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By Elif Emil-Kaya

Samarium (Sm), as one of the rare earth elements (REEs), has gained significant attention in the production of samarium- cobalt (SmCo) magnets due to their high corrosion and oxidation resistance, as well as their high-temperature stability. SmCo magnets find applications in various industries, including but not limited to national defense, aerospace, military and medical equipment. Sm and Co have been classified as critical metals due to their economic importance and supply risk. Recovering Sm from SmCo magnets is an effective method to ensure a stable supply. The present study investigates an integrated hydrometallurgical treatment and combustion process for the preparation of rare earth oxide (Sm2O3 ) powders from SmCo. Initially, SmCo powders are exposed to nitric acid, and the resulting slurry is selectively oxidized at 250 °C to obtain Sm(NO3)3 , Co2O3 and Fe2O3 . Subsequently, the selectively oxidized powders are leached with water to extract Sm. Sm2O3 powders are produced from the obtained leaching solution using an energy- and time-efficient solution combustion process. Finally, the optimal conditions for the production of Sm2O3 are identified, and the produced powder is characterized through X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) analysis.

Nov 1, 2024

By A. A. Terchick

It has been reported in the literature that there is a substantial economic incentive for removing sulfur from coal. Therefore, U. s. Steel initiated an investigation to determine the feasibility of lowering the sulfur content of its Pittsburgh-seam coal. Preliminary crushing and washability studies on a representa-tive sample indicated that substantial sulfur reductions could be attained. Figure 1 shows the effect of the top size of a given coal sample on the sulfur content of the float-l.45 specific-gravity fraction of coal. At a top size of 3 inches, the raw-coal sulfur content of 2.32 percent was reduced to 1.64 percent. Crushing to a top size of 20 mesh reduced the raw-coal sulfur to 1.25 percent. Below a top size of one inch, the sulfur content decreased rapidly as top size was decreased. Figure 2 shows the effect of specific gravity of separation on pyritic sulfur. Normally this coal has an organic-sulfur content of approximately 1 percent. As expected, pyritic sulfur was reduced as the separating gravity was lowered for all the various size fractions shown. The rate of decrease in pyritic sulfur was gradual above 1.45 specific gravity, but great below 1.45. Greater sulfur reductions were attained on the coarser sizes with decreasing

Jan 1, 1971

By Barry D. Simmons

The Millenbach copper-zinc orebody is an ideal Canadian example of a stratabound base metal deposit in volcanic rocks. The mine, operated by Lake Dufault Divison, Falconbridge Copper Ltd. is located five miles north of the city of Noranda in northwestern Quebec. The deposit occurs within an Archean volcanic sequence which forms part of regional acidic volcanic center within the Abitibi greenstone belt. Preproduction ore reserves totalled 2,075,000 tons grading 3.5% copper, 3.6% zinc, 1.1 ounces per ton silver, and 0.02 ounces per ton gold. Stratabound lenses of massive sulphides together with underlying stringer sulphides are closely associated with a dome of quartz-feldspar porphyritic rhyolite approximately 3000 feet below surface. The paper describes the presently known geology of the deposit and includes documentation of sulphide mineralogy and textures as well as sulphide/ host rock relationships. The stratigraphy, petrography and chemistry of the volcanic host rocks are described with emphasis on the alteration intimately associated with the sulphide bodies. Although the volcanic stratigraphy is complex within the mine area, the presence of only low-grade metamorphism and the relative lack of structural deformation allow detailed interpretation of geological history. Presently recognized evidence strongly suggests that the sulphides were deposited at and near sea-floor, by hydrothermal solutions. The dome of porphyritic rhyolite appears to have been the most significant factor controlling sulphide localization.

Jan 1, 1975

By R. Schipper

Two bench scale biochemical reactors (BCRs) were operated over a period of 3 months for the removal of uranium, radium, and selenium from mining influenced water (MIW). A BCR is an anaerobic reactor comprised of organic and inorganic substrate including woodchips, straw, sawdust, and limestone. Uranium and selenium are removed in a BCR by biological reduction of oxidized species (i.e., selenite, selenate) to less soluble forms (Pahler et al. 2007, Blumenstein et al. 2008, Rutkowski et al. 2013). It is believed that radium may be removed through absorption to the biomass in the BCR. The bench scale BCRs were constructed of 6 inch PVC columns with a top to bottom flow configuration. The bench influent water consisted of three different water ratios from two adit seeps. BCR hydraulic retention times of 24 to 36 hours were targeted during the study. Influent concentrations ranged from 19 ug/L to 1.86 mg/L for dissolved uranium, 12 ug/L to 270 ug/L for dissolved selenium, and 4.9 pCi/L to 24 pCi/L for radium 226. The average and maximum dissolved uranium removal was 93.6% and 98.5% respectively, the average and maximum dissolved selenium removal was 93.3% and 98.9% respectively, and the average and maximum radium 226 removal was 89.5% and 100% respectively.

Feb 23, 2014

By J. Yao

Synthetic indium-bearing zinc ferrite (IBZF) was mechanically activated by a tumbling mill. Subsequently, the behavior and kinetics of leaching zinc and indium from the initial IBZF and activated IBZF in sulfuric acid solution were investigated. The results demonstrate that the tumbling ball milling enhances the leaching reactivity of IBZF and increases the zinc and indium extractions. The reaction temperature and H2SO4 concentration have an important effect on leaching zinc and indium from the initial IBZF and activated IBZF. The kinetic model -ln(1-x) = kt was used to describe the kinetics of leaching zinc and indium from the initial IBZF and activated IBZF and to calculate the kinetic parameters. The tumbling ball milling causes a decrease in activation energy and reaction order, which indicates that the dissolution of IBZF after mechanical activation by a tumbling mill becomes less sensitive to temperature and H2SO4 concentration. For the zinc leaching, the activation energy decreases from 73.9 to 70.3 kJ/mol and the reaction order decreases from 0.72 to 0.70. For indium leaching, the activation energy decreases from 78.1 to 73.5 kJ/mol and the reaction order decreases from 0.82 to 0.69. It is found that the dissolution rates of the initial IBZF and activated IBZF are controlled by surface chemical reactions.

By J. P. Vandenhoeck

Sizing devices used commercially are unfortunately not 100% efficient, the splits that can be obtained are usually inferior to the results obtained in the laboratory. Often the capital and operating costs of equipment capable of high sizing efficiency cannot be justified by the economics or requirements of the process. To reconcile the desired sizing efficiency needed to obtain optimum process requirements with the sizing efficiency of equipment economically practical, it is often necessary or desirable to predict the gradation and weight splits of the products obtained based on the expectant efficiency of the contemplated sizing device or method. The less efficient the sizing device one must employ, the more important it is to know the results that may be expected for the establishment of the optimum flow sheet and the more difficult it becomes to estimate the results accurately. Air classification equipment which sizes materials by opposing the drag force created by an air stream acting on a particle with a combination of gravitational, inertial or centrifugal forces are substantially less efficient than, for example, a laboratory sieve analysis. Air classifiers allow oversize material to contaminate the fine fraction and leave undersize material in the coarse fraction. The techniques employed to predict the gradation and weight splits obtained from air classification outlined below are adaptable to other sizing devices less than 100% efficient such as screens, sifters and wet classifiers.

Jan 1, 1965

By Robert E. Jones

The barite industry shares with its associates in the minerals industry the impediments of excessive federal and state regulations. We have learned to exist with the Organic Act of 1976, the Mine Safety and Health Act of 1966, and the Multiple Use Act of 1955. I do not mean to imply by the above that all aspects of mining legislation have been detrimental, however, each of you has been subjected to interpretative restrictions by federal or state bureaucrats. As frustrating and costly as this is to the barite industry, it is not the primary problem facing our segment of the industry at the present time. Our major difficulty today deals not with too much government regulation, but with the lack of a cohesive and consistent government energy program. This administration and those that have preceded it have dealt with intermittent energy crises on an emergency basis. If we remove the political rhetoric which has surrounded each of the more recent major crises, we can liken the action of our federal government to that of a rural volunteer fire department which devotes its entire efforts toward extinguishing existing fires rather than the developing of programs designed to prevent future fires. The lack of a comprehensive energy program has created an environment in which long range planning is extremely difficult, if not impossible.

Jan 1, 1983

By Kevin A. Foo, Joseph L. Young, William W. Reid

The title of this paper is "Designing Very Large Bio-oxidation Plants". To our knowledge, only one such plant has been designed and built to date, and that is U.S. Gold's Tonkin Springs plant in Nevada. This plant was commissioned in Spring of 1990 and operated for a short time successfully as a bio-leach plant but U.S. Gold did not have the financial strength to overcome the consequences of construction delays and increased capital cost. The plant has temporarily been 1 put on a standby basis. Recently, < > a potential joint venture between Tonkin Springs Gold Mining Company and Homestake Mining was announced. Homestake will operate the mine with the technology and subsequent improvements would be co-owned by both companies. This paper is not a "how to" type publication because we feel that such an approach could be dangerous if used improperly. Rather, we discuss some of the important aspects of process selection, testing and design that need attention, and some of the lessons learned to date. As with all developments, improvements and new knowledge will accrue as more companies use bio-oxidation technology. The Tonkin Springs plant is fair evidence that bio-oxidation has "arrived" as a technology, and that successful design and operation of plants treating greater than 1000 t/d of feed is possible.

Jan 1, 1990

By Corale L. Brierley

This paper lists commercial bioheap and stirred tank bioleach operations and explains the status of these operations. A total of 17 commercial-scale bioleaching plants have been commissioned. Bioleaching plants are divided into two technology applications: bioheaps and aerated stirred­tanks. In bioheap leaching, secondary copper ores or sulfidic refractory precious metal ores are crushed and bioleached on pads. Stirred-tank technology is used to bioleach base and precious metal concentrates.

Jan 1, 1999

By Kenneth B. DeGraaf

The development of precious metal recovery processes using chloride systems has mostly evolved from the development of chloride based treatments for base metal concentrates or ores. The recovery of silver from chloride solutions within a process designed for the treatment of base metals usually is part of a solution purification stage. This paper discusses the development of the silver recovery stage used in the GCM HydroCopper process.

Jan 1, 1990

By Gary P. Marshall, Jeffery S. Thompson, Robert E. Jenkins

The effectiveness of the new DuPont Passivation Technology in eliminating acid generation from iron sulfides is presented. Passivation is achieved by treatment with a dilute basic perman­ganate solution. This treatment produces a thin impervious layer of iron/manganese oxide on the sulfide surface, providing a bar­rier to the environment so that the sulfide is not available for undesirable reactions such as the production of acid.

Jan 1, 1998

By W. C. Labys

This chapter reports on recent modelling effects to analyze the US steam coal market with an econometric as well as a programming approach. The background to coal modelling is examined first. The particular aspects of the steam coal market to be modelled are then presented and the corresponding coal model described. Empirical results are presented and analyzed. Conclusions are then drawn regarding potential modelling applications in the policy area.

Jan 1, 1979

By Antonio Jorge de Sousa

In order to compare several mining variants, on the point of view of the variability of the ore quality parameters, a conditional simulation technique is applied to a complex pyrite deposit (FEITAIS orebody, Portugal). Exploitation methods such as cut and fill and sublevel stoping are studied by the a.m. methodology. For each mining variant, it is assessed the influence of several mining operators on the variability of grades.

Jan 1, 1982

By S. Dinescu

The paper deals with the modeling of longwall shearer cutterhead interaction with the coal, in order to study the influence of different limiting factors of the haulage speed, and the cutting regime ensuring optimal energy consumption A computer simulation model is used to draw-up the torque vs haulage speed and the haulage force vs haulage speed dependence diagrams, for different strength of coal and different degrees of bit wear.

Jan 1, 2008

By Harry C. Oussoren, James C. Miles

A new seven kilometer long subway line is being constructed through dense glacial soils under a major thoroughfare in Toronto. Eductor, deep well and vacuum wellpoint systems are being used to lower the water levels by as much as 16 metres for the construction of the twin tunnels and associated structures. The design and performance of the dewatering systems will be described. Unanticipated difficulties and their solution will be presented.

Jan 1, 1999

By S. Bhattacharjee, S. K. Singh, R. K. Galgali

A method for the preparation of zirconia- toughened mullite using dc plasma is presented. An indigenously developed 50-kW thermal plasma reactor is used for the preparation of zirconia-toughened mullite using a dissociated zircon and alumina mixture. Both XRD and SEM studies of the product confirmed the formation of mullite and zirconia. The zirconia grew as equiaxed grains of uniform size (~5 µm) in a mullite matrix.

Jan 1, 2002

By Anthony Busigin, Stephen Pogorski, Colin R. Phillips

The precision of radon daughter measurement techniques is a complicated function of uncertainties arising from concentration and flowrate fluctuations during sampling, counting statistics and many other factors. Optimization of a measurement technique requires that all these uncertainties - not just counting statistics - be considered. In this work, the optimization procedure of Busigin and Phillips (1980) is tested against Monte Carlo experiments for the case of the modified Tsivoglou method.

Jan 1, 1981

By Josh Struble, Fu Yuet, Jan Zywiel, Kevin King

This paper discusses the application of Integrated Inertial/GPS technology for position determination of earthmoving equipment in an open-pit mine. Different GPS augmentation methodologies are introduced and discussed. Principles for the operation of the Applanix POS MC (Position and Orientation System for Machine Control) are also presented, together with test results conducted at the Twin Creeks Newmont mine, using the POS MC and Caterpillar’s CAES (Computer Aided Earthmoving System).

Jan 1, 2005

By Ben H. Daud

A computer model has been developed at Consolidation Coal Co.&apos;s Central Engineering Dept. for preliminary economic evaluation of deep coal mine reserves. Since it was first formulated more than two years ago, the model has been used for the following purposes: (1) ranking studies of coal exploration projects, (2) marketing surveys, (3) preliminary sale and acquisition analysis of coal reserves, and (4) parametric analysis in conjunction with detailed feasibility studies.

Jan 1, 1979

By Paul G. Greenhill

The Australian Mineral Industries Research Association (AMIRA) was established by the Australian mineral industry in 1959 to develop and manage collaboratively funded research projects. Owned and managed by industry, it coordinates research that answers questions defined by the sponsoring companies of the projects. Now over 35 years old, the Association is an excellent example of what can be achieved through collaborative research and an industry - backed research organisation.

Jan 1, 2000