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By R. M. Carland, F. F. Aplan

Six natural zeolites were evaluated for their ability to selectively remove heavy metal cations from solution. Ion selectivity was found to be Pb+2>Zn+2>Ni+2 and Cu+2>Co+2 from their respective solutions. The presence of K+, Ca+2 and Mg+2 in the actual waters to be used may seriously interfere with the ion exchange and elution of cations from zeolites. Zeolites were found not to be effective in removing precious metals from their cyanide solutions.

Jan 1, 1995

By Lawrence A. Ph. D. Hansen, J. David Deatherage

Laboratory testing programs were conducted to investigate the performance under compression loading of several types of geomembranes and geotextiles proposed for use in heap and dump leach projects. Synthetic liners of several thicknesses were sandwiched between representative subgrade soils and cover materials, thus modeling in the laboratory the actual installation conditions expected. Performance was evaluated by visual inspection and vacuum testing. Several testing procedures and equipment were used to investigate the effect of these testing parameters on the predicted performance.

Jan 1, 1987

By Yongqin Zhang

A single bubble released into surfactant solution first accelerates, reaching a maximum velocity then decelerates to reach a terminal velocity. Modeling this "velocity profile" is fundamental to understanding the motion of bubbles in flotation systems. This contribution considers the terminal velocity. Modeling is by a combination of the Navier-Stokes equation for flow around the bubble and the Marangoni effect induced by surfactant on the bubble surface. Numerical simulation is shown to agree with experiment for bubbles in pure water and surfactant solutions.

Jan 1, 1999

By R. Debkowski

The current underground infrastructure of an old monumental salt mine along with using it as a tourist, museum, nature, resort, conference and cultural events place is presented in the paper. At present, mainly in the monumental part of mine, only a small part of the historical chambers, which together with galleries form a tourist route available to visitors. Moreover, the essential activities aimed to make the tourist route more attractive and to change the decor of the underground sites are discussed.

Jan 1, 2006

By Daniel P. Coughlin, Robert C. Thomas, Christopher S. Romanek, Kristian W. Paul

Two separate constructed treatment wetland (CTW) systems receiving the same metal contaminated, acid sulfate water over different lengths of time and at different rates were evaluated for metal attenuation. Both wetlands are the alkalinity generator portion of a succesive alkalinity producing system (SAPS). Sequential extractions are employed to determine phases of metal removal. Results indicate that Fe, Al, Zn, Ni. and Cu accumulate in the organic substrate over time. Manganese accumulates initially, but is not retained in the system over time.

Jan 1, 2000

By P. J. Kientzler, Y. C. Lo

The current study is concerned with the analysis and attempt at simulating the product size distributions obtained from a vibrating ultrasonic device. Systematic experiments of comminution were performed with natural sizes as well as monosizes in order to understand the breakage behavior of the device. A precise analysis of the device's breakage performance in the case of fine grinding of alumina samples will be presented. Initial steps to model the breakage events using a detailed mathematical algorithm will be discussed.

Jan 1, 1992

By V 7. 0 / 300 dpi

In the last ten years the U.S. coal industry has experienced the collapse of several large silos. In addition, other problems such as extensive structural damage, small "live" capacities, inadequate feed rates, arching, coreholes, and particle segregation have been common to the industry. This paper explains the relationship between those problems and stored material properties, silo hopper configuration, silo structural design, and granular flowability. Methods of identifying, repairing, and/or modifying damaged silos, and designing new silos are given.

Jan 1, 1989

By Sukumar Bandopadhyay

A present dominant problem is that of high downtime of the longwall shearer used in the coal production process. The means by which this problem can be overcome are many, but one of, the most important ones is that the-use of an expert system can reduce diagnostic and repair time. In this paper, a fault-diagnostic expert system model is presented. Specifically, the diagnostic architecture of the longwall shearer expert system and its use for diagnostic reasoning are discussed.

Jan 1, 1989

By B. D. Nichols, W. S. Gregory

SOLA-DM is a three-dimensional finite-difference computer code designed to model the dynamics of an incompressible fluid and the transport of discrete particulate material around obstacles impervious to flow. The numerical methods used in this code are described. SOLA-DM was used to predict the particle flux sampled by the 10-mm Dorr-Oliver Cyclone and MINIRAM dust monitors. Various geometric and dynamic variations of monitor and airflow combinations were tested. The code predictions are shown in computer-generated graphic plots.

Jan 1, 1987

By W. V. Harper

The travel path of a freed radioactive particle in an aquifer must be estimated from a limited number of available samples. This paper discusses geostatistical methods that minimize the 'uncertainty' associated with the predicted hydrologic surfaces and the predicted travel path. However, any estimation method will produce a single smooth predicted path. This 'sensitivity' will he evaluated using a geostatistical simulation method. The techniques will be illustrated using published data from the Wolfcamp and Pennsylvanian aquifers in the northern Texas Panhandle.

Jan 1, 1990

By G. G. O. O. Uwadiale

A number of Nigerian iron ore deposits have been upgraded to the specifications of concentrates for the blast furnace and the direct reduction iron- and steel-making plants. Depending on the mineralogy of the ore deposits, the techniques of oil agglomeration, magnetizing reduction, washing and scrubbing, gravity concentration, and reverse froth flotation have been utilized. A mode of distributive management of the deposits, in the direction of their technoeconomic utilization in the country's developing iron and steel plants, is presented.

Jan 1, 1990

By D. E. Ranta, M. G. Schulz

Mining of Molybdenum at Questa, New Mexico has been accomplished by block cave methods since August, 1983. As caving progresses, a periodic geologic evaluation is made of the rock types present in finger raises on the Grizzly Level of the mine. The production maturity of the cave can be monitored by relating this data to geologic cross-sections through the orebody. The draw point mapping program is a simple and effective tool that is used in making draw control decisions at Questa.

Jan 1, 1992

By Ernest Peters

To model the zinc pressure leach, equations have been written that describe the rates of individual reactions taking place, including (a) oxygen mass transfer, (b) ferrous oxidation by dissolved oxygen, and (c) ferric reactions with ZnS and other minerals. In the continuous process, at steady-state, these take place at the same rate, and so the equations can be solved simultaneously. Model calculations using simultaneous equations are shown in graphical form to demonstrate the effect of different variables on the leach performance.

Jan 1, 1993

By H. Barry Holt, Charles A. Bischoff

On November 15, 1990, President Bush signed the Clean Air Act Amendments of 1990. The new legislation is sweeping in its demands for cuts in smog, acid deposition, toxic air pollutants and ozone-depleting chemicals. The Amendments will siqnificantly alter air quality permitting and compliance and are estimted to cost billions of dollars to implement. This article provides an overview and summary of each of the eleven titles of the Amendments. It also addresses how the Amendments will be implemented.

Jan 1, 1991

By David J. Kruse

Accurate field measurements are essential when validating a conveyor design. They are fundamental in determining a conveyor's behavior, its long-term maintenance requirements, and the life expectancy/ condition of the installed equipment. Field measurements are also invaluable in forensic engineering, particularly when vital equipment has failed This paper will discuss a wide variety of data acquisition equipment, field measurement techniques and accuracies achieved State-of-the-art, custom designed monitoring equipment, as well as, ''08-the-shely instruments and sensors, will be discussed.

Jan 1, 2004

By P. R. G. Bak

The integration of interactive computer graphics technology with data analysis tools can assist in the evaluation of deposit models: the super- imposition of mine openings on complex geology can be quickly perceived using dynamic visualisation, colour-coding and transparency control while analysis functions assist in quantifying displayed information. To illustrate the functionality of such integration a research prototype system is presented which allows the interactive visualisation and evaluation of deposit models comprising both structural boundaries and the distribution of continuous properties.

Jan 1, 1992

By K. Hanumantha Rao, K. S. E. Forssberg, H. R. Manouchehri

This paper summarizes the practical considerations of the various electrical separation methods used in mineral processing. The effective factors related to mineral characteristics and equipment attributes are described and analyzed with reference to conventional industrial applications of the electrical methods. Some new aspects of electrical methods application and their potential for mineral beneficiation, apart from the mineral systems that have been successfully beneficiated, are also presented. In addition, wet dielectric separation, which now appears to be promising, is briefly cited.

Jan 1, 2000

By K. C. Liddell

Chemical processing research made notable advances during 1986. This overview is necessarily brief. It is intended, though, to give the flavor of selected areas where recent activity has been high. At the 1986 Annual Meeting of The Metallurgical Society, a symposium was held on hydrometallurgical reactor design and kinetics. R. G. Bautista, R. J. Wesely, and G. W. Warren edited the resultant proceedings volume. This is the first available volume on this subject. It includes 26 papers on fundamental kinetic studies, modeling of reaction kinetics and reactor performance, and pilot and production-scale operations. Metals discussed include silver, gold, platinum, titanium, cobalt, nickel, zinc, copper, manganese, and iron. Agitated tanks, heaps, dumps, pachucas, pressure auto-claves, electrolytic reactors, liquid membranes, and fluidized beds are among the reactor types covered. An international symposium dealt with iron control in hydrometallurgy. It was sponsored by the Metallurgical Society of CIM, the Institution of Mining and Metallurgy, The Metallurgical Society of AIME, and Gesellschaft Deutscher Metallhutten and Bergleute. J. E. Dutrizac and A. J. Monhemius edited a proceedings volume containing 41 papers. These covered many areas of process chemistry, solvent extraction, precipitation, treatment of pickle liquors, impurities, residues and the environment, and process selection. Precious metals Concerning precious metals processing, the US Bureau of Mines IC 9059 is noteworthy. It includes papers presented at a USBM briefing at the Western Mining Conference in Denver. Topics covered included ion exchange, staged heap-leaching direct-electrowinning, and mercury precipitation during cyanide leaching of gold ores. Also dealt with were carbonaceous gold ores, carbon adsorption and desorption, heap leaching, the carbon-in-pulp process, and precious metals recovery from electronic scrap and solder. R. C. Sandberg and J. L. Huiatt (Journal of Metals, June 1986, and USBM RI 9022) developed a method to recover silver, gold, and lead from a complex sulfide using ferric chloride, thiourea, and brine-leach solutions. Gallium Gallium recovery was also a subject of considerable interest. Much information on this topic is proprietary. But two papers described solvent extraction of gallium. V. P. Judin and R. G. Bautista (Metallurgical Transactions B, 1986) developed an equilibrium model to separate gallium chloride from aluminum chloride. Tributyl phosphate was the extractant studied. T. Sato and H. Oishi (Hydrometallurgy, 16, 1986) investigated gallium extraction from sodium hydroxide by using Kelex 100. Data were given on the equilibrium distribution and the extraction kinetics. Galena Interest continues in recovering lead by hydrometallurgical processing of galena. J. E. Dutrizac; S. H. Kim, H. Henein, and G. W. Warren; and M. C. Fuerstenau et al. (Metallurgical Transactions B, 1986) all investigated leaching of PbS by ferric chloride. Dutrizac reported parabolic kinetics and reaction control by outward diffusion of lead through a porous layer of elemental sulfur. Kim, Henein, and Warren, however, reported that two leaching reactions occur. A nonoxidative reaction produces H2S and there is an oxidative leaching by ferric ion. Acid dissolution was found to predominate when the acid activity to ferric activity ratio is high. Surface chemical reaction was reported to be controlling. Fuerstenau et al. also reported that mass transfer through the sulfur layer is rate determining. But they believe that the species transferred are chloro complexes of ferric ion. In other work on lead, A. Y. Lee, A. M. Wethington, and E. R. Cole, Jr. of the USBM described an environmentally acceptable hydrometallurgical alternative to the smelting of lead concentrates (RI 9055). Uranium In spite of depressed prices, much work has been reported on uranium processing. R. G. L. McCready, D. Wadden, and A. March-bank (Hydrometallurgy 17, 1986) described the nutrient needs for in-place leaching by T. ferrooxidans. They reported the optimal conditions for uranium solubilization. L. E. Eary, H. L. Barnes, and L. M. Cathles (Metallurgical Transactions B, 1986) carried out an experimental and modeling study of uraninite dissolution. They concluded that ferric ion preferentially leaches uraninite in pyritic ores. Hydrogen peroxide was found to be less selective. A. Vuorinen, P. Hiltunen, and O. H. Tuovinen (Hydrometallurgy 15, 1986) studied redox and precipitation reactions of iron and uranium in leach liquors. P. T. Chiang (Hydrometallurgy 17, 1986) reported on the effect of uranium loading in the DEPA-TOPO process to separate uranium and iron from wet-process phosphoric acid. F. J. Hurst (Hydrometallurgy 16, 1986) conducted a fundamental study of the separation of uranium from phosphoric acid by DEPA and TOPO. D. E. Chia and W. C. Cooper (Hydrometallurgy 16, 1986) reported on bench and pilot scale work to recover uranium by the HIMIX process. They reported that the acid consumption to produce an eluate suitable for yellowcake

Jan 5, 1987

By N. J. Peberdy, C. N. Moreton, K. C. Garner

Introduction During the past decade a major objective of the process industry has been to use digital computer technology to improve plant operating efficiencies. This objective implied some form of optimization, a concept that has various interpretations depending on the view of the prospective user. For the purpose of this paper, optimization of a process plant is defined as the establishment and setting of plant operating conditions that maximize some mathematical yield function, i.e. maximum profit, minimum residue, etc. Analysis of these objectives and the available design and implementation techniques led to the conclusion that digital computer and optimization techniques are not the stumbling blocks, but rather the development and derivation of the mathematical models of the unit operations and process plants to be optimized. Such models should not only describe the optimized (steady-state) objective, but also how one steers to this state (control algorithm). Due to the multidisciplinary nature of the skills associated with the design and operation of process plants, the development of suitable models by a single discipline, such as the process control engineer, was found to be not only difficult but often impossible, due to budget and human resource limitations. To over-come these limitations, a computer aided design (CAD) tool has been developed. It aims to provide a productivity tool to the various disciplines, at the same time coordinating the technical input from each. The system described is but the starting point in an evolutionary development of a tool that, with use, is becoming more efficient and cost effective to use. Development has become an application engineering activity rather than the preserve of the computer specialist. Project phasing The development of a mathematical description of a process plant requires coordination of information from conceptual design to operation management. The activities required to build and operate a process plant are divided into four basic chronological activities or phases. These activities are often undertaken by different organizations and disciplines. As a result, continuity is often lost with the resultant loss of critical design data. The major activities are considered to be: conceptual and flowsheeting; detailing around the P & ID; building and commissioning; and plant operation. The CAD system described provides a design tool to be used for each of these activities, as well as providing continuity between the activities and the disciplines involved. The heart of the system is the dynamic simulation of the flowsheet. Each of the activities will be discussed, leading to two simple examples that demonstrate the use of the simulator. Figure 1 shows a schematic format of the various activities and the path followed by the dynamic flowsheet simulator in the life of a project. Flowsheet development The prime requirements in the design and develop¬ment of a process flowsheet are • selection of the correct unit operations to achieve the most economic (capital and operating) beneficiation of the specified reserve ; • the sizing of the unit operations to achieve the desired results, as a function of the projected feed rates etc., to handle the time related (dynamics) of the process; and • the production of a set of engineering documents showing the drawn and labeled flowsheet with an equipment list and process specification for each of the unit operations. The question may well be asked at this stage why dynamic flowsheet simulation should be considered when steady state modeling has been found to be adequate to date. With the increases encountered in the cost of capital, one often cannot afford the luxury of designing around the compounding worst case technique. Further, a more accurate design of the control surges can be achieved. No information is lost in that the steady state solution is in fact a subset of the dynamic model. In generalized state space modeling, the differential equations describing the process dynamics are illustrated in the following matrix notation: XDOT=A.X+B.U(1) Y =C.X+D.U(2) where XDOT describes the set of first order derivatives of the system state Vector, and X- is the system state Vector; A - is the system matrix operator which in the general nonlinear case is both a function of X and time ; U- is the process input vector; B - is the input mapping matrix; Y - is the set of observations; C - is the output mapping matrix which maps X - onto Y; and D- maps the input onto the observations. Thus, by time integration of the system dynamic equations, described in (1), the dynamic trajectory away from any set of initial conditions can be deter¬mined. Further, by finding the conditions at which XDOT = 0, the steady state solution can be determined.

Jan 1, 1987

By H. Huang, R. N. Gow

"The reactivity of an enargite mineral electrode was investigated spectroelectrochemically under conditions typically found in alkaline sulfide leach solutions, with pH 11-13 and Na2S additions of 50 and 250 gL-1. A bulk enargite electrode was cycled between 0 and -1,000 mV for each set of solution conditions. Raman spectroscopy was used to determine and compare surface formations against species in mass-balanced EH-pH diagrams generated using STABCAL. Previously, it was determined that arsenic could be selectively leached under alkaline conditions at an average solution potential of -300mV, across the pH range 11-13. Operating under such conditions allowed for the selective leaching of arsenic with elemental sulfur formation. From several of the voltammograms obtained during this current testing, the formation of elemental sulfur appeared at increasingly reducing conditions with increasing sulfide concentration. At high concentrations, copper started to dissolve, possibly as a bisulfide complex, reducing the selectivity of the leach, unlike previous studies. However, the presence of the higher sulfide concentration is also anticipated to prevent passivation by consuming any surface formation of elemental sulfur. This study provides insight into the operating parameters of alkaline sulfide leaching in regards to the selectivity of arsenic leaching, as well as guidance for control of reagents and solution potential and, of course, the need for water treatment afterwards.IntroductionEnvironmental limitations on the pyrometallurgical processing of arsenic-bearing concentrates have forced operations to consider other solutions. Attempts to hydrometallurgically process enargite (Cu3AsS4) fall into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under basic conditions. The authors believe that the selective leaching of arsenic is more amenable because it produces a solid copper phase, preferably chalcocite (Cu2S) or covellite (CuS) that could then be processed using conventional methods already in place in the copper and gold industries. Potential leaching methods include alkaline sulfide leaching (Achimovicovica et al., 1999; Anderson and Twidwell, 2008a,b; Tongamp et al., 2009 and 2010), hypochlorite leaching (Vinals et al., 2003; Curreli et al., 2005; Mihaljovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and acid leaching (Gow et al., 2014b) with or without fine grinding to mechanically activate the enargite surface and increase normally slow leach reaction kinetics (Achimovicova et al., 1999; Balaz et al., 2000; Balaz and Achimovicova, 2006). In this study, the reactivity of enargite under alkaline sulfide leach conditions was examined."

Jan 1, 2015