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By Martino Scialpi, Miriam Piemontese, Claudio Cimiotti, Matt Kendall, Nicholas Karlin, Roberto Schuerch

The Los Angeles, California JWPCP effluent outfall tunnel will transport secondary-treated effluent from the Joint Water Pollution Control Plant in Carson to the White Point Manifold. Upon completion, through ground conditions ranging from soils to hard rock, the tunnel will be approx. 7 miles (11 km) long with a finished internal diameter of 18-ft (5.5 m). This paper will present the Tunneling Condition Assessment Report (TCAR) and Tunnel Operation Plan (TOP) developed prior to construction, as well as the actual TBM performances achieved along the northern portion of the alignment in soft ground, shallow cover, and beneath a densely urbanized area.

Jun 23, 2024

By A. D. S. Gillies, A. Haghighat

"A study has been undertaken at the Missouri University of Science and Technology (MS&T) limestone Experimental Mine to determine new fans set up and wiring options.to install additional mine ventilation capacity. Selection for main fans has been undertaken according to the mine’s required performance specifications and fan characteristics. Available fans for ventilating the mine are Joy and Alphair axial fans each of 24 kW each and two Spendrup booster fans of 12 kW each. The installation of main mine fans on the surface and underground entails numerous considerations. Design of a ventilation network for the Experimental Mine incorporating surface and booster fans has been accomplished using Ventsim Visual program software. The ventilation network has been separated into two segregated parts. A main surface fan and a booster fan have been used in each segregated part of the network. The mine has had a vane axial Joy fan in place for many years. The Alphair 4800 VAX 1800 full blade adjustable pitch vane axial fan was selected and installed as the other surface fan and eventual replacement for the Joy fan. Main surface fans have been connected individually to booster fans in series. The Alphair main surface fan has been installed vertically. Four different wiring options and related cost estimations for addition of the new main fans to the ventilation network have been considered. The analysis resulted in an innovative steel frame design used to allow the fans, when necessary, to be moved to the side of the shaft so that blast pressures do not damage the blades. INTRODUCTION Main fans are the heart of a mine’s ventilation network and play a key role in supplying required airflow (Haghighat, 2014). The Missouri S&T Experimental Mine has been developed in uniform limestone with few stratigraphic features. The mine floor is approximately horizontal and water drains well. A study has been carried out on MS&T Experimental Mine. Selection of main fans has been undertaken according to the mine’s required performance specifications and fan characteristics. Ventsim Visual computer simulation has been used to assist in design of the ventilation network. Wiring circuits, fan foundations and flexibility have been considered as the three main parameters for surface fan installation at the Experimental Mine. Two surface and two underground wiring options and three surface set up options and related cost estimates for the new surface fan system were investigated. Frequent use of explosives in the mine occurs throughout each year. Flexibility in changing the position of a surface fan is important. A number of options have been considered for the location of a vertical main fan positioned on the upcasting shaft. The mine is used for a variety of purposes and flexibility has a high priority amongst design considerations."

Jan 1, 2015

By J. A. Marts, R. C. Gilmore, Jr. Bogin, S. A. Saki, J. F. Brune, J. W. Grubb

"Most, if not all longwall gobs contain explosive gas zones (EGZs), i.e., zones of explosive methane-air mixtures that can cause – and have caused – mine fires and explosions. If the coal is prone to spontaneous combustion, oxygen penetration into the gob must be avoided. This paper summarizes the significant research findings from five years of computational fluid dynamics (CFD) modeling research conducted at the Colorado School of Mines (CSM) under funding from the National Institute for Occupational Safety and Health (NIOSH). CSM Researchers have developed CFD modeling techniques to identify where and under what circumstances EGZs can form in longwall gobs and how EGZ formation and oxygen penetration depend on the ventilation method, face and bleeder ventilation parameters, injection of inert gases and the operation of gob ventilation boreholes. Recognizing these explosion and fire hazards is an important first step in improving the safety of longwall coal mines. CSM modeling research has shown that EGZ formation can be effectively controlled by adjusting ventilation parameters, choosing the proper ventilation pattern and injecting inert gases where necessary. INTRODUCTION In a project sponsored by the NIOSH Office of Mine Safety and Health Research, researchers at the Colorado School of Mines have examined gas compositions and flows in longwall gobs in order to assess explosion and fire hazards. Since gob areas are inaccessible, researchers developed a series of computational fluid dynamics (CFD) numerical modeling tools to characterize these hazards. A variety of CFD models were developed to cover progressively sealed as well as bleeder ventilated gobs for both coal and trona mines. The explosion and fire hazards posed by EGZs in longwall gobs can be summarized as follows.• If the EGZ lies closely behind the longwall face, flames and pressures from an explosion can penetrate the shield supports and reach the active face area, creating blast trauma, burn hazards and toxic, unbreathable atmospheres. • EGZs can be pushed around inside the gob by roof collapses and cave-ins. If they get pushed out into the face area, sudden methane inundations and explosion hazards in face areas can result. • Fresh air flowing into the gob can create an explosion hazard as the gas composition in the gob moves from fuel-rich inert to explosive, creating EGZs. • Ignition sources inside the gob can be frictional ignitions or spontaneous combustion. • Bleeder ventilated gobs are surrounded on all sides by an EGZ that forms along the fringe areas between the fresh-air ventilated bleeder entries and the methane-rich interior of the gob. It is suspected that diffusion flames can propagate rapidly along these EGZ fringes if an ignition occurs"

Jan 1, 2015

By Guy Reed, Russell Frith

In situ or pre-mining horizontal stresses are arguably the least well understood of the principal inputs into underground coal mining geotechnical engineering design, whether analytical, empirical, or numerical. This is a direct result of both the cost and difficulty of obtaining meaningful stress measurements, the various limitations of the measurement method in terms of sourcing strata types that approximate the assumed conditions of the post-measurement mathematics to convert measured strains into stresses, and a common practice by some geotechnical professionals to preferentially utilise generic values rather than interrogate the available measurement data for cause and effect relationships between horizontal stress magnitudes, directions and a range of associated controls. That numerical modelling simulations attempt to mimic reality but often rely on simplified generic horizontal stress input assumptions is a particular cause for further consideratio The paper attempts to further explore the nature of in situ horizontal stresses using a range of stress measurement results from the Australian coal sector supplemented by several international studies addressing the same basic issue, the result being a number of credible and highly relevant “cause and effect" inter-relationships between the three principal in situ stresses in addition to the influence of rock properties (e. Young's Modulus and Poisson's Ratio), cover depth and the larger-scale structural geological environment. In particular, the paper demonstrates that despite being commonly overlooked as a primary rock/coal material property, Poisson's Ratio and the associated K Effect are intrinsic to understanding 3D in situ stress measurement results and therefore, predicting in situ stress magni- tudes more generally for geotechnical analyses purposes. As a fundamental question, the paper addresses whether it is necessary and of engineering value to characterise in situ horizontal stresses: according to distinct "domains," in the same way that more easily identifiable geotechnical properties such as rock mass ratings, coal seam thickness, ply splits, and cover depth are often treated.

Jun 25, 2024

By Daniel Hodouin, Claude Bazin, Sami Makni

SCOTT COULTER: Thanks, Eric. Thank you all for coming. Our first speaker today is Claude Bazin. Claude received a degree in metallurgical engineering in 1980 from Laval University in Quebec. He worked for a short time in a mineral processing plant and then returned to Laval to complete graduate studies in the field of process modeling and control. He obtained his master's degree in 1983 and his Ph.D. in 1990. In 1987 he joined Brunswick Mining, New Brunswick, as research metallurgist and subsequently process control engineer. In 1990 he joined Helzfield Mines, New Brunswick, as senior metallurgist. In 1991 he accepted a position of professor at the department of mining and metallurgy at Laval University, a position he is still holding. He's a member of the CIM, TMS, and the Society for Mining, Metallurgy, and Exploration. Claude's topic today is "On-Line Material Balance for Flotation Plants." INTRODUCTION CLAUDE BAZIN: During the last two decades, the on-stream analyzer (OSA) has gained the stat& of key instrument for the control of flotation plants. The OSA is currently used in almost every sulphide flotation plant (Leroux and Franklin 1994), and its application to oxide mineral flotation plants is increasing. The OSA assays are sent to the flotation operators via an operator console or to control loops of various degrees of complexity (McKee 1991) implemented in a distributed control system (DCS). Operators and/or controllers take control actions based on these assays to ensure an adequate operation of the plant. Although this application pays off very rapidly for the purchase of the OSA, one could ask, "Could we get more from the OSA?" Some plants reported the use of OSA measurements for process optimization (McKee 1991). The optimization strategy is based upon economic indices calculated from metal recovery using the 2-product formula (Wills 1992, p. 124). The 2-product formula is sensitive to measurement errors in the assays and can lead to considerable scatter in the calculated indices (Hodouin et al. 1993). Least squares algorithms provide a robust alternative to filter out measurement errors (Spring 1992). This paper presents some applications of a recursive least squares algorithm that provides real-time estimates of the mass flow rates within a flotation plant using OSA and mass flow rate measurements.

Jan 1, 1998

By Nathaniel Arbiter

The question of automation of concentrator operations with computer control is under increasing consideration. Some of the problems involved will be discussed from the viewpoint of the availability of the requisite, detailed knowledge of the unit operations. The justification for full-scale automation of a mill must ultimately be economic--an increase in profitability over and above the cost of instrumentation and development, Potential savings would be in three probable directions: decrease in operating labor costs by substitution of machine control; improved metallurgy through continuous effective control; and decreased operating costs by achieving higher unit capacities and process efficiencies.

Jan 1, 1962

By Quispe Mamani, Mayra Casas Azañero

The research is located within Asuncion and Cospan districts, which according to their geological features in contrast with previous studies pointing out Au, Mo and Pb anomalies create an environment of prospective interest. The objective is to use ASTER Satellite Images to identify ore-bearing hydrothermal alteration zones. To do this, processing techniques such as the combination of bands by RGB 943 and 461, band ratio 4/6, 4/5, 5/8 and 2/1 to identify advanced argillic, argillic to phyllic and propylitic alterations. In addition, indices defined by Ninomiya were used as a third technique in order to reinforce the data obtained from the previous techniques. The results in the study area are confirmed by the SAM spectral mapping technique using spectral signatures from the USGS library. Identifying kaolinite, alunite and pyrophyllite, assemblages of the advanced argillic alteration. Concluding in 3 areas of interest with the band ratios, 5 areas with the Ninomiya indexes and 9 areas validated with SAM, which were contrasted in 13 areas of prospective interest with well-marked argillic alteration.

Feb 1, 2025

By L. G. Austin

A simple finite difference algorithm has been used to compute a simulation model for unsteady-state ball milling. The model considers the mill to act as if it were three fully-mixed reactors in series (one-large/two- small), it incorporates the-Rogers-Austin mass transfer law relating mill hold-up to flow rate through the mill, and it allows for the reduction in breakage rates caused by over-filling of the mill at high flow rates. The computation is rapid and requires only small storage space. Examples are given of use of the model.

Jan 1, 1984

Software exhibitors at MINExpo will feature the newest, the best, the most comprehensive computer-based tools available to get minerals from the ground to the market. From the ?cloud? to the pit, the variety that will be featured is almost limitless ? a digital tool for every phase of the mining lifecycle. Blue Sky Network SkyRouter brings the Blue Sky Network to the cloud. Using its interactive Web portal, SkyRouter, with detailed mapping and integration with Google Earth, the Blue Sky Network links enterprises to personnel and assets anywhere on earth through Iridium satellites. The cloud-based solution is designed to support connectivity with remotely dispersed mobile assets, including Blue Sky?s dual-mode GSM and Iridium tracking and communications services. This enables seamless connectivity with assets in problematic cellular reception areas, where only 10 percent of the Earth is covered, and in remote locations.

Jan 1, 2012

By T. Gupta, T. Ghosh

"In recent years, the demand for Rare Earth Elements (REE) have grown rapidly due to increasing demand and global supply shortage. The supply deficit of these critical elements has encouraged the search for new sources of REEs, possibly Coal and Coal byproducts. Coals from certain parts of the world can be rich in REEs, and can approach a total concentration of 1000 ppm. Two Alaskan coal samples were investigated for the effect of size and density on the concentration of REEs on three selected size fractions. Flotation tests were conducted for finer fractions. Additionally Bottom ash and Fly Ash samples from a power plant have been examined for REE concentration. The results show that the upgrade potential for REEs on ash basis from whole coal basis ranges from 2:1 to 4:1 for Wishbone Hill and Healy coal samples respectively. Flotation of the finer fraction for both coal samples, conducted under similar conditions, reveal higher concentration of REE’s in the tailings. Both coal samples have a comparatively higher LREE content than HREE. Trends of REE content of the power plant products on ash basis revealed that Fly Ash has a slightly higher concentration of both LREE and HREE than Bottom Ash. Keywords: Rare Earth Elements, Coal, Coal Ash INTRODUCTION Rare Earth Elements (REEs) and their compounds are vital components in industrial, automotive, petrochemical, defense and medical applications. Dysprosium in combination with other elements is used in laser materials and nuclear control applications. Neodymium is present in magnets that are used in green power generation such as the manufacture of wind turbines and also in hybrid cars. Europium, Terbium and Yttrium are used for devices that have visual displays such as computer screens and laptops [1, 2]. REEs pose fewer environmental problems of disposal and recycling than conventional heavy metal counterparts [1]. Rare-earth metals are key ingredients for radar systems, avionics, modern national defense and satellites [2-8]. In the last 25 years China has been mining, processing and refining Rare Earth elements at affordable prices thus gaining a virtual monopoly in the market. The many fold rise of the prices of REE elements over the last few years and frequent disruptions in supply has forced various nations to invest in indigenous extraction of REEs by increasing production from previously productive sites and to expand the production from new alternate sources including coal and coal byproducts [9]. Coal and Coal beds have been found to be significantly enriched with certain critical metals and can be a potential source for both Light Rare Earth Elements (LREE) and Heavy Rare Earth Elements (HREE) [10]. Moreover, coals with high REE concentrations have been discovered in Pavlovka and Rakovka coal deposits in Russia, Appalachian deposits in USA, Sichuan Basin deposits in China and others across the globe [10-13]. A recent study from China looked at how different trace elements (including numerous REEs) partition in various size fractions of Antaibao coal from China. The finding indicates that the REEs, phosphorous, and thorium all have their high concentrations in the particle sizes 0.5 to 3 mm, and 6 to 25 mm. REEs are also often present in the form of phosphates such as monazite in coal [13, 14]. The objective of the study is to identify the concentration of REEs in Alaskan coals and to investigate the effect of density and size in the distribution of REEs in coal and coal byproducts."

Jan 1, 2016

By H. M. Woodrooffe

In the U.S.S.R. three of the world's major-known phosphate deposits are located. These have an estimated reserve of 2,600 million short tons of contained phosphorus. The best known lies in the "Khibiny Massif', an alkalaic rock formation some 600 square miles in area with mountain peaks rising to an altitude of 3300 ft above the surrounding terrain. Location and Climate The Khibiny Massif lies north of the Arctic Circle in the Kola Penin-sula, 100 miles south southeast of Murmansk, at a latitude of 67° 30' north and a longitude of 35° 30' east. It is serviced by rail from Murmansk and Leningrad (900 rail miles south). Figure 1. The phosphate operations are centered about the two cities of Apatity and Kirovsk. The former has a population of 35,000 and is on the Leningrad¬Murmansk railway. Kirovsk, 15 miles to the east, is now a city of 85,000. The region is at the limit of the tree line with most of the ground cover typical tundra. The mean annual temperature is -4°C and, in a normal year, precipitation occurs on 240 days. Because the temperature does not exceed freezing for 300 days each year, virtually all of the precipitation is snow. The two towns are nestled between mountains and, because of the weather, extensive avalanche control systems incorporating major engineering construction have been introduced to divert snow slides away from the populated areas. General Kirovsk was first settled in 1923 and the apatite occurrences were recognized shortly after. In 1933, the first concentrator for the recovery of the mineral was completed, producing in its first year of operation 170,000 tons of concentrate. With the growth and demand for phosphate in the U.S.S.R., a second concentrator was erected at Apatity. It calve on stream in 1963. Because of the severe climate, in the early days mining was limited to 85 days per year. With the introduction of new techniques and improved mining methods, the season has been extended to 115 days.

Jan 1, 1972

By R. L. Keiski, H. Miettunen

"The serpentinite massifs of Hitura are located in the municipality of Nivala in Central Finland. The most important sulfide minerals in the ore are pentlandite, pyrrhotite and chalcopyrite. The ore body consists of amphibolite rocks in contact with serpentinite against mica gneiss. The mean Ni grade of the ore is about 0.7%, and the highest Ni grades have been encountered in close contact. In general, the inner parts of the ore are strongly serpentinized ultramafite and some sulfides have been converted to mackinawite and valleriite. The degree of alteration varies considerably within the ore body and, correspondingly, the grain size of the sulfides varies as well. In this study, flotation tests were done with samples from different zones of the ore body. The flotation test results on the bench scale and plant scale are discussed in terms of the mineralogical features of the ore. Ores in the North Hitura zone differ from those in the South Hitura zone.IntroductionThe Hitura nickel mine, like the entire Nivala area, is part of the Bothnian Svecokarelian schist zone, where numerous Ni-Cu boulders have been discovered since the early 1930s. The Nivala area has therefore been the subject of exploration activities by the Geological Survey of Finland (GSF) and mining companies. The first period of exploration started in 1936, and the Makola nickel deposit, located 3 km south of the Hitura mine, was discovered by GSF in 1937. About 415,000 tonnes of ore were mined at Makola between 1941 and 1954. In 1937, during the exploration and development stage of the Makola mine, boulder tracing and a geophysical survey revealed a significant ultramafic body with some lowgrade Ni-Cu occurrences in the South Hitura zone.In 1961, GSF continued the exploration program in the area and discovered the North Hitura ultramafic complex and its allied Ni-Cu occurrences. In 1964, Outokumpu Oy bought the property and, after underground exploration, comprehensive mineralogical studies, process research and a feasibility study, production started in 1970 (Isohanni et al., 1985)."

Jan 1, 2015

By Yashar Pourrahimian, Magreth S. Dotto

Fragmentation by blasting is a critical process in hard rock mining. The blasting process and outcomes are highly influenced by rock mass properties and their response to higher stresses and loading rates. Each rock mass is unique, but some features affect the blast energy similarly, leading to similar outcomes. Having analyzed these features and their influence on blast results, they can be incorporated into the blast design to achieve better outcomes. This paper presents a numerical model validated by a case study from the actual mine blasts that studied the effect of rock mass properties on explosive energy production, attenuations, and overall blast outcomes. The results show that when the model parameters are calibrated based on real data, they can be used to simulate the fragmentation process and therefore be used to aid blast design.

Jun 25, 2023

By R. L. Grayson

A goal programming-based worker scheduling model has been incorporated in the Mine Management Support System (MMSS) for assigning workers to prioritized jobs on a shift basis. In the model the accomplishment of each regular and non-regular job is a goal. The objective is minimization of the deviations away from the goals. A number of coefficients are used as premultipliers of the decision variables in order to address practical considerations associated with the utilization of workers and the requirements of jobs. Some of these premultipliers will be updated expertly within MMSS, timely updating the statuses of the dynamic parameters.

Jan 1, 1991

By Luc Morin

What you don't know won't hurt you! This attitude can get you into trouble when considering your process! When trying to extract the most and the best possible performance from a mineral processing circuit this should be reworded to say: What you don't know about your process will hurt your profits! Today, with the popularity of joint ventures, custom milling contracts and process audits by specialists, not knowing is a formula for trouble! Good Sampling Systems are no longer considered a luxury' Not too long ago the practice of grab sampling was considered acceptable and became the norm. Today, it is rare to hear metallurgists say, "All I need is a trend not a good representative sample. so I'll just grab a sample every few hours." Buyers and sellers of quality products have found that grab sampling leads to poor partnerships'

Jan 1, 1999

By John S. F. Dunlop

One of the more difficult problems frequently facing geologists and mining engineers is that of estimating the ore reserves of mineral deposits. Cost conscious mining operations invariably require an accurate knowledge of tonnage and grade for both short and long term planning. A case study is presented, showing how a classical frequency distribution was fitted to a population of drillhole assays. Using these results, a grade- tonnage curve is derived using the Lasky expressions, and the results discussed. A geostatistical analysis is then presented. First, variograms are drawn, models fitted to them and analyses made of drift and anisotropy. Second, simple block kriging is carried out and the results plotted on large 1000 scale plans, suitable for overlay with routine .mine plans. Kriging results are verified using two independent techniques: random kriging on a regular grid and inverse distance weighting. Finally an attempt is made to optimize the drilling grid, and to fully tabulate the total computer running costs for the work described.

Jan 1, 1979

By Andrew S. Prokopovitsh

The Bureau of Mines is concerned with all the approximately 60 industrial minerals, although its research program currently is focused on 10 of them--bauxite, chromite, clay, manganese, phosphate, potash, refractories, sulfur, titanium, and zirconium. To alleviate reliance on imported materials, particular attention is directed to those minerals having a potential for production from domestic resources. Another important consideration is environmental problems associated with the production of industrial minerals, principally in mining and mineral processing operations, The Bureau also is looking at the opportunities to substitute more abundant minerals for scarce raw materials such as rutile, fluorspar, and bauxite. In its overall minerals surveillance, the Bureau's mining and metallurgical research and development are coordinated with its minerals information activities from which reviews, projections, and forecasts identify the potential for critical disruptions and short supply situations.

Jan 1, 1975

By John W. Rushton

Maintenance and inventory are usually the last items considered in mine development. They need to be addressed properly and early. The micro-computer brings sophistication within the reach of even the smallest mines. Maintenance and inventory programs, if properly installed, will reduce costs 15 to 25% and allow management time to address the mining and metallurgical problems at start up. Shops and warehouses are rarely designed properly. Large engineering firms spend 5 to 20 times more than is necessary for first class facilities. There is an optimum design, size, and layout. Take the time necessary to assure you get the right people, programs, and facilities in that order. Maintenance, inventory, and inventory control must be addressed early if a small mine is to have a chance at optimizing costs during the first two years of operation. This is hard work and is usually put on the back burner until the mine is in some degree of trouble. Hiring an experienced maintenance superintendent is important but it is not the complete solution. Maintenance systems, design of facilities, and use of computers are not skills that maintenance people usually have. In addition, the work of ordering spare parts and working with erection people is a full time job and any maintenance people on site during construction are quickly recruited. The end result is that few mines start up with an adequate Maintenance or Inventory System in place. The months, and in some cases years, that the mine attempts to operate without a system are both painful and expensive. Designs of successful integrated maintenance and inventory programs are virtually 100% supported with some outside assistance. Our system is the approach that we are most familiar with and this paper will isolate how Rushton International would go about setting up systems and designing support facilities. Micro-computers are the only way for a small mine to go. ~ini-computers cost more originally and operating costs are many times higher than even the most sophisticated micro system. Micro- computer software is developed further and recent advances in hardware makes medium priced units equal to most mini's in RAW COMPUTER POWER. Mines in general, and especially small mines, have no need for main frame power. MAINTENANCE A good maintenance program has: 1. Equipment Master List a. Equipment Detail Reports 2. Work Order and Backlog Control Program 3. Component Control Program 4. Tire Program 5. Wear Materials Program 6. PM Control Program 7. Maintenance History Program 8. Performance Program We also track miscellaneous items such as MSHA training and inspections, timekeeping, etc. Rather than going through the program step-by-step, it makes more sense to go through a typical Maintenance Day and show how the programs are used. The first thing maintenance supervision needs to know is "how we are doing." We

Jan 1, 1987

By John Murray, Daniel Ebin, Robert Gould, Yiming Sun, Lizan Gilbert

The Atlanta Plane Train Tunnel West Extension is being constructed at Hartsfield-Jackson Atlanta International Airport using the Sequential Excavation Method (SEM). The tunnel has shallow ground cover and mixed-face conditions and passes underneath the SkyTrain and MARTA stations and airport terminal buildings. It includes a twin tube Bifurcation with a span of over 45 feet and ground cover of 12 feet. A flat roof is being constructed at the Bifurcation to maximize rock cover and minimize surface settlements. This paper focuses on design and construction challenges for the Bifurcation and tunneling beneath the world’s busiest airport, while minimizing impacts to operations.

Dec 1, 2022

By S. K. Kawatra, S. K. Valluri, S. J. Root

Common carbon dioxide capturing reagents, such as amines and sodium hydroxide, are expensive, toxic, and energy intensive to regenerate. We have added frothers to a sodium carbonate solution in order to increase the surface area available for CO2 transport within the packed bed of a counter current scrubbing column. Addition of frothers has improved the performance of sodium carbonate scrubbing solutions to be on par with sodium hydroxide scrubbing solutions. This novel enhancement of a relatively inexpensive CO2 capture-regeneration cycle shows potential to allow plants to turn a profit by sequestering a waste product. These results are discussed in detail in the following manuscript. INTRODUCTION The combustion of fossil fuels converts chemical energy to thermal energy. CO2 is produced as a byproduct of the reaction. 80% of the world’s electricity is produced by using this thermal energy to power a generator, accounting for 40% of global carbon dioxide emissions. In an effort to stabilize the rising atmospheric CO2 levels, researchers are investigating the application of carbon capture and storage (CCS) systems in power plants. [1] Efforts to capture CO2 at some power plants have been successful, but the cost of installing and operating the required equipment is high. As such, very few power plants have CCS systems. If CO2 can be captured and processed into a product that can be sold at a profit, installing CCS systems in power plants will be a very attractive business decision. In order for the sale of captured CO2 to become a profitable venture, the cost of capturing the CO2 from a flue gas must be reduced. BACKGROUND The most common method for separating CO2 from a flue gas is by passing it through a counter-current packed bed scrubbing column. The flue gas enters the bottom of a column while a solution of a chemical with properties advantageous to the absorption of CO2 is pumped to the top. The fluids interact in a packed bed, where the CO2 is transported from the gas to the liquid. CO2 is an acid gas, so it is common for the scrubbing solution to be alkaline in nature in order to neutralize the carbonic acid that is formed when it is dissolves into water. The exhaust exits the top of the column free of carbon dioxide, which exits the column in the scrubbing solution, reacting or complexing with the absorbent. Figure 1 is a schematic drawing of a CO2 scrubbing column. It shows the molar flowrates and compositions of the gas and liquid at the bottom [1], the top [2], and an arbitrary height in the column [Z]. [2,15] L is the molar flowrate of liquid at any point in in the column. G is the molar flowrate of gas at any point in the column. Since the CO2 is transported from the gas to the liquid, L and G are variable with respect to height. To simplify calculations, the CO2 free molar flowrates Ls and Gs are often used. X is the fraction moles of aqueous CO2 per mole of CO2 free liquid. Y is the fraction moles of gaseous CO2 per mole of CO2 free gas. Figure 2 is a composition diagram of the scrubbing column depicted in figure 1.

Jan 1, 2019