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By V. G. Papangelakis, G. P. Demopoulos

The high temperature (180-200 OC ) pressure oxidation (02 - HzSO4) process for the recovery of gold from refractory concentrates (FeS2/FeA8S) is simulated with the aid of a computer model. The model centers on the continuous operation of a multi-stage horizontal autoclave. In particular the effects of key process parameters controlling the autogenous operation of the autoclave are critically examined. The building elements of the model are (i) the continuous particle size distribution function of the concentrate, (ii) the residence time distribution function of the slurry and (iii) the shrinking core kinetics. Conversion is calculated on the basis of the segregated flow model. For the calculation of the particle size distribution at the exit of each compartment the population balance model is employed. The effects of feed rate, feed preheating, cooling, autoclave configuration and rate limiting regime (chemical reaction vs. gas-liquid mass transfer) on the autogenous steady state operation are discussed. Finally optimum reactor design and operation criteria are indicated.

Jan 1, 1990

By M. A. Barclay, D. Samson, A. M. Esteves

Several companies have adopted policies and standards aimed explicitly at increasing ‘local procurement’, recognising that local economic participation has benefits for companies and communities alike. From a corporate perspective, local economic participation is seen as one means of maintaining a social license to operate, as well as ensuring reliability of supply by having a supplier located nearby. From a community perspective, the participation of local businesses in the resource project is a means by which the benefits of resource development can flow into their communities. This paper is based on the research undertaken to produce a good practice guide for the mining, oil and gas sector. Our research revealed that the extent to which the local community will actually benefit from local procurement initiatives is dependent on the capacity of the community to supply goods and services to the project and, even more importantly, on its ability to adapt to the inevitable changes that accompany large-scale resource development. We provide guidance on adapting impact assessment tools to guide planning of procurement interventions.

Jan 1, 2011

By Chris Campbell-Hicks

Methods used for assay of gold values in resource estimation, grade control or downstream processing are based almost entire­ly on Fire assay or Aqua Regia techniques. Both these tech­niques frequently produce spurious results. The mechanism of error is explained. Major decisions are made based on this often flawed data. This is what our operating budgets and projected cash flows are based on. Project economics demands metallur­gical accountability for performance predicted. Accountants and more astute members of the board are often not sympathetic to gold out-tum from plant production which is occasionally or consistently less than that predicted. Equally importantly, better than budgeted gold out-tum, resulting from under assaying will produce reconciliation or accounting problems (surplus cash flow) often denying correct timing of expansion or acquisition. Both these scenarios can be avoided if 'real world' extractable gold values are presented to financial managers at all stages. Such extractable gold results are now possible, and compared to fire assay and aqua regia, the assays are faster, cheaper, simpler and more accurate.

Jan 1, 1996

By MD Cadzow, TW Quaife, DJ Lunt, TS Giraudo

The Macraes Gold Project, operated by Gold and Resource Developments NL, engaged Minproc Limited to assist with the evaluation of a pressure oxidation circuit, this being the key component of a recovery enhancement project. The initial study gave sufficient confidence in the process to enter into project execution. The project is the first to license Newmont Mining Corporation's pressure oxidation technology, which aims to improve gold recovery from the carbonaceous sulfidic flotation concentrate. This paper outlines the fundamental chemistry of the process followed by a description of the plant that was ultimately installed. A summary of the commissioning is given together with an overview of the production results for the first three months of operation. The project ramp-up was rapid, with design temperature and throughput being achieved within days of hot commissioning. Gold recoveries have exceeded expectations and the project has increased the nominal gold output at Macraes from 110,000 oz/y to 150,000 oz/y. Ongoing plant optimisation and problem solving, mainly associated with scale formation, is discussed.

Jan 1, 2000

By H. Nematollahi

The comminution laws The grindability of the ores or minerals is an important factor that could not be deduced from their mineralogical characteristics (Testut, 1958). Many theories have been proposed to determine the amount of work required in a comminution operation as a function of the nature of material, size and shape of the minerals before and after of comminution. The most important laws are proposed by Rittinger, Kick and Bond. According to Rittinger (1867), the work is directly proportional to the new surfaces produced during the comminution. Kick (1885) believes that the work needed to produce similar modification is proportional to the volume or mass of the material. Bond, during his 25 years of experience and research, reached to the conclusion that on the average the energy required for a known comminution is between the Rittinger's and Kick's laws (Bond, 1952). According to Bond's Third Theory, the work input is proportional to the new crack tip length produced during the particle breakage, and equals the work represented by the product minus that represented by the feed.

Jan 1, 1994

By Frederick W. DeVries

The following charts were presented at the Randol Gold & Silver Forum 2000, held at the Hotel Vancouver (Vancouver, B.C.) from April 18-21, 2000. It must be borne in mind that the "facts" stated and con­clusions drawn by the author were not as the result of a rig­orous technical investigation, but rather as a member of a journalistic team seeking a rapid view for presentation as news to a TV audience. Since the author's visit, some retrenchment on the part of the operators on estimating the cyanide content of the spill seems to have occurred. This does NOT alter the conclusions that (a) the spill was an intolerable embarrassment for the world mining industry, nor (b) the potential damage to future mining investments, should prompt action not be taken: 1. to understand the reasons for the dam failure, and 2. to draw up firm concepts of how to avoid future fail­ures of dams at mining properties containing materials that are toxic, environmentally unfriendly, or with as highly dis­comfiting a profile as cyanide.

Jan 1, 2000

By Merwin Bernstein

Peru has been an important source of metals since Aug. 29, 1533. On that day Francisco Pizarro took charge of the 24 t (772,000 oz) of gold and silver that constituted Atahualpa’s ransom. At today’s prices, the value of that booty ranges between $100 and $150 million, depending on the proportion of gold to silver. Since then, Peru’s silver and gold production has been legendary. Current mine production Most of Peru’s metals are mined from the Andes Mountains and its foot-hills. The Andes run the length of the country parallel to the Pacific coastline from Ecuador to Chile, a distance of nearly 3000 km (I 875 miles). They are about 300 km (187 miles) wide and much of the range is more than 3000 m (9900 ft) in elevation. High plateaus (altiplanos) occupy a large part of the range. Both flanks are rutted by large valleys and canyons. Many of these peaks are prodigious. which make road building expensive and adds to the cost of mining.

Jan 1, 1993

By R. Venugopal, T. C. Rao, J. P. Barnwal, K. Udaya Bhaskar

The performance characteristics of a multigravity separator for the recovery of heavy minerals of lead, zinc, copper and silver from a lead rougher-flotation concentrate were studied. Factorially designed experiments were carried out on three operating variables, i.e., the amount of wash water, the drum inclination and the drum rpm, of a multigravity separator. The experiments were carried out at two levels of each variable. With the experimental data, regression equations were developed for different metal grades and recoveries. The analysis revealed that drum speed has a major influence in determining the heavy-metal grade and recovery. Drum inclination is the next most important variable, with the amount of wash water being the least important. A concentrate containing 40% lead, 9.4% zinc, 1.5% copper and 1,400ppm silver was obtained with recoveries of 74.8%, 65.9%, 64.1% and 53.2%, respectively. Finally, the predicted values of grades and recoveries at intermediate levels are compared to actual experimental data to test the validity of the equations developed.

Jan 1, 2000

By Thomas J. Feeley

The US Department of Energy (DOE) is supporting the engineering development of three advanced physical coal cleaning technologies: selective agglomeration, advanced flotation and advanced cycloning. Each is capable of significantly reducing the pyritic-sulfur content of US coals. The objective is to provide the coal and electric-utility industries with a cost-effective option for addressing the SO, emission reductions required by the 1990 Clean Air Act Amendments (CAA). A secondary objective is to evaluate the potential of advanced coal cleaning for removing trace elements that are precursors to the formation of hazardous air pollutants (HAS). The proposed National Energy Strategy (NEE) and the 1990 CAA lay a foundation for a more efficient and environmentally sustainable energy future (1991). The need to use energy resources in an environmentally sound manner presents critical challenges and opportunities for coal preparation during the next decade, particularly regarding the control of SOS and HAY emissions. The principal challenge is the development of cost-effective coal preparation approaches for sulfur and HAY precursor removal.

Jan 1, 1993

By O. Ofor

Finely-ground hematitic ore, too high in silica (quartz) to be commercially viable, was treated by emulsion flotation. A three-component emulsion mixture was used at temperatures ranging from ambient (22° C) to 30° C, 40° C, 49 °C, 59° C and 68° C. The optimal emulsion dosage and composition at ambient temperature were used to determine that dosage for higher-temperature flotation tests. The crushed ore (100%, -8 mesh) was repeatedly washed with tap water, and the filtrate's ionic content was analyzed. The separation efficiency values (a measure of the selective separation and concentration of hematite from gangue minerals) demonstrated temperature dependence, with marked increases at temperatures above ambient. The optimal separation efficiency occurred within the range from 30° C to 60° C. The improved separation efficiencies at temperatures exceeding ambient are explained by quartz depression. This depression is attributed to: • the precipitation of quartz-activating cations, principally calcium and magnesium, at increasing temperature; and • temperature's effect on the collector's solubility and attachment to the aqueous hematite surface.

Jan 1, 1993

By Sigmund J. Sulinski

The following is a progress report on a continuing study being made by the Sanitary District for purposes of developing reliable data for predicting costs and progress on future tunnel contracts. All data available to date on five separate tunnel contracts has been analyzed. All were machine-mined in soft ground, all used steel ribs and wood lagging and finished inside diameters varying from 5'6" to 6'6". Basic data regarding progress per shift, hours mined per shift, hours of downtime per shift, cause of downtime and type of soil mined were reported by the District's resident engineer at the job site. Figure 1, Weekly Mining Report is an example of the form used. Data regarding manpower and equipment used during tunnelling operations was also supplied by the resident engineer during the course of construction. Soil type being mined was verified by the resident engineer during construction, by visual observation, and compared with data listed on a previously prepared soil profile. The soil profile is a graphic presentation of anticipated soil stratas superimposed on a cross section

Jan 1, 1997

By B. Whitmoyer, J. Tian, J. E. Sneckenberger, M. A. Jerabek, C. A. Chandler

A computational procedure has been developed to determine the lung volume function for the upper airways of the human respiratory system. This analytical procedure computes a person's partial lung volume from an experimental two-microphone acoustic measurement of the upper airway passages obtained through a molded tubular mouthpiece. The theoretical transfer function for the two microphone signals as well as the related acoustic impedance and reflection coefficient for the upper airways are calculated using two-channel spectrum analysis techniques. An inverse spectrum analysis scheme then converts the reflection coefficient to an impulse response from which the airway area function is extracted using an area recovery algorithm. Numerical integration of the upper airway area function yields the lung volume function for the upper airways of the human respiratory sysytem. A software program to accomplish this computation of human upper airway volumes will be described in this paper. Application of this computational procedure to the measured tracheal acoustic impedances of 15 human subjects will illustrate the program's capability toward early detection of lung dysfunction using a prototype clinical facility.

Jan 1, 1991

By D. D. Banerjee, S. K. Kawatra, T. C. Eisele

To reduce their sulfur emissions, many coal-fired electric power plants use wet flue-gas scrubbers. These scrubbers convert sulfur oxides into solid sulfate and sulfite sludge, which must then be disposed of. This sludge is a result of reacting limestone with sulfur dioxide to precipitate calcium sulfite and calcium sulfate. The majority of the sludge is simply landfilled, but with increasing landfillimg costs this can cost the plant millions of dollars per year. As a result, this option is rapidly becoming less attractive. Producing marketable materials from the sludge is a far more promising avenue, provided that the products can meet the necessary specifications at a reasonable cost. In this paper, a method is described for using froth flotation and water-only cyclones to remove unreacted limestone from scrubber sludge. The water-only cyclone was found to be very effective for removing the coarser unreacted limestone, grinding ball chips, gravel, and similar coarse impurities. Froth flotation was found to remove fine unreacted limestone, with a minimum of reagent addition.

Jan 1, 1995

By A. Unal

Coal resource characterization usually calls for estimating more than one variable over a block or node simultaneously. Within the realm of geostatistics, each variable has been evaluated independently from the others assuming a lack of significant correlation. Research conducted with coal seams, however, has shown that the variables of immediate interest, such as seam thickness, ash, sulfur content, and density depict some correlation schemes in distinct zones, if not throughout the entire area. The above findings have two immediate consequences : (1) correlation analyses provide guidelines to determine the geologically distinct zones, and (2) where possible, cokriging should be used instead of kriging. This will maximize data utilization decreasing the frequently criticized high estimation errors. The cokriging formulation will also provide more accurate estimates for under sampled variables using better-sampled ones. This is a common case with coal with regard to the non-cored reconnaissance drill holes for which only very few variables were recorded. A case study illustrates the improvements that may be obtained by taking advantage of the intervariable correlations.

Jan 1, 1986

By J. Hong, K. Han, C. Park, C. Yoon, H. Yoon, N. Kim

The contents of three platinum group metals (PGM-platinum, palladium and rhodium), from the spent automotive catalyst, and two NIST SRM (National Institute of Standard and Technology Standard Reference Material, Used Auto Catalysts) were determined by the X-ray fluorescence (XRF) spectrometry. The XRF technique has been proven to be a fast, effective and accurate method in determining not only PGM but also other solid materials of less soluble for wet digestion analysis. The detection limit of the XRF analysis is better than that of the inductively coupled plasma mass spectrometry which usually requires significant dilution to avoid high dissolved solid concentration. However, the XRF technique suffers from a strong matrix dependent problem. The objective of this study was to examine the applicability of the XRF analysis where the sample matrix was not exactly the same as the standard materials with particular reference to PGM analysis. This study enabled to compare the effect of various matrices including alumina, iron, copper and nickel on determination of the contents of PGM.

Jan 1, 2004

By Xiangze Shu, Yuzhong Xing

All programs used to optimize main fan nowdays have to be run on the large and medium- sized computers. With a lot of array elements, complex processes, low convergence speed and large storage, these programs are both time consuming and difficult to be used in the micro computer. This program uses two languages (dBASEIII and BASICA) to calculate the network and to choose the fan respectively. It allows user to compare and choose the parameters of various kinds of fan and to transfer the selected fan parameters to the master program by a data communication system. Then the user can get the air quantity, the air pressure, the power and the efficiency of the main fan. The advantages of this program arc as follows: 1. It can be run on IBM-PC or compatible micro computer. 2. It can select a fan more quickly and less time consumingly. 3. It can choose desired one or a set of fans according to user's requirements. 4. It is suitable for the research institutions and coal mines.

Jan 1, 1991

By C. Flores, L. G. Twidwell, T. S. Jordan

It is well known that manguniferous silver ores containing manganese intimate) associated with silver are not amenable to conventional extraction methods. The segregation process has been applied primarily to the recovery of copper from oxidized and oxide-sulfide ores. A new alternative process, consisting of segregation roasting followed by flotation to recover the silver from refractory manganiferous silver ores, was studied using a 23-factorial experimental design. Laboratory investigations were conducted on a manganiferous silver ore analyzing 0.02% copper, 0.09% lead, 0.33% zinc, 12.55% manganese and 187 g/t silver. The investigation was designed to study the effects of the addition of salts, coke and copper (11) oxide on silver recovery. The results indicated that 79.3% of the silver can be recovered in the absence of copper oxide and 88.4% of the silver can be recovered with a copper oxide content of 1.5% at 750°C, 2% salt (NaCI). 1 % coke and 30 min of roasting. It was concluded that the addition of copper oxide improves silver recovery.

Jan 1, 1996

By Fred H. Seymour

In spite of the progress made by geostatistical theory over the years, evaluation of low grade open pit gold deposits continues to be challenging. Many Carlin type deposits are modelled from exploration drilling spaced on 10C foot centers. From these drill holes, 50 by 50 by 20 foot blocks containing about 4000 tons of material are estimated. The block size is a compromise between being large enough for a good geostatistical estimation and being small enough for practical pit limit analysis and mine planning. Most of these gold deposits are highly variable and include ore and waste zones that are too small to be properly defined from exploration drilling information. Because of this, selective mining is controlled by sampling closely spaced blast holes where the density can be as high as 50 blast holes per exploration drill hole intercept. Figure 1 illustrates an example of the ore/waste contact definition before and after blast hole sampling. With exploration information only, a tentative ore/waste contact can be drawn between the exploration blocks.

Jan 1, 1989

By B. J. Arnold

A coal's size distribution clay content and moisture content can affect its handling behavior. But the combined effects of these properties and the effects of other properties are not known. Research underway at CQ Inc.'s (formerly EPRI's) Coal Quality Development Center (CQDC) and at Iowa State University (ISU) will answer these questions as part of a four year project to develop a coal handleability index for utilities to use when specifying coals. This paper will present preliminary data from the first year of the project, which focused on obtaining data on the chemical and physical properties of carious coals and their measured handling properties. Additionally, size, ash and moisture analyses and shear test data for several coals used at one power plant will be presented along with correlations between these physical and chemical properties and the measured handling properties. These data lead to the conclusion that while moisture content is the most important variable, the amount of -44 µm (-325 mesh) coal fines is a significant factor in determining coal handling behavior.

Jan 1, 1992

By M. H. H. Mahmoud, T. A. El-Barbary, E. A. Abdel Aal, I. A. Ibrahim, A. K. Ismail

Fertilizer-grade phosphoric acid with a P2O5 concentration of 50% should contain less than 1.5% Fe2O3, otherwise, the P2O5 water solubility of the fertilizers prepared from high-iron acids will be low. High-iron Egyptian phosphate concentrates fromAbu-Tartur and Sebaiya- West were leached with sulfuric acid and recycled phosphoric acid to produce 50%-P2O5 phosphoric acids containing 4.0% and 2.7% Fe2O3, respectively. The high iron contents were reduced to the industrially accepted limit of 1.5% Fe2O3 by precipitation with potassium sulfate. The factors affecting the effi¬ciency of the precipitation process, e.g., temperature, time and K2O/Fe2O3 ratio, were systematically studied, and the optimum conditions were achieved. The clarification of the prepared phosphoric acid from iron-containing sludges was also investigated by varying the time and temperature. The utilization of the separated sludges as fertilizer and recovery of P205 by pulping in water were also evaluated.

Jan 1, 2000