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By Nick Hasenack

In the pelletizing plant of Hoogovens, Estel BV, a varying mixture of hematites and magnetites is used for the production of acid and (occasionally) fluxed pellets. Optimum results regarding productivity, quality and process control are obtained with mixtures containing 30-40 % magnetites. A decrease of the magnetite ratio or an increase of the basicity has a great influence on both productivity and heat and power consumption. Tests have been carried out to find the extent to which magnetite can be replaced by b.f. dust, mill-scale and coke breeze. Pilot plant tests show that about 80-100 % of the production loss due to a decrease in magnetite content or to the increase in basicity can be regained without damage to the quality by adding coke breeze. The amount of coke breeze should be limited tot 1,5 %; if this percen¬tage is chosen higher, the quality of the pellets deteriorates rapidly. The amount of coke breeze to be added should be about 30 % above the theoretical value, based on heat balance considerations. The results achieved by incorporating b.f. dust and mill-scale into the pelletmix were also encouraging, but as some types of mill-scale are very difficult to grind and the supply of b.f. dust is limited, the research has not been carried out extensively in this field. The pilot plant tests on replacement of magnetite by coke breeze have been followed by industrial tests, during which the breeze was added to the ore feed before the dry-grinding system.

Jan 1, 1977

By H. Maleki

Interwest Mining Company has been collecting geologic data within the last decade in preparation for underground mining of extensive coal reserves in its Bridger Coal property in southwestern Wyoming. During a preliminary data collection program in 2000, Interwest Mining completed geologic investigations, including surface mapping, drilling, aerial photography, rock testing, and limited groundwater investigations. Core from 12 exploration boreholes in the area of interest was tested to determine the mechanical properties of the coal seam and the immediate roof and floor for evaluation of the feasibility of underground mining. Geologic investigations identified the presence of one 7-to-17-ft-thick coal seam throughout the reserve under 1400 ft of cover. During a geotechnical feasibility study in 2002, the authors reviewed available data while completing comparative analyses identifying critical deficiencies in these data. The study projected moderate-to-difficult mining conditions, considering the weak nature of near-seam strata and depth of cover, and thus recommended limiting the longwall reserves to an overburden depth of less than 900 ft. These shallow remaining reserves were located at depths within regional mining experience to justify longwall mining methods. Based on a critical examination of available data, Bridger proceeded with more detailed data collection to improve understanding of the depositional and structural setting of the reserve, hydrogeologic conditions, overburden strength, and premining stress conditions. Additional data was collected during 2003 and 2004 field programs. Since 2003, Bridger has had the opportunity to observe ground behavior in a series of up to 1200-1600-ft- long rectangular openings created during highwall mining. These narrow unsupported openings remained stable in the short term in large areas but the overburden subsided locally in the long-term depending on geologic and panel layout designs. These localized subsidence events allowed an examination of in-situ coal strength based on back analyses of stress. The unextracted highwall areas near Ramp 17 provided an ideal location to access the underground reserves using a 6-entry set of mains. The existing north-south oriented longwall layout for the Bridger Coal was selected by Bridger to maximize resource recovery from the D41 reserves while considering operational and geotechnical constraints. At 45-degrees deviation from preexisting joints and mild horizontal stress field, this orientation was considered beneficial for overall stability while using both sets of joints for facilitating the caving process. The present layout utilizes pillars on 80- to 90- by 200-ft centers, 17-ft entry spans and 750-ft wide longwall panels (Figure 1). Gate pillars are on wide spacings and are intended to act as abutment-abutment pillars to limit strata deformation over the gateroads during longwall mining.

Jan 1, 2008

By M. Robson

Water & Earth Technologies, Inc. (WET), Habitat Management, Inc. (HMI) and Chevron Mining, Inc. (CMI) together developed a solution for reclaiming steep southwest facing slopes in mining Area 12C that have historically been prone to excessive erosion, low vegetation establishment and continuing maintenance. Area 12C is located in the east wing of the Chevron McKinley Coal Mine, 27 miles northwest of Gallup, New Mexico, on Navajo Nation land administered by the Office of Surface Mining (OSM). Mining in this area was completed in May of 2007. Challenges encountered for this reclamation project included the need to reclaim graded material on a slope of 18-35% with southwest facing aspect, the presence of undisturbed rock outcropping that needed to be avoided during reclamation, the operational need to limit bulldozer pushes and the inability to import or export additional materials for construction. Two different reclamation alternatives were considered for Area 12C. The first alternative would use a traditional reclamation approach including three levels of draining terraces designed to convey water on a 3% slope to a single riprapped down drain. Terracing and down drains have been used to reclaim areas with similar terrain conditions elsewhere at the McKinely Mine and have failed to adequately control erosion (Williamson 2006). Terrace overtopping and down drain blowouts have been issues in maintenance and functionality for the mine. Maintenance routines consist of cleaning out terraces where they have filled in with sediment and repairing damaged or blown out terraces and down drains.

Jan 1, 2010

By D. R. Nagaraj

Adsorption of sulfide collectors such as xanthate on pyrite has been studied extensively over several decades using a wide variety of techniques. In spite of this, there are unanswered questions as to the identity of adsorbed species on pyrite surfaces -dixanthogen vs. iron xanthate complexes. Far less is known in non-xanthate collector systems. We have used Secondary Ion Mass Spectroscopy (SIMS) successfully in the past to obtain direct evidence for the identity of the adsorbed collector species on copper sulfides, galena and Cu-activated quartz. The present study is an extension of the SIMS analysis to investigate the adsorption of xanthate, dithiovhosphate, dithiocarbamate, and modified thionocarbamates and thioureas on pyrite. Adsorption of these collectors on chalcocite was also studied for comparison. An attempt was also made to obtain SIMS spectra for pure dixanthogens at room temperature. Only in the case of dithiocarbamate (DTC) was there direct evidence for the presence of not only the collector dimer, but also iron-DTC complexes. On chalcocite, only the copper-DTC complexes were detected (no dimer). In the case of xanthate, the collector molecular ion and its S adduct -which are possible fragments from dixanthogen -were detected on pyrite, along with a fragment peak: suggesting Fe2X. For dithiophosphate, the collector molecular ion and Fe(DTP)(OH) complex were detected (no dimer). For modified thionocarbamate and thiourea, adsorption on pyrite was negligible.

Jan 1, 1997

By Roland Arnold, Richard Gradnik, Martin Zeindl

This paper presents the details of the Kramer tunnel project in the Federal State of Bavaria, Germany. This road tunnel, which has been under construction since December 2019, is the key component of the western bypass of the town of GarmischPartenkirchen. Once completed, it will relieve the town’s central district from enormous volumes of traffic. The contractor is the joint venture named ARGE Kramertunnel consisting of BeMo Tunnelling and Subterra. The whole project will be completed and handed over to the project owner, Staatliches Bauamt Weilheim, in 2023. The opening of the entire bypass section including the tunnel to traffic is planned for 2024. The tunnel, with a total length of 3,609 m (2.24 miles) and an estimated cost of EUR 178 million (incl. VAT), is designed as a single-tube, double-lane structure with one traffic lane for each direction of travel. The safety issue that exists for single-tube tunnels is solved by a parallel escape tunnel passable for vehicles. All tunnels and ducts are excavated according to the principles of the New Austrian Tunnelling Method (NATM). In order to reduce the geological risk for the owner, the escape tunnel was supposed to be completed before the design process for the main tunnel ever began. The exploratory tunnel was awarded to a competitor with an separate contract.

Jun 13, 2021

The initiation of a panel cave is an extremely important and infrequent event in the life of a large underground caving operation. A new cave was initiated at the Henderson Mine in 1991, 15 years after its first cave had been developed in 1976. The original cave was started after a half billion dollars had been invested in the development of the mine, mill and 23 km haulage system. Many things had changed since 1976, the most significant of these being much lower realizations for molybdenum. In 1976 the high demand for molybdenum and uncertainty of caving characteristics, formed the basis for a very conservative cave initiation sequence with miles of boundary weakening and inspection drifting. In 1991 the highly competitive molybdenum market in conjunction with 15 years of caving experience made for a very different mining climate.

Jan 1, 1994

By Z. Zhongwei

The leaching kinetic of mechanically activated sphalerite with acid FeCl3 solution was investigated. The result has shown that mechanical pre-treatment has greatly enhanced the leaching process. Comparing with the original concentrate, the activated one can be leached more completely at relatively lower temperature with diluter FeCl3 concentration within a shorter leaching time. The activation energy for the activated concentrate is 27 KJ/mol, while for the original one is 52 KJ/mol.

Jan 1, 1995

By A. M. Raichur

Flocculation of fine coal is usually accomplished with the addition of commercially available organic flocculants. Recently it has been shown that biopolymers derived from microorganisms can be used to flocculate coal. The biopolymers flocculate coal efficiently and render the coal surface hydrophobic. The increase in hydrophobicity can be utilized either to separate the coal flocs from mineral matter. It can also be used for reducing the moisture content of fine coal. In this regard, flocculation and settling tests of fine coal with biopolymers and synthetic flocculants was undertaken and the results are discussed here. Also, a transport model was developed for the time-dependent settling tests for fine coal.

Jan 1, 1996

By Ralph S. Mattson, Frederick T. Hancock

GENERAL DESCRIPTION The Granduc mine is situated on the west side of Granduc Mountain in the Leduc River area of north¬west British Columbia about 51 km (32 miles) north¬east of the town of Stewart. Entry is by means of a 16.6-km (10.3-mile) long haulage adit from the concentrator site at Tide Lake. The principal ore mineral is chalcopyrite. Ore mineralization varies from dis¬seminated to irregular semimassive stringers generally associated with highly folded and sheared biotite-rich sections of metasediments. The ore bodies vary in width from 3.6 m (12 ft) to over 18 m (60 ft) in a zone some 800 m (2600 ft) in length dipping at an average of 75° to the west and plunging steeply to the south. Capping varies in thickness from 0 to over 300 m (1000 ft). SELECTION OF MINING METHOD In the early stages of planning the primary require¬ments to be met by the mining method were: (1) suit¬ability to high output and productivity, (2) adaptability to mechanization in order to minimize operating costs, and (3) minimization of the costs and the development period for preproduction. Considering these, the selection of a mining method was narrowed to a choice be¬tween sublevel long-hole stoping or sublevel caving. A method utilizing backfill was ruled out as uneconomical, especially since mill tailings would not be readily available. At the time, the following facts about the ore body were recognized: (1) the average width of the ore body was 12 m (40 ft), (2) 30% of the stoping blocks were in areas of 6 m (20 ft) or less in width; (3) in many cases, ore zones were located in parallel lenses or were irregular in shape; (4) major faults were present in the hanging wall close to the ore, with minor faults within the different ore zones; and (5) the ore itself was lami¬nated with fractures and jointing crossing such bedding planes. Considering these factors, the two stoping meth¬ods were compared. Sublevel Open Stoping The characteristics of sublevel open stoping are: 1) It is generally not used for widths below 6 m (20 ft) since the ratio of waste development increases as level intervals are reduced to insure good control of long-hole drilling. 2) This method is used where ground is relatively competent. Otherwise more pillar support is required, increasing ore losses or mining costs with pillar recovery. 3) The method is not easily adaptable to parallel ore zones separated by relatively narrow waste bands. 4) Close control of pillar and stope design will per¬mit some degree of dilution control. Sublevel Caving Sublevel caving is characterized by the following: 1) The method can be used for a variety of ore widths, recognizing that 3 m (10 ft) in width may be an economical minimum. 2) It is particularly favorable where wall rock is weak. 3) The method has flexibility so that irregular ore bodies or parallel lenses can be mined. 4) The need to leave pillars for support is eliminated 5) Dilution and tonnage recovery are interrelated. With concern about the stability of the hanging wall and the geometry of the ore bodies, there was a growing favor to choose the sublevel caving method. However, this method was relatively new to Canadian mining practice. Teams were sent to Sweden to tour mines using sublevel caving and to study their methods and any extraction and dilution problems. The objective was to develop cost and performance data and ore recovery grades and tonnages for feasibility comparisons. Next, detailed mine plans were developed covering a three-year period using sublevel caving and sublevel open stoping. Extensive analyses of the development and production costs for each method were made. With sublevel caving, ore losses of 10% with a 20% dilution rate were used. The same ore loss was estimated for sublevel open stoping with dilution varying from 11 to 15%. As a result of these studies, the decision was made to use sublevel caving partly because slightly lower op¬erating costs, together with higher productivity, offset the adverse effects of higher dilution; and partly be¬cause, at the start, there would be less risk in being able to handle the ground, and the method offered more flexi¬bility. Open stoping was not ruled out for testing at a later date. It was recognized that some other method of mining would be required for mining the ore extensions below the glacier, where surface subsidence must be avoided. During the operating life of the mine, open stoping was tested in narrow width ore zones and found un¬satisfactory due to wall failure. A cut-and-fill stope, utilizing run-of-mine waste from development, was also operated on a trial basis. A sequence was finally estab¬lished that permitted ground control; however, produc¬tivity needed considerable improvement in order for open stoping to be considered as a sole alternative for mining below the main haulage level. At the termination of operations in June 1978 over 13 000 000 t (14,500,000 st) had been extracted from above the main haulage level at production rates varying from 3270 to 7250 t/d (4000 to 8000 stpd). Sublevel Caving Methods Two basic methods were used, transverse and longi¬tudinal. The transverse method was used mainly in the upper C ore body in widths greater than 18 m (60 ft), and occasionally as an alternative to the longitudinal method in localized areas where strike faulting inter¬fered with normal development. The longitudinal method was used in ore bodies varying in width from 3.6 to 18 m (12 to 60 ft), with a multilongitudinal varia

Jan 1, 1982

By Zhenqi Cai, Mike Lichte, Kimberly Kennedy

The Ohio River Tunnel is the first of three combined sewer overflow tunnels to be constructed under Allegheny County Sanitary Authority's Clean Water Plan. The project consists of a total of approximately 5.5 miles of 18-ft and 14-ft finished diameter, segmentally lined deep rock tunnels and smaller diameter dewater and flow connector tunnels, as well as 8 deep flow drop and access shafts varying from 25-ft to 70-ft in finished diameter and 130-ft to 170-ft in depth. This paper describes the project components and the primary engineering challenges faced during design, including tunnel alignments and shaft site optimization with tight right-of-way constraints and multiple railroad and highway crossings. Assessment of tunneling methodology as well as tunnel and shaft designs and constructability included overcoming 5-bar hydrostatic pressure, abrasive bedrock, and the selection of the appropriate support of excavation systems in high-permeability alluvial soils adjacent to the Ohio River.

Jun 23, 2024

By M. McPherson, G. Danko

Methods of measuring in situ rock thermo-physical properties are rapidly evolving. Among those existing in the literature, a particular measurement procedure was selected for further development. The measurement is based on creating a spherical temperature field in a drill hole using a point source heater of constant heat flux. The bivariate temperature distribution 0 (r, t) is measured at several points along the length of the drillhole, radius r from the heater and at particular time intervals (t). A number of different evaluation methods were tested for calculating the unknown thermal conductivity (k) and diffusivity [] from the measured temperature and the known heat flux. The results showed that evaluation using the finite difference scheme and small temperature differences measured at points close together, cannot give a reasonable result. In order to solve the problem a new general analytical evaluation method is developed. Using an appropriate technique, it is possible to simultaneously obtain values for k and [], incorporating a semi least square technique to reduce the uncertainty in the evaluation. The new device and evaluation method makes it possible to obtain from a single drill hole highly precise k and [] values within an 8 hour period. The method has been used in several underground mines in the U.S. with good results.

Jan 1, 1987

By Pratt Rogers, Aaron Young

This paper considers the mining industry’s need for digital transformation (DT) and presents a three-part review of the foundational components of the DT process: ubiquitous data, connectivity and decision-making. It also provides a discussion on the future of DT in mining as well as a research direction, which identifies the need of academia to provide support for mining companies in the form of both research and the education of digitally literate, dynamically capable mining engineers into the coming decades.

By E. Taskin

Diasporic bauxite from the Mugla-Milas region was mechanically activated in a planetary mill for different activation times and the structural changes were examined by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and specific surface area analysis (BET ? Burnauer, Emmett and Teller). Non-activated and activated bauxite samples were leached directly in alkaline (Na2O) solution at atmospheric conditions and the activation procedure led to the amorphization and structural disordering of the diasporic bauxite structure, which increased the dissolution efficiency. Effects of milling speed, liquid/bauxite ratio and leaching time on alumina extraction in direct alkaline leaching of diasporic bauxite were also studied. The alumina extraction was ~7% for non-activated bauxite and ~70% for activated (75 minute) bauxite. Key words: Diasporic bauxite, Mechanical activation, Alkaline leaching, Alumina extraction

Jan 1, 2009

By Thomas A. Mekelburg

Due to a tight ash constraint on the clean coal product and difficult middlings washability characteristics, a considerable amount of coal was being lost in the jig middlings at the Monterey No. 2 Mine. An investigation was conducted into circuitry to recover this lost coal with minimal effect on the total clean coal ash. A reverse two-stage hydrocyclone system cleaning at low specific gravities was selected. This system is currently recovering approximately 5.8 kg/s (23 tph) of 11.5% to 12.5% ash coal. The specific gravity of separation for the system is about 1.5 and the probable error is 0.13.

Jan 1, 1984

By Ing. H. Kellerwessel, Ing. M. Esna-Ashari

This paper refers to the new crushing and grinding process, invented by Professor Schonert (Ref. 1), Clausthal, Germany. The process is known as high pressure particle bed comminution or interparticle crushing. Several papers already describe fundamentals of the process, the equipment used, results of lab size and large scale tests and the first results of commercial operations (Ref. 2 to 7). Of course, we will treat the topic from the perspective of a downstream gold ore upgrading or leaching process. Some recently executed testwork indicates that the process provides special advantages in this field. To describe the process generally, in view of the already existing publications.

Jan 1, 1998

By R. Sellaro, E. Sarver

It has long been understood that extended occupational exposures to respirable mine dusts can lead to chronic lung disease. In underground coal mines, coal workers pneumoconiosis (CWP) and silicosis are major concerns. While many efforts have been made with the aim of understanding the mass-based concentrations and silica contents of respirable dusts under a variety of mining conditions, little research has been completed in characterizing dust at the individual particle level (by composition, size and shape). This study employed scanning electron microscopy with energy dispersive x-ray (SEM-EDX) to analyze dust samples collected from an underground coal mine in Central Appalachia. The results indicated that particle characteristics can vary widely between locations, though many trends might be explained based on knowledge of mining conditions. A continuous personal dust monitor (CPDM) was also used during the collection of some samples to determine respirable dust concentrations, which were compared against estimated concentrations based on the particle-level analysis.

Jan 1, 2014

By Richard C. Corson

The objective of blending materials in a bedding pile is to reduce the variation in successive samples taken from the materials to be blended. In designing a bedding and reclaiming operation, several mechanisms are available to effect the reduction of variability, or increase in homogeneity, of the materials. These mechanisms can act before stacking, in the stacking process, in reclaiming and after reclaiming. In evaluating alternative methods of stacking and reclaiming, the potential user must judge each method on the basis of certain criteria; the capital cost of the equipment, the allowable absolute variability of the reclaimed product and the effectiveness of blending. Several stacking and reclaiming methods have been tested using a computer simulation. Based on the results of this program, factors were developed to describe the effectiveness of blending for chevron stacking of discrete materials and preblended materials, bucket wheel reclaiming and drum reclaiming. From these factors, the total effectiveness of a combined stacking and reclaiming system can be determined.

Jan 1, 1985

By Daniel Su

This paper describes recent ground control challenges encountered at the longwall recovery areas of one of Bailey Mine?s two longwall faces and the proactive measures taken by CONSOL management and engineering to mitigate them. The challenges derived primarily from the following causes: (1) irregular roof coal and draw slate thickness, (2) presence of thick sandstone at the recovery area and extremely weak rocks below the sandstone, (3) close proximity to a regional anticline, (4) low shield set pressure and tip load, and (5) ineffective primary roof support that led to progressive failure of the headgate roof. The presence of the anticline contributed to extensive fracturing of the sandstone. Excessive pot-out in advance of the shields frequently occurred near mid-face due to the presence of thick draw slate and irregular roof coal near the recovery area. This, in turn, resulted in face heights that exceeded the maximum reach of the shields. Subsequently, during longwall meshing, when the advance rate slowed considerably, fractured sandstone would often break loose, causing the shields to yield, thereby reducing the height and inhibiting shearer movement. To improve the headgate and face conditions within the longwall recovery area, several actions were taken, including: (1) assessing site-specific roof geology by conducting in-mine roof coring around the recovery areas and by mapping immediate draw slate and roof coal thicknesses within surrounding entries, (2) increasing pump pressure and thus shield set pressures (3) diligently monitoring shield set pressures and longwall extraction horizon, (4) installing additional cable bolts and roof screening to prevent progressive failure of the immediate headgate roof, (5) fully-grouting supplemental cable bolts to improve headgate support stiffness, and (6) gluing the headgate roof within the recovery areas with polyurethane. As a result of these collective efforts, longwall recovery delays at Bailey Mine were reduced from 21 days in 2006 to nearly zero in 2009.

Jan 1, 2009

By V. B. Menon, L. D. Michaels, M. E. Mullins

Introduction The cleaning of coal to remove sulfur and inorganic impurities has, in recent years, become an essential operation in any coal utilization process. US coals, on average, contain about 3% total sulfur, of which more than 60% is generally inorganic or pyritic sulfur. Existing technologies such as heavy media cycloning, selective agglomeration, and electrostatic separation have the potential for removing about 80% of the pyrite from coal (Khoury, 1981). In view of the large volumes of coal being used today, there exists a need for the development of new processes to further improve the separation of pyrite from coal. Colloidal particles in suspension possess surface charges that are related to the chemical composition of the particles. In aqueous suspensions, the surface charge is a function of pH. For coal-pyrite mixtures, it is possible, by an adjustment of the pH (also a function of polar molecules), to reach a state where the charge on coal is very close to zero, but the charge on pyrite is still substantial. The introduction of collector particles with a charge opposite that of the pyrite should then result in the selective flocculation of pyrite and collec¬tor. These flocculates should settle out much faster than coal and could be removed from the bottom of the settling column. This note discusses our preliminary observations of the effect of clay-based collector particles, especially bentonite, on the settling behavior of coal and pyrite. These experiments were conducted with a view to developing a new electrokinetic flocculation process for separation of coal-pyrite mixtures. Experimental The objective of the experiments was to determine the effects of clay-based additives on the settling rates of clean coal, pyrite, and coal-pyrite mixtures. Illinois Colchester (No. 2) coal was obtained after processing in an existing coal cleaning facility. This coal was reported to contain less than 0.3% pyritic sulfur, which was in the form of a fine powder with an average particle size of 5µm. Pyrite (of average particle size 5 µm) was also obtained from the same facility and reportedly contained less than 0.1% coal. The zeta potentials of coal and pyrite in water were measured as a function of pH using a zetameter. The pH was adjusted by adding sodium hydroxide or hydrochloric acid to the suspensions. Sedimentation experiments were conducted in 50-mL glass cylinders, and settling rates were measured by noting the height of clear liquid above the settling front as a function of time. Settling behavior was also charted by periodically taking photographs of the system. The following systems were investigated: •a slurry consisting of 2.5 g of clean Illinois Colchester coal in 50 mL of water of pH 6.0, with and without the addition of 0.5 g of bentonite (Fisher, purified grade) ; • a slurry consisting of 2.5 g of pyrite in 50 mL water of pH 6.0, with and without the addition of 0.5 g of bentonite ; and • a slurry consisting of a mixture of 1.25 g clean coal and 1.25 g pyrite in 50 mL water of pH 6.0, with and without the addition of 0.5 g of bentonite. In addition, experiments were conducted with kaolinite (Bath, South Carolina) and alumina (Fisher, purified grade) as collector materials to verify the observed effects. Results and discussion Figure 1 shows the zeta potential values for the Illinois coal and pyrite as a function of pH. The zeta potentials of coal and pyrite decrease with increasing pH, changing from an initially positive value at low pH to a negative value at high pH. The point of zero charge (PZC) for the coal is at a pH of 6.2, while the PZC for pyrite occurs at a pH of 10.3.

Jan 1, 1988

By W. D. Elston, A. E. McLaughlin, G. B. Hampton, W. L. Barham, J. F. Murphy, W. H. Cundiff, J. W. Mulloy, R. G. Breuer, J. W. Shaffer

Introduction Alumina (aluminum oxide) is the material from which all the world's aluminum is produced. In the Western World, all the alumina is made from bauxite by the Bayer process. In the nearly 150 years since aluminum was first isolated by Oersted, the metal has grown from a laboratory curiosity to a position of major importance in the world's commerce. In terms of annual production rates aluminum is first among nonferrous metals. Oersted's discovery-reduction of aluminum chloride with potas¬sium amalgam-was improved on by Ste. Claire Deville, whose so¬dium amalgam reduction of aluminum chloride led to the commercial production of aluminum in France in 1855. Ste. Claire Deville's method prevailed until 1886 when Charles Martin Hall and Paul T. Heroult each invented a process for the production of aluminum by the electrolysis of alumina dissolved in molten cryolite. The inven¬tion by Karl Josef Bayer in 1888 of an economical process for making very pure aluminum oxide (alumina) from bauxite established the necessary link between known ores and the Hall-Heroult reduction process. Bayer's work completed the scientific base-the ore bauxite refined to alumina by the Bayer process (U.S. Patent No. 515,895), the alumina reduced to aluminum in the Hall-Heroult cell (U.S. Patent No. 400,766--upon which today's aluminum industry is founded. Small-scale production of aluminum in the U.S. began in 1888 utilizing the Hall cell. By 1903, bauxite properties and a Bayer process refining step had been incorporated into the production activities. On this base the aluminum industry in the U.S. has grown at an annual compounded rate of 15%. Since 1946 the annual growth rate has been 10%.1 The rapid growth of the industry is the result of many factors among which are the existence of widespread bauxite ore deposits; a sound and economic production technology; and the properties of the metal-lightness, strength, ductility, good electrical and heat con¬ductivity, and pleasing appearance, which lead to ever greater de¬mands for aluminum in an industrializing society. At the inception of the industry, the only market that could be found for aluminum was in the production of cooking utensils. How¬ ever, the rapidly accelerating industrial and technological development of the Western World soon created new needs for aluminum, and today aluminum is marketed in a broad range of industrial, commer¬cial, and consumer applications. The principal uses for aluminum are:' building and construction, 22%; transportation, 18%; electrical, 13%; packaging, 11%; consumer durables, 10%; machinery and equipment, 7%; other, 19%. The 1974 production of primary alumi¬num in the world was 14.5 million short tons, which at an approximate ingot price of 40¢ per lb puts a value of $11.6 billion on the industry product prior to fabrication. While aluminum is widely distributed in the earth's crust and is a major constituent of many rocks and soils, to date no method of extraction of aluminum from such nonbauxite material has been brought to commercial practice in the Western World. In the USSR alumina is produced by the complex processing of nepheline syenite, but elsewhere all commercial production of alumina is from bauxite. A brief discussion of recent developments and other processes for alumina is included in the subsection "Other Processes for Alumina," page 19-15. In early 1973, a major U.S. aluminum producer announced the successful development of processes for the production of aluminum from aluminum chloride. This achievement promises to exert a major influence on the future of the aluminum industry. In the initial com¬mercial application of this new technology, Bayer alumina will be chlorinated, and the aluminum chloride then reduced by electrolysis. Important claims for the new processes are lower energy requirements (one-third less than obtainable in Hall cells) and reduced labor costs. Capital costs are said to be no greater than for conventional plants. While the announced intention is to produce the aluminum chlo¬ride from Bayer process alumina, the new chloride reduction process will eliminate the other raw materials, carbon and fluorides, required by the conventional Hall cells. The electrodes in the chloride cell will not be consumed on the reduction process and the electrolyte will have, as the name indicates, a chloride rather than a fluoride base. 2. Bauxite Definition and Origin. Bauxite is a naturally occurring raw material composed principally of a mixture of one or more of the hy¬drated aluminum oxide minerals gibbsite (Al2O2 3H2O), boehmite (Al2O3 H2O), and diaspore (Al2O, - H2O), and impurities of silica, iron oxide, titania, and other various elements in trace amounts. It is an end or near-end product of chemical weathering. Depending on the amount of iron impurities, the color of bauxite varies from dark red and brown to pink to white. Some bauxite is finely divided, free digging earthy material, while other forms are dense and rocky, requiring explosives in mining. Many gradational forms exist. It is one of the most variable of mineral raw materials in chemical composition and physical appearance. It is generally believed that bauxite deposits resulted from intense chemical weathering of aluminum-bearing rocks or formations under tropical or subtropical conditions with alternating wet and dry sea¬sons. Topographic conditions were favorable for drainage and the in-situ accumulation of aluminum, iron, and titanium oxides. There was low to moderate topographic relief with a minimum of erosion during long quiet periods in earth history.2 The occurrence of bauxite is widespread and it has been found on all continents except Antarctica. Production was reported from 27 countries in 1974, at which time total world production was over 79 million metric tons. Of this production 76% was from seven coun¬tries-Australia, Jamaica, Surinam, Guinea, USSR, Guyana, and Greece-which ranked in that order of production. In Table 1 are shown typical compositions of bauxite from some

Jan 1, 1985