Better links can be created among local land-use planners, the state's permitting authority and designation office, and mine designers. Mining companies should take more interest in local land-use plans and in resource inventories; states should consider devolving to local government responsibility for accepting mine permit applications and designation of unsuitability petitions.

Jan 1, 1982

By Mustafa Yalçin, Ali Ihsan Arol

Coconut shells are the most widely used raw material for the production of activated carbon used in the gold production by cynanide leaching. There have been efforts to find alternatives to coconut shells. Shells and stones of certain fruits, have been tested. Although promising results to some extent were obtained, coconut shells remain the main source of activated carbon. Türkiye has become a country of interest in terms of gold deposits of epithermal origin. Four deposits have already been discovered and, mining and milling operations are expected to start in the near future. Explorations are underway in many other areas of high expectations. Türkiye is also rich in fruits which can be a valuable source of raw material for activated carbon production. In this study, hazelnut shells, peach and apricot stones, abundantly available locally, have been tested to determine whether they are suitable for the gold metalurgy. Parameters of carbonization and activation have been optimized. Gold loading capacity and adsorption kinetics have been studied.

Jan 1, 1995

Operation of a pilot-scale Floatex density separator was studied using a pyrite concentrate slurry feed. Experimental measurements were further utilized in parameterization of a hindered settling simulation model. The model incorporates particle slip velocity calculation and also a separation efficiency function, adjusted to describe the feed material characteristics. The model was used to compute the overflow and underflow compositions when both fluidization bed pressure and teeter water flow rates were varied. In addition, prediction accuracy and the model validity were evaluated. The simulations gave good results when the teeter interstitial velocities were moderate enough to avoid excessive turbulence in the fluidization. Prediction of the cumulative overflow and underflow size distributions in most experiments yielded essentially less than 10% relative error between the sample data and the estimated value of the 50% passing sizes.

Jan 1, 2011

By R. Mensah-Biney

The kinetics of gold-bromide loading onto activated carbon has been investigated in a batch stirred reactor. The amount of gold adsorbed by the carbon was correlated with time based on a second-order equation. The rate constant for gold-bromide species onto activated carbon ranged from 0.27 to 1.2 x 10-3 (kg/t)-l(min)-l from a solution containing 25 ppm of Au, with 0.8 g carbon per liter of solution at 30° C. The equilibrium saturation capacity (Q.) was 36±3.0 kg/t from the same system. The rate of loading increased with decreasing particle size, decreasing pH, increasing temperature, and decreasing concentration of gold in solution. The calculated activation energy E. was 8.8 kcal/mole, significantly higher than those reported for physical adsorption. The equilibrium saturation capacity (Q.) increased with increasing concentration of gold in solution, but was independent of other variables such as temperature, agitation speed, particle size and pH. These rate constants and equilibrium saturation capacity for the gold-bromide species are higher than those reported for the gold-cyanide systems.

Jan 1, 1996

By A. L. Hinde

Ideally, mill circuits should be controlled so that excessive random disturbances are reduced in frequency and amplitude. It is difficult to derive an objective measure of the effectiveness of any chosen control strategy. Often, the response of the circuit to pulse or sinusoidal disturbances is used as a measure of the effectiveness of control, but this is not adequate in many circumstances because such disturbances bear little resemblance to those that occur in practice, and such an approach cannot be easily related to the profitability of the reduction process. A superior approach appears to be the application of the theory of stochastic processes. This theory permits both real process disturbances to be modelled accurately, and useful objective functions for control to be derived. A test of the usefulness of stochastic theory in mill control was made on the gold ore milling circuit shown in Figure 1. This circuit was fed with an ore which had a liberation characteristic such as that shown in Figure 2. It is simple to show that, for such a liberation characteristic, the recovery of valuable mineral will vary as the standard deviation of the particle mass-size distribution varies even though the mean particle mass-size is kept constant. Similarly it may be shown that excessive perturbations in the circulating load in a milling circuit such as that shown in Figure 1 can affect liberation. Figure 3 shows how, as the cyclone feed density increases and the sump water addition decreases at constant sump level, the cyclone operation becomes unstable and the discharge "ropes? with a consequent catastrophic coarsening in product size. By minimising the variance of the circulating load it is possible to reduce the probability of initiating instabilities of this nature.

Jan 1, 1977

By H. E. Goetzman

A cooperative research project supported by the taconite industry and the Minnesota DNR was undertaken to establish quality standards for carboxymethyl cellulose (CMC) based organic binders. The objective of this study was to identify the effect of CMC quality parameters such as degree of substitution, molecular weight, and purity as well as the effect of inorganic extenders such as sodium carbonate on performance. These factors have been evaluated by green-ball testing with two taconite concentrates followed by pot-grate tests. Balling tests with bentonite and Peridur were conducted to provide baseline data. At a constant DS the molecular weight as measured by viscosity had the greatest effect on green-ball drop strength. Dry-ball compression strength was most dependent on CMC addition rate and sodium carbonate content. DS was not found to have a major effect on green-ball quality for medium molecular weight CMC.

Jan 1, 1988

By E. Valdiviezo, J. F. Oliveira

Adsorption of residual flotation reagents onto equilibrium fluid cracking catalysts is a promising method of purification of flotation process water. In the present paper, adsorption of sodium dodecyl sulphate (SDS), dodecyl ammonium chloride (DAC) and sodium oleate onto a spent catalyst from petroleum industry was studied by analysing the residual concentration of the surfactant after contact with the zeolite catalyst. The adsorption of the DAC was rather low but SDS and sodium oleate presented a high affinity for the catalyst surface. The loading capacity was 4.2 kg/ton for SDS and 5.5 kg/ton for oleic acid. After the treatment of the loaded catalyst with a HCI 1 N solution these surfactants are desorbed and the catalyst may thus be regenerated. This would be an additional advantage to its low cost, not to mention its condition as a discarded product and its availability in large tonnages.

Jan 1, 1995

By H. Y. Yang, L. L. Tong

For gold recovery, a Chinese refractory, high-sulfur gold concentrate was subjected to biooxidation with high pulp density in a single stirred-tank reactor. The flotation concentrate contained 36.9 percent sulfur (S) and 33.9 percent iron (Fe). Different experimental regimes for biooxidation were applied. With a mixed culture and by controlling the amount of addition of the gold ores and the pH of the biooxidation system, maximum iron oxidation of 82.6 percent and sulfur oxidation of 79.3 percent were achieved. The experimental results indicate that the pH control was beneficial to the biooxidation of this concentrate. Approximately 28.4 percent of elemental sulfur (S8) was found in the oxidizing slags. Two dissolution mechanisms of elemental sulfur are proposed: (1) FeS2 → S80 → S2O32− → SO42− and (2) FeS2 → S80 → SO42−. The high pH had a positive effect on the reduction of the S8. The results of thermodynamic analysis indicate that as an oxidant the dissolved oxygen can effectively reduce the Gibbs free energy of the pyrite oxidation process and, compared with the reaction of ferric iron as the single oxidant, the oxidation of pyrite is easier. The efficiency of the gold recovery was related to the iron oxidation as well as the sulfur oxidation. Gold and silver recoveries of 92.4 percent and 66.4 percent, respectively, were achieved.

By P. G. Tzeferis

Factory beet molasses media were used as cheap sources of sucrose for microbial leaching of Greek nickeliferrous laterites using strains of Penicillium and Aspergillus sp. Nickel recoveries of up to 62% and cobalt recoveries of up to 50% were obtained by leaching in a two-phase system in which bioacids were produced by fungal metabolism in molasses ferrocyanide pretreated media. The addition of potassium ferrocyanide to the molasses substrates prior to leaching was found to have a beneficial effect by increasing the level of citric acid bioproduction, thus improving the leaching efficiency of the fermentation liquid. The metals known to interfere with citric acid production (i.e., Fe, Cu, Ca and Mn) were those most efficiently precipitated. Considering the much lower commercial price of molasses in the industrial market compared to sucrose and glucose carbohydrate media, molasses could prove to be a promising alternative, despite the cost of the required pretreatment.

Jan 1, 1995

By W. J. Whiten

A rule-based control system was developed for a 7-foot Hydrocone crusher with automatic set regulation, based on operating data collected in the field. When implemented in a plant PLC, the system was found to behave as predicted. Benefits included a significant reduction in the frequency of control actions, the incidence of power overloads, and the standard deviation of feeder speed, whilst maintaining crusher performance.

Jan 1, 1992

By Matthew A. Omofoma, Andrew P. Hampton

The application of the Cyprus Cyanisorb process was investigated using a pilot scale facility at the NERCO DeLamar Silver Mine (DSM) in Owyhee County, Idaho. The purpose of this process is to remove cyanide from the DeLamar mill tailings slurry prior to its introduction to the tailings impoundment. This will maintain the tailings impoundment solution in a detoxified condition and thus prevent migratory bird mortalities. The cyanide removed is to be collected and recycled to the mill. The process successfully recovered approximately 90 percent of the weak acid dissociable cyanide (WAD), reducing the effluent tailings cyanide concentration from about 300 ppm to less than 20 ppm. This was accomplished by stripping the slurry with air in a packed tower and recovering the volatilized HCN in a packed absorption tower. Data were obtained for the design of the full scale facility including the stripping and absorption towers, currently under construction at the DeLamar Mine site. Finally, test results indicated that the final pH of reneutralization can be optimized to provide for minimal gold and silver losses, while selectively precipitating unwanted metal impurities (Zinc, Selenium, Iron, and Copper) from solution

Jan 1, 1992

Current scrubber capacities vary from 1.89 to 4.72 m3/s (4,000 to 10,000 cfm), and there is interest in using scrubbers with capacities up to 6.61 m3/s (14,000 cfm). This paper describes research to compare the effectiveness of blowing and exhausting face ventilation systems using high-capacity scrubbers with flows up to 6.61 m3/s. Tests were conducted in a surface ventilation gallery with exhaust and blowing systems operating under similar conditions. The mining machine was equipped with a machine-mounted scrubber. Methane gas was released at constant flow at the mining face and measured at several face locations. Effectiveness of exhausting and blowing systems was compared by determining average face methane concentrations. For each operating condition tested, blowing ventilation was more effective than exhausting for controlling face methane levels. Raising scrubber flow to 6.61 m3/s reduced methane levels for both blowing and exhausting systems.

Jan 1, 1996

By Kenneth N. Han

The effect of anions such as sulfate, chloride, and nitrate on the solubility of rare earth element-bearing phosphates and fluorocarbonates has been examined using relevant thermodynamic data. The study has found that these anions have significant influences on the overall dissolution of rare earth elements (REEs) from various sources in the aqueous media. The thermodynamic calculations in this study have indicated that the speciation of REEs with the anions tends to increase the overall solubility of the REE-bearing minerals. However, in some cases, strong precipitation of REEs with some of these anions causes an adverse effect on the solubility of these elements. It has been found that sulfate ion has the most pronounced effect on the solubility compared to nitrate and chloride, in which the latter two acids exhibited almost identical results. The calculated results have indicated that REE-oxide (hydrated) is the easiest compound to dissolve, followed by carbonate, phosphate, fluoride, sulfate, fluoro-carbonate, and oxalate in that order.

By Toyohisa Fujita, Mitsuo Mamiya, W. Tai Yen, Hiroki Kogita

Green algae taken from an acidic mine drainage and blue-green algae taken from an alkaline hot spring stream were collected and tested for their ability to recover or remove dilute metal ions. Experimental results demonstrated that unwashed blue-green algae and washed green algae effectively adsorbed base metals ions and eluted them at pH 1. It was also found that washed and dried algae adsorbed precious metal ions more effectively than unwashed algae. For example, the washed and dried blue-green algae was capable of adsorbing 0.31 kg of gold per kg of algae. The gold from tetrachloroaurate solution which was adsorbed on washed blue- green algae was found to change to a metallic state following initial metal binding. In the case of a dilute gold complex solution leached with thiourea, only a small amount of gold could be captured by algae. Further experiments were conducted on components of the algae, such as alginic acid, agar, cellulose and chitin and mixtures of these components, in order to determine their contribution to metal adsorption characteristics. However, a mixture of these two components demonstrated both good adsorption and desorption characteristics indicating an interaction between the individual components.

Jan 1, 1995

"Iron ore is the source of primary iron for the world’s iron and steel industries. Its production can be reported as crude ore, usable ore or iron content of ore. Historically, the U.S. Geological Survey (USGS) used reported crude ore production from China in tabulations of world iron ore production while other countries have typically reported their production in terms of usable iron ore. When China’s crude ore production was tabulated with usable ore production from other countries, world iron ore production totals have been overestimated by 10 percent to a high of content and may include products such as concentrates, direct-shipping ore, pellets, and sinter.• Iron content, also referred to as metal content or grade, denotes the amount of elemental iron in the crude or usable ore.BackgroundIron ores consumed in the steel industry typically require an iron content greater than 58 percent before being considered commercially usable. Iron ores that are not commercially usable must undergo beneficiation to raise the iron content. Approximately 98 percent of the world’s usable iron ore production is consumed in blast furnaces to make pig iron, which is further processed to make steel.High-grade iron ore mines can supply usable iron ore, known as direct-shipping ore, to blast furnaces, with minimal physical processing and no beneficiation. With direct-shipping ore, the reported production for crude ore and usable ore are the same. Ore from low-grade deposits must undergo beneficiation to increase the iron content before it can be used by the steel industry. In this instance, the mined material is called crude ore and post-beneficiation concentrates are called usable ore; the amount produced will be less than the crude ore amount. With the notable exceptions of countries such as Australia and Brazil, most of the world’s iron ore deposits are low-grade and require beneficiation."

Feb 1, 2017

By Heribert F. Broicher

As of 1998 German companies have been engaged in research and development of LIF analyzers for rock identification, i.e. for the fingerprinting of rock by the analysis of laser-induced fluorescence (LIF). Test work in Germany, Sweden and South Africa showed the potential of this new technique, which operates online and in realtime (1). In 2003 the Finnish company IMA Engineering Ltd Oy commenced building and marketing LIF analyzers under the trade name OreSpex. Today, one OreSpex analyzer has been installed in the Kiruna Mine, Sweden to check the phosphorus content of train loads. In 2004 a second OreSpex analyzer was built for dilution control in the Argyle Diamond mine, Australia. In 2005 another LIF analyzer will be used for test work in various mines in the US. The principles of the technology and status of ongoing work are presented.

Jan 1, 2005

By F. A. Kruse, R. J. Madrid, P. L. Hauff

Sub-microscopic gold grains in disseminated gold deposits in Nevada are often directly associated with the clay mineral illite. Delineation of gold ore-zones can be improved by accurate characterization of the associated illite varieties or polytypes. X-ray diffraction studies of clay minerals from several disseminated gold deposits demonstrate that illite polytypes reflect lateral and vertical zonation around the ore bodies. Polytypes act as geothermometers indicating temperatures of ore deposition and proximity to hypogene and supergene fluids. Visible/near infrared spectral measurements using a field-portable reflectance spectrometer provide a reconnaissance technique for mapping the in-situ distribution of illites. Changes in the visible/near-infrared reflectance spectra are observed as illites progress from the lower temperature, less ordered 1 M variety to the higher temperature 2M type. The combination of the reflectance spectroscopy with the X- ray diffraction data creates a powerful tool for detailed mineralogic mapping for gold exploration.

Jan 1, 1989