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By J. Philip Bromberg

Any effectuation of a viable program of air pollution control will' require a basic understanding of the chemistry of atmospheric processes, the fate and migration of SO2, and the ultimate health effects of the sulfur oxides themselves. The migration and ultimate fate of Sop discharged into the atmosphere will be discussed with particular emphasis on the various conflicting views and how these relate to our present emission control regulations. Our present lack of knowledge is a severe detriment, and consideration will be given to those particular areas where future research may best be directed to provide the answers to a number of perplexing questions.

Jan 1, 1976

By R. S. Mateer

Linear programming on desktop computers is commonly used to optimize coal blending proportions. The objective function is usually the cost of the blend. The constraints consist of materials and heat balances as expressed as linear functions of the blend. This is illustrated in Example 1. Inclusion of a sulfur compliance constraint is more complex because the maximum permitted sulfur percentage is not a pre-specified constant. Rather, it is a function of the calorific power of the blend itself. The current limit of 1.2 pounds of sulfur dioxide per million Btu may be expressed as: Sulfur Max % = 0.6 • H/10,000 with H in Btu/lb.

Jan 1, 1994

By Scott D. Kinsala, Patrick T. Flynn, Andrew T. Rosol

During calcination of diatomaceous earth, cristobalite is formed in varying percentages. Also, during efforts to recycle products containing natural diatomaceous earth, various heat treatments are used which may or may not result in the formation of cristobalite. The ILO (International Labor Organization) Encyclopaedia of Occupational Health and Safety states that conversion begins at 450'C and in the presence of a flux, is complete at 800'C. Due to the potential adverse health effects associated with crystalline silica, a more thorough understanding of the time/ temperature relationship is needed. Tests performed under controlled conditions do not substantiate the claims made in the ILO Encyclopaedia.

Jan 1, 1991

By Charles D. Litton

This Bureau of Mines paper describes a novel fire detector that can be used to discriminate between smoke produced by a fire and smoke produced by a diesel engine. The detector uses a pyrolysis technique whereby a sample of smoke- laden gas passes through a short, heated tube within which fire smoke particles pyrolyze and increase their number concentration and decrease their average size, while diesel smoke particles are unaffected. The detector is designed for use in mines that use diesel-powered equipment where the detection of fires is complicated because of the diesel emissions background levels of smoke and other products of combustion.

Jan 1, 1989

By D. K. Gibson, A. I. M. Ritchie

The phenomenon of acid drainage is likely to occur whenever pyritic rock is broken up, permitting access of air and water. The basic chemistry of the oxidation process is described by the equations below:- FeS 2 +1120 + 7 02 ➔FeS04 +112S04 +1440k.J This reaction proceeds rather slowly, although believed to be bacterially catalysed to some extent. Once sufficient ferrous ions and acidity have been established the following two reactions take over, yielding the same net result but at a much greater rate. First, ferrous ions are oxidised to ferric; this is an extremely slow reaction unless bacterially catalysed.

Jan 1, 1991

By Daniel P. Farjeat, Hector A. Canseco, Juan M. Schmitter

Since the early sixties, tunneling in the soft clay of Mexico City, has been done with the aid of open face shields and recently with compressed air. The use of pressurized shafts up to 1.5 kilograms per square centimeter, (147 kilo pascals) with vertical locks to launch the shields, have been used in two cases. After advancing almost 200 meters of tunnel, the same vertical locks were transformed into horizontal locks, to continue the work. Due to the high decompression times involved, it was necessary to install long locks, using the tunnel itself as part of the system. This article describes those cases.

Jan 1, 1981

By Yuji Tsuneno, Yoshikazu Mikami, Yasuo Takeuchi

A new device was successfully developed in order to overcome the difficulty of drilling longer holes for anchors in soft soil bedrocks or swelling bedrocks, which is one of the major impediments to rapid excavation by NATM (New Austrian Tunnelling Method). With higher rotation (1200 - 1800 r.p.m.) and lower percussion energy (4 - 6 kg.m), the new drill has following advantages: (1) Applicability covers soils and medium hard rocks with the same drifter. (2) Longer hole (more than 9m) is achievable only with air flushing even in cohesive soils or rocks. (3) Better borehole stability is obtainable even in earth or in fissured rocks.

Jan 1, 1981

By Roy J. Leonard

Two small diameter sewer tunnel projects being hand dug under major highways in the Greater Kansas City area encountered problems which were unforeseen from the geotechnical engineering information supplied with the contract documents. Both tunnels were being excavated by experienced crews using steel liner plates. One required the use of compressed air for completion, while the other required poling boards. Both contractors overran their budgets and filed changed condition claims, and this promoted further geotechnical engineering investigations. Fissured clays beneath a water table were encountered at both sites, but the character of these clays differed; however, both were inadequately described in the original geotechnical engineering reports.

Jan 1, 1987

By Gabriel Babut, Ion Matei, Roland Moraru

Several controlled recirculation systems are in operation wor1dwide. As an unconventional technique of ventilation the implementation of such a system requires particular safety conditions and a well-founded set of feasibility factors and parameters. On the other hand, many mines in Romania are facing problemms in meeting the growing ventilation demands, so that controlled air recirculation could give an answer. The present paper presents the results of the work in this field, based on a detailed theoretical approach. Parameters wich must to be taken into account were identified and analysed, numerical simulation are carried out and an experimental test-scale model is presented.

Jan 1, 1997

By M. Ghiani, R. Peretti, A. Zucca

The paper deals with the experimental application of a pilot flotation column to baryte and fluorspar ores. The column has been installed in parallel with the cleaning stages of two different industrial flotation plants where the above ores are processed using conventional cells with mechanical impellers. The effect of several parameters, including froth height, wash water additions, pulp feedrate and air supply rate, has been investigated. It has been shown that by finely tuning the above parameters good flotation performances can be achieved. The experimental results demonstrate the greater versatility of the column flotation and its superior separation efficiency, especially for the fine particle size fractions, over conventional cells.

Jan 1, 1995

By C. A. Wiggins

The new Niagara Falls Intake Tunnel, mined in the highly fractured Lockport Dolomite, encountered prolific inflows of water contained in rock seams directly linked to the Niagara River. These inflows were pressurized and, more significantly, contained high concentrations of dissolved H2S gas. The contractors attempts to control the water/gas inflows included cement and chemical grouting from inside the tunnel. Ultimately, improving the rate of air exchange in the tunnel by increasing the fan capacity, in conjunction with a pattern down-hole pre-grouting program along the tunnel alignment allowed the contractor to control the concentration of H2S gas and complete the tunnel.

Jan 1, 1997

By R. Hogg

The various sub-processes which, together, make up the unit operation of froth flotation all depend on the characteristics of the feed solids, the solution phase, the air bubbles and the mechanical/hydrodynamic action of the machine. Characterization is obviously necessary for evaluation and process control, but the relationships between characteristics and process response are often unclear. A model-based characterization scheme is proposed in which material and system characteristics are evaluated in the context of simplified models for the individual subprocesses. The general basis for such an approach is discussed using the process of particle attachment and the influence of mineral liberation as examples.

Jan 1, 1989

By R. Llerena, P. Dunstan, R. L. Amelunxen

A single four feet diameter cell, treating a Cu/Mo rougher concentrate, has been fully instrumented and linked to a Distributed Control System. This has enabled the writers to further understand the mechanics of operation of the cell, particularly that of the "TRANSITION ZONE". This is the volume between the feed port and the pulp-froth inter- face. The results have shown a need for the re-designing the control loops whereby the Transition Zone volume (or pulp level ) becomes the single most important control parameter to achieve the de- sired recovery. Air consumption, previously thought to have played this role, is now kept at precoalescence level s for maximum efficiency.

Jan 1, 1988

By P. Mousset-Jones, F. Calizaya

Ultrasonic anemometry is a relatively new method of measuring the air velocity in underground excavations and is not widely used. The method has been mainly used for surface applications, such as meteorology and fluid flow measurement. Several instruments were looked at to determine their applicability for continuous underground monitoring systems. The units fall into two main categories: variable distance units and fined distance units. The method relies on the acceleration and deceleration of ultrasonic pulses transmitted through a moving airstream. This study presents some of the results of the testing of variable and fixed distance ultrasonic anemometers in a wind tunnel and a mine drift.

Jan 1, 1995

By Sharon G. Roness

Powder River Basin (PRB) mines were originally built to serve power plants designed specifically for their: coal. Sulfur was the major concern. Btu content and sodium limited the market for some plants. The PRB market has now extended to plants that are converting from other coals because of the Clean Air Act. These new customers are more sensitive to constituents that affect boiler and precipitator performance. At the same time, the prospect of deregulation is forcing power companies to improve cost controls. Kerr-McGee Coal's Jacobs Ranch Mine has responded to the changing marketplace with an expanded coal quality and customer service program.

Jan 1, 1998

By B. M. Ghadiali, J. B. Putnam, T. P. Smirnoff, M. A. Elioff, P. F. Ryan

Geotechnical investigations for the Mid-City Extension of the Los Angeles Metro revealed high concentrations of toxic hydrogen sulfide (H2S) gas as well as methane. Testing techniques employed to determine the extent of gasses, and to identify potential treatment measures, included gas sampling with cone penetrometers and soil-gas extraction with air injection testing. A gas reservoir model was developed to predict inflows into excavations. Other studies included a hazard evaluation and a general data search for other H2S occurrences and geologic conditions that could facilitate the accumulation of H2S. The paper describes the investigations and proposed design and construction alternatives.

Jan 1, 1995

By T. W. H. Parker, S. B. Sadleir

ABSTRACT A comprehensive program of air flush core and reverse circulation drilling, trial mining and beneficiation test work was carried out in 1980-1982 to re-assess the potential of the Mitchell Plateau bauxite deposit. The results generally confirm previous work by Amax Corporation. The bauxite is a medium available alumina and reactive silica deposit which responds well to wet screen beneficiation. High grade pockets have developed locally, with the potential for refractory grade extraction. A major feasibility study of the Mitchell Plateau bauxite deposit was completed in 1983. Due to the unexpected severity of the downturn in the alumina market, development of the project has been deferred.

Jan 1, 1984

By A. Bleier, E. D. Goddard, R. D. Kulkarni

The influence of the collector structure on the amine (RNH2, R=alkyl) flotation of quartz has been systematically investigated using a modified Hallimond microflotation cell. This study focuses on the effect of varying chain length, branching in the alkyl group R, polyfunctionality of the collector molecule, and alkyl substitution on the nitrogen atom. In addition, adsorption at the solution/air interface and electrokinetic results for the solid/solution interface were employed to further elucidate the role and the interrelation of the structural parameters in the flotation process. Estimates of an electrical double layer attractive energy between the bubble and the solid particle are made.

Jan 1, 1976

By G. Castillo, J. Mortensen

"INTRODUCTION Molybdenite is typically produced as a co-product in the copper ore flotation process. At the Rio Tinto Kennecott Concentrator (RTKC) in Copperton, Utah, the molybdenite is initially floated with copper sulfides and other value minerals producing a Cu-Mo concentrate. This is then separated in the molybdenum plant by depressing copper sulfides and pyrite and floating only molybdenite. The molybdenum plant in RTKC comprises the rougher circuit and several stages of cleaning to achieve a certain grade requirement of Mo. The rougher circuit is where the first stage of separation occurs. Cu sulfides and pyrite are depressed in the rougher circuit by adding NaSH under nitrogen and in the cleaner circuit by adding NaSH under air. The depression of Cu sulfides (and pyrite) by NaSH is related to the redox activity1. It is important therefore to maintain a reducing potential in the circuit in order to achieve effective Cu-Mo separation. If the rougher circuit is under air, like RTKC’s molybdenum cleaner circuits, it is harder to maintain the target redox potential because NaSH oxidizes rapidly in the presence of air thereby increasing NaSH consumption significantly. CU-MO SEPARATION AND ROLE OF PULP POTENTIAL The collector adsorption on copper sulfide minerals is through an electrochemical mechanism2. The collector changes the surface chemistry of the Cu mineral allowing it to float. Molybdenite, or MoS2, on the other hand, floats readily in the presence of a frother as it is naturally hydrophobic. Usually, hydrocarbon oil extenders such as diesel or burner oil are added to enhance Mo recovery. In order to effectively separate Cu from Mo, the collector complex on the copper surface needs to be destabilized or desorbed using a reducing agent such as NaSH or Nokes. As long as the circuit is under highly reducing conditions, the collector remains detached from the sulfide mineral surface allowing Cu sulfide depression. Therefore, it is important to measure the oxidation-reduction potential (ORP) continually and maintain the reducing condition with addition of NaSH. For a given collector each mineral will have a characteristic potential or electrochemical window for flotation to occur3, therefore, it is necessary to reduce the potential outside of this window in order to effectively separate Cu and Fe sulfides from MoS2 minerals2. In RTKC plant, the target reducing condition is between -450 to -550 mV to effectively destabilize the collector and depress Cu and Fe minerals. Typically the dosage of NaSH used in the molybdenum plant could range from 6 to 30 gallons/min (gpm). The high dosage of NaSH could pose risk of H2S exposure. RTKC wanted to evaluate alternatives to NaSH in order to reduce its consumption and minimize risk of H2S gas generation."

Jan 1, 2016

By C. Meyer, J. J. Eidel

Major gaps in understanding hydro- thermal systems remain after a century of studying fossil ore deposits and active geothermal areas. The periodically rejuvenated concept of "stacking" ore deposit types has never been verified by a continuous sample. Basal and marginal regions of both “fossil" and "active" hydrothermal systems normally lie beyond the limits of economic exploration, remaining inadequately exposed. Incomplete scientific under- standing of he vertical transitions clearly limits the efficacy of exploration programs for hydrothermal ores of all types. The Continental Scientific Drilling Committee's (CSDC) Panel on Mineral Resources has defined dedicated research objectives and add-on experiments to industry or government drill holes of opportunity.

Jan 1, 1988