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By Omar A. Muhtadi, David A. Milligan

7.1 INTRODUCTION The circulating fluid (generally an aqueous cyanide solution) is the major active component of heap leaching. This solution extracts precious metal from the heap and is then processed to recover the precious metal. The solution continuously recycles through the heap to recover more precious metal. With each cycle through the heap, water and chemicals are lost. Make-up water and chemicals must be added to balance losses from evaporation, seepage, entrainment, and chemical reaction in the heap, as well as any other processing losses. Adding more water than needed can result in a build-up of water as inventory in the various ponds and can eventually require that water be discharged from the operation. This is an extremely undesirable condition, and can often be very expensive in both investment in water treating facilities and operating costs. Most heap leach facilities operate under a zero discharge permit; thus, a situation requiring water discharge can result in permit violation. Chemical solution control must be managed to maintain the optimum pH, dissolved oxygen content, and cyanide content, while preventing "scaling". Calcium-based precipitation is a common scaling problem in mill reclaim waters. A buildup of these deposits can result in severe reduction of water flow, loss of pump efficiency and eventual interruption in metal production. In addition, problems of plugged sprinkler heads, blinded leach pads and fouled carbon (in carbon recovery systems) can be and often are experienced when scale control is not maintained. The remainder of this chapter discusses chemical solution control and scaling prediction/prevention in the context of a "closed" system. Sizing of ponds to accommodate precipitation and runoff, collection systems, and other similar design considerations are not discussed here. These topics are deferred to later chapters, e.g. Chapter 10 considers design of collection systems while Chapter 12 discusses pond sizing. 7.2 CHEMICAL CONTROL Chemical composition of the circulating solution must be controlled by the operator if the heap leaching process is to be successful. The primary or essential chemical control parameters in any heap leaching operation are:

Jan 1, 1988

By Edward I. Erlich

1984 saw the 30th anniversary of a momentous event in Soviet geology-the discovery of kimberlites in Siberia, an event that vaulted the Soviet Union to second rank among the world's producers of both gem and industrial diamonds. There are many legends associated with this story, legends about those who predicted the discovery and those who achieved it in the field. The story told here unfolded during the field campaigns of the 1940s through 1960s, as witnessed by the authors and their companies of an earlier generation. This story illustrates science, chance, and human emotions at work, resulting in a blend of conviction, courage, bureaucratic sniping, and competition for glory. At the same time, it is an illustration of the workings of the Soviet exploration system. In a broader sense, it is the realization of the Russian image-boundless natural wealth, indomitable ingenuity, and the rigid political economic system that permeates the Russian landscape as well as the people. Most accounts of the Siberian diamond saga begin with statements such as, "This discovery confirmed the predictions of...", or "It was a result of predictions of one of the greatest Soviet geologists, Academician V.S. Sobelov...". These are only part of the truth. It had become apparent even in the 1930s that the Siberian Platform contained one of the Earth's greatest Basaltic provinces, described in a monograph by Sobolev...; and at the end of the thirties, G.G. Moor of the Institute of Arctic Geology found alnoites, similar in many ways to kimberlites. At the same time, the famous polar geologist, N.N. Urvantsev found other kimberlite like rocks in the southern Taymir Peninsula, adjacent to the Siberian Platform. In publications describing these rocks, Moor and Urvantsev mentioned for the first time the possibility of finding diamondiferous kimberlites similar to those in South Africa. Unfortunately, Urvantsev spent little time in the field between terms in concentration camps. Moor was considered by his superiors to be no more than a good descriptive petrographer; they suggested to him that his conclusions should be backed up by more highly regarded specialists. Thereupon, Moor asked Sobolev to coauthor a paper with him and this became the widely quoted prediction about diamonds in Siberia. Another early paper should also be mentioned, an unpublished paper found by M.I. Rabkin in the geological archives of the Norilsk Metallurgical Plant, written by Yu. M. Sheinmann when he worked in the concentration camp there in the late forties. This report placed the probable location of yet-to-be-discovered kimberlites within less than 100 km of their correct location.

Jan 1, 1990

By S. R. Maynard

The Ortiz Mountains lie 25 mi (40 km) northeast of Albuquerque, New Mexico in Santa Fe County (Figure 1). Approximately 350,000 ounces (11,000 kgs) of gold have been produced from the Ortiz Mountains since the 1820s. The 100 square mile (260 square km) Ortiz Mine Grant was secured from the Mexican government in 1833 by Jose Francisco Ortiz for the purpose of mining gold. The Grant has remained more or less intact to the present. The mineral rights are currently owned by Ortiz Mines, Inc. of Joplin, Missouri and are leased to LAC Minerals, USA, Inc. (west half) and to Gold Fields Mining Corporation (east half).

Jan 1, 1989

By C. Tsiouvaras

Restoration of bauxite mining areas constitutes a difficult issue to address due to the destruction of the vegetation and soil decay of the excavated area. In this study woody species growth, in relation to altitude, heavy metal concentrations and mechanical texture of the underlying mining waste, were investigated. The research was implemented on restored sites of a bauxite mine in the Fokida Prefecture of Greece. These sites were located in three different elevations and the restoration took place in two phases, in 2001 and 1996. Heavy metals measurements showed some correlation among the different metals, whereas their concentration was also associated with plant growth parameters.

Jan 1, 2007

A roof rating system has been devel¬oped for upper seam damage prediction during mul¬ti-seam mining based on structural and geologic conditions in the upper seam. Two primary consid¬erations -geologic and spatial - form the basis of the classification system. It includes factors commonly found in geomechanics classification systems as well as factors which are peculiar to multi-seam mining, such as those which define the two adjacent seams and the innerburden. This rating system has been applied to numerous case studies to form empirical relationships for quan-titatively predicting potential upper seam damage based on anticipated subsidence and strain values and vertical movements.

Jan 1, 1988

By Thomas F. Pugsley, Wilf J. Davies, James Gallagher

Falconbridge Limited is developing a major nickel mine at Craig which lies between 600 m, 915 m and 1500 m below surface and is accessed on the 600 m and 1250 m levels of Onaping Mine. To supply adequate ventilation for mine development and initial ore production, two raises, 1200 m long are to be driven in norite and granitic gneiss. Falconbridge has purchased a Robbins 97RL Raise Drill and a string of 330 mm drill pipe to ream these raises in 600 m legs at diameter. The paper describes the introduction of deep hole, large diameter raise boring technology into Falconbridge operations involving contractors and specialists in the technology.

Jan 1, 1989

By Rick L. Williamson

International lending institutions have charters requiring projects that are seeking loans to adhere to certain environmental performance standards, including compliance with host-country environmental laws, as well as observance of international environmental policies and guidelines. The most commonly applied international environmental policies and guidelines are those established by The World Bank. Lenders require a review by an independent engineer to determine that the feasibility study plans have been developed in accordance with the applicable environmental commitments. Lender agreements require independent engineer evaluation of environmental performance through the construction phase and initial operations phase of the project, culminating in the issuance of an "Environ- mental Completion Certificate."

Jan 1, 2001

By R. L. Urie, L. Burdzinski

Non-operational mine facilities are subject to placement on the EPA's National Priority List (Superfund). Once a mine site is undergoing investigation and/or remediation, MSHA regulations for health and safety may no longer be applicable. This paper addresses the changes in the applicable and relevant standards that apply to health and safety and public health related to site contaminants. The implementation of health and safety plans, and the development of public health risk assessments are described. Examples are presented from Superfund activities at the Eagle Mine, near Minturn, Colorado; the Anaconda Smelter near Mill Creek, Montana; California Gulch near Leadville, Colorado; and Bunker Hill, Idaho.

Jan 1, 1991

By S. R. S. Sastri, G. V. Rao

Because the nickel contained in lateritic nickel ores does not occur in an identifiable mineral, it is generally accepted that these ores are not amenable to beneficiation. For this reason, such ores are either directly smelted or leached to extract the nickel. In this paper, a process for enriching the nickel content of the lateritic nickel-bearing chromite overburden, normally a waste material generated during chromite mining, is described. In this flotation process, a nickel preconcentrate containing >1.1% Ni was obtained from material containing as little as 0.36% nickel. An empirical relationship was developed to predict the grade of nickel that can be obtained.

Jan 1, 1997

By Douglas J. Pendrell, Marvin D. Simmons, E. Raymond Boc

The U. S. Army Corps of Engineers is in the early stages of design for an estimated 14 m (46 ft) diameter tunnel in northeast New Jersey. This tunnel will carry flood waters from the upper end of the Pompton River in Wayne County, to an outlet in Newark Bay, a distance of 33 km (20.5 miles). The tunnel will be constructed by a tunnel boring machine (TBM), the size of which is unprecedented at the present time. The alignment is through Triassic and Jurassic sandstones, siltstones, and shales that include three beds of basalt that range in thickness from 76 to 310 m (250 to 1020 ft).

Jan 1, 1991

By Malcolm J. McPherson

Within the world of mining health and safety, increasing attention is again being given to underground fires and explosions. This paper reviews the effects of open fires in mine entries on the ventilation system, and outlines current methodologies of attempting to control such a fire. The particular hazards of a fuel-rich fire are discussed. There appear to have been no really significant advances made in methods of extinguishing mine entry fires in the last several decades. The final section of the paper introduces research that is investigating the simultaneous production of an inerting, cooling and quenching atmosphere by means of a dense water fog.

Jan 1, 1993

By N. P. Reddy, Y. J. Wang

Stall or aerodynamic stall of axial flow fans has long been recognized as an important operational problem in mine ventilation. To develop a technique for characterizing fan stall in multiple fan ventilation networks, a research project was initiated through the Generic Mineral Technology Center for Mine Systems Design and Ground Control. Considering that fan stall is related to multiple operating points, this paper discusses a numerical model for multiple fan ventilation networks, and numerical methods for solving multiple networks solutions. It is hoped that the results of this project will lead to an innovative method of ventilation network analysis and simulation, thus preventing stall.

Jan 1, 1993

By W. J. Pennstrom, J. R. Arnold

This paper focuses on solution-balance management around heap-leach operations. Experience has shown that increased leach recoveries can be achieved by utilizing various leach-solution recirculation techniques. The most prominent solution-recirculation technique is intermediate leaching. The net effect of intermediate leaching is to increase recovery plant performance by increasing solution concentration tenors, to increase metal recovery by increasing the total leach time and to decrease the overall capital expenditures required for metal-recovery facilities. The adverse effect on the flow of cash from increased metal inventories in the recirculating solutions is offset by increased metal recovery and lower operating costs per unit produced.

Jan 1, 2000

By J. S. Stachulak

Installation of a computerized mine monitoring and control system in two planned construction phases began in 1983. Phase one consisted of providing a central monitoring station located on surface for monitoring underground CO detection in Frood Mine's heated area. The implementation of this project annualized labour savings of $200,000. The cost of installation of an early fire warning system was $100,000. There are several CO sensor monitoring carbon monoxide trends through mine heated areas. To obtain an early warning, it is not good enough to know that a fire has started, but it is also necessary to know where the fire is located.

Jan 1, 1989

By Fernando Concha, Arturo Barrientos

The flow in a hydrocyclone is divided into a boundary layer around the walls, an exterior inviscid flow and an air core in the center of the equipment. The boundary layer flow over the lateral walls is associated with the short circuit of particles to the underflow, while the boundary layer over the top of the hydrocyclone and the outer part of the vortex finder tube is related to the short circuit of particles to the overflow. Classification takes place in the exterior flow. The model can be validated with pilot or industrial data and simulates the performance of hydrocyclones in a wide range of design and operating variables.

Jan 1, 1992

By David S. Yantek, Paul Jurovcik, Eric R. Bauer

Workers in coal preparation plants, where vibrating screens are significant noise sources, are often exposed to sound levels exceeding 90 dB(A). The National Institute for Occupational Safety and Health, a major coal company, and a vibrating screen manufacturer conducted a cooperative study of vibrating screen noise. Rubber isolators reduced sound levels by 1 dB. Urethane screen panels did not reduce sound levels in this case. Drive noise was determined to be the dominant noise source on the screen. Damped side plates reduced vibration levels on the screen sides by 1 to 7 dB(A). Detailed results of the study are presented.

Jan 1, 2005

By Ernest Peters, Fiona M. Doyle

The leaching and bulk decomposition of sulfide minerals is of enormous commercial importance in several areas of the minerals industry. These include: direct leaching of ores or concentrates for the recovery of the contained metal values; decomposition of sulfides to recover associated values such as encapsulated gold; and the potentially hazardous oxidation of sulfides in waste disposal facilities. A significant challenge to successful future developments in these areas is to improve our fundamental understanding of the mechanisms of the chemical, electrochemical, and bacterially-mediated interactions between sulfides and aqueous solutions. The paper summarizes current understanding of these mechanisms, and discusses promising new directions for research.

Jan 1, 1989

By Serge Payant, Michael G. Li, Lionel J. J. Catalan

Alkaline solution rinsing for decommissioning of an acid-leached residue was evaluated by column experiments, neutralization tests and solid characterization by XRD and SEM. It was found that consumption of a strong alkali during residue neutralization was much greater than that required to neutralize the soluble acidity. The excess alkalinity was consumed by solid-phase conversions unnecessary for the success of decommissioning. Alkaline rinsing did not reduce the time requirement for decommissioning when compared with plain water rinsing. Since no benefit is gained to compensate for the additional costs associated with excess alkali consumption, we conclude that strong alkaline solution rinsing is in fact inferior to simple water rinsing.

Jan 1, 1998

By Fabio Amaya, Andrés Marulanda, Ramiro Gutiérrez, Alberto Marulanda

The behavior of a salt rock mass is strongly related to a creep phenomenon. The amount of creep depends on the level of stress generated in the underground excavation. Additionally, security conditions and the lifespan of an underground cavern excavated under this geological conditions depend on the evolution of creep. Based on the experience of the failure of the Old Underground Salt Cathedral of Zipaquirá(Colombia) and the construction of the new one, the theoretical framework to predict the creep behavior of a salt rock mass is explained. The theoretical formulations are calibrated based on actual observations of the material behavior to predict the lifespan of this striking structure.

Jan 1, 2003

By V. R. Degner

Given: the process tonnage, performance objectives, and plant floor area, the paper will outline the metallurgical and machine hydrodynamic scale-up procedures for translating the lab flotation test results to the design of a full size flotation machine installation, including the machine number, size, and arrangement. Machine selection considerations for rougher, scavenger and cleaner duty, and special considerations relative to specific applications, will be summarized where appropriate. The value of kinetic modeling in quantitative metallurgical (lab to full size machine) scale-up will be reviewed considering a coal installation, and design information for additional applications such as copper, molybdenum, iron, phosphate, and potash will be discussed.

Jan 1, 1986