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By E. Wiewiorowski

A new technology for recovery of metals from spent catalysts containing aluminum, cobalt, molybdenum, nickel and vanadium was developed. The catalysts are decomposed in two consecutive pressure leaching steps. Sodium aluminate-sodium hydroxide systems are lixiviants in both leaching steps. Selective extraction of molybdenum and vanadium is achieved in the first leaching step. The leach liquor is processed for separation and recovery of these two metals. The residue from the first leaching step is further processed in a second leaching step where alumina is solubilized. The residue from this operation is a nickel-cobalt concentrate. Alumina is separated from the second stage leach liquor by precipitation; the depleted liquor, a sodium aluminate solution, is recycled to the first and second leaching step. This technology has advantages over other approaches for the recovery of metals from spent catalysts because no solid waste is generated.

Jan 1, 1988

By W. Irwin

As a consequence of the oil crisis of the 70?s, the commercial value of coal increased very sharply and an upward trend in coal prices although now less pronounced, continues today. The graph shown in figure 1 illustrates the trend in the F.O.B. price of U.S. metallurgical coal. This trend occurs during a time when mechanized mining is firmly established as a means of production throughout the coal mining world. With modem methods of mining, mechanical cleaning is a necessity and quality control is no longer entirely dependant upon coal face practice. The efficiency of fine coal recovery is of vital economic importance to present day operations and good practice in this field contributes significantly to improving profitability. Numerous processes are available for the duty and this paper discusses one such system, namely the practice of froth flotation.

Jan 1, 1980

By J. K. Brooke

Fluorine is a lively element in both its chemical and economic behavior. It was not isolated as an element until 1886 by Moissan. However, its principal source to this day, fluorspar, was known and its special merits recognized long before that time. Our own mining brother, Agricola, is credited with having named fluorite, the mineral name, in 1546 from the Latin, "fluere", to flow. It made things melt and was already being used as a flux. Because fluorspar has been found as a relatively common gangue mineral in metal ore veins, it has long attracted the attention of geological thinkers seeking to, explain the whys and wherefores of veins. Fluorine has been thought of as one of the principal mineralizers, holding metals in ascending vein solutions for deposition close enough to the eventual surface to be accessible for profitable mining.

Jan 1, 1964

By K. Hanna

This paper describes a method to improve coal mine entry intersection design. The method considers the effect of in situ stresses, local geologic conditions, rock physical properties, and mining sequence. Development of the method is discussed, including the results of field instrumentation studies and numerical modeling investigations. Data required to evaluate the effects of roof span, mining sequence, entry orientation, and bolting patterns on intersection stability are also presented. Ground control studies conducted by the U.S. Bureau of Mines in two underground mines in the Illinois Coal Basin have shown that in situ horizontal stresses and roof geology have a critical effect on intersection stability. Methods to reduce the adverse effects of these parameters are emphasized. Typical failure behavior associated with specific geologic and horizontal stress conditions is' presented to illustrate proposed control methods to alleviate adverse ground conditions.

Jan 1, 1988

By R. M. Parlman

Interest is increasing in obtaining incremental improvements in mineral recoveries in flotation processes because of changing world economic conditions. Research on collector reagents, long indispensable components in flotation systems may provide the cheapest and simplest route to higher metal recoveries. Sulfhydryl group - containing compounds (-SH) and their salts, e.g., dithiophosphates, xanthates and a few other derivatives are commonly used to promote the flotation of sulfide minerals. Alkyl mercaptans, another class of sulfhydryl compounds, have long been known to have collecting properties but have been relegated to dormancy for one reason or another. This paper reports results from new investigations of alkyl mercaptans, trithiocarbonates, and a petroleum oil with a variety of western domestic and Canadian ores for copper and molybdenum sulfides recovery. Specific opportunities are pointed out to the industry for mineral recovery enhancement through the use of the proper reagent combination.

Jan 1, 1980

By George M. Meisel

This paper is devoted to a discussion of the factors governing design of concentrators for large grinding circuits. Emphasis is placed on the manner in which use of ever larger grinding mills has affected the size of grinding bays, service cranes, gear reducers and electric motors, and the selection of ancillary equipment for cushioning of the starting load of large mills. Information is presented on the effect of using large grinding mills on the capital and operating costs of concentrators, e. g. : (Fig. 1) ? Benefits in lower cost of mills, drives and materials handling equipment, plant space, power, grinding media, operating labor and maintenance, and in ease of instrumentation and automation. ? Penalties in distribution of materials from the grinding mills to multiple lines of equipment which have not been developed to commensurately large sizes, and higher cost of ancillary equipment.

Jan 1, 1968

By L. D. Cruz

In Exxon's Los Bronces Expansion Project in Chile, a stochastic simulation is performed to resolve the complex decision problem of matching the mine to mill system capacities from both technical and economic standpoints. The unique combination of weather conditions at the mine and the 30-km belt conveyor network for ore transport to the mill necessitates this analysis in the planning phase to optimize the design capacity of the sys tem. Appropriate statistical distributions of major equipment performance, snow storm duration, power outage, etc, ate developed from actual mine local records and manufacturers specifications. The interactions of operational constraints including ore storage capacities, number and sizes of individual equipment, ore variations, and mine and mill production rates are studied more realistically than in a traditional planning approach. Details of the computer modeling and typical results of simulation studies are discussed.

Jan 1, 1981

Adsorption of acrylamide based homo and copolymers on hematite was investigated as a function of phe nature of the polymer charge and functionality of the polymer. Effect of addition of sodium dodecylsulfonate and dodecylamine hydrochloride was also studied and was determined to result in an increase or decrease in the amount of polymer adsorbed depending on, the charge characteristics of the surfactant and the polymer, pH of the suspension, concentration of the various species and the order in which these species were added to the system. The surfactant adsorption under given conditions on the other hand, was found not to be affected by the presence of the polymer molecules. The data is analyzed to elucidate the mechanism of adsorption of polyacrylanide type polymers on hematite both with and without the surfactant species king present in the system.

Jan 1, 1982

By John J. Murray, Michael T. McRae, Michael A. Krulc, Kathy L. Schuler

The San Vicente Pipeline Tunnel Project involves the construction of an 8.5-foot-diameter water pipeline in an 11 mile tunnel in San Diego, California. The tunnel is located in extremely variable geologic conditions of strong granitic and volcanic rocks, weak sedimentary rocks, abrasive conglomerates, and mixed face conditions. One reach of the tunnel is a 5,200-foot mixed face reach that includes Friars Formation Conglomerate overlying granitic rock. Due to the variable ground conditions in this reach, the use of a TBM was deemed too risky and the contract documents required drill-and-blast and hand mining methods. Although it was not required, the contractor elected to construct this reach using NATM methods. This paper describes the geology of the 5,200-foot mixed-face reach, the design evaluation, and the construction challenges faced on this project.

Jan 1, 2007

By Roberto J. Guardia, Ted Lewtas, Peter Rasmussen, Klaus Winkler

As part of the Lake Fort Smith Water Supply Dam Enlargement project, located in northwest Arkansas, microtunneling methods were used to install two side-by-side,1.53m (60-in) inside-diameter steel pipes between the intake structure shaft and the lake. The 46.6 m- (153 ft-) and 41.7 m- (137 ft-) long tunnels were excavated in Pennsylvanian sedimentary bedrock ranging from coarse sandstone to siltstone and shale-like claystone. The intake tunnels were constructed 18.3 m (60 ft) below lake level from the dry shaft. Special installation methods and procedures described herein were used to complete the lake taps. Installation difficulties that caused minor delays are also reviewed. After the excavation of the Intake shaft was completed, the two lake taps were installed in approximately ten weeks with the same microtunneling machine.

Jan 1, 2005

By Bruno Bussière, Guosheng Zhan, Michel Aubertin, Vincent Martin, Robert P. Chapuis

The study evaluates the hydrological behaviour of exposed and covered waste rock dumps. The objectives were to determine the major factors influencing unsaturated flow in waste rock dumps and covers, and to improve the in-situ, laboratory and numerical modeling characterization methods. Using material properties obtained from in-situ and laboratory tests, waste rock dumps of different configurations, with and without covers, were modeled. It was found that a properly designed “Store, divert and release” (SDR) cover allows most of the water to be diverted downslope and discharged outside of the waste rock dumps. The SDR cover seems to work efficiently even in extreme storm events. The numerical modeling results show that the unsaturated hydraulic properties (e.g. air entry value and water entry value) of the materials largely control the infiltration of water into waste rock dumps.

Jan 1, 2005

By Donald J. Olson

The North 27th St. ISS Extension tunnel will, under present plans, be the last constructed section of Milwaukee Metropolitan Sewerage District?s (MMSD?s) existing deep tunnel system. The 6.5 m (21 ft) finished diameter tunnel is approximately 3,260 m (10,590 ft) long and is located in NE Milwaukee County. When disputes over the pro-cesses to be used in owner-directed pre-excavation grouting in rock threatened the completion date stipulated between MMSD and the State of Wisconsin, the MMSD and J.F. Shea, the contractor, entered into a unique agreement. Shea accepted responsibility for all shaft and tunnel grouting and water control during the project in exchange for settlement of claims related to grout quantities and perceived delays. This significantly reduced risk for the MMSD and helped ensure the stipulated completion of the project.

By H. Y. Sohn, R. D. Hagni, M. K. Kojo

Reflected light microscopy was used to study the mineralogy and textures of experimental reactions of a nickel concentrate with a slag. Such an interaction is an important step in the bath smelting of nickel sulfide concentrate. Concentrate particles in the central portions of the pellets are rounded and develop vermicular SO2 gas porosity. In the outer portions of the pellets, the original minerals of the concentrate, pyrrhotite, pentlandite, pyrite, chalcopyrite, and violarite have agglomerated and reacted to form two intergrown phases: 1) pyrrhotite solid solution (Fe0.75Ni0.18Cu0.01S) and pentlandite solid solution (Fe0.58Ni0.51Cu0.03S). Magnetite formed euhedral crystals, skeletal crystals, and dendrites at the margins of the matte. Prismatic ferrohypersthene and octahedral Mg-Al-Fe spinel crystals and dendrites are present in the glassy slag.

Jan 1, 2001

By G. E. Vaninetti

During its modem era, the southern Powder River Basin (PRB) in Wyoming has grown from meager origins in the early 1970s to become one of the most important coal-producing regions in the United States. In 1993, production and sales of southern Powder River Basin coal exceeded 190 Mt (209 million st), or about 20% of the US coal industry. Despite the remote location of the PRB relative to its potential markets, most coal industry observers anticipate continued strong growth to meet utility compliance plans for Phases I and II of the Clean Air Act Amendments (CAAA). This article is an overview of supply and demand issues concerning the marketing of southern PRB coal. It reviews the events leading up to the recent run on spot coal and offers a forecast of demand and prices.

Jan 1, 1994

By Joseph G. Selmeczi

Lime and limestone-based SO2 scrubbing processes have demonstrated reasonably good success in removing low concentrations of SO2 from flue gases. While most of the operating problems experienced in the early days of scrubbing have been worked out, problems usually increase and removal efficiency drops with increased amounts of SO2 present in the gas stream. In order to overcome these difficulties, yet still taking advantage of lime and limestone as the lowest cost neutralizing agents, a host of so-called double- alkali systems were developed. These processes take advantage of cations such as Na+ and NH4+ capable of forming highly water soluble bases or basic salts, such as hydroxide, carbonate or sulfite, which having been neutralized or acidified by the absorbed SO2 can be regenerated with a lower cost base such as lime.

Jan 1, 1974

By Jan M. Mutmansky, Y. J. Wang

In the mathematical analysis of electrical networks, the electrical devices are often modeled using idealized network elements such as current sources, voltage sources and resistors. An analogous approach is outlined for the modeling of mine ventilation networks, which can be considered nonlinear resistive networks. The proposed modeling technique uses the following five basic (nonreducible) elements: H, Q, D, R and N. These elements are characterized by their pressure gain or loss, their air quantity and their pressure-vs.-quantity relationships, each of which may be known or unknown. In addition to the definition of the basic elements, the necessary conditions for which there exists a unique solution are discussed. This is performed using theoretical developments derived from electrical circuit theory and illustrated in example networks. The proposed procedures are useful in the solution and characterization of mine-ventilation networks.

Jan 1, 1998

By Kenneth N. Han, Jianshe Liu

Various techniques used in the removal of metal ions from effluent streams have been reviewed. These techniques include recovery of metals by biological treatment, chelating agents, adsorption, ion- exchange and chemical precipitation. The main thrust of this paper however, is concerned with the removal of cadmium and zinc ions from the solution by adsorption utilizing liquid fluidized beds. The bed particles used were silica of 150x200 mesh. The range of the concentration of these ions studied was 10-3 to 10-5 M. Important variables examined included flow rate, concentration of metal ions and amount of bed particles. A mathematical model describing the concentration profile of metal ions in the axial direction in liquid fluidized beds has been developed. The equation of continuity was solved numerically and the results were used to predict the recovery of metal ions in fluidized beds.

Jan 1, 1992

By J. Litsenberger, T. E. Marshall, P. R. Coyle, L. J. Prosser, A. T. Iannacchione

For the first time in an underground stone mine, the relationship between roof movement and microseismic emissions was examined in conjunction with two distinct roof fall areas. As roof monitoring increases in acceptance and monitoring technology advances, the goal of providing reliable roof fall detection systems to enhance the safety of underground mine workers moves closer to reality. Instrumental to reaching that goal is the ability to interpret accurately and completely roof movement and microseismic emissions, which can serve as precursors to roof falls. This paper examines the capabilities of convergence and microseismic monitoring systems to better understand roof rock failure mechanics and to anticipate roof falls. An understanding of how these techniques are used and how they interact with each other is critical in developing the most effective ground control strategy for our nation’s mines.

Jan 1, 2004

By E. V. Bowman

This paper is intended to deal with the material handling aspects of fine coal cleaning as applied to a recently built plaint in: southern West Virginia. This plant is processing 160 tons per hour of 1/4" x.0 coal on a two shift basis. Past experience with this very friable low volatile metallurgical coal indicated that its plastometer readings, varied directly with the size and length of time elapsing between mining' and ultimate consumption. Due to the mines location with, respect to its consumers, little could be done to decrease the time element. Studies indicated that the plastometer readings are considerably less in the minus 60 mesh range than that experienced in the plus 60 mesh sizes. Therefore, handling the coal in such a manner as to have the least amount of degradation became extremely important.

Jan 1, 1961

By Peter Shuttleworth, Chris Fesq, Eddie Woods

Precast concrete segmental linings for tunnels have traditionally been designed with conventional steel bar reinforcement. In many cases, this has been satisfactory in service, but in others, major problems have occurred with the durability of the linings. Commonly this has resulted from corrosion of the reinforcement, mainly from chloridesin ground water, causing spalling of the concrete and leading to very expensive and disruptive repair programs. This paper discusses the relative merits of designing tunnel linings with steel fiber reinforcement to provide long-term durability, improved impact resistance and toughness for greater load capacity across joints, enhanced robustness during transportation and erection, plus improved fire resistance with the addition of polypropylene fibers. Guidance is also given in the selection of the correct fiber type, mix design and testing methods to establish the optimum dosage required and production techniques to ensure even distribution and compaction.

Jan 1, 2005