Search Documents

By K. Avarmaa, P. Taskinen

"The solubilities of rhodium (Rh) in a molten silver alloy in doré-smelting conditions for treating copper refinery slime at temperatures of 1,000 to 1,300 °C were measured using a high-temperature equilibration-quenching technique and direct phase analysis by electron probe X-ray microanalysis. The results obtained indicate that the solubility of rhodium in molten silver is very limited: only 0.04 to 0.26 weight percent at 1,000 and 1,300 °C, respectively. The thermodynamic properties of rhodium in molten silver were estimated from the solubility data. The compositions of the solid rhodium alloys in equilibrium with molten silver-rich doré metal were also measured in this study. The excess rhodium in the doré alloy will precipitate during the refining as solid, greater than 99 weight percent Rh.IntroductionSilver refining is a core step of the processes of anode slime treatment and precious metals recovery in copper refineries (Hait, Jana and Sanyal, 2009; Ludvigsson and Larsson, 2003). It separates the oxidic materials, such as nickel oxide (NiO) and barium sulfate (BaSO4), from metallics after the de-coppering and de-selenation steps of the anode slime, and refines the silver bullion from the undesired elements present (Cooper, 1990; Hyvärinen, Lindroos and Yllö, 1989). Doré metal is a silver-rich alloy which after the smelting step will be refined electrolytically, and the remaining constituents of gold as well as the platinum group metals (PGM) will be subsequently recovered in their own processing stages.Because of low concentrations of PGMs in copper, they are typically soluble in the doré metal in anode slime treatment. This can be concluded from their binary phase diagram data with silver (Massalski et al., 2007). One exception is sometimes encountered in the anode slime smelting operations if the smelter feedstock is rich in rhodium, as may be the case if the raw materials contain secondary raw materials such as e-scrap. The solubility of rhodium in solid silver is less than 0.04 weight percent (Królas and Sternik, 1995), and its solubility in molten silver is highly uncertain. The only experimental information in the literature (Królas et al., 1993; Elliott, 1985) suggests that the silver-rhodium alloy system at 960 °C forms a eutectic, which locates less than 2 °C below the melting point of pure silver (Arblaster, 2015). Early observations (Rössler, 1900) propose that rhodium is insoluble in molten silver even if solid silver-rhodium solutions have been recently produced on a nanoscale (Kusada et al., 2010).The aim of this study is to measure experimentally the solubility of rhodium in molten silver at doré metal smelting and refining temperatures. The silver alloy used to mimic the doré alloy contained silver and about 1 weight percent of the alloying elements copper, gold, palladium, rhodium and tellurium. The experiments were carried out in metal-slag equilibria with nitrogen-oxygen mixtures as the atmosphere, employing an equilibration-quenching technique and using direct phase composition analysis by electron probe X-ray microanalysis (EPMA) (Jak, Hayes and Lee, 1995)."

Jan 1, 2017

By Jamal Rostami, Ataollah Rahbar

"Uma Oya Multipurpose Development Project is under construction in Sri Lanka. This project involves 2 Rolled Concrete Core (RCC) Dams connected through a tunnel currently under construction by Drill and Blast method. The water is transferred from first diversion dam to the 2nd regulatory dam and from which, it will be transferred through a 14 km headrace tunnel to the top of a 650 m deep drop shaft that feeds the high pressure water to an underground powerhouse and turbine chamber for generation of 120 MW of electricity. The Headrace and Tailrace tunnels are being excavated by two 4.4 m diameter double shield TBMs. The headrace tunnel has already passed 5km milestone and is mined in hard rock, while the tailrace tunnel has been completed in rather weak and fractured ground. This paper will review the history of the project along with the geology of the site. The operation of TBM in headrace tunnel will be discussed in more detail, focusing on the challenges of excavating through very strong and abrasive quartzite and gneiss on this site, as well as reaches of tunnel in high inflow of water reaching 400 L/Sec. INTRODUCTION This paper aims to introduce the Uma Oya Multipurpose Development Project (UOMDP) as a hydro mechanical project in Sri Lanka, targeted generating hydro-electric power, transferring water for irrigation purposes and controlling seasonal devastating flood. This project lies in the south-eastern part of the central highland region of Sri Lanka (Figure 1). The main part of the project is located in the south-western part of the Badulla district in the province of Uva. The south-eastern end of the project site is in the central west of the Moneragala district (province of Uva). Bandarawela is the largest urban setting within the project area, located halfway between the upstream and the downstream ends of the planned hydropower plant and combination of dams, tunnels, and downstream facilities. The Multi-Purpose Project Of Uma Oya is planned to convey water from Uma Oya to Kirindi Oya Basin for hydroelectric energy generation includes Puhulpola RCC Dam on the Uma Oya river, Dyraaba RCC Dam on the Mahatotilla Oya river, a conveyance tunnel from Uma Oya to Mahatotilla Oya (L=3750m), a long feeder tunnel from Mahatotilla Oya to Kirindi Oya. The feeder (power) tunnel Lot consists of a headrace tunnel (L=15554m), the surge shaft (L=200m) and tank on the upstream of the vertical shaft, a vertical shaft with steel lining (L=650m), an underground powerhouse and a tailrace tunnel (L=3650m)."

Jan 1, 2016

By K. N. Han, H. C. Cho, R. Kim

"A comprehensive analysis of the effect of OH- on various cations in hydrometallurgical systems has been investigated. Cations chosen for this analysis included groups 1A and 2A, rare-earth elements and other common transition metal ions such as Cu2+, Fe2+, Fe3+, Mn2+, Ni2+, Co2+, Ag+, Cd2+, U4+, UO2 2+, Hg2+, Al3+ and Zn2+. The Newton-Raphson technique was used to calculate and plot various metal species over a wide range of pH. This study has clearly shown that by adjusting the concentration of OH-, the separation of Fe from Mn, U from V, Ce and Eu from other rare-earth elements, and In from Sn is possible. The effects of hydrated metal ions on the separation and removal of various metals from each other under various conditions is discussed.IntroductionThe primary purpose of hydrometallurgical processing is to extract, remove and purify various metals from diverse sources. Hydrometallurgists are frequently preoccupied by the extraction of cations in metallic form, but overlook the important role anions play in such processes. A proper choice of anions can determine the fate of successful extraction, removal and purification of metals (Esmaeili et al., 2005; Brbooti et al., 2011; Wei et al., 2005; Jeppesen et al., 2005; Al-Tarazi et al., 2004), and also separation (Farha et al., 2011; Sevenich and Fritz, 1983; Rashid, 1974) of cations from various solutions.In this study, the authors have examined some of the effects that anions play in various solutions. The anion considered in this study was the first hydroxide, OH-. Other anions, such as Cl-, Br-, I-, and CN-, will be dealt with in the second part of the series of two papers."

Jan 1, 2015

By S. J. Stokowski

An extensive drilling and laboratory testing program indicates that diagenetic dolomitization of the Oligocene Sombrerito Fm. limestone, southwestern Dominican Republic, is detrimental to the usefulness and quality of the potential construction aggregate resource. The first part of this program was the collection, photographing, and geologic logging of diamond drill cores to allow lithologic subdivision of the strata into potential quarry layers. The primary lithostratigraphic units are: I (youngest) approximately 10 m of white, dense marine limestone; II, approximately 5 m of white, interbedded dense and chalky marine limestone; III, 2+ m of tan, chalky calcitic dolomite. Unit I has been often altered by lateritic weathering and/or dolomitization; Unit II is often altered by dolomitization. The quarry layers were individually crushed, by core, into coarse aggregate sizes for chemical and physical (specific gravity absorption, MgSO4 soundness, sand equivalent, and LA degradation) analyses. The non-weathered units decrease in coarse-aggregate yield and quality with depth and dolomitization. Dolomitization typically causes about 5% lower yield of coarse aggregate, a sand equivalent of about 20 units below the original value, an increase in absorption of about 3%, an increase in the LA of up to 13%, and a decrease in the average 5-cycle MgSO4 soundness by about 17%.

Jan 1, 1987

By Shingo Morimoto, Toru Sasaki, Masato Shinji

"1. INTRODUCTIONTunnel face stability is one of the most important consideration in New Austrian Tunneling Method. In general, if all of the material properties of ground can be obtained through the field investigations, the tunnel face behavior can be predicted using numerical simulation prior to tunnel construction. However, estimating the safety of a tunnel face is difficult, especially in cases where the ground is very weak such as in an urban area.In this study, numerical analyses of tunnel excavation in very weak ground conditions, such as a low cohesion and low internal friction angle, were carried out. The relationship between the average shear strain distribution on the tunnel face and the overburden was analyzed. This relationship estimates the shear strain of the tunnel face relative to the critical shear strain obtained by the ground properties. The critical shear strain was defined as an allowable value for the maximum shear strain. We proposed the allowable overburden as tunnel face stability index (TFI) that satisfies the critical shear strain criterion of ground. Finally, a design chart of the allowable overburden for various cohesion values and friction angles of ground was created. This chart is useful in the preliminary tunnel design stage to judge the necessity of additional counter measures against normal tunnel support design.2. WEAK GROUND MODELING AND ANALYSIS PROCEDURE2.1 Setting material propertiesWith reference to a past study1), the material properties were adopted on the basis of material properties in the standard worst rock classification case called “DII”2) for standard support pattern of weak ground in Japan. The typical material properties for “DII” are listed in Table 1. In addition, Fig.1 shows the distribution of the representative weak ground according to cohesion and internal friction angle. When the internal friction angle is relatively high and the cohesion is weak, the ground is categorized as sandy ground. Furthermore, when the internal friction angle is low and the cohesion is strong, the ground is categorized as clayey ground."

Jan 1, 2016

By M. S. Safarzadeh

Over the last fifty years, the treatment of enargite concentrates has not received much attention, primarily because of the availability of other clean concentrates suitable for processing with existing smelting and/or leaching technologies. As traditional copper ores have become scarcer, copper-arsenic ore deposits have garnered more interest. Arsenic release is a significant concern during the treatment of enargite concentrates by pyro or hydrometallurgical methods. Enargite is also very refractive in standard leaching procedures. Thus, economical treatment options for enargite concentrates are needed. Preliminary experiments have shown that the acid bake-leach process could be adapted and used for the treatment of enargite concentrates. In this study, low-temperature (100-400º C) sulfuric acid baking of an enargite concentrate followed by water leaching has been evaluated. The results indicate the thermal transformation of enargite to copper sulfate happens during sulfuric acid baking, with most of the arsenic being released from the concentrate into the gas phase when baking at 400º C. The condition for maximum copper extraction (~100%) from the concentrate was found to be 400º C, a sulfuric acid concentration of 0.5 mL/g and two hours baking time. Part of the arsenic was captured in the form of arsenopyrite (FeAsS). X-ray diffraction (XRD) analysis proved the presence of some arsenic in the form of claudetite (As2O3) in the baked concentrate. Acid baking of pure enargite behaved in a similar fashion.

Nov 1, 2011

By Keith Wallace

Although systematic control of ventilating air currents in underground mines dates back to the Greek and Roman empires, quantified analysis dealing with the cost of providing airflow did not appear until about 1860 when the first fans with acceptable efficiencies became available. Initially, these were introduced to avert methane explosions initiated by shaft bottom furnaces. However, discussions arose on how much coal the steam driven fans consumed in comparison with shaft furnaces in order to produce the sane amount of airflow. Ventilation economics had arrived. In 1981/82 a project was funded by the Department of Energy and carried out at the University of California, Berkeley in order to analyze and compare alternative ventilation designs from the viewpoint of economics and systems efficiency1. This paper highlights some of the results of that study.

Jan 1, 1983

By H. Wilcox, M. Prichard, Y. P. Chugh

Environmental considerations related to the disposal of coal combustion byproducts (CCBs) and the impacts of deforestation associated with the harvesting of timber for utilization as roof supports in mines should become more severe in the future, as landfill space and suitable timber reserves become more scarce. To help address these concerns, lightweight artificial supports, such as post and crib elements, that use large percentages of coal combustion byproducts as aggregate have been developed for use in underground mines. These structural products show equal or better engineering characteristics than timber, and they have the potential to replace timber support in underground mines. CCB-based ultralight structural material (ULSM) has also been developed and commercialized for use in the construction of ventilation stoppings in underground mines. The bulk densities of these blocks range from 0.40 to 0.64 g/cm3 (25 to 40 lb per cu ft) with more than 75% CCBs. Efforts are also given to develop and demonstrate large volume CCB-based subgrade improvement technique for road construction. Soil treated with SIUC fluidized-bed combustion (FBC) fly ash developed an immediate bearing value exceeding 25% with a swelling strain of less than I %, which is greater than untreated soils, and met Illinois Department of Transportation (IDOT) standard specifications. In this paper, development procedures, engineering characteristics and beneficial uses of CCB-based structural products are given.

Jan 1, 2002

By R. Schuerch, C. Cimiotti, G. Anagnostou, J. Nickerson, P. Perazzelli

"This paper presents experiences gained from the construction of the Lake Mead Intake No. 3 project. The 4.7 km long tunnel was excavated with a hybrid TBM (able to operate in both closed and open mode). The tunnel crossed metamorphic and sedimentary rocks under a hydrostatic pressure of about 14 bar. During the excavation of the tunnel the TBM encountered difficult ground conditions caused by a combination of high water pressure, poor ground quality and locally low depth of cover. The adverse conditions required the TBM to be driven in closed mode at very high support pressures (10 – 15 bar) for approximately 60% of the tunnel length. The paper summarizes the main problems encountered during TBM excavation and analyzes the evolution of the TBM parameters over the entire tunnel length. INTRODUCTION The Lake Mead Intake No. 3 project is located approximately 30 km away from the city of Las Vegas in Nevada, USA. The project consists of the construction of a deeper third intake for the biggest reservoir in the United States, which is formed by the Hoover Dam. The construction of the new intake was required due to the constant drawdown of the lake level (more than 40 m in the past 20 years) and the consequent risk that the shallower intakes 1 & 2 may run dry. The project included the fabrication and positioning on the lake bottom of an intake riser, the excavation and lining of a 185 m deep shaft and construction of a 4.7 km long tunnel. One peculiarity of the project is that the water table is located about 140 m above the tunnel elevation (i.e. corresponding to a hydrostatic pressure of 14 bar at the current lake level). The tunnel was constructed using a tunnel boring machine (TBM) able to operate in both open and closed mode (Mc Donald & Burger, 2009). The present paper focuses on the TBM tunneling experience gained from the Lake Mead Intake No. 3 tunnel. The TBM excavation started on December 27, 2011 and finished on December 10, 2014 with the breakthrough to the intake structure at the bottom of Lake Mead. GEOLOGICAL CONDITIONS The assessment of the ground conditions encountered during construction was mainly based upon qualitative descriptions of the tunnel face conditions (during open mode operations) and analysis of the extracted muck (during closed mode operations)."

Jan 1, 2016

By Edward K. E. ] [Williams

Conditioning is any treatment of an ore with or without reagents which affect its floatability. While it can start in crushing or grinding circuits and continue into the flotation circuit, conditioning will refer here only to reagent treatment in an agitated tank designed for the purpose. Such treatment is often unnecessary with sulphide ores and collectors or with amines,* but it has long been recognized as essential with fatty acid collectors in the flotation of non-sulphide minerals, The requirements can be extremely variable, depending upon ore alteration, the presence or absence of slimes, and 1 the minerals to be separated. The study described here was concerned with the recovery of oxidized molybdenum minerals from an ore containing the element in both sulphide and oxidized form. Flotation of the iron minerals with which the oxidized molybdenum was associated was the basis for the process. Recovery and optimum concentrate grade without desliming depended upon a twenty to thirty minute conditioning of the pulp with flotation reagents at forty to fifty percent solids and at high turbulence. The objective in the study was the determination of design and operating criteria for conditioners in order to permit scaling-up of the results without repeating the entire study on a larger scale.

Jan 1, 1968

By Luzheng Chen

Pulsating high-gradient magnetic separation (PHGMS) of fine hematite from tailings was studied using a pilot PHGMS separator to investigate the possibility of its application in industry. The results of this investigation indicate that PHGMS is effective for recovering fine hematite from the tailings and greatly improved the separation performance compared with the conventional high-gradient magnetic separation at the same conditions. By applying the pilot separator with a 1-mm rod matrix to a tailings containing 28.76% Fe, a concentrate assaying 54.35% Fe with 35.89% recovery was achieved. It was found that the separation performance of the pilot separator closely correlates with the main pulsating parameters, i.e., pulsating stroke and frequency. It was also found that a change in the wire diameter of the rod matrix from 2 to 1 mm causes a weak drop in concentrate grade but results in a considerable rise in recovery. This finding proves that the improved performance achieved by the pilot separator is attributed to the pulsating of slurry and to the use of a 1-mm rod matrix. When the first commercial SLon-2500 PHGMS separator with a 1-mm rod matrix was applied to recover fine hematite from the tailings, the results duplicated those achieved with the pilot PHGMS separator.

Jan 1, 2009

By H. P. Knudsen

In most open pit gold mines ore waste selection is based on estimates made from blasthole samples. These estimates frequently are biased. While it is true that high grades and "outliers" can induce a bias they may not be the only reason for the persistent bias seen at many mines. This paper focuses on a source of the conditional bias. In this paper it is shown that the poor blasthole sampling can cause a conditional bias in the estimates.

Jan 1, 1991

By L. R. Stoiser

The mineral resource potential of the Los Bronces deposit was successfully evaluated by an intense, coordinated program over a 37-month period (April 1978-May 1981) as part of an economic feasibility study. The program included more than 120 km of core drilling, 63 km of access road construction under adverse topographic and climatic conditions, detailed geological mapping, plus other related activities. This Tertiary-age copper-molybdenum deposit is composed of an earlier mineralized porphyry-type body intruded in part by a large complex of mineralized hydrothermal breccia pipes. Both intrusive and extrusive igneous rocks are present. Erosion, oxidation, leaching, and supergene enrichment of copper have resulted in a deposit now exposed at the surface that contains more than 368 Mt grading about 1% copper equivalent as sulfides.

Jan 1, 1982

By Russell H. W. Chadwick

Reviewing events in the minerals industry, in economic geology, and in my own exploration work, I find that the most compelling subject for comment is the increasing ferment in ore deposits theory. New discoveries and continued investigations of bedded deposits of lead and zinc, copper, iron, uranium, etc., coupled with the availability of much new and significant data from sedimentary and metamorphic petrology, geochemistry, and oceanography, has led many economic geologists like myself to become disenchanted with former simplistic notions. Now disenchantment among serious people should presuppose both valid objections to the old, and valid new substitutes. I can sum up my own position and, I believe, what most of the recent writers on ore deposits theory are trying to tell us, by saying that a physico-chemical (bench science) approach to a natural science is neither correct nor useful, and that the obvious cure is a return to the study of the geology of ore deposits. More specifically, ore should be viewed merely as an unusual concentration produced, in stages, by the natural processes inherent in the geochemical cycle. In criticizing the conceptual basis of a science, one is involved simultaneously in the inherent character of the science, its subject matter, and the old and new concepts. I have found it impossible to make a clean separation along those lines. As a result, and as the title suggests, these are not-quite-random reflections on genesis, a matter near and dear to all true treasure hunters since Agricola.

Jan 1, 1967

By C. C. Harvey

Asia is experiencing a growth market for industrial kaolins for use in ceramics, paper, plastics and other market sectors. Export and import data for the Asian countries reflects this growth with the Peoples Republic of China as the major exporter of clays and Japan the major importer. The growth in tonnage and product sophistication of kaolins produced on Belitung in Indonesia is typical of developments that are taking place in many locations in Asia. This region therefore presents opportunities for mineral processors and a challenge for the exploration geologist, the mineral processing engineer, the mineral economist and the marketing specialist.

Jan 1, 1996

By Jens Classen, Martino Gatti

"GENERAL PROJECT DATAThe Sparvo Tunnel is part of the “Variante di Valico” project, a new 65km (40mi) highway link between Bologna and Florence, designed to renew the existing A1 route which connects Bologna and Florence. It is composed of 2 x 2,5km (1,55mi) twin tunnels excavated inside a complex geological context, characterized by the presence of a series of surface landslides and methane gas.The inclination is 2,6 % and the minimum radius is 1.400m (4.600ft). The two tunnel tubes were excavated by a 15,6m (51ft) diameter EPB-TBM from summer 2011 to summer 2013. The internal diameter of the concrete lining is 13,6m (44,5ft), made up of precast concrete segments 2m (6,5ft) long and 70cm (28”) thick, being the largest and heaviest segments ever produced. Excavation went smooth apart from initial problems concerning clogging problems and a main bearing damage of the TBM, which are discussed in a further paper during the congress. No structural damage was observed until the end of the TBM drives.SITE OBSERVATIONS DURING THE POST-EXCAVATION PHASEThe first evidence of the stress state of the segmental lining appeared on November 20, 2013 inside the northern tube (1st drive). Ring No. 884 showed obvious signs of overstress, resulting in spalling and crushing of the concrete, and the subsequent bending of the reinforcement, as visible in figure 1.At this time the tunnel invert was already partially backfilled, and construction traffic was running through the tunnel. First safety measures included closing of the tunnel, and initial measurements of the displacements."

Jan 1, 2016

By E. Viet Howard

During the recent expansion of precipitate copper production at the Chino Mines Division of Kennecott Copper Corporation, Santa Rita, New Mexico, local studies of the dump leaching process were intensified. As these studies progressed it became apparent that a reliable method for locating leach solutions within the dump was required, since the contact between leach solutions and the copper-bearing material would determine, in great part, the recovery of values. In the past, the problem of determining leach solution contact has been attacked by various methods, including destructive testing (dump dissection), indirect observation (such as chloride or dye tracers), and mathematical or laboratory model studies. These methods have not proved completely satisfactory for the studies now being developed. Investigation of methods for in situ observation of leach solutions led to consideration of radiation logging in drill holes, which are petro¬leum exploration and development techniques for locating fluids and measuring porosity in the subsurface. Standard oil field logging equipment was leased, modified, and tested. After successful testing, the equipment was purchased for additional studies. Applications and results of the methods are described in this paper.

Jan 1, 1968

By Chee Theng

"Keep calm and carry on mining. That has long been the conventional wisdom in the mining industry, a largely cyclical one that has weathered roller-coaster booms and busts. But in the years from 2002 to 2016, an unprecedented steep rise in commodities prices that lasted a decade and then took a sharp turn downward had made it hard for gold and silver miners to stay the course.“The last 15 years highlighted some of the structural and inherent challenges that our industry has, from product price uncertainty to long lead times to the capital intensity of our business,” said Mitchell Krebs, president and chief executive officer of Coeur Mining, who was the luncheon speaker at the American Exploration & Mining Association’s 122nd Annual Meeting held Dec. 5-9, 2016, in Reno, NV.Looking back, Krebs said, “We were given this enormous gift of a commodities super cycle, and the industry kind of blew the opportunity.” While gold prices rose 319 percent and silver prices rose more than 200 percent over the 2002 to 2016 period, the XAU index of 30 gold and silver mining companies’ stock prices went up by only 20 percent.Entering 2016, precious-metals prices have made a comeback, with gold rallying strongly from a six-year low at the start of the year. This time, the industry is ready. Companies are leaner and meaner, with lower costs, reduced debt and an increased focus on higher grades and quality ounces. Although opportunities were missed in the past, the industry has got its act together and is now well positioned to take advantage of a price upswing and even to show profits when prices fall, as they did in August 2016, pushed down by a strong dollar."

Feb 1, 2017

By H. C. Verakis

Permanent ventilation controls such as stoppings, overcasts, and undercasts for use in coal mines are required to meet MSHA’s safety standards for fire endurance and flexural strength. Due to technological advances in materials and their design for use as ventilation controls, an engineering program was established to evaluate newer or “nontraditional” ventilation controls. The program is intended to assist manufacturers, enforcement personnel and mine operators in determining if “nontraditional” ventilation controls, for example plastic membrane construction and lightweight block, meet the prescribed safety standards. The program is presented with a description of required tests and examples of products evaluated.

Jan 1, 2003

By M. S. Riyazulla

The Hutti greenstone belt comprising predominantly of low-potassium tholeitic basalt has undergone regional metamorphism of a transition zone between greenchist to amphibolite facies. The important mineral constituents of the volcanic suite are amphibole and plagioclase which appear to be the product of regional metamorphism. These minerals have been recognized as the main indicators of metamorphic temperature and pressure. With a view to understand the P-T conditions of metamorphism of the belt, electron microprobe studies were carried out on amphibole and plagioclase and the chemical data was used to decipher the metamorphic conditions. The results obtained indicated a metamorphic temperature of about 6000 c and pressure of 5 kbs. for the Hutti greenstone belt.

Jan 1, 1996