Search Documents

By P. Verhoeven, G. Hefter, P. M. May

The dissociation (ionisation) constant of hydrogen cyanide, pKa(HCN), has been measured by high precision glass electrode potentiometric titrations in saline solutions containing up to 5 mol/L sodium chloride. The dissociation constant of water that is necessary for the calculation of pKa(HCN) has also been measured. In saline solution, and in contrast to literature values, pKa(HCN) changes considerably at both high and low ionic strengths as a result of changes in activity coefficients. In addition an equation is presented, using literature data, that describes the variation of pKa(HCN) with temperature up to 150°C. The significance of the changes in pKa(HCN) for optimising the pH of alkaline cyanide gold recovery streams is briefly discussed.

Jan 1, 1991

By Joel K. Witt, Jackson G. Jenkins, Wendy M. Gort, Brent A. Whitman

A major concern for operators of leaching/SX-EW plants is a phenomenon known as gunk or crud. The build up of gunk is typically the result of fine particulates which are transported via the leach operation to the solvent extraction plant. The particulates develop into a solid layer that concentrates at the aqueous/organic interface. This can cause phase separation problems which can result in entrainment and other deleterious operating conditions. Most operations physically remove the gunk from the SX settlers and process it via a centrifuge or coalescer to remove valuable organic. While both methods have served for many years, Magma is currently evaluating the use of a chemical surfactant which induces a definitive separation of particulates from organic.

Jan 1, 1994

By A. M. Johnson, D. H. Carlson, D. L. Johnson, S. T. Bagley

A biologically assisted ferric iron leaching system was evaluated for in situ recovery of three copper sulfide oresfrorm northern Michigan. Laboratory scale bacterially assisted ferric sulfate leaching tests were run on the three ores. A T. ferrooxidans strain was found that could be adapted to copper in solutions at concentrations as high as 20 g/L. Column leaching of 4.5 to 2 mm (-4 +I0 mesh) material yielded extractions of 80-90% copper from one ore and 70 and 60% from the other ores. The highest copper extractions were from the Mount Bohemia ore deposits located in the Keweenaw Peninsula, which have fracture controlled chalcocite mineralization. The Bohemia ores are apparently well-suited for in situ solution mining.

Jan 1, 1987

By Graham Andrews

Experiment shows that the microbial degradation of pyrite does not necessarily proceed stoichiometrically. Under some conditions sulfur is oxidized preferentially leaving something approaching iron in composition; under others, the pyrite is converted almost to elemental sulfur. A kinetic model for the process based on three elementary biochemical reactions can explain these observations. The diffusion of sulfur along grain boundaries and dislocations in the solid pyrite uncouples the oxidation rates of sulfur and iron from the requirements of stoichiometry. This mechanism also explains qualitatively why bacteria adsorb preferentially at dislocation sites on pyrite surfaces, why they form "pits" at these sites, and why amorphous pyrite is more readily degraded than pure crystals. The rate-limiting step for pyrite oxidation is discussed

Jan 1, 1989

By P. Muduli, Y. Xi, T. M. Yegulalp, A. J. Arias

A short review of current practices and recent developments is followed by a description of a newly developed approach for solution of the optimum, ultimate pit limit problem. The new approach utilizes network modeling of the problem for solution by maximum flow algorithm. The latest developments in the implementation of maximum flow algorithm present significant time and memory savings as compared to initial development due to Ford and Fulkerson (1956). Results of a series of computational tests are presented to demonstrate how this approach performs as compared to the well-known Lerchs Grossman algorithm. It is also shown that the solution by the new method automatically includes several optimal solutions based on a predetermined number of benches to be included in the analysis.

Jan 1, 1994

By E. Topuz, C. Patrick

Longwall face-to-face equipment transfers or moves are the largest source of nonproductive time in a long wall-mining system. Detailed planning and resourceful thinking are paramount for economical, safe and timely longwall moves. New equipment and innovative techniques are frequently tested to reduce overall more time. Determining the cost-effectiveness of these ideas is difficult since the decision is influenced by many subjective factors. A project scheduling simulation model of the longwall move process was developed to analyze and assess the economic viability of innovative transfer methods and equipment. The model provides a project-duration frequency distribution and lists of critically indexed activities and paths. It compares the monetary savings from reduced transfer time and capital costs for several ideas.

Jan 1, 1996

By K. R. Price, M. Gauna

Jim Walter Resources No. 4 mine produces coal through retreat longwall mining at 610 to 670 m (2000 to 2200 ft) of depth. A three entry, total yield pillar, longwall development experimental region was established for three adjacent longwall panels utilizing 6.1 m (20 ft) wide gate section pillars. Presently, the first longwall panel is completed with roadway deformational behavior monitored for a ground control assessment of the mining system. Data illustrate that the total yield pillar gate section design at No. 4 mine is presently comparable to gate section designs having large equal size chain pillars. Ground conditions will continue to be monitored during the mining of subsequent longwall panels in order to determine the ground control implications from multiple panel extraction.

Jan 1, 1986

By F. M. Doyle, C. V. Diniz, A. H. Martins

A proposed process for the direct production of battery¬grade Mn02 leaches manganese ore with HCl to remove heavy metals selectively. The acidic manganese chloride solution produced is contaminated with Cu, Ni, Co, Pb and Fe at levels that preclude immediate utilization. This paper reports on screening tests to measure the uptake of Cu, Ni, Co, Pb, Fe and Mn from acidic chloride solutions onto different chelating ion exchange resins. Dow M-4195, which contains the bis-picolylamine,functional group, showed promise for detoxifying manganese chloride process solutions. Column ion-exchange tests demonstrated the ability of this resin to produce pure manganese chloride solution from an acidic manganese chloride leach solution contaminated by Cu, Ni, Co, Pb and Fe.

Jan 1, 2000

By Barada K. Mishra

The potential merit of the discrete element method (DEM) as a numerical tool for analyzing process engineering problems involving particulate material is discussed. In this method, the dynamic equilibrium equations for each distinct and deformable body are solved. Therefore, it readily lends itself to modeling large numbers of discrete, interacting bodies as in mineral processing operations where a charge of particulate material is processed. Here some applications of DEM are reported: motion of particles in the ball mill, mixer, and jig. Although DEM has made very little headway in mineral processing research, it is shown here that a host of other areas of industrial interest in the context of flow of particulate materials can also be made amenable to analysis by this method.

Jan 1, 1993

By J. H. Tylczak, R. Blickensderfer, D. J. Singleton

As part of its research on wear of mining and mineral processing equipment, the US Bureau of Mines evaluated the erosion-corrosion characteristics of 12 alloys in phosphoric acid waste water. Tests were conducted on 2- and 5-cm-diam specimen8 in 12- and 60-cm-diam ball mills by grinding phosphate rock in gypsum pond water with an initial pH of 1.6. For comparison, grinding tests also were conducted in tap water. Static corrosion tests in gypsum pond water also were carried out. For all alloys tested, the wear by erosion-corrosion was greater than the sum of erosion plus static corrosion. A low-alloy, high-carbon steel and a high-manganese, nitrided stainless steel were the most cost-effective materials

Jan 1, 1987

By D. G. Chedgy

Careful consideration is given to the type of cleaning equipment and control systems to be used when selecting circuits for washing fine coal (0.5 mm x 0, or 28 mesh x 0, size fraction). However, desliming, declaying, and sizing procedures required for efficient operation normally are not evaluated in sufficient detail, resulting in disappointing system performance. This paper details desliming and de. watering circuit design that is effective based on recent test data. The circuit maintains control of the 0.5 mm x 0 (28 mesh x 0) (declayed) size fraction with minimal misplaced material and maximized circuit efficiency. A discussion of circuit design parameters and control systems, as well as results from the testing program, are included in this text.

Jan 1, 1987

The declining grades of surface deposits have re-confirmed the need for greater production rates. Large scale production requires increased investments in expensive and sophisticated equipment. The key to successful operations can depend entirely on proper equipment utilisation and in this program of research at the Department of Mining and Metallurgical Engineering, University of Queensland, much emphasis has been placed on the analysis and improvement of this aspect of a load-haul-dump operation. For a model to be successfully integrated into a mine engineering function and readily accepted by mine operating personnel, it has to offer more than just results. The concepts used in its design and construction must include sufficient detail to enable engineers to apply it usefully and with confidence.

Jan 1, 1979

By David J. Hammel

This chapter will summarize some of the important applications in the geotechnical (pit slope, spoil pile and tailings stability, and hydrology), the environmental (including reclamation), and equipment selection and analysis areas. Virtually all aspects discussed are applicable both for planning of new mines and for evaluating existing operations. Probably the most influential item which has affected the areas discussed in this chapter and possibly most areas discussed in this book is and will continue to be, in the next decade, the myriad federal and state environmental, safety, and reclamation regulations affecting new mine development and continued operation of existing properties. Computer applications have been and will continue to be instrumental in assisting in planning to meet the challenges of the requirements dictated by these regulations.

Jan 1, 1979

By John R. Marks

In April 1990, the Homestake Gold Mine embarked on a five year, $US 23 million underground drifting and drilling program to explore promising ore targets north of the current mine. This paper describes the ventilation and air-conditioning system that was installed for the 4m x 4m x 5.2 km (ultimately) drift, which is being driven at about 8m per day in 48OC (118.5 F) crystalline rock. Design parameters are described first. Differences in South African, Canadian and U.S. drift ventilation and civil tunneling techniques proved interesting. Details are then given on equipment selection, installation and performance. Costs are included. Special note is made of safety considerations for a long, dead-end drift.

Jan 1, 1991

By A. S. Ibrado, D. W. Fuerstenau

The adsorption of the cyano complexes of Ag(I). Cu(l), Hg(II), Cd(II), and Zn(II) on activated carbon was investigated as a function of pH and correlated with the speciation diagram for each metal. The results show marked changes in uptake with pH, closely resembling the predominance profiles of their neutral and singly charged cyano complexes. Multicharged negative complexes are repelledby the negatively charged carbon surface. The sensitivity of activated carbon to the charge of the adsorbing species indicates that silver adsorbs as an anion, not chemically bound to the coadsorbing counterions. For the same reason, activated carbon is selective to metals that preferentially form neutral and singly charged cyano complexes, namely gold and silver.

Jan 1, 1990

By D. B. Dreisinger, H. J. Sohn, J. S. Sohn, G. A. Kordosky

The transport of lithium through a supported liquid membrane was studied with a mixture of D2EHPA and TBP in kerosene as a mobile carrier. In the flat- sheet supported liquid membrane(SLM) system, experiments were carried out to investigate the effects of concentration of mobile carriers in the membrane solution, hydrogen ion in the feed solution, and temperature on the transport of lithium. Experimental results agreed well with a transport model for permeating lithium across the liquid membrane. The permeation rates of lithium can be explained in terms of diffusion of a Li-complex through the membrane phase. For a practical application of an SLM method, a hollow fiber module has been used and lithium can be concentrated more than three times in 24 hours.

Jan 1, 1993

By M. T. Ityokurnbul, M. P. Trubelja

Concentrate flow rates were measured for the flotation of -100-mesh Lower Kittaning coal in a computer-controlled 0.076 x 3.5-m pilot flotation column. The variables studied were recovery zone height, airflow and solid feed rates. The specific projected surface areas of the feed, concentrate and tailing streams were determined from the measured particle size distributions. The results obtained show that the concen¬trate flow rate was independent of recovery zone height but was dependent on the hydrostatic pressure setting (measure of froth depth), gas flow rate, solid loading and particle size. New correlations for column carrying capacity and yield are provided as a function of bubble surface area flux and the specific particle projected surface area.

Jan 1, 1999

By M. Stefanakis, A. Kontopoulpus, K. Adam

The application of Bacterial Oxidation as a pretreatment step for the extraction of gold from the Olympias refractory pyrite concentrate is described. A wide review of Bio-oxidation is presented focusing on the current process developments and commercial applications relevant to the treatment of gold bearing sulphide ores and concentrates. Preliminary batch and semi- continuous tests on the Olympas concentrate indicated that with Bacterial Oxidation quantitative gold liberation may be achieved. fie effect of such parameters as pH, Eh, temperature, particle size, operating pulp density and retention time on the extent of sulphur oxidation and subsequent gold extraction by conventional cyanidation are also examined. Finally, a preliminary evaluation of Bacterial Oxidation as a potential process alternative for the treatment of the Olympias concentrate is presented.

Jan 1, 1989

By M. Jawed

Coking coal reserves in India are distributed geographically in Giridih, Raniganj, East Bokaro & Jharia Coalfields (J.C.F.). 97% of prime coking coal in JCF coming through underground mines is credited to Bord & Pillar mining systems inspite of the fact that it results in heavy mining losses. The cost of mining in B & P mines has been much higher due to various factors. In this paper, O.R. model has been discussed with case study for optimizing the cost of production in operational underground mines. Also, a computer algorithm has been discussed using a schematic flowchart, which provides the trend of mining-losses 'in different mining, systems with changing design parameters and finally selects, the optimum mining system for undeveloped seams based on economic appraisal criteria.

Jan 1, 1989

By E. V. Manlapig, B. K. Gorain, N. W. Johnson, K. Ward

A flotation model developed at the Julius Kruttschnitt Mineral Research Centre was used to predict the performance of copper rougher and scavenger circuits at the copper concentrator at Mount Isa Mines. The model describes the kinetic response of an ore in a flotation cell in terms of ore floatability, cell characteristics and froth recovery. The floatability parameters of the rougher feed ore were obtained directly from a detailed plant survey. Flotation analysis was carried out for twenty different size-by-liberation classes to account for the effects of particle size and liberation on flotation. This paper investigates the capability of the model to predict the flotation behavior of 20 different size-by liberation classes in the rougher and the scavenger banks.

Jan 1, 2000