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By Hasan Nizamoğlu, M. Deniz Turan, MÜCEVHER TURAN, RAMAZAN ORHAN

Tailings (flotation waste) that is formed during copper production may be considered in the class of valuable wastes due to the amount of copper it contains. Owing to the decreasing grade values in copper ores, utilization of wastes such as tailings that carry certain amounts of copper as secondary sources has become a necessity in both the economic and environmental sense. This study investigated the usage conditions of five different ammonia salts as leaching reactants for the purpose of selective extraction of copper from tailings. For this purpose, the effects of parameters such as leaching temperature and leaching time were examined at different concentrations of ammonium hydroxide, ammonium carbonate, ammonium nitrate, ammonium chloride, and ammonium persulfate. The copper extraction efficiency in the case of using the aforementioned salts by themselves were listed as (NH4)2CO3 (73%) > (NH4)2S2O8 (69%) > NH4OH (64%) > NH4Cl (42%) > NH4NO3 (40%). The highest copper extraction efficiency was obtained in the leaching process that was conducted with the solutions obtained by mixing ammonia salts in the best conditions. Accordingly, as a result of 6 h of leaching at 30 °C in the presence of 22.5% NH4OH and 100 g/L (NH4)2S2O8, 91.47%of the copper was transferred into the

Jun 3, 2020

By Yoginder P. Chugh

The term "fatigue" in mechanics, is used to refer to reduction in the strength of a material subjected to fluctuating or alternating stresses. Stresses that vary with time are called fluctuating stresses and if during fluctuation the stresses also change sign, they are called alternating stresses. In the field of rock mechanics, the term fatigue (static fatigue) has often been misused to refer to failure of geologic materials in time domain under constant load. To avoid confusion, we use the ten cyclic fatigue here to refer to failure of rock under alternating or fluctuating stresses. Fatigue in metals has been studied for over 100 years. Fatigue properties of geologic materials have, however, received little attention in the past. This is probably because until recently very little was known in regard to the behavior of geologic materials even under static loading. Secondly, suitable equipment for conducting cyclic fatigue experiments was not available until quite recently. A few cyclic fatigue studies have been undertaken on geologic materials to relate it to percussive or rotary drilling mechanisms (e. g. Grover et a11*; Burdine2). The results of these studies were inconclusive due to limited effort. Cyclic fatigue in concrete has been studied more extensively than geologic materials (e.g. Nordby3, Gray et al 4 and Bennett et a15) and mechanisms of fatigue in concrete are better understood than in geologic materials.

Jan 1, 1975

By Barrie A. Wigmore

There are two aspects of financing western coal development -- whether there is going to be enough money to finance the prospective large development of the industry, and the specific techniques of raising money for that development. To take the first question of whether there is going to be enough money around to finance your industry, I think it is quite clear that the restrictions on the development of western coal are going to be non- financial. Environmental impact problems are creating the greatest delay in coal mine development, at the moment; but getting enough personnel, mining equipment, railroad equipment, and failure of the Department of Interior to act on leasing federal coal lands all appear likely to create significant bottle- necks in the development of western coal -- larger bottlenecks than financing. Financing appears straightforward for the industry. There are many projections of the financing required to meet Project Independence goals. The National Academy of Engineers estimated that development of 500 million tons per annum of western coal would be necessary by 1985 to meet the Project Independence goals which might require $20 billion of capital spending. It is generally agreed that 500 million tons a year is not a realistic possibility. Carl Bagge?s estimate of production of 250 million tons a year by 1983 appears a more reasonable projection. Development

Jan 1, 1976

By Joyce Lappin-Randolph

In 1977, Vertical Crater Retreat (VCR) Mining was developed at the Homestake Mine and by 1983 had become a fully integrated mining method contributing 60% to total underground production. VCR has proven successful for continuous ore blocks exceeding 55,100 tons (50,000 st) with dips greater than 60" and provides a productivity average of 39 tons (35 st) per man shift (tpms) which is 92% greater than Open Cut-and-Fill. Discontinuous ore bodies, small pods, or flat structures not amenable to bulk systems are mined with Mechanized Cut-and-Fill (MCF) and have been able to achieve a 32 tpms (29 st) average productivity. Small, low grade, remnant ore bodies were not economically viable with large scale bulk techniques and couldn't support the development required for a MCF system. As a result, Homestake began researching modified bulk mining methods to increase production rates and maintain safety, while lowering costs. A modified version of VCR with significantly diminished development was prototyped in an effort to reduce initial capital investment and expedite the production phase. This modified method is called Small Block Vertical Crater Retreat (S. B. VCR). Geology The Homestake Gold Mine is located in the northern Black Hills of South Dakota at Lead. Having been active since 1876, it now extends from the surface to the 2,440 m (8000 ft) level underground.

Jan 1, 1987

By Jackson M. Langton

INTRODUCTION The Morenci-Metcalf district is located on the southern slope of the white Mountains in Greenlee County, Arizona. Both porphyry copper deposits are four to six miles northwest of Clifton, the county seat, and the new Metcalf mine is situated approximately one mile northeast of the Morenci open pit (Figure 1). Chase Creek, a south-flowing tributary of the San Francisco River, dissects the district and separates the two ore bodies. More than 1,200 exploration and development drill holes have been completed in the district and the Morenci-Metcalf ore bodies have been delineated on a 400-foot grid. Recently initiated drilling programs have revealed new data about deeper protore and associated hypogene alteration. This information, correlated with surface mapping and petrographic studies, was utilized to propose a plausible geochronologic sequence for this region. The reasoning behind this study has been helpful in locating new ore beneath leached capping indicative of only protore mineralization. The scope of this paper is to establish a practical solution to a highly theoretical problem of ore genesis and to familiarize the reader with stratigraphic, structural, and mineralogic events responsible for localizing ore in this district. Continued research will possibly alter the proposed time span and relative displacements, but it is doubtful that the order of events will vary significantly. Geochronologic conclusions are therefore presented as general hypotheses and additional geologic mapping,

Jan 1, 1972

By Duluth Engineers' Club, Engineers' Club of Northern Minnesota

"During the last ten years great strides have been made, on the Mesabi Range, in the practice of beneficiating low grade iron ore material. By .beneficiation is meant all methods of removing impurities, and raising the iron content to a point where it can be sold in open market, the principal impurities being silica and moisture. The • general processes to which low grade iron ores are amenable are as follows:1. Thermal(a) Drying ; removes hydroscopic or atmospheric moisture. .(b) Calcining; removes carbon dioxide from iron carbonate, molecular water from hydrated hematites, and atmospheric moisture.Roasting; removes sulphur, carbon dioxide, molecular water and atmospheric moisture.Agglomeration; primarily for the purpose of preparing finely divided material for blast furnace; briquetting and sintering.2. MechanicalScreen sizing; removes rock and sand.Classification; removes sand by means of currents of water of varying velocities.Log washing; removes fine sand.Jigging; removes larger particles of impurities than is possible by log washing. Certain types of jigs remove fine sand.Reciprocating tables; recover fine iron particles from sand discarded by above processes.Magnetic separation; applicable to the commercial separation of the magnetic oxide of iron from gangue material. From a scientific standpoint it is possible to separate certain hematites and limonites from their gangue:(g) Miscellaneous processes; comprise dry concentration, electro-static separation and other processes."

Jan 1, 1920

By J. W. Francis

The paper about to be presented deals with the relatively straightforward problem of mining two seams of coal separated by an interval. This may seem to be a simple problem but within a twenty-mile radius of Consolidation Coal Company's Burning Star # 4 Mine at least seven (7) different techniques of two-seam mining have either been tried or are now in use. This great variety of techniques should point out that there is no single simple solution; a conclusion often reached when dealing with mining problems. As a background for the techniques presently in use at the Burning Star # 4 Mine, we will briefly outline the other five (5) stripping techniques used in the area: 1. Captain Hine 6360 Range Diagram (Figure 1) 2. Leahy Mine Range Diagram (Figure 2) 3. Burning Star # 3 Mine 5860 Range Diagram (Figure 3) 4. Burning Star # 3 and # 4 Mines Dragline in Pit Range Diagram (Figure 4) 5. Captain Hine 2570/5561 Range Diagram (Figure 5) Each of these techniques was chosen because it provided the best and least expensive alternative for mining the coal under the particular restraints encountered. The Mine Engineers at our Burning Star # 4 Mine, Mr. Dennis Mahan and Mr. William Weaver, will now detail two additional mining techniques, out-lining our experience to date.

Jan 1, 1977

By Luis Pommier

The requirements of metals by modern society have created big challenges for mining engineers minerals processing engineers, metallurgical engineers and economists to produce these metals economically from mineral deposits which contain, with time, less and less value. The advances of science and technology allow, today, the exploitation of mineral deposits which only few years ago would not have been considered economical. However, there are limitations both on the minimum grade of recoverable values contained in the ore to be fed to a mill or on the concentrate to be smelted, and on the maximum content of "impurities" i.e. chemical elements which are difficult or expensive to refine from the ore, from the concentrate or from the metal. It is also known that the cost of treatment in a mill or in a smelter, for unit of metal contained in the ore or in the concentrate, increases as the grade of the recoverable values contained in them decreases and also if the content of impurities increases. In order to work a mineral deposit economically it is necessary to ensure not only that it has more than a minimum content of values, less than a maximum content of impurities and that there exists a good up-grading or metallurgical process but also to ensure that the opti-

Jan 1, 1971

By Allan G. Provost

Shaft construction is assuming ever increasing importance when new mining enterprises are considered. The reasons for this increased emphasis is the much greater depths at which many new ore-bodies are being developed and the rapid depletion of near surface reserves requiring mines to go to greater depths on existing deposits. These greater depths increase the probability of exposure to unfavorable geologic conditions and it is more likely that high ground and/or water pressures will be experienced at these depths. The large capital costs involved and the critical position of a shaft in the overall mining program necessitate that this element of project development be given careful and critical consideration. The Henderson No. 2 Shaft is located in the Rocky Mountains of north central Colorado (See Figure I), about 55 miles west of Denver, near the community of Empire in Clear Creek County. At the 10, 442 foot collar elevation, winter arrives in late September and brings snow to contend with until May. The labor force for Shaft No. 2 is approximately 90 men. They are provided access to the project via all-weather U. S. Highway 40. SHAFT DESIGN The Henderson No. 2 Shaft is a 28-foot I. D. circular, concrete lined (1 foot thick) vertical shaft. The final depth will be approximately 3100 feet

Jan 1, 1972

By Praterm J. D.

The process parameters for effective utilization of nitric acid as an oxidant for copper-iron sulfides have been developed. Leaching variables found to be important were acid concentration, temperature, time, atmosphere, pressure, mineral type, particle size, and percent solids. Particular attention was devoted to analysis and control of fumes evolved during the oxidation. Responses recorded were metal extraction, elemental sulfur formation and oxidation, product gas composition and evolution rate, reagent consumption, and residue flotation response. The paper concludes by laboratory testing a flow sheet based on the above observations. Ninety-eight percent of the copper contained in a chalcopyrite-bornite concentrate was recovered, requiring 1. 6 pounds of nitric acid to be regenerated externally per pound of copper extracted. Iron remained in the leach residue as hydrogen jarosite and was ultimately rejected from the system by froth flotation. Sixty percent of the sulfur contained, in the heading concentrate reported in the elemental form; the remainder was oxidized to sulfate and eliminated with the hydrogen jarosite in the flotation tails or by neutralization of the solvent extraction raffinate with lime. Nitrogen was evolved primarily as NO and NO2; up to 3 percent N2O was also present. Gases containing sulfur were absent except when pyrrhotite was solubilized in the absence of soluble copper. In this case, H2S was evolved.

Jan 1, 1972

By John L. Shafer

A process for the conversion of stibnite (Sb2Sj) concentrates, crude antimony oxide, or metal to a pure cubic antimonous oxide (senarmontite) has been developed on a laboratory scale. The conversion of stibnite to senarmontite has been piloted. The high purity of the final product is the result of forming antimony trichloride as a low temperature distillable intermediate. To obtain the antimony trichloride the stibnite, or crude oxide is slurried in molten antimony trichloride and reacted with gaseous hydrogen chloride. Antimony metal is oxidized to the trichloride with chlorine. The hydrogen sulfide produced from the hydro- chlorination of stibnite can be upgraded to a strength of 95% or greater for further treatment. The crude antimony trichloride is separated from the gangue by a preliminary evaporation and then is fractionally distilled and the trichloride distillate has less than 50ppm of arsenic and lead combined (the most troublesome impurities in antimony processing). The purified antimony trichloride is then hydrolyzed with sodium or ammonium hydroxide to produce the cubic form of antimonous oxide (senarmontite) to the exclusion of the rhombic form (valentinite) which is photosensitive. The advantage of this process is the ability to treat a wide range of antimony ores, concentrates, and metal to yield a high purity oxide in a controllable range of particle sizes.

Jan 1, 1975

By J. Yao

Synthetic indium-bearing zinc ferrite (IBZF) was mechanically activated by a tumbling mill. Subsequently, the behavior and kinetics of leaching zinc and indium from the initial IBZF and activated IBZF in sulfuric acid solution were investigated. The results demonstrate that the tumbling ball milling enhances the leaching reactivity of IBZF and increases the zinc and indium extractions. The reaction temperature and H2SO4 concentration have an important effect on leaching zinc and indium from the initial IBZF and activated IBZF. The kinetic model -ln(1-x) = kt was used to describe the kinetics of leaching zinc and indium from the initial IBZF and activated IBZF and to calculate the kinetic parameters. The tumbling ball milling causes a decrease in activation energy and reaction order, which indicates that the dissolution of IBZF after mechanical activation by a tumbling mill becomes less sensitive to temperature and H2SO4 concentration. For the zinc leaching, the activation energy decreases from 73.9 to 70.3 kJ/mol and the reaction order decreases from 0.72 to 0.70. For indium leaching, the activation energy decreases from 78.1 to 73.5 kJ/mol and the reaction order decreases from 0.82 to 0.69. It is found that the dissolution rates of the initial IBZF and activated IBZF are controlled by surface chemical reactions.

By Barry Hunsaker

I cannot help but be reminded, as I stand here today, of my boyhood years and heritage, both of which are inextricably tied to this very valley and are, in a: bay, apropos of the theme of this Keynote Session. I remember the scarcity of people. For example, 48, 000 in Phoenix and 436, 000 in the State in 1930 and 65,000 in Phoenix and 499, 000 in the State in 1940. Today Phoenix boasts a population of over 500, 000 and the State a population of 1, 500,000. I remember the' lack of facilities, goods and services, including gas and electric power. I recall stories of my grandfather who had the freighting or teaming contract to haul all the supplies and generating equipment, by wagon mind you, up the old Apache Trail to Roosevelt Dam. . .a three day trip from the nearest railhead which, by the way, was not Phoenix, for it did not merit a railhead on those days, but the village of Maricopa approximately 25 miles south of Phoenix. I remember chopping firewood, heating wash water on an open fire in a No. 3 wash tub at the rear of the house and doing my school homework by the light of a kerosene lamp just 25 to 35 years ago within what is now a large metropolitan area

Jan 1, 1965

By Keivan PakIman, Maziar Pasdarpour

Transportation tunnels are highly sensitive to ground movements and are required to be stable and secure for safe operation. In urban areas, the interaction between tunnels and adjacent piles, which are widely used to support buildings and other structures, requires careful consideration. The seismic response of tunnels may vary depending on the lateral stiffness and strength of the tunnel walls, while the axial loading and seismic impact of adjacent piles may cause soil displacement and stress changes that can damage the tunnel lining. As a result, tunnel owners often impose strict limits on the design of new piles lying close to existing tunnels including maximum allowable tunnel deformation, stress change limits, and minimum tunnel to pile separation distances. This paper describes a numerical analysis of the inuence of the axial loading and seismic impact of bored pile foundations on subway tunnels, undertaen using the nite element software laxis D. ased on the results of the numerical analysis, the paper suggests a more realistic and less conservative approach for designing piles in close proximity to transportation tunnels. INTRODUCTION The interaction between tunnels and adjacent piles can cause stress changes and displacements in the soil and structures which may adversely impact structural performance and tunnel safety. It is therefore important to take account of relative load transfer and piling conguration when designing new piles in

Jun 23, 2024

By Jacques B. Wertz

Recurring movements remotely connected with the Murray fracture zone and the San Andreas fault complex, together with the slow northwestward drift affecting the Baja California peninsula, could progressively have accentuated the tensional situation already connected with the anticlinorium in southern Arizona. From the fragmentary data gathered on the Texas lineament, it appears that a very mild curvature, concave to the northeast, may be present along this belt throughout Arizona. Those localities where the successive changes in direc¬tion of the strands of the lineament belt seem to occur do generally coincide with intersections of both north-northwestern and northeastern breaks. It is along the outward, southern fringe of the belt (at such structural centers like Bisbee, Baboquivari, Ajo) that the greatest impact of regional movements could be expected to have occurred through tangential-torsional stresses. Although it si accepted that the north-northwestern and more particu¬larly the northeastern fractures in Southeast Arizona are propitious to or partially responsible for mineralization, it seems undeniable that the Texas lineament belt must have greatly increased the potentialities for ore throughout the Arizona copper province. While intrusive bodies occur near major intersections, with the Texas lineament belt as a common denominator, it seems, the ore deposits are to be found close to one of the intrusive stocks, varying in distance from contiguity (Bisbee) to one or two miles away (Silver Bell orebodies).

Jan 1, 1970

By J. D. Miller

Physical separation of bitumen from low-grade Utah tar sand deposits containing a relatively high viscosity bitumen phase (Sunnyside and Tar Sand Triangle deposits) has been accomplished by traditional size reduction and froth flotation techniques. At appropriate experimental conditions more than 90 percent of the bitumen can be recovered in a concentrate, containing more than 20 weight percent bitumen, which should be a suitable feed material for subsequent hot water or thermal processing. The efficiency of bitumen recovery depends on the extent of size reduction, promoter and dispersant addition. Rejection of greater than 60 percent of the sand at ambient temperature and ease of water removal from the concentrate make such a process strategy both energy and cost effective. The energy required to achieve effective separation by the ambient temperature process is significantly less than the energy required for the recently developed hot water process. The flotation behavior of the tar sand has been analysed with respect to flotation pH, contact angle measurements and the apparent iso- electric point of the bitumen. The best flotation response at pH 7.8 to 9.0 can be correlated with the maximum in contact angle developed between the air bubble and bitumen surface and with the apparent iso-electric point of the bitumen (-pH 8.0).

Jan 1, 1981

By J. P. Vandenhoeck

Sizing devices used commercially are unfortunately not 100% efficient, the splits that can be obtained are usually inferior to the results obtained in the laboratory. Often the capital and operating costs of equipment capable of high sizing efficiency cannot be justified by the economics or requirements of the process. To reconcile the desired sizing efficiency needed to obtain optimum process requirements with the sizing efficiency of equipment economically practical, it is often necessary or desirable to predict the gradation and weight splits of the products obtained based on the expectant efficiency of the contemplated sizing device or method. The less efficient the sizing device one must employ, the more important it is to know the results that may be expected for the establishment of the optimum flow sheet and the more difficult it becomes to estimate the results accurately. Air classification equipment which sizes materials by opposing the drag force created by an air stream acting on a particle with a combination of gravitational, inertial or centrifugal forces are substantially less efficient than, for example, a laboratory sieve analysis. Air classifiers allow oversize material to contaminate the fine fraction and leave undersize material in the coarse fraction. The techniques employed to predict the gradation and weight splits obtained from air classification outlined below are adaptable to other sizing devices less than 100% efficient such as screens, sifters and wet classifiers.

Jan 1, 1965

By E. E. Malouf

For centuries small amounts of copper have been recovered from acid mine-drainage waters. In recent years, the expansion of copper-bearing waste dump leaching for copper recovery has established a technological basis that is rapidly converting the art of copper leaching' into a science. Leaching of copper, whether from copper-bearing ore or waste, follows well established chemical reactions. These reactions are commonly in an acid circuit, but where leaching of copper is to be made in rock that is a high acid consumer, ammonia and ammonia carbonate, as well as cyanide leach solutions, can be used effectively. Current hydrometallurgical processes are being applied at an ever increasing rate to recover the trace amounts of copper in copper mine waste by in-place leaching. Currently approximately 300, 000 tons of copper are produced annually in this manner where as recently as ten years ago, only one-eighth of this amount of precipitate copper was produced.. Where copper occurs as an oxide in higher concentrations as to be classified as an ore rather than waste, then the hydro-metallurgical processes are applied as percolation or agitation leaching in vats, pachuca tanks, or prepared heaps. This approach gives better control over the recovery of the leach solutions, particularly in the processes where ammonia or cyanide leaching agents are to be used.

Jan 1, 1972

By A. Bruynesteyn

Most ores and coals contain sulphide minerals such as pyrite, FeS2, the sulphur portion of which is a ready substrate for a variety of sulphur oxidizing bacteria. Although there are several bacteria capable of oxidizing sulphide minerals, the most often discussed culprit is Thiobacillus ferrooxidans.. Oxygen from the air slowly oxidizes pyrite into sulphuric acid, but T- ferrooxidans can increase this reaction rate several 100,000 times.

Jan 1, 1991

By Yeonuk Choi, Gus Van Weert

cyanide control in effluents is becoming a critical environmental issue for the gold extraction industry. Silver impregnated carbon removes free cyanide effectively to the ppb level from solution in high throughput columns. By re-calcining the cyanide saturated carbon, the impregnated silver is restored to activity and the cyanide destroyed outside the effluent stream. Many gold mills already have an activation kiln on site, which could make retrofit relatively easy.

Jan 1, 1993