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By P. Zhang, D. W. H. Su, M. Van Dyke, H. Dougherty

This paper describes the scientific data acquisition, data interpretation, and sophisticated 3-dimensional modeling processes of an ongoing gas well stability research program by the National Institute for Occupational Safety and Health (NIOSH). Results from the NIOSH field instrumentation programs and the parallel 3-dimensional numerical modeling programs indicate that overburden depth, overburden geology, surface topographic relief, strata dip of the coal measure rocks, and casing cementing alternatives are the dominant factors affecting longwall-induced subsurface deformations and gas well casing stresses. Topographic relief could produce localized longwall-induced deformations if weak-to-strong rock interfaces are present near the bottom of stream valleys. Strata dip has significant impact on longwall-induced subsurface deformations. Cementing alternatives are found to have significant impacts on longwall-induced deformations and gas well casing stresses.

By F. P. Schwarz

Even in an otherwise care-fully done sampling procedure, reducing subsample weight, or splitting, when the grain size of material is too large commonly generates significant error. Such error can be estimated from the standard deviation of differences between values of PAIRED ASSAYS. Samples from split-ting steps immediately before comminution, and showing a restricted range of grade, generate paired assays. Splitting steps characterized by relative standard deviations exceeding 16% generate nonrepresentative data. Such steps should be redesigned to optimize reliability of assay-dependent studies. A sampling scheme can be graphically characterized, and then redesigned as appropriate, using a SAMPLING NOMOGRAPH. Use of the nomograph avoids continued replication of assays. Generally at a splitting step, excessive error can be reduced by comminuting more material. Unnecessary effort can be mitigated by comminuting less finely and/or by splitting to a smaller weight.

Jan 1, 1992

By Nikhil Dhawan, Shrey Agrawal, SHAILA MIR

The current study investigates the effect of microwave processing on low-grade banded iron ore using charcoal, coking coal, and non-coking coal. Charcoal showed better microwave heating response at low temperatures, and the coals exhibit better heating response at higher temperatures. Low carbon dosage ~ 12% is sufficient to generate concentrate with 61.8% iron grade and ~6% for 94.8% iron recovery comprising of magnetite phase suitable for iron-making applications. The process separation efficiency of ~ 95% is achieved at 6% carbon dosage and decreases with an increase in carbon due to formation of the fayalite phase. The metallization degree showed a strong dependency on reductant dosage and achieved amaximumvalue of 22.7%at 18%charcoal. The comparison of ore with pure iron oxide and the synthetic mixture of iron oxide indicated that the underlying bonding due to banded structure enhances the Joule heating during microwave irradiation and thereby aids in attaining higher temperature and better separation.

Sep 21, 2020

By Piyush Rai, Suresh Kumar Sharma, Punit Paurush

The present study has been conducted in surface limestone mine to select the controllable blasting design parameters affecting the peak particle velocity (PPV) for assessment of ground vibration. The study aims at using two prominent statistical tools, namely, principal component analysis (PCA) and stepwise selection and elimination (SSE) techniques for identifying the key controllable parameters affecting the PPV. For determining the correlation coefficient between blasting design parameters and PPV from 44 field scale trial blasts, multi-variate linear regression (MLR) technique was done. It was found that the PCA and SSE eliminated a huge number of controllable parameters to identify the most important parameters, affecting the PPV. The PCA eliminated 6 number of parameters while SSE eliminated 5 number of parameters, and the coefficients of determination (R2) obtained were 0.616 and 0.584 for PCA and SSE respectively. The predictor equations were evolved, and these equations were used to validate the PPV results for another set of 21 field scale trial blasts. The predictor equations have been found to be fairly accurate in predicting the PPV values. Further, the PCA technique provides very near prediction of PPV with high degree of correlation in comparison to SSE technique. The paper highlights the role of state-of-art statistical tools in selecting the blasting design parameters affecting the PPV in field-scale blasting.

Mar 1, 2021

By Harry M. Conger

Kaiser Steel Corporation's Eagle Mountain Mine is located in the Colorado Desert, 60 miles east of Indio, California. Concentrates from the mine are shipped by rail 164 miles to the company's steel mill at Fontana, and also to Longbeach, California for export. Temperatures are typical of the lower desert ranging from a high of 120 degrees in the summer to a low of 25 degrees in the winter. The average annual rainfall of about two inches comes mainly as cloud bursts during the summer months. From its inception, the Eagle Mountain Mine has had the problem of breaking its mine rock. Practices followed from 1949 until 1962 were very costly, did not produce uniformly good fragmentation, and were incapable of sustaining high production. During this period, every conventional type of explosive then in use was tried and found to be unsatisfactory for one reason or another. The first slurry test work at Eagle Mountain was started in 195E and finally by 1962, after having tried all the slurry mixtures then available including some "home made" formulas, a metallized slurry was perfected at the mine which overcame all of the disadvantages of former blasting methods.

Jan 1, 1965

Refractory copper ores (CROs) in central Africa contain copper minerals that are locked up in a micacious solid matrix or associated with carbonate, sulfide and phosphate minerals. Several researchers have reported that the recovery of copper from CRO material by an acid-leaching process is not economically feasible, due to the presence of excess gangue-acid-consuming minerals such as calcites, dolomite, asbolane and iron oxides. Since the proportion of acid-insoluble copper (CuS) is about 28% of total copper and total free sulfur is extremely small, sulfide flotation was considered unfavorable. Consequently, hundreds of millions of tons of CRO material have been stockpiled specifically at the Nchanga Mine of Zambia. In terms of copper distribution in CRO material, a significant portion of total copper exists as carbonates (39%) and oxides (17%), while 28% of the copper is acidinsoluble (CuS). The rest of the copper is in the form of carbonates (16%) and (hydr) oxides (17%). This means that only about 72% of total copper is recoverable through the non-oxidative acid-leaching process. In this study, batch leach tests were performed on CRO solids (d95 = 95%) to establish the gangue acid consumption values at different feed pH values and to evaluate the leaching characteristics of copper, manganese and iron within the CRO material. Subsequently, continuous leach tests were performed on CRO solids (106 um, 80% passing) using optimum leach conditions derived from batch tests. This paper aims to show that sustainable copper recovery can be achieved by selecting leaching conditions whereby gangue acid consumption (GAC) values become significantly small and the final concentration of manganese and iron in the leach solution are appreciably low.

Nov 1, 2011

By LUIS ALBERTO TORRES-CRUZ

The assessment of liquefaction vulnerability is crucial to understanding the potential consequences of a tailings dam failure. The “Plewes method” is a relatively well-known and simple screening method to assess liquefaction potential based on results of cone penetration testing (CPT) which may be complemented with laboratory testing. The objective of the current work is to emphasise the screening nature of the method and its uncertainties when applied in tailings deposits. Specifically, the paper highlights the difficulties in assessing the intrinsic uncertainty of the method and the additional uncertainty that results from variations of the slope of the critical state line (λ10) along the depth of the CPT sounding. The results of the method are too uncertain for detailed characterisation of tailings even when a relatively low intrinsic uncertainty is assumed. However, the method characterises weaker soils with lower uncertainty (although still too high for detailed characterisation) than stronger soils. The uncertainty of the method is negatively affected by the relatively low λ10 values that are typical of nonplastic tailings. It is suggested that the results of the method should be presented in scatter plots in which the spread of the data is consistent with the uncertainty of the method.

Jan 28, 2021

By Charles M. Hauptman

The Karst asbestos deposit, discovered seventy years ago, is 32 miles south of Bozeman in southwestern Montana. The deposit is about one-half mile west of the Gallatin River which flows in a deep V-shaped valley flanked on either side by rugged mountains. The Madison range is west of the river and the Gallatin range lies to the east. A busy all-weather highway, U.S. No. 191, follows the river and is the major north-south route between Bozeman and the Gallatin valley to the north and Idaho and the west entrance of Yellowstone National Park to the south. The asbestos deposit is a large body of serpentinized peridotite in which anthophy11ite.occurs, both as distinct veins and as a disseminated mineral in the peridotite mass. The known exposures of the asbestos-bearing rock occur on a steen south slope at an "elevation of about 7000 feet, an elevation 'which is about 1200 feet above the Gallatin River. Over the years, a number of small companies have attempted to exploit the Karst asbestos deposit without continuing success. The present operator, Galaxy Mining Corporation, has attempted a systematic approach to the problem by utilizing geologic and engineering surveys to determine the economic and technical feasibility of a mine and plant to produce a finished asbestos pro-duct. The results of this work indicate a high probability of success for the project. However the company now faces that dilel1lJllB so common to the non-metallic mineral business; that is, whether to continue a research program of further mineralogical and technological studies in conjunction with detailed market surveys or to rely on the work done to date and embark on a pilot progril1n

Jan 1, 1971

NICOR Mineral Ventures, Inc. retained Neyer, Tiseo and Hindo, Ltd. to evaluate the potential effects of a planned dewatering operation at NICOR's proposed, 258-acre silica sand mining facility near South Rockwood, Michigan. The ?orebody? is a horizontally extensive, friable, quartz sandstone from the Sylvania Formation which also serves as an aquifer for some of the rural, residential development near the site. We conducted an aquifer test on the site which identified the important aquifer properties. Using these data and an analytical model, we determined that the radius of influence would be expected to range up to 6000 feet from the quarry during its final development stage. An inventory of water supply wells revealed that most wells had sufficient available drawdown and would not be adversely affected. A long-term groundwater monitoring program was recommended to monitor the possible effects at some of the closest wells.

Jan 1, 1987

By M. Manrique, S. A. Pirzada, P. R. Taylor

A thermal plasma-assisted laminar flow reactor was used to evaluate the kinetics of converting alumina to sodium aluminate in flight. Free energy minimization calculations were used to determine experimental conditions. The experimental variables included alumina particle size, alumina/sodium nitrate molar ratio, temperature and residence time. A mathematical model for the conversion was developed and validated. Experimental and mathematical results are presented.

Jan 1, 1998

By Jue Kou, Hongda Xu, Tichang Sun, Shichao Wu, Wenli Han

To investigate the effect of simultaneous change in particle size of raw materials (including ore, reductant, and dephosphorization agent) on the direct reduction process of high-phosphorus oolitic hematite, the experimental research of method with direct reduction and magnetic separation was conducted to investigate the effect of simultaneous change in particle size of raw materials on the final reduction products in the form of mineral composition, reduction speed, metallic iron particle morphology, phosphorus distribution, and powdery reduction iron. The results revealed that under the same conditions of reduction temperature, the raw material particle size affects the mineral composition of the final reduction product, the coarser the raw material particle size, the slower the reduction speed, the lower the metallization rate, and the larger the final metallic iron particle size formed. Under the same conditions of raw material particle size, the reduction temperature affects the mineral composition of the final reduction product, the higher the reduction temperature, the faster the reduction speed, the higher the metallization rate, and the larger the size of metallic iron particles within a certain reduction time. Neither the raw material particle size nor reduction temperature affects the form of phosphorus present in the reduction product. Both the raw material particle size and reduction temperature affect the grade of powdery reduction iron to a less extent, but affect the recovery rate and phosphorus content significantly. At the same reduction temperature, the recovery of powdery reduction iron and phosphorus content gradually decreases with the increase in raw material particle size. For the same raw material particle size, the recovery of powdery reduction iron gradually increases, and the phosphorus content gradually decreases with the increase in the reduction temperature. The results identified the effect of simultaneous changes in particle size of raw materials on the direct reduction process of high-phosphorus oolitic hematite and provide a basis for the selection of raw material particle size for the industrial application.

Dec 20, 2022

By G. Kemp Williams, Peter H. Dohms, Barry A. Hillman, Laurie A. Williams

Introduction In 1969, the US devalued the dollar. This action, over the ensuing four years, resulted in the deregulation of the price of gold. It also resulted in the rebirth of the US gold mining industry. The extreme inflation of the 1970s led to a dramatic increase in the price of precious metals. Consequently an increased interest in the exploration for and mining of gold has occurred. The enthusiasm began among the few existing producers who had survived on marginal profits during a prolonged period of fixed prices and constantly rising costs. Then came the newcomers. They saw the opportunity to enter an industry that historically had been characterized by small operations with low capital costs. It was not until the late 1970s that large mining companies recognized that investment in gold projects could generate cash flows that previously were associated only with world class deposits. Today, gold mining has tremendous appeal for the entire mining community, despite the dramatic price drop from 1980-81 levels. There are even major firms with no mining experience attempting to gain a foothold. But how easy is it to enter the US gold mining industry? What are the basic factors that influence the economics, and what are they likely to be for the remainder of the decade? How has the industry changed, and what is the composition of the active companies? An examination of the industry will help to answer these questions. US Gold Mining History The current gold rush is actually the fifth in the 208-year history of the US. The first recorded commercial mining of gold occurred in the Southeast in 1799. It produced from small, yet relatively rich placer deposits. The famous California gold rush of 1848 placed the US as a major producer with 62.2 t (2 million oz) of output by 1850. More than 93.3 t (3 million oz) was mined by 1853, equivalent to 63% of world production. But the richest placers were soon depleted. By the end of the Civil War, annual production had declined to well below 62.2 t (2 million oz). The government then relaxed prices and the industry again began to recover. The 1870-80s saw the great mines of the California Mother Lode and Grass Valley brought into production. This was followed by development of Nevada's Comstock, which later became one of the world's largest producers. Discovery of gold at Cripple Creek in 1892, coupled with technological advances in the use of large dredges in the California placers, resulted in significant production increases. And, with the expansion of the Homestake mine at Lead, SD, in 1898, US output again surpassed the 93.3-t (3 million-oz) level. By 1905, produc¬tion climbed to 124.4 t (4 million oz) with the addition of the Alaskan deposits, new output at Goldfields, NV, and the introduction of the cyanidation process. During World War I, the government forced the shutdown of gold mines. By 1920, total production had dropped to little more than 62.2 t (2 million oz). Many mines remained closed until the Great Depression. This, combined with the devaluation of the US dollar in 1934, resulted in a gold price increase to about $1.13/g ($35 per oz). Then began the fourth gold rush. By 1937, output had again surpassed 124.4 t (4 million oz). This was due to an increase in primary production and new byproduct production from base metal operations. Unlike the previous period of growth, however, this period was short-lived. The imposition of Executive Order L-208 in 1942 once again forced the shutdown of most mines. At the end of World War II, cumulative US gold production had

Jan 12, 1984

By K. V. Godfrey

With the increasing need to exercise better control over mill circuits has come a requirement to develop rapid, accurate means of measuring circuit parameters. One of the most important parameters is the assay of the material in the circuit (or about to be introduced to the circuit). To date, most on-stream analysis has been performed using X-ray fluorescence equipment. Neutron activation offers an alternative method in certain circumstances, and one which has several interesting advantages. Recognizing the need for a simple, safe neutron activation unit suitable for on-stream analysis in the mineral industries, Atomic Energy of Canada Limited has designed, built and tested the SHERLOCK system. One prototype (SHERLOCK I) is located in Ottawa and is now used primarily in research. A second prototype (SHERLOCK III) is located in Vancouver at the laboratories of B.C. Research. This unit is being used for some development research and for evaluating the unit in specific applications. Most of the work completed to date has been aimed at proving the technique and in developing some of the parameters needed to design systems for a milling plant. Funding for the work has been through research grants and through sponsor¬ship by interested companies.

Jan 1, 1971

By I. E. Odom

The rare magnesium-lithium clay mineral hectorite occurs at many places in the McDermitt caldera of Nevada-Oregon. Commercial development of several high purity deposits began in 1986. The hectorite was precipitated in a lake environment formed after collapse of the McDermitt caldera. Hectorite beds and lenses are associated with volcaniclastic sediments, limestones, dolomites, zeolites and locally sandy bentonites. The high purity deposits appear to be associated with hydrothermal areas. The hectorite consists of extremely small flake-shaped crystals, and Ca is the predominant exchangeable ion. Its color ranges from white to light green. Commercial uses developed to date include high brightness magnesium aluminum silicate products, organophilic clays, pulp retention, and ceramics. The MAS is used as a suspending agent, binder, stabilizer and thixotrope in aqueous solutions for cosmetics, household cleaners, pharmaceuticals and miscellaneous industrial applications. Organoclays are used in printing inks and paints.

Jan 1, 1992

By H. W. Gao

During the last decade, the feasibility of applying the in situ leaching technology to the recovery of copper from deeply buried deposits containing chalcopyrite has received much attention.(1-4) The major incentive for using this technology is that under certain circumstances, copper in deep underground deposits, which cannot be mined economically by conventional means, can be recovered economically. Basically, this technology involves rubblization of the deeply buried copper ore body followed by in-place leaching of the rubblized copper ores. Rubblization of the ore can be achieved by some suitable method such as the use of block caving mining. The rubblized chimney is then filled with water until the original water level is reached. Leaching occurs when the eater saturated with oxygen is introduced into the chimney- and flows through the fractured rock masses and within pores of rocks. As the dissolved oxygen oxidizes the primary sulfides, heat is generated. Because of low conductivity of the surrounding rocks, the generated heat is able to raise the temperature of the chimney. The increase in the temperature of the chimney and the relatively high content of dissolved oxygen in the leach solution under high hydrostatic pressure will result in an enhanced dissolution of the primary sulfide minerals. To ensure a successful application of the in situ leaching technology, a complete understanding of the effects of the ore particle size distribution, ore grade mineralogy, temperature, pressure, lixiviant concentration, pH, etc. on the rate of copper recovery is necessary so that copper can be recovered efficiently and the amount of copper extracted can be predicted. These can be achieved through mathematical modeling of the in situ leaching process and conducting laboratory tests. In this paper we will present a mathematical model that simulates the in situ leaching process as depicted in Figure 1. To model this process properly, not only the 'kinetic and thermodynamic aspects of leaching chemistry must be known, but the effects of heat generation, the physical aspect of fluid flow and other related multicomponent transport phenomena must be considered. Furthermore, since most factors involved in the leaching process change with time, a leaching system must be described using unsteady state equations.

Jan 1, 1981

By K. D. Luxbacher, E. C. Jong

Perfluoromethylcyclohexane (PMCH), a member of the perfluorocarbon tracer group of compounds, has been shown to be a viable supplement to the widely used tracer gas sulfur hexafluoride (SF6). This viability stems from the fact that PMCH can be used concurrently with SF6 while maintaining adequate chromatographic separation and comparable sensitivity during analysis. However, the release of PMCH in an underground mine ventilation system is challenging due to its physical characteristics. While SF6 exists as a gas at room temperature and pressure and can be accurately released by a variety of means, PMCH exists as a volatile liquid at room temperature and pressure, preventing it from being deployed in a similar manner. One method to release PMCH is to use a permeation plug passive release vessel (PPRV), which allows for the controlled release of the gas. This paper presents the results of a study evaluating various preparation techniques, plug thicknesses and plug materials of an aluminumvessel PMCH release source, so that a source appropriate for the mine scale may be developed.

Jan 1, 2015

By J. L. Cupp, R. C. Ford, B. R. Romig

The Climax Molybdenum Mine, located near Leadville, Colorado, is the site of a lengthy mining history spanning more than 80 years. In the 1960’s, extraction of molybdenum from oxide ore located adjacent to the massive molybdenite sulfide deposit resulted in the construction of an earthen core dam to impound fine-grained oxide tailing in the Eagle River Valley. Through recognized value of water storage and reclamation opportunities, a tailing removal project was initiated in 1993 to convert the impoundment facilities to a post-mining beneficial land use of developed water resources. An evaluation of the effect residual materials and lake dynamics would have on in-stream water quality was performed. Eagle Park Reservoir stands as a model for future reclamation efforts that involve water delivery to highly sensitive receiving waters. This paper provides a case study on project development, the evolution of water quality assessment, and the regulatory framework that contributed to this project’s success.

Jan 1, 1999

By S. A. Lolon, J. F. Brune

"INTRODUCTION In underground longwall coal mining, the mined-out areas or gobs frequently contain methane which can form explosive methane-air mixtures. Historically, there have been many events of mine fires and explosions recorded in the United States and other countries that have demonstrated the existence of such explosive mixtures, herein referred to as Explosive Gas Zones (EGZs), inside and around the perimeter of bleeder-ventilated longwall gobs (Loane et al., 1975; Lynn et al., 1986; Elkins, et al., 2001; McKinney et al., 2001; Dziurzynski and Wasilewski, 2012; Brune, 2013). The risk of mine explosions can increase if the EGZs migrate out from the gob into the surrounding mine entries. Several factors can induce EGZs outflowing from the gob, but the most common cause is the fluctuating barometric pressure. Atmospheric pressures change regularly every day but can fluctuate abruptly and become increasingly hazardous in adverse weather conditions. Other sudden pressure changes can result from roof falls, failing ventilation controls and fan outages. Any such fluctuation of mine ventilation pressure will disturb the pressure differential between the gob and the surrounding mine workings and may cause EGZs to outgas from the gob. The correlation between major mine explosions and abrupt barometric pressure changes has been studied and confirmed for explosions in coal mining countries including the United States, South Africa, Australia, and Poland (Hosler, 1948; Boyer, 1964; Kissell et al., 1973; Fauconnier, 1992; Hemp, 1994; Wasilewski, 2014; Belle, 2014; and Lolon, 2017). Disastrous mine explosions appear to happen more frequently during stormy weather, which, in the United States, typically occurs during the late fall and winter seasons. ROOT CAUSE AND EFFECT OF GOB BREATHING Gob breathing is the result of the pressure differential between gob internal and external pressures caused by external atmospheric pressure fluctuations that occur naturally as a result of gravitational and thermal forces in the atmosphere (Lindzen and Chapman, 1969). Other major and sudden pressure changes may be caused by fan failures, failures of ventilation controls or roof falls can also cause an unexpected gob breathing. Normal barometric fluctuations occur every day but usually do not pose an explosion risk as they occur gradually so gob pressures have sufficient time to equilibrate. More extreme fluctuations associated with cyclonic weather systems and storms often result in more rapid and larger drops or rises in barometric pressure (Hosler, 1948; Fauconnier, 1992). A study by Lolon (2017) found that the timing of historical mine explosions showed consistency with the occurrence of abrupt and intense barometric variations."

Jan 1, 2018

By L. Frederick

Measurement of gamma radiation occurring in nature to characterize geological formations has been widely recognized in mineral exploration. Different methods and apparatuses have been developed for drill hole logging purposes. Geological formations vary in amount of naturally emitted gamma radiation. A gamma signature from a geological formation is captured by utilizing different types of gamma detectors. A natural gamma radiation detector (NGRD) can be used to control mining whenever there is a significant difference between the radiation levels in the mineral or ore being mined and the waste materials surrounding the ore. Surface miners, such as the one shown in Figure 1, can precisely control the elevation of the cutter as the machine moves over the surface of the formation. This type of machine is predominantly used in selective mining operations, e.g. surface coal mining. If there is a means to know the position of the cutter relative to the interface between the ore and waste, the miner can recover all or most all of the valuable mineral with very little out-of-seam dilution. This paper discusses the results of a successful application of gamma detectors to control a surface miner at one of North American Coal Corporations? locations - Red Hills Mine. The mine has nine coal seams in total with thicknesses ranging from 12? to 60?. The bottom six seams (Figure 2) are minable. The mine has complex geology and a significant amount of annual rainfall (4.7 ft). The mine produces approximately 3.5 million tons of coal and about 40 bcy of overburden per year. The operation utilizes diverse mining equipment including Dragline Marion 8200, electric shovel P&H 2800, Caterpillar end dump trucks CAT 785 and 789; bulldozers CAT D11, D10, D8, and D6. Coal is mainly extracted by utilizing a Wirtgen SM 4200 surface miner that is loading CAT 785 trucks with high volume coal bodies and payload of 150 t. Operational cutting depth is 24 inches with maximum cutting depth of 36 inches. Surface miner operators determine a cutting depth based on multiple cues, the most important being visual observations of a coal seam being cleaned or mined. The cleaning process involves removal of the last foot of waste material covering the coal seam. This is one of two critical phases in the coal extraction process. If, during the cleaning process, an operator sets a cutting head too deep, valuable product is wasted. If it is set too shallow, waste material is left to be mined with the coal. The second critical phase occurs in the last cut on the interface between the coal and waste material at the bottom of the coal seam. If the cutting head goes deeper than favorable, then waste material is delivered to a power plant.

Feb 27, 2013

By Ali Behrad Vakylabad, Esmaeel Darezereshki, Babak Koohestani

As a by-product of the steelmaking industry rich in iron and zinc, electric arc furnace dust (EAFD) landfill disposal is restricted in many countries due to the metal lixiviation risks. Several approaches have been examined to recycle or reuse EAFD. Hydrometallurgical methods mainly include the preparation of pregnant acid leached solution (PLS) using inorganic acids followed by selective metal recovery using different methods. We herein proposed a hydrometallurgical process initiated by acid leaching and finalized by thermal treatment to produce nano-ZnO from EAFD. At the condition of this study, only 67% of zinc was leached by sulfuric acid from EAFD into PLS while 98% of surplus leached iron was removed through precipitation by sodium hydroxide. Additional purification of iron removed PLS was accomplished using di-2 ethylhexyl phosphoric acid to extract Zn+2. The addition of ammonium hydroxide to purified PLS provided (Zn(OH)2)3(ZnSO4)(H2O)5 as the final precursor for nano-ZnO that ultimately transformed to nano-ZnO (60 ± 6 nm particle size) at 850 °C. The achieved results were scrutinized through various tests and analyses including TEM, XRD, SEM, EDS, FTIR, and TGA.

Mar 10, 2021