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By A. M. Marabini

Flotation of rutile with N-benzoyl-N-phenyl-hydroxylamine (N-BPHA) has been investigated. Initially, floatability tests were performed in a Hallimond tube. The results indicated that rutile was floatable in the pH range from 2 to 4 at N-BPHA concentration between 2x10-3 M and 2x10-2 M. Selectivity against hematite was recognized when operating at pH values below 2. Following the hypothesis of the formation of a surface chelate between N-BPHA and titanium ion, this compound was precipitated from a solution of Ti(SO4) to which N-BPHA was added. I.R. spectrometry oft the rutile before and after treatment with N-BPHA solution confirmed the presence on the rutile surface of the same compound. The absorption isotherm and kinetics were determined by analyzing N-BPHA in solution with an U.V. technique. A hypothesis for the mechanism of adsorption of N-BPHA on rutile is suggested.

Jan 1, 1982

By MOHAMED WAEL, ANASTASIA GOEVA, ABDULAZIZ TAWFEEQI, IHTISHAM TARIQ, S. M. ZAKIR HOSSAIN, NIAZ ALI KHAN, MUHAMMAD FAISAL IRFAN

Carbon dioxide (CO2) mineral carbonation is a carbon capture and storage (CCS) technique that can sequester CO2 permanently in the form of durable carbonate minerals. Extendable permanent storage capacity — onshore and offshore storage reservoirs — and the exothermic nature of the mineralization process make this technique attractive [1]. In the present study, maximum carbonation efficiency for aqueous mineral carbonation was achieved through two steps: optimization of calcium leaching from cement kiln dust followed by the reaction of pure CO2 with the calcium hydroxide precipitates formed by hydroxylation using sodium hydroxide (NaOH). Optimization of calcium leaching is highly important, as it is a rate-limiting reaction step in mineral carbonation and also influences and enhances the carbonation efficiency. To maximize the calcium leaching as well as carbonation efficiency, response surface methodology — with either Box-Behnken design or central composite design — was applied. It is the most well-known statistical, fully randomized and bias-free method for determining optimized conditions using quadratic regression models.

By Brian F. Osborne

A continuous on-line particle size analysis system for solid/liquid suspensions is described. The basic sensor utilizes a centrifugal principle to separate particles according to size, the resultant separation being measured by means of beta-ray attenuation. Results obtained when analyzing a variety of materials at sizes from 65 mesh (210 microns) to 20 microns are discussed in de- tail. Accuracies better than 2% are demonstrated. The effects of particle specific gravity, and mixtures of materials of diverse specific gravities, are discussed from a practical and theoretical viewpoint. It is demonstrated that particle specific gravity has a minimal effect on the size reading obtained. This renders the instrument suitable for handling materials where the ratio of light to heavy component may change. The design of the first commercial installation of this instrument is described in detail. This installation will be capable of analyzing three streams in sequence, measurement at three particle sizes being effected on each stream.

Jan 1, 1973

By Eugene E. Brucker

In recent years, there has been increased interest in construction problems presented by karst topography. Twenty-five years ago, karst areas were by-passed for development. Today, the high cost of land and population pressures are requiring utilization of karst areas. Areas exhibiting karst features can be satisfactorily developed so that construction can proceed in a normal manner; or the areas may be left undeveloped and the underground drainage system abused by improper use causing or contributing to structural collapse, excessive erosion, and a grave threat to the stability of land development and the environment. The term "karst" is a comprehensive term applied to areas underlain by soluble rock that possess a topography formed chiefly by the dissolving of rock and the diversion of surface waters to underground routes. There are four features which contribute to the maximum development of karst. 1. A soluble rock, preferably limestone, must be present at or near the surface of the ground. Occasionally, dolomite will suffice.

Jan 1, 1970

By R. D. Lopez

The concept of "heat recuperation" for the grate-kiln pelletizing system was first implemented at the Sydvaranger plant in Norway in 1974. Essentially, heat recuperation involves bringing hot air from the second stage of the pellet cooler to the drying zone to increase drying-air temperature to the maximum limit. 'Burner-fuel savings result from a lower kiln secondary-air mass flow at a higher temperature. Because of the fuel benefits achieved at Sydvaranger, heat recuperation has been included innumerous new grate-kiln plants built since then, and some older plants have been retrofitted for heat recuperation. In recent years there has been much confusion about the fuel benefits of heat recuperation. To answer some of the questions, a mathematical model was developed and plant tests were conducted at Minntac Phase 111. Minntac is a magnetite taconite concentrating and pelletizing plant, and Phase III has two indurating lines. This paper presents the results of the studies and plant tests.

Jan 1, 1980

By Stanley O. Reichert

At nuclear facilities, three types of radioactive waste must be managed: (1) high-level liquid waste containing fission products from the chemical separation of irradiated uranium, (2) low-level condensates from the concentration of the high-level waste, and (3) dry solids such as obsolete process equipment, spent ion exchange resins, and irradiated metal scrap. The geological and environmental characteristics of a site are important considerations in planning the waste management program. At the Savannah River Plant, low-level liquids and dry solids are safely and economically placed in the soil where the geologic and hydrologic conditions are favorable. Within the general area where the waste originates, studies are made to locate seepage basins and burial grounds in the most favorable sites: (1) soils should have a high ion exchange capacity and moderate to low permeability, (2) the water table should be deep, and (3) burial sites should be relatively distant from the nearest flowing stream.

Jan 1, 1968

By H. Zhu, A. G. Journel

Qualitative and interpretive information as obtained from geological and/or geophysical studies, in addition to precise measurement, is incorporated into the estimation process through an indicator variable. The indicator conditioned estimator is formulated as a cokriging, and its expression is data value dependent as opposed to that of the traditional kriging estimators. The solution of the dual cokriging system provides simultaneously an estimate of the unknown and an estimate of the conditional probability that the unknown belongs to a specific population or class. Being an unbiased and minimum-error-variance estimator by construction, the indicator conditioned estimator is better in the least square sense than the ordinary kriging estimator because it uses additional information carried by the indicator data. A case study using a large reference database is presented; the indicator conditioned estimates have a smaller conditional bias and a smaller error variance than the ordinary kriging estimates. The results also showed that the indicator conditioned estimator is more efficient for selection in mining.

Jan 1, 1990

By S. Nunoo

The shape of particles has a significant effect on the shear strength and deformational characteristics of granular materials. Weathering can change the grain shapes. For example, more weathered sands tend to be rounder regardless of particle size. Particle shape analysis was performed on samples collected from the Questa mine rock piles, a debris flow and the pit alteration scar. In order to increase the validity of the particle shape analysis, 4 persons including 2 geologists and 2 mining engineers were involved in describing the particle shapes. The results of this analysis indicate that rock fragments in the collected samples are mainly subangular, subdiscoidal and subprismoidal. The sphericity and angularity of the rock fragments of the older analogs are similar to those of the rock piles. This suggests that short-term weathering (<100 years) has not noticeably changed the particle shapes at the test locations. Rock piles made of more angular particles are more stable compared to rock piles with rounded particles.

Jan 1, 2009

By Gary Beerkircher

WaterFlush Technology and WaterFlush crushing offers significant operational ben­efits in gold milling operations. WaterFlush crushing is the technology that Nordberg Inc. has developed, tested and proven in an actual operation during the 1980's. Patents have been obtained for both the process and the apparatus of implementa­tion. WaterFlush involves volumetric process controlled water flow into the ore feed cav­ity of a WF cone crusher. While the addition of water in itself is not new, the con­trolled amount of water coupled with the WF crusher operating parameters are revolution­ary. The WF crusher is a specially designed version of Nordberg's Omnicone crusher oper­ating at higher speeds, with a reduced ec­centric throw and higher horsepower capabil­ity. The results are increased capacity, higher crushing energy input and a finer crusher product. The WF crusher product is a slurry containing 40-60% solids by weight.

Jan 1, 1990

By Paul F. Ziemkiewicz, John J. Renton, Thomas Rymer

Any viable model or deterministic formula used to make predictions must follow certain criteria. The standard models and procedures used to project acid load from mining activities operate from a number of assumptions, some of which, although logical, are scientifically oversimplified and, hence, invalid. Highly variable field parameters have lead to highly variable acid projections. Kinetic tests are in themselves misnomers in that no parameters associated with chemical reaction kinetics are ever determined. Sampling error coupled with assumptions made as to the distribution mode of pyritic materials in rock units can lead to highly inaccurate conclusions explaining why acid generation often occurs where none is predicted. The fact that probability theory and paradigms governing luck and chance have not been incorporated into the science of acid prediction undermines any credence placed on such projections. To date, with few exceptions, the acid prediction is logically closer to a game of chance than practical science.

Jan 1, 1991

By M. Misra, J. Nanor

The removal and stability of arsenic over a wide pH range (3.0-10.0) from synthetic solutions and industrial waste effluents (including mining waste tailing slurry) can be accomplished with addition of impure lanthanum chloride alone or in conjunction with ferric sulfate. The long term stability of these correspond­ing precipitated compounds is critical from the disposal stand­point. In this paper test results of this new process for arsenic removal and stabilization from the above mentioned systems are presented. Also, precipitated arsenic compounds (lanthanum arsenate, lanthanum-ferric arsenate, ferric-lanthanum arsenate and ferric arsenate) from synthetic solutions have been charac­terized. The characterization technique used was XRD. XRD patterns which shows that the lanthanum arsenate and lan­thanum-ferric arsenate formed in acidic and alkaline pH at room temperature are crystalline. On the contrary, ferric arsenate and ferric-lanthanum arsenate compounds formed under the same conditions as lanthanum arsenate were amorphous.

Jan 1, 1998

By Warwick Hoffmann, Robin Batterham, David Conochie

CRA has been actively involved in developing a bacterial oxidation process for the treatment of low grade, refractory gold resources. Success in this application is dependant on the design of large, energy efficient reactors. It was identified at an early stage, that the conventional, bottom sparged bioreactor is inherently inefficient because air must be compressed to a pressure above that at the bottom of the tank. This inefficiency increases as the size of the reactor increases. CRA has developed a novel approach to the aeration problem. In this, venturi aeration is used to aspirate air into a liquor stream. The stream is then reintroduced at the top of a draft tube bioreactor. The advantages found with this technique include · low energy requirements and high oxygen utilisations. From results at the 30 m3 scale, we predict an energy usage of -500 kWh/t sulphur oxidised at a scale of 1000 m3.

Jan 1, 1993

By F. W. DeVries, J. Brent Hiskey

The search for noncyanide lixiviants for treating gold and silver ores and concentrates is not a new endeavor. However, in recent years, the overall activity to seek a less environmentally controversial reagent than cyanide has occasioned considerable developmental work. While the elegant economy and simplicity of cyanide, because of its selectivity and the ease of recovering gold and silver from the cyanide complexes, is well recognized, two failings have justified the search for alternates: increasing concerns and costs to assure avoidance of environmental damage from cyaniferous liquids and solids, and the need to simplify recovery of gold and silver from refractory ores. Generally, process development work to date on the alternate reagents has lacl<::ed environmental focus ( Hiskey and Devries, 1992). This paper covers briefly the chemistry of various alternates to cyanide and reviews their environmental implications. In each case, environmental overtones are reviewed following the chemistry. For ease of follow-up, the authors have listed sources of information in detail. Alternates examined include:

Jan 1, 1992

By J. A. Meech, C. A. Harris

Expert Systems are being used in the Mineral Industry with ever­increasing frequency. A major advantage of these systems over conventional computer programs is that the knowledge and intelligence of human experts can be captured directly onto a computer for transfer to novices or other lesser experts. These programs allow rapid construction of process models that are not well-understood in fundamental terms, but for which good operational reasoning exists. In addition, user-friendly access to "high-tech" knowledge can be provided to unsophisticated personnel who otherwise might be turned off by unintelligible jargon. As such, these systems can be important training tools for new operators. This paper describes the features of Expert Systems that relate to gold processing plants. Applications include grinding circuit control, supervisory control of reagent addition and pulp density, monitoring and control of CIP/CIL carbon inventories and the operation of carbon stripping and regeneration facilities. A consultative Expert System is described that provides advice on laboratory cyanidation testwork

Jan 1, 1992

By S. Vukcevic, R. Winby, P. C. Miller

There is considerable interest in the bioleaching of chalcopyrite concentrate for the production of copper. The residue of bioleached chalcopyrite often contains gold that needs to be recovered. Despite the high efficiency of copper bioleaching, the residue may contain appreciable quantities of copper, and the difficulties of cyanidation of gold from copper bearing materials are well recognised. This paper reports the results of using different methods to recover the gold values from bioleached chalcopyrite concentrate. In particular, the behaviour of cyanide and cyanide in the presence of ammonium ions as gold lixiviants were studied. The ammonia was employed to reduce the impact of the copper on cyanide consumption. Thiosulphate as a gold lixiviant was also employed with the aim of achieveing rapid leaching rates and to reduce the impact of residual sulphur species on lixiviant consumption. Bromine solution was used to research acidic gold leaching. The paper describes the advantages and disadvantages of using different reagents with respect to reagent consumption, selectivity and kinetic efficiency.

Jan 1, 1997

By David Martin Menne, Chris Campbell-Hicks

Optimisation of many oxide gold processing facilities, in most cases, either does not really take place or if it does take place it happens too late or takes too long. This is unf01tunate as extra profits and early cash flows are lost, in new projects, and/or may not be realised at all in others. The situation is easily avoid­ed by ensuring that the plant optimisation happens immediately following commissioning or for an established operation simply 'biting the bullet' and making it happen immediately as a 'better late than never' decision. This type of optimisation requires intense undiluted focus on each and every problem or restriction that contributes to reduced plant performance or bottlenecks, without letting go, until the predetermined outcome is produced. Thus a dedicated person with specific quantative goals is required for these tasks. Methodology and strategies for optimi­sation are discussed and numerous examples presented. The secret of successful heap leaching is discussed.

Jan 1, 1998

By Lothar Baumann, Wilhelm Knickmeyer

In mechanized roadheading predominantly two methods of rock breakage are applied at present: the cutting method by means of picks and the cutting/crushing method by means of roller cutters. Both systems meanwhile reached a high degree of technical development and consequently show very few possibilities of further improvement. While application of hard-metal picks is limited by rock hardness, the roller cutters require a high specific thrust, and, accordingly, heavy carrier systems. Roller-cutter equipped tunneling machines are therefore only cost-effective in hard-coal mining if the high investments for transport and assembly are justified by a corresponding length of road to be headed. The limit for acceptable cost-effectiveness is at present a minimum heading length of approximately 3 km. In order to improve the specific cutting performance of roller cutters by activation, Bergbau-Forschung carried out a research project sponsored by the Commission of the European Communities and the provincial government of

Jan 1, 1981

By Steven G. Vick

Not too long ago a mill superintendent, when asked where his tailings were being disposed, could simply shrug his shoulders and point to the open end of the thickener discharge pipe. This “out of sight, out of mind” approach to tailings disposal is a practice of the past. Today there are very few planned hardrock or energy-related mining facilities where tailings disposal has not been identified as the major area of impact and controversy. In fact, development of some ore bodies has been stymied altogether by lack of suitable sites or methods for tailings disposal. The bottom- Iine result is that tailings disposal often controls the permitting lead time and has a significant influence on construction cost (up to 2070 in some cases) of new minemill complexes. The following article, the first in a series of three, explores technical background and historical perspectives on siting and design of tailings impoundment facilities.

Jan 6, 1981

By M. Li, J. D. Miller

Existing process technologies for the production of soda ash from trona involves dissolution in hot brine, sedimentation and filtration for the removal of impurities, and subsequent crystallization for the recovery of soda ash. In this regard, mining and operating costs, particularly energy costs, are higher than desired. A preferred processing strategy might be to remove gangue mineral contaminants from the plant feed prior to dissolution in hot brine. Such a preprocessing strategy at ambient temperature and pressure has been limited by the lack of satisfactory process technology. Now based on recent results from laboratory research at the University of Utah it seems that the run-of-mine trona ore can be treated at ambient temperature and pressure using a special flotation procedure to separate the gangue minerals and make a trona concentrate with a purity of almost 99% trona at a recovery of more than 97%. The concept of such a new processing strategy is discussed with respect to current plant practice.

Jan 1, 2002

By G. T. Adel

Hindered-bed separators are often used in the minerals processing industry to classify particles according to size and density. A new technology, known as the CrossFlow, was recently developed to overcome some of the limitations associated with hydraulic separators. The innovative feature of this unit is a novel feed presentation system that improves separation efficiency and capacity. In the present work, a detailed process engineering evaluation was conducted to determine the basis for the improved performance of this unit. The evaluation included controlled separation tests using well-characterized feeds, particle and liquid tracer experiments, and mathematical modeling studies. Data obtained from this work show that the new separator is capable of maintaining good separation efficiencies at higher solid feed rates than traditional designs due to improved hydrodynamics in the separation zone. This paper reviews the operating principle of the CrossFlow separator, discusses the results of the tracer experiments and modeling studies, and presents test data obtained from recent laboratory and plant trials.

Jan 1, 2001