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By James A. Finch, Xiang Zhou, Yue Hua Tan

Methods to determine frother functions, control of bubble size and froth properties, are now widely used. Some collectors also exhibit frother functions which are less understood. Using a water-air system in a mini-mechanical flotation cell setup, this paper determines bubble size and water overflow rate for three amine collectors: one primary amine (dodecylamine, DDA) and two commercial ether amines (Flotigam® EDA and Flotigam® 2835-2L) and their combination with two common frothers, MIBC (methyl isobutyl carbinol) and PPG 425 (polypropylene glycol, molecule weight 425). Compared to the frothers, the amines were less effective in reducing bubble size, giving larger minimum size and the two commercial amines showed evidence of coalescence at low concentration. In blends, at fixed frother dosage, frother eliminated the coalescence but as amine concentration increased the amines dominated bubble size. Water overflow was a strong function of reagent type. For fixed 1-cm froth depth, PPG 425, Flotigam® 2835-2L and to a lesser extent DDA produced overflow while MIBC and Flotigam® EDA did not. In blends with frother overflow increased except with Flotigam® EDA. Mechanisms are briefly explored. The principal benefit of blending identified is the elimination of coalescence if residual concentration of the two commercial amines is below ca. 10 ppm.

By William F. Stowasser

The organization and operations of the information gathering system, and examples of the products prepared for the commodity phosphate rock by the Division of Nonmetallic Minerals, U.S. Bureau of Mines, are used to describe the Bureau's commodity program. Selected examples from publications about phosphate rock are used to illustrate the program. The Commodity Divisions reporting to the Office of the Assistant Director-¬Metals, Minerals and Materials, have the responsibility in the Bureau of Mines to maintain commodity records, understand the present supply and demand status of the commodity, and forecast future supply, demand, and problems. Within the Divisions, commodity specialists have the broad charter of acquiring as much information about a commodity as is necessary to characterize its history, current status, and future. This information and understanding are the base for the development of mineral policies. To accomplish these objectives, the commodity specialists acquire data and information about each commodity and produce a number of standard publications each year. In addition, as circumstances dictate, each specialist will prepare or participate in the preparation of special documents for specific purposes or problems associated with his commodity. In the preparation of reports and publi¬cations, he may communicate with industrial organizations and other Government agencies.

Jan 1, 1975

By D. P. Patil, B. K. Parekh

Water is the mainstay for beneficiation of fine size coal and minerals; however, it is also the least desirable constituent in the final product. The basic concept of the novel process described in this paper is based on the differential surface heat absorption capacity of individual particles, which differs for different species of mineral. When a mixture of fine material is exposed to a radiant energy source, the various solids components present in the mixture will absorb heat energy depending on their composition and there will be difference in the surface temperature of the particles. When this differentially heated solid mixture is placed on a moving belt, which is coated with low temperature melting resin, the hotter component of the mixture will stick to the belt and relatively cooler will stay free on the belt and fall off at the end of the belt run. Experiments were conducted with pyrite, coal and quartz of 6 x18 mesh particle size. The goal of the test program was to find the optimum conditions at which there exists a required temperature difference between minerals and coal particles by controlling the operating and system variables. Preliminary tests results showed that there is a potential for separating mineral matter from coal using the thermo-adhesive separation technique.

Mar 2, 2022

By C. Y. Chen

In order to put an end to the uneven environmental standards and enforcement established by various coal mining States in the United States, the Congress passed and the President signed the Surface Mining Control and Reclamation Act (Public Law 95-87 or the Act) on August 3, 1977. Within one year after passage, the Secretary of the Interior was directed to promulgate permanent program regulations implementing Title V provisions of the Act. These regulations were to form the basis for State regulatory programs under the Act and to allow States to assume primary regulatory responsibility. In order to implement the underground mining provision of the Act, the Secretary is directed in section 516(a) of the Act to promulgate rules, but ones which take into consideration the distinct differences between surface coal mining and underground coal mining. The regulations developed by the Secretary and promulgated on March 13, 1979, with respect to subsidence control, included (1) a subsidence control plan as part of the permitting process, (2) substantive provisions establishing performance standards for subsidence control, and (3) provisions providing for the prohibition of mining under perennial streams, impoundments larger than 20 acre feet, and certain public facilities and urban areas.

Jan 1, 1985

By Ronald L. Wiegel

Success has been achieved in developing mathematical models of rod mills, ball mills and recently to a limited extent autogenous grinding mills. There is also considerable activity in the development of mathematical models of various mineral concentration opera¬tions, such as flotation, magnetic separation and electrostatic concentration. However, at present there is a technological gap which hinders the integration of both size reduction and mineral concentration models into an overall process simulation model. This gap exists because size reduction models have been aimed at describing the size of the product and have not dealt with the equally important problem of identifying the product composition in each size fraction. Without this information the concentration model is ineffective. This situation is especially critical in the simulation of the magnetite-taconite beneficiation process, where a portion of the ore is rejected from the process following each stage of size reduction. Consideration has therefore been given to the merging of a size reduction model and a mineral liberation model to permit prediction of mineral composition as a function of size. The results of this integration of size reduction and mineral liberation models are discussed from both theoretical and practical viewpoints using batch grinding data for a magnetite iron formation sample as a demonstration vehicle.

Jan 1, 1975

By Y. Gonzalez

The reaction kinetics of sulfuric acid leaching of brass foundry flue dusts were studied. As received flue dusts were separated into two size fractions, a coarse fraction (median size 103.5 microns) and a fine fraction (median size 3.4 microns). Experiments were performed on both fractions al-though most results are reported for the coarse fraction. Leaching experiments were conducted in a stirred reactor to determine those factors which govern the kinetic response of the sys-tem. The kinetics were followed by determining the increase in the concentration of dissolved copper with time. The effects of temperature, concentration and oxygen partial pressure on the rate of copper dissolution were examined. In addition, reaction residues were examined by SEM, EDAX and X-ray analysis. An activation energy of 4.8 kcal/mole (20.08 kJ/mole) was calculated. The rate was found to be significantly dependent on oxygen partial pressure and acid concentration. The order of the reaction with respect to oxygen partial pressure and hydrogen ion concentration was approximately 1.50 and 0.37, respectively. Results indicate that the dissolution reaction is limited by diffusion and can be described by the following mathematical expression where ~ is fraction of copper extracted in time t

Jan 1, 1988

By C. G. Cunningham

The Marysvale volcanic field of west-central Utah contains large areas of argillically altered rocks (fig. 1) that, in turn, enclose smaller areas of fine-grained, medium-grade, replacement alunite deposits and coarsely crystalline, high-grade vein-type alunite deposits. The largest replacement alunite deposits are [ ] located peripheral to a 23-m.y.-old monzonite stock called the Central Intrusive (fig. 1). The deposits formed in near-surface, highly oxidizing environments at the tops of hydrothermal plumes that were spaced irregularly around the stock. The deposits are horizontally zoned from alunitic cores through kaolinitic to propylitic envelopes. Vertically, characteristic alteration minerals progress from a pyrite-propylitic alteration assemblage at the base, upward through alunitic, jarositic, and hematitic assemblages to a flooded silica cap as shown on figure 2. The silica caps are cut by hydrothermal explosion breccias. d34Sso4 values of + 11.5 to + 15.4 permil indicate that sulfur in the hydrothermal plume was derived from underlying Mesozoic evaporites. The sharp upward transition from pyrite- propylite to alunite probably marks the paleowater table, and the top of the flooded silica cap represents the paleoground surface. Basin-Range extensional tectonism began shortly after alteration, and buried the replacement alunite deposits in basins beneath sediments eroded from uplands. The deposits were only recently exhumed.

Jan 1, 2013

By Rolph Linder

It is generally known and accepted that the efficiency of the blast furnace process, expressed by the symbols specific production and coke consumption, is influenced by a large number of variables connected to the type of burden, the alloy contents of the produced iron and the conditions of production as composition and preheating of the blast, the furnace heat losses and the possible use of fuels added on the tuyere level. It is furthermore obvious, that the coke consumption of the process will be influenced by specific production which could be said to be the result of two counter-acting influences. With high production, realized through intensive blowing, the passage time of the ore through the furnace is shortened leading to a decrease of the indirect reduction taking place in the upper part of the shaft within the temperature range of 300 to 1000°C. Simultaneously the external heat losses (constant in time) will be smaller calculated on each ton of iron and the resulting change in coke consumption will be the effect of both those influences. It is certainly of interest to be able to predetermine the effect of those variables before a change in the production practice is carried out.

Jan 1, 1964

By Roger J. Araujo

A photochromic material is one which undergoes a change of color when exposed to light and reverts to its original color when the light is removed. Review articles carrying extensive bibliographies have been written by Brown and Shaw (1) and by Schwab and Bertelson (2). Organics. Schwab and Bertelson divide the reactions in different organic photochromic materials into some half-dozen categories; Windsor (3) reduces these to the following three main classes of general interest, based on how they work. 1. Stereoisomers. Absorption of light breaks one of the chemical bonds in a. ring molecule, thus allowing the molecule to unwind and form a different geometrical arrangement. The reverse process is a reforming of the bond. Examples of this class are the spiropyrans and the anils. 2. Dyes. A triphenyl methane dye, for example, is oxidized by energetic light; the absorption characteristics of the positive ion so formed are different from those of the original electrically neutral benzene rings. 3. Triplet States. In the class of polynuclear aromatic hydrocarbons, ground-state molecules are excited first to a singlet state by irradiation, and then go, via the lowest triplet state, to an excited triplet state. Visible light is absorbed in the triplet-triplet transition.

Jan 1, 1970

By S. J. Stokowski

An extensive drilling and laboratory testing program indicates that diagenetic dolomitization of the Oligocene Sombrerito Fm. limestone, southwestern Dominican Republic, is detrimental to the usefulness and quality of the potential construction aggregate resource. The first part of this program was the collection, photographing, and geologic logging of diamond drill cores to allow lithologic subdivision of the strata into potential quarry layers. The primary lithostratigraphic units are: I (youngest) approximately 10 m of white, dense marine limestone; II, approximately 5 m of white, interbedded dense and chalky marine limestone; III, 2+ m of tan, chalky calcitic dolomite. Unit I has been often altered by lateritic weathering and/or dolomitization; Unit II is often altered by dolomitization. The quarry layers were individually crushed, by core, into coarse aggregate sizes for chemical and physical (specific gravity absorption, MgSO4 soundness, sand equivalent, and LA degradation) analyses. The non-weathered units decrease in coarse-aggregate yield and quality with depth and dolomitization. Dolomitization typically causes about 5% lower yield of coarse aggregate, a sand equivalent of about 20 units below the original value, an increase in absorption of about 3%, an increase in the LA of up to 13%, and a decrease in the average 5-cycle MgSO4 soundness by about 17%.

Jan 1, 1987

By Walter N. Campbell

The Simon Silver Mine is located near Mina, Nevada, approximately 50 miles northwest of Tonopah and 40 miles east of Hawthorne. It is an old property which was last worked in 1932 and closed operations due to problems arising from low metal prices. Federal Resources Corp. acquired the property in 1963 and undertook a completely new development program since the old surface plant and underground workings were beyond feasible repair. The deposit of silver, lead, zinc and copper is predominantly replacement of limestone. In the summer of 1964, a new surface plant was constructed and on December 2, 1964, sinking of a three compartment vertical shaft started and was completed to a depth of 1088 feet in April of 1965. Following the sinking program an 850 foot crosscut was driven to intersect the mineral zone on the 1000 level after which drifting, crosscutting and raising totaling some additional 4280 feet has been completed along with considerable diamond drilling and long holing into the walls. To date, two ore bodies have been encountered and test stoping operations are underway together with development of the 800 level for servicing, ventilation and access. The present development of ore is directed towards substantiating sufficient reserves to warrant the construction of a flotation mill.

Jan 1, 1967

By Alfredo Menendez, Alberto Sarmentero

A B S T R A C T The Los Pijiguaos bauxite is one of the largest accumulations of trihydrate alumina ore recently discovered; it is a plateau type, with no overburden, relatively soft tertiary quartz-bearing bauxite developed on a pre-Cambrian Rapakivi Granite batholith. The deposits are found in the northwestern rim of the Guiana Shield, State of Bolivar, Venezuela, and were discovered in 1976 after a grass-roots exploration campaign. Target areas were mainly selected on the basis of geological and geo¬morpholigcal criteria, guided by correlation with known deposits elsewhere in the Guiana Shield. The vertical. lateritic profile consists of an upper concretionary zone, followed by a mottled zone, a palid zone and finally the weathered rock merging into fresh granite. The upper concretionary zone displays a cellular, pisolitic or spongy texture and contains the following minerals: gibbsite (60-90%),quartz (5-10%), hematite (5-10%), goethite (under 5%), boehmite (traces), kaolinite (traces). The gibbsite content decreases sharply downward from the lower limit of the concretionary zone and the kaolinite and quartz content increases in the underlying mottled zone. The mottled and palid zones display a pseudo rapakivi texture and quartz, kaolinite and mica are the. essential minerals.

Jan 1, 1984

By John Duff Erickson

Determination of the final pit limits of an open pit copper mine is a problem that has far reaching effects on the life, profitability and operation of a mine. The solution to this problem requires that all of the significant variables affecting the final pit limits be considered together with corporate objectives as the guiding principle. This paper discusses the use of these variables and how they should be applied to plan the future of a mine. The objectives of a final pit plan; are determination of the extent and location of ore reserves, the allowable stripping to be accomplished to uncover the ore, the final pit surface intercept, final pit topography and the contained metal values in both ore and waste. The objectives of the plan must be consistent with corporate objectives as they pertain to profit, future investment in the mine, return on investment, alternative investments, conservation and perpetuation of the corporate entity. The subject will be treated in three parts: economic considerations, effect of leaching and pit design technique. At the outset, it is assumed; that the extent of and metal values in the mineralized area to be considered have been reasonably defined by development drilling and sampling.

Jan 1, 1968

By Stephen D. Hill, C. R. Ferguson, T. H. Jeffers, P. G. Bennett

The U.S. Bureau of Mines' Salt Lake City Research Center has developed porous polymeric beads containing immobilized non-living biological materials for extracting metal contaminants from waste waters. Immobilized biological materials include peat moss, algae, biological polymers, and other materials that demonstrate high affinities for heavy metals. The beads, designated as BIO-FIX beads, have distinct advantages over traditional methods of utilizing biological materials in that they have excellent handling characteristics and can be used in conventional processing equipment or low-maintenance systems. Toxic metals such as copper, cadmium, zinc, lead, and mercury are several of the many heavy metals effectively removed from mine waste waters using BIO-FIX beads, Continuous cyclic testing indicated that the beads continued to produce treated effluents which met National Drinking Water Standards (NOWS) after 150 loading-elution cycles. Adsorbed metals were removed from the beads using dilute mineral acids. In many cases, the extracted metals were further concentrated to enable processors to reclaim the metals, thus minimizing the generation of a hazardous sludge, Tests indicated that use of the beads in a low­maintenance system was particularly effective for treating remote acid mine drainage waters and small toxic seeps from hard-rock mining districts.

Jan 1, 1991

Dunn has written an excellent paper providing a wealth of advice on what is often the most costly consumable in the mineral processing plant. As he pointed out, grinding media selection and quality control can play a major role in successful plant operation. Owing to the economic importance of this topic, there are some important factors related to media sizing that I believe merit further comment. Dunn made reference to a slightly simplified version of the Azzaroni (1981) equation and pointed out its successful use for the Henderson SAG and Climax ball mills. Although both formulas are empirically based on successful plant experience, a notable discrepancy between them is that Bond has factored the work index by the ore specific gravity. This is invariably so, as the Bond work index is derived from the mass grindability (in grams per revolution) measured in a test mill with a fixed volume of solids load (Bond, 1961). A material having the same structural integrity but double the density of another will have double the grindability and just over half the work index. Thus, for the general case, specific gravity should be incorporated into any media sizing formulation that uses work index as the criterion for resistance to breakage.

Jan 1, 1990

By Terry Mattioli, Buck Bradshaw, Terry Fagg, Larry G. Nisle

Deposition of calcium carbonate scale on activated carbon in the Pinson Mining mill carbon column circuit was causing erratic gold recovery rate, long acid wash time, high carbon attrition and long strip times. Continuous addition of a blended antiscalant into the mill thickener overflow at 8 ppm reduced the average carbon acid wash weight loss from approximately 10% to < 2%. Cleaner carbon improved the gold loading rate in the mill column. The loading on Column I was increased to 175-225 oz/ton carbon from 125-150 oz/ton for a two-day carbon advance cycle. The higher loading capability has given Pinson more flexibility and better control of gold flow through their carbon adsorption, stripping and electrowin­ning processes. Preventing calcium carbonate build-up on activated carbon with this antiscalant reduced acid wash batch time. This enabled Pinson to acid wash and regenerate every batch of stripped carbon for all the adsorption circuits. Shorter strip times have also resulted from the lowering of the calcium carbonate scale level in the loaded carbon. Carbon consumption has been reduced and is now averaging 0.046 lb/ton ore for the first six months of 1990 compared to 0.072 and 0.083 lb/ton respectively in 1989 and 1988.

Jan 1, 1990

By Ronald R. H. Cohen, Margaret W. Staub

Two pilot scale bioreactors designed to treat acid mine drainage primarily using sulfate reducing bacteria were constructed underground at the Eagle Mine Superfund site in Minturn Colorado. The project was designed to test th applicability of microbiological treatment on water with high metals concentration and to test the process in an underground environment. Objectives were, 1) to compare metal removal, pH increase, and sulfate reduction in a single stage reactor with a double stage reactor of equal volume at varying flow rates; 2) to determine where within the substrate treatment occurs· and 3) to examine volume versus surface ara as a design parameter for optimizing metal removal processes. Results from the reactors showed that the single stage reactor and double stage reactor performed equally well for the removal of Cd, Cu, Pb, Fe, Mn, and Zn. pH increased above 6.5 in both reactors. Greater than 97% of metals were removed within the first ten inches of substrate. Volume proved to be a more useful parameter for determining removal rates than area. Using volume as a design parameter rather than surface area enables PMDT systems to be constructed as packed columns rather than broad wetlands, Thus, space requirements are significantly reduced.

Jan 1, 1993

By Raymond E. Krauss

The McLaughlin Mine is based on a world class epithermal gold deposit located in the coastal thrust fault of northern California, about 1 12 air km (70 air miles) north of San Francisco. Owned and operated by Homestake Mining Co., the McLaughlin deposit contains about 18 Mt (20 million st) of gold ore at an average grade of 5.2 g/t (0.152 oz per st), or about 93 t (3 million oz). The area was identified as a gold target by Homestake in early 1978. Drilling confirmed it to be a commercial deposit by 1980. The mine was then planned, engineered, built and brought into production by March of 1985. The deposit was historically a part of the Knoxville District. It was mined for cinnabar, which was used to produce mercury for use in recovering gold and silver in the Mother Lode and Comstock districts. At that time, the mine was called the Manhatten and later the One Shot Mine. It was worked for more than 100 years, producing about 76,000 flasks of mercury without any awareness of the presence of economic concentrations of gold. By 1978, the site was largely disturbed and entirely unreclaimed.

Jan 1, 1990

By S. G. McDowell

Automation techniques are used during the design stage of continuous miners to decrease the time required and ensure the accuracy of the design. This is followed by automated manufacturing processes to reduce manufacturing time and improve the quality and consistency of parts. Combined, the result is a more reliable machine that can provide ongoing production capability. With the use of automation to enhance operator effectiveness and monitor machine condition, the productivity of machines is also improved. Productivity of continuous miners doubled over a 10-year span (Fig. 1). Although this article focuses on the continuous miner, it should be recognized that production increases of the continuous miner would not be realized without increased capabilities throughout the rest of the mining system. There are several aspects of automation that have played a role in providing increased continuous miner productivity. Though some are considered indirect, they still had significant influence on the overall result. Basically, productivity increases are obtained by cutting, loading and transporting the coal at a maximum rate. In addition, these tasks must be consistent, with minimal downtime. Therefore, the miner had to improve in operational capability and reliability. Automation techniques used during machine design, manufacturing and operation have all played significant roles in achieving higher productivity.

Jan 1, 1991

By N. S. Tombs

This paper presents the experimental results of an ongoing investigation into various properties related to the performance and durability of concretes made using existing and new cement replacements. The process of cement and concrete production is investigated focusing on product performance and environmental performance. The overriding factor for the progression of a material will be product performance however; each material selected will have many intrinsic environmental benefits. The study combines Ordinary Portland Cement (OPC) with each cement replacement candidate using the most common replacement percentages, 10, 20, 25, 30 and 50 percent. A 35N/mm2 concrete is then prepared and analysed in the fresh and hardened state. In addition, a chemical and physical analysis of each replacement material has been performed and results compared to the control samples containing OPC only and Ground Granulated Blast Furnace Slag (GGBS) as a replacement. The results show that in their present form the replacements used in this research do not compare with the strengths achieved by the controls. The right balance of chemical composition and particle grading needs to be achieved to produce a realistic replacement material. The processes required to achieve this must strike a balance between monetary and environmental cost.

Jan 1, 2006