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By A. Unal

Coal resource characterization usually calls for estimating more than one variable over a block or node simultaneously. Within the realm of geostatistics, each variable has been evaluated independently from the others assuming a lack of significant correlation. Research conducted with coal seams, however, has shown that the variables of immediate interest, such as seam thickness, ash, sulfur content, and density depict some correlation schemes in distinct zones, if not throughout the entire area. The above findings have two immediate consequences : (1) correlation analyses provide guidelines to determine the geologically distinct zones, and (2) where possible, cokriging should be used instead of kriging. This will maximize data utilization decreasing the frequently criticized high estimation errors. The cokriging formulation will also provide more accurate estimates for under sampled variables using better-sampled ones. This is a common case with coal with regard to the non-cored reconnaissance drill holes for which only very few variables were recorded. A case study illustrates the improvements that may be obtained by taking advantage of the intervariable correlations.

Jan 1, 1986

By J. Hong, K. Han, C. Park, C. Yoon, H. Yoon, N. Kim

The contents of three platinum group metals (PGM-platinum, palladium and rhodium), from the spent automotive catalyst, and two NIST SRM (National Institute of Standard and Technology Standard Reference Material, Used Auto Catalysts) were determined by the X-ray fluorescence (XRF) spectrometry. The XRF technique has been proven to be a fast, effective and accurate method in determining not only PGM but also other solid materials of less soluble for wet digestion analysis. The detection limit of the XRF analysis is better than that of the inductively coupled plasma mass spectrometry which usually requires significant dilution to avoid high dissolved solid concentration. However, the XRF technique suffers from a strong matrix dependent problem. The objective of this study was to examine the applicability of the XRF analysis where the sample matrix was not exactly the same as the standard materials with particular reference to PGM analysis. This study enabled to compare the effect of various matrices including alumina, iron, copper and nickel on determination of the contents of PGM.

Jan 1, 2004

By Xiangze Shu, Yuzhong Xing

All programs used to optimize main fan nowdays have to be run on the large and medium- sized computers. With a lot of array elements, complex processes, low convergence speed and large storage, these programs are both time consuming and difficult to be used in the micro computer. This program uses two languages (dBASEIII and BASICA) to calculate the network and to choose the fan respectively. It allows user to compare and choose the parameters of various kinds of fan and to transfer the selected fan parameters to the master program by a data communication system. Then the user can get the air quantity, the air pressure, the power and the efficiency of the main fan. The advantages of this program arc as follows: 1. It can be run on IBM-PC or compatible micro computer. 2. It can select a fan more quickly and less time consumingly. 3. It can choose desired one or a set of fans according to user's requirements. 4. It is suitable for the research institutions and coal mines.

Jan 1, 1991

By C. Flores, L. G. Twidwell, T. S. Jordan

It is well known that manguniferous silver ores containing manganese intimate) associated with silver are not amenable to conventional extraction methods. The segregation process has been applied primarily to the recovery of copper from oxidized and oxide-sulfide ores. A new alternative process, consisting of segregation roasting followed by flotation to recover the silver from refractory manganiferous silver ores, was studied using a 23-factorial experimental design. Laboratory investigations were conducted on a manganiferous silver ore analyzing 0.02% copper, 0.09% lead, 0.33% zinc, 12.55% manganese and 187 g/t silver. The investigation was designed to study the effects of the addition of salts, coke and copper (11) oxide on silver recovery. The results indicated that 79.3% of the silver can be recovered in the absence of copper oxide and 88.4% of the silver can be recovered with a copper oxide content of 1.5% at 750°C, 2% salt (NaCI). 1 % coke and 30 min of roasting. It was concluded that the addition of copper oxide improves silver recovery.

Jan 1, 1996

By B. J. Arnold

A coal's size distribution clay content and moisture content can affect its handling behavior. But the combined effects of these properties and the effects of other properties are not known. Research underway at CQ Inc.'s (formerly EPRI's) Coal Quality Development Center (CQDC) and at Iowa State University (ISU) will answer these questions as part of a four year project to develop a coal handleability index for utilities to use when specifying coals. This paper will present preliminary data from the first year of the project, which focused on obtaining data on the chemical and physical properties of carious coals and their measured handling properties. Additionally, size, ash and moisture analyses and shear test data for several coals used at one power plant will be presented along with correlations between these physical and chemical properties and the measured handling properties. These data lead to the conclusion that while moisture content is the most important variable, the amount of -44 µm (-325 mesh) coal fines is a significant factor in determining coal handling behavior.

Jan 1, 1992

By M. H. H. Mahmoud, T. A. El-Barbary, E. A. Abdel Aal, I. A. Ibrahim, A. K. Ismail

Fertilizer-grade phosphoric acid with a P2O5 concentration of 50% should contain less than 1.5% Fe2O3, otherwise, the P2O5 water solubility of the fertilizers prepared from high-iron acids will be low. High-iron Egyptian phosphate concentrates fromAbu-Tartur and Sebaiya- West were leached with sulfuric acid and recycled phosphoric acid to produce 50%-P2O5 phosphoric acids containing 4.0% and 2.7% Fe2O3, respectively. The high iron contents were reduced to the industrially accepted limit of 1.5% Fe2O3 by precipitation with potassium sulfate. The factors affecting the effi¬ciency of the precipitation process, e.g., temperature, time and K2O/Fe2O3 ratio, were systematically studied, and the optimum conditions were achieved. The clarification of the prepared phosphoric acid from iron-containing sludges was also investigated by varying the time and temperature. The utilization of the separated sludges as fertilizer and recovery of P205 by pulping in water were also evaluated.

Jan 1, 2000

By A. M. Marabini, V. Alesse, Belardi. G.

An alternative flowsheet was designed for the flotation treatment of a complex sulfide ore from the Sotiel Mine in Spain. The ore contains 0.71% Cu, 2.24% Pb and 5.63% Zn. Two specially developed synthetic collectors, methyl-mercapto-benzoxazole (MMBO) and 6n-propoxy-mercapto-benzo-thiazole (PMBT), were examined. MMBO exerts a specific action on copper and zinc minerals after treatment with copper sulfate, and PMBT exerts a specific action on Pb minerals. Flotation operating variables (pH, frother type, frother quantity and feed particle size) were examined by means of rougher flotation tests to determine the optimum conditions for the new collectors. Once the optimum conditions were determined, a series of open flotation circuits were run on feeds of various particle sizes (obtained by different types of grinding). The objective was to obtain high-grade Cu and Zn concentrates. The results of the open-circuit tests demonstrated that a Cu concentrate grading from 18% to 23% Cu and a Zn concentrate grading from 40% to 48% Zn can be produced.

Jan 1, 1996

By S. Majumder

The longwall face supports are provided to prevent the caving of the immediate roof at the working face. The thickmess of the immediate roof may be obtained from the working height and the average bulking factor. A strong bed, capable of withstanding maximum bending moment among the beds within the above roof, can be identified. The load on the strong bed may be obtained by finding out the overlying beds that will rest on the former during sagging. The limiting span, L, for this unsupported loaded bed, as a beam with built-in ends, can be calculated. The support density required at the supported span (face to goaf edge), a, during the first fall, is now estimated with a view to have a safety factor 2 at the face end, when bending failure occurs at the barrier end. However, the above value is inadequate to provide necessary safety margin against bending failure at the face end, during the subsequent cavings as cantilever, for L/a less than 20.6. d For the latter case a separate expression is derived.

Jan 1, 1986

By Mulong Yu, Yosry A. Attia

Beneficiation of high magnesium Florida phosphates requires ultrafine grinding to liberate the dolomite (the main source of magnesium), and a separation process capable of dealing with ultrafine sizes such as selective flocculation. The objective of this study was to investigate the feasibility of separating dolomite from apatite ultrafines by selective flocculation. To achieve this objective, selective polymeric reagents to either dolomite or apatite must be first designed and synthesized. This challenging task was accomplished by carefully selecting complexing/chelating agents which are selective to either the Ca or Mg ionic sites on the minerals, and incorporating these reagents into the structure of long chain water soluble polymers to obtain either selective flocculants (with high molecular weight, MW, polymers), or selective dispersants (with low MW polymers) to either the dolomite or the apatite particles. Synthesis and testing of these polymers on individual and mixed mineral slurries, and on a sample of natural high magnesium phosphate ore, have been attempted and the results are described in the paper. The preliminary results showed encouraging signs for the feasibility of selective flocculation separation of dolomite from apatite.

Jan 1, 1993

By Péter Siklósi, János Zámbó, Károly Solymár

It is fundamentally important to evaluate bauxites in a realistic, commercial way on the basis of the processing technology both for the supply of existing alumina plants and for the designing of new ones. The evaluation system developped by ALUTERV-FKI consists of chemical, mineralogical, texture and technological testing. The commercial value of bauxites is basically determined by their available alumina content and the caustic soda consumption required for their processing. However, their contaminants have to be taken into consideration, too. The commercial value of bauxites also depends on the processing technology and their possibly unfavourable chemical and mineralogical composition can be /at least partially/ compensated by R&D efforts. The selection of the optimum processing technology and the effects of further developing the same are demonstrated on monohydrate bauxites containing goethite and carbonates. Some of the technological solutions /desilication or deironing of bauxites, hydrothermal treatment of the digestion residue / make at the same time possible the complex processing of the bauxites, the profitable utilization of their main components.

Jan 1, 1984

By D. Harris, M. Osterberg

This paper examines the economics of acquiring mineral exploration rights by royalty-rate bidding when the royalty basis does not provide for full cost recovery. Bidding takes place prior to exploration and the documentation of actual tonnage and grade. Consequently, it increases considerably the risk to exploration capital when the fraction of cost recovered is small and the product price exhibits large fluctuations. Price and grade risk are demonstrated on a 360-Mt (400-million-st) porphyry copper deposit by Monte Carlo simulation of discounted-cash-flow analysis. Copper price is modeled as a stochastic price process, and costs are based on US Bureau of Mines cost models. When both grade and price risk are considered, the probability for a negative NPV is 0.54, given a royalty rate of 5% applied to a basis that allows the recovery of costs up to 50% of product price. Investment risk could be considerably reduced by defining the royalty basis to allow greater cost recovery. Although such a basis would require society to share in the risk, society would benefit from greater resource development.

Jan 1, 2000

By T. R. Ellis

The author attempted to concurrently apply the US Uniform Standards of Professional Appraisal Practice (USPAP) and the Australian VALMIN Code to a complex mineral property appraisal assignment and previously to some modest assignments. This led the author into many severe difficulties. These difficulties included the high standards needed in the work of others and information and statements required from the client under the VALMIN Code. The exercises highlighted many positive features of both sets of standards. However, the author concluded that, without modification, VALMIN is incompatible with USPAP and the US regulatory environ¬ment. The author found that VALMIN violates US legal decisions regarding real property appraisal due to its requirement to include many items of business value. The US Securities and Exchange Commission's prohibition on reporting quantitative resource estimates proved to be a severe problem under VALMIN. Some VALMIN requirements could not be met due to the extent and quality of documents specified. Implications and thoughts regarding the development of a set of US minerals appraisal standards are discussed. Management considerations for complex mineral-property appraisal assignments are also presented.

Jan 1, 2000

By Anthony G. Fonseca, W. W. Wen

About 45-50% of the coal mined in the U.S. passes through coal preparation plants; east of the Mississippi River this number increases to about 75-80%. Although the cost for coal preparation is worthwhile to some, the coal industry faces the challenges of continuing downward pressure on the price of coal and the impact of new environmental regulations. Coal preparation, as commercially practiced today, is an effective process achieving 75-803 ash reduction, 15-8m trace element reduction, and 85-90% Btu recovery; it is less effective for pyrite reduction (35-70%), and on-line operating time (40-60%), and suffers from obsolete control systems. Methods will be discussed for reducing costs of coal preparation and improving the performance of coal preparation plants. Comments are included on equipment selection, especially for -28 mesh coal, and prep plant operation and control practices. Btu recovery, ash and pyrite reduction, fines processing including dewatering and slurry fuel use options are emphasized. Trace element removal and expert control systems for maximization of prep plant operation also will be highlighted.

Jan 1, 1995

By J. V. Calara, J. D. Miller

The sign of the surface potential for complex non-reactive ionic solids cannot be predicted solely from consideration of the hydration energy of gaseous ions which constitute the ionic lattice. Accurate analysis of these systems must involve the hydration energy of surface ions, which requires knowledge of the crystal structure, the identification of cleavage planes, and the calculation of binding energies of surface ions. Surface binding energies for ionic solids can be deter- mined if the Surface Madelung Constant is known. A computational technique was developed for the calculation of Madelung Constants for infinite lattices which gives excellent agreement with the values calculated by other more complicated methods reported in the literature. Extension of this technique permits the calculation of Surface Madelung Constants and binding energies of surface ions, ?Us, for semi-infinite solids. The hydration free energy of gaseous Ions, ?Fh, together with the calculated binding energy of surface ions, ?Us, allows calculation of the hydration energy of surface ions, ?Gh, as for the case of the ionic solid, MX:

Jan 1, 1976

By Josef Arnold, Norbert Fuegenschuh

The “Eggequerung” is an important part of the German Railway’s (Deutsche BahnAG) modernized Dortmund—Kassel line. The heart of this 13-km-long (8 miles)construction lot is the double-track Egge Tunnel with a total length of 2,880 m(9,450 ft.). The tunnel was driven using the New Austrian Tunnelling Method (NATM).The construction contract also called for a reinforced concrete secondary lining, guaranteed for a full water pressure of 30 m (100 ft.) water column. Preliminary geological study already showed that very problematic geological-hydrological conditions would have to be expected. This talk describes the chosen NATM driving concept that was adapted to the prevailing geological and hydrological conditions, the special driving method applied in geologically difficult zones as well as the water control concept used during driving. The flexibility and the limits of the NATM under exceptional hydrological conditions are illustrated. Also described are reinforced concrete lining works for the watertight secondary vault (reinforced concrete secondary lining without water-proofing membrane).

Jan 1, 2003

By Bob Rautenberg, Luminita Calin

The Tunnel and Reservoir Plan (TARP), commonly known as the Deep Tunnel Project, was developed by the Metropolitan Water Reclamation District of Greater Chicago as a two-phase solution to the problem of waterway pollution and basement flooding due to sewer system backups created by the combined sewer overflows. With only one contract left before completion of the Phase I tunnels—the 12.4 km(7.7 mi.) long Little Calumet leg—the pollution control phase of the 175.7 km(109.2 mi.) long system will be 93% complete, once the Torrence Avenue tunnel project comes to an end. This paper describes the Torrence Avenue tunnel project, currently under construction by the joint venture of Kenny (Sponsor) / Kiewit / Shea. Mining of the10.4 km (34,151 feet) long and 8.3 m (27'-4") diameter mainline tunnel was completed in a record thirty-one-weeks period and the concrete lining is nearing completion. Details on the complete muck handling system, numerous mining and concrete lining records will be given.

Jan 1, 2001

By XUEWEN WANG, Changda Zhang, Huaguang Wang, Mingyu Wang, Bin Hu

The copper smelting process produces plenty of copper slag every year, which is a hazardous solid waste, but a secondary resource. In the present study, the extraction of copper, nickel, and cobalt from copper slag was investigated through the process of sulfation roasting–water leaching and the process of sulfation roasting–sulfate decomposition roasting–water leaching respectively. Compared with the process of sulfation roasting–water leaching, the process of sulfation roasting–sulfate decomposition roasting–water leaching is a better choice, which could not only get almost the same leaching of copper, nickel, and cobalt as the former process, but has a lower leaching of iron and aluminum. For the process of sulfation roasting–sulfate decomposition roasting–water leaching, the leaching of Cu, Ni, and Co reached up to 74.2%, 71.1%, and 69.6% respectively, under the optimal conditions including sulfation roasted with 80 wt% sulfuric acid addition at 200 °C for 60 min and sulfate decomposition roasted at 650 °C for 60 min, followed by water leached at 90 °C for 30min with a liquid–solid ratio of 2 ml/g. The leaching of Fe and Al was only 4.9% and 17.6%.

May 4, 2020

By Ali Kazmi, Wern-ping N. Chen

A load rating procedure was performed to evaluate safe load capacity of the Port of Miami Tunnel (POMT), FDOT Tunnel No. 871071 SR 887. The rating procedure performed on a total of eleven stations beneath roadways and with fill depth less than the tunnel exterior diameter (42 ft). Calculations on tunnel sections passing beneath roadways were performed to evaluate the structural response of the sections subject to moving vehicular loads, dead load, and earth pressures. Ratings were performed in accordance with AASHTO and FDOT guidelines. The procedure considered two types of vehicles (HL-93 and FL-120) and two rating levels (Design level and Permit level). As part of HL-93 vehicle, Tandem load was also considered for rating, separately. For HL-93 and HL-93 Tandem, inventory and operating level ratings were performed. The results show rating factors are high. The minimum rating factor is 16.8 using Inventory truck HL-93. For Permit level using FDOT FL-120 truck the minimum rating factor is 6.9. As can be seen, rating factors are higher than comparable analysis for bridges. This paper explains how the procedure can be implemented for tunnels and evaluates the rating results.

Dec 1, 2022

By Frank E. Chase

Preventing pillar squeezes, massive pillar collapses, and bumps is critical to the safe and efficient recovery of coal during room-and-pillar retreat mining. To help prevent these problems, the U.S. Bureau of Mines (USBM) has developed the Analysis of Retreat Mining Pillar Stability (ARMPS) computer program. ARMPS calculates stability factors (SF) based on estimates of the loads applied to and the load-bearing capacities of, pillars during retreat mining operations. The program can model the significant features of most retreat mining layouts, including angled crosscuts, varied spacings between entries, barrier pillars between the active section and old (side) gobs, and slab cuts in the barriers on retreat. It also features a pillar strength formula that considers the greater strength of rectangular pillars. The program may be used to evaluate bleeder designs as well as active workings. A data base of 110 pillar retreat mining case histories has been collected across the United States to verify the program. It was found that satisfactory conditions were very rare when the ARMPS SF was less than 0.75. Conversely, very few unsatisfactory designs were found where the ARMPS SF was greater than 1. 5.

Jan 1, 1995

By Alafara A. Baba, Yakubu A. Dallatu, Kehinde I. Omoniyi, Shemang Y. Chindo, Edith B. Agbaji

As a result of the rise in global demand for pure copper, there is urgent need to consider the processing of low-grade chalcopyrite ores. Ammoniacal leaching solutions have been reported as an effective and efficient leachant for the dissolution of chalcopyrite. This work reports different parameters that influence the leaching kinetics of a Nigerian chalcopyrite-rich siderite ore obtained from Wase Local Government Area, Plateau State, Nigeria, and assayed as 11.30 wt% of Cu. At the optimum leaching conditions (0.4 mol/L NH3-( NH4)2SO4 leachant concentration; 75 °C reaction temperature; 45 μm particle size), the extent of chalcopyrite ore dissolution reached 87.4% within 120 min. The dissolution rate was affirmed to conform to the diffusion control mechanism with the activation energy, Ea, of 38.84 kJ/mol and a reaction order of 0.661 for the leachant concentration being established. The leaching mechanism was affirmed by characterizing the raw ore and the leached product by XRD and SEM-EDS analysis. Ascertaining optimal leaching conditions for copper using alkaline leachant is advantageous from the environment and economic points of view.

Jan 6, 2023