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By Shouci Lu, Sun. Keji

Most phosphate ores in China are characterized by fine dissemination of the intergrown minerals and high content of carbonates. Therefore, in order to recover phosphorus minerals by flotation, some technological problems must be solved, such as fine particle flotation and separation of phosphate from carbonates. For effective flotation of finely ground phosphate ores and selective separation of phosphorus minerals from carbonates, S-series and L339 modifiers have been developed. A series of combined collectors with improved collector ability and selectivity have been developed and applied in several flotation plants in China. In this paper, CCLS, a combined collector for phosphates and PA-31 and a collector for reverse flotation of carbonates, are described. It has been found that some surfactants added with fatty acids function well in flotation at lower temperature, hence heating pulp in winter may be excluded. It is important for energy savings. The synergy mechanism of these additives in fatty acid flotation is discussed in this paper.

Jan 1, 1999

By Fathi Habashi

SELENIUM AND tellurium are by-products of electrolytic copper refining. Copper anodes contain 0.01-0.2 % Se and up to 0.04 % Te; during electrolysis these deposit as a slime at the bottom of the cell. Such slimes contain 2-15% Se and 0.5-8 % Te, as selenides and tellurides of gold, silver, and copper. The following compounds have been identified in the slimes: (Ag, Au)Te2, Ag2Se, Ag2Te, CuAgSe, Cu2Se, Cu2Te. Anodic slimes from copper electro¬lytic refining are a grayish black powder, minus 200 mesh. When this complex mixture is decomposed in an acid medium, elemental selenium and tellurium can be obtained, while in an alkaline medium, both metals go into solution. Acid leaching The slime is charged in acid digesters of 800-900 lb capacity, heated to 260°C with 78 % H2SO4, for 8-12 hr. During digestion the following reactions take place:

Jan 1, 1970

By Irwin R. Higgins, Richard S. Dennis

Acid recovery employs ion exchange resin as an adsorption media for the separation of inorganic acids from mixtures of acids and their metallic salts. This technology has been used to treat spent pickling and plating liquors to recover acid for reuse in the bath and to reduce waste acid neutralization costs. Acid recovery can also be used for electrolyte treatment to facilitate valuable metal recovery and to improve product quality. Conventional fixed bed ion exchange (I-X) systems are impractical for acid recovery because of complex control design and large resin inventories needed to process strong acid concentrations. TETRA'S CCIX™ continuous I-X contactor has been used successfully in a simple, continuous operating mode to separate acid from its salt. Efficient separation is enhanced by refluxing which allows acid to be produced as a salt-free product at nearly its original strength. Continuous treatment also recovers heat to the bath and improves metal quality due to consistent acid quality.

Jan 1, 1995

By W. K. Collins, C. L. Dahlin, D. C. Dahlin, W. K. O’Connor, G. E. Rush

Direct mineral carbonation was investigated as a process to convert gaseous CO2, into a geologically stable final form. The process utilizes a slurry of water, with bicarbonate and salt additions, mixed with a mineral reactant, such as olivine (Mg2SiO4) or serpentine [Mg3Si2O5(OH)4]. Carbon dioxide is dissolved into this slurry, resulting in dissolution of the mineral and precipitation of magnesium carbonate (MgCO3). Optimum results were achieved using heat-pretreated serpentine feed material and a high partial pressure of CO2 (Pc02). Specific conditions include 155°C, PC02 = 185 atm and 15% solids. Under these conditions, a 78% conversion of the silicate to the carbonate was achieved in 30 minutes. Process mineralogy was utilized to investigate the appropriate feed characteristics, identify the process products and interpret the mineral dissolution and carbonate precipitation reaction paths. Key words: Mineral carbonation, Carbon dioxide sequestration, Carbonates

Jan 1, 2003

Allis Mineral Systems' Grate- Kiln system can economically convert low-grade iron ore into high- grade iron-ore pellets suitable as feed material for blast furnaces for making steel. These pellets can also be fed to a direct reduction process for making sponge iron. The Grate- Car system combines the company's [ ] Grate-Kiln system for iron-ore pelletizing and Accar system for iron- ore reduction. The Grate-Car system consists of a traveling grate, a ported rotary kiln and a rotary cooler that are coupled in series. This system eliminates the pelletizing plant's rotary kiln and annular cooler. It reduces the need for some auxiliary equipment. This results in lower capital cost and lower energy consumption. The traveling grate provides that static bed handling necessary for heat hardening pellets before their discharge into the kiln. The ported kiln provides the reducing atmosphere with a more precise means of controlling the kiln axial temperature profile than conventional rotary kilns.

Jan 1, 1997

By G. M. Riddle

As an important part of the concept validation phase of the MX Advanced ICBM development program, Air Force System Command's Intercontinental Ballistic Missiles (ICBM) Program Office developed and demonstrated large trenching and cast-in-place equipment for placing many miles of buried concrete tunnel rapidly and economically. A tunnel or "buried trench" containing a mobile ICBM is one of the candidate basing models for MX. Upon remote command, the cannister housing the missile would break out of its concrete tunnel and earth overburden by erecting itself to a suitable angle and then launching the missile. The ICBM Program Office developed two each trenchers, cast-in-place machines, and breakout mechanisms, as well as a mobile concrete truck unloader. The machines were demonstrated in varying soil conditions in the southwest US. The breakout mechanisms were demonstrated nearby as well. This chapter describes the development program, the machines, and the demonstrations. No manuscript received

Jan 1, 1979

By D. W. Dew, D. M. Miller, P. C. van Aswegen

The bacterial oxidation (BIOX®) process for pre-treatment of refractory ores for gold recovery is marketed by BIOMIN Technologies S.A. The process was originally developed by GENMIN who are still providing testwork, design and commissioning assistance to BIOMIN. This process offers an alternative to the more conventional roasting or pressure oxidation techniques with the following advantages: • Greatly reduced capital costs for small to medium size plants. • A relatively flexible and easily controllable process requiring relatively unskilled labour for operation. • Improved gold recovery. • A process that is environmentally friendly. The principal disadvantage of bacterial oxidation is the relatively slow kinetics compared to pressure oxidation and roasting, a plant residence time of 4 to 5 days typically being required to obtain complete liberation of gold from refractory sulphide minerals. Bacterial activity is also slow to recover from disruptions such as air supply failure or contamination by toxic species such as cyanide. Optimum plant performance depends on judicious management and sound training of operators.

Jan 1, 1993

By Z. Kowalski

Landfilling of waste causes the degradation of natural environment, not only due to land occupation, but also due to pollution of air, water and soil. The flotation waste from zinc-lead industry also poses such problem. There is a need to find the way to utilise substantial amount of these wastes and backfilling seems to be a good solution. Recently, in Poland only sand was used for backfilling. However, it will be more beneficial to substitute the sand with the industrial solid waste, especially flotation waste. The tests were performed in the laboratory to examine the use of flotation waste as a main ingredient for backfilling. The use of flotation waste is possible only when it is combined with other waste with specific bonding properties, especially regarding the prevention of leakage. The outcome of tests shows that flotation waste combined with cement and fly ashes can be used as a backfilling material. This paper presents the preparation of flotation waste for using it for backfilling.

Jan 1, 2006

By K. Eric Livo

The Front Range Infrastructure Resources Project (FRIRP) of the U.S. Geological Survey (USGS) is currently using Landsat Thematic Mapper? and air- borne-visible-infrared-imaging-spectrometer (AVIRIS) data along with planned thermal-infrared data and interferometry-synthetic-aperture radar (IFSAR) data to assess the industrial-minerals quality and quantity along the Colorado-Wyoming Front Range Urban Corridor and to characterize surrounding areas. Landsat? satellite data show synoptic views of the corridor, which may readily be used to identify potential regions of permissible terrain, such as river drain-ages, pediment surfaces, upturned lithology, and bed- rock exposures, where various types of deposits may occur. Descriptive models of these deposit types are used to define the physical features that need to be recognized and characterized. In the case of Landsat? data, the measured light is either reflected or partly absorbed by surface materials, depending on the wave- length of the light, which allows coarse mineral classifications to be made.

Jan 1, 1999

By Richard A. Hunnisett

Silica sand is one of the world's most plentiful resources and is a basic necessity in our way of life. The end uses of silica sand are an integral part of our homes, transportation, and places of work. The environmental legislation enacted in the early 1970's, coupled with the oil embargo and higher than normal inflation, have had a very real impact on the industry and its primary consumers, the foundries and glass producers. The present environmental laws directed at air and water pollution and the working environment can, in most cases, be met, but not without large capital expenditures for equipment. These expenditures must reduce the funds available for expansion and modernization of existing processes which are necessary if the costs to produce industrial sand are to remain at acceptable levels. The concern for the future is the enactment of more stringent laws, and the available technology and equipment to economically comply with them.

Jan 1, 1978

By B. C. Cornilsen, X. Shan, D. H. Carlson, J. H. Johnson

Airborne respirable Diesel Particulate (DP) presents an additional health hazard in that it has been shown to be mutagenic. This problem is of increasing concern as more coal mines introduce diesel vehicles. If the DP present in coal mine air is to be controlled it must first be measured. This paper describes development of the laser Raman spectroscopic measurement of the amount of DP in DP/coal mixtures collected on filters in the laboratory and in coal mines. The Raman technique provides a chemical measure of the carbonaceous material in each component, and is not dependent upon particle size. When this work was begun there were no known analytical methods for this measurement. Side-by-side in-mine comparisons of the results obtained from Raman, neutron activation analysis, and size selective analyses (MOUDI and personal samplers) are presented. The neutron activation and size selective analyses were obtained by the USBM Twin Cities Research Center and University of Minnesota. Good agreement has been found among these three methods.

Jan 1, 1991

By Michael J. Martinson, John R. Larsen, J. Warren Andrews

Measurements reported in the paper were recorded in an active Green River, Wyoming, trona mine, partly as a teaching exercise and partly to provide the mine in question with additional input data for its ventilation network program. Measurements were made: - in representative three-entry intake airways in room and pillar sub-mains; - between the lower portion of a vertical down-cast hoisting shaft and the start of an intake airway system established in a room and pillar main; - in a representative downcast section of a divided vertical shaft, and of the collar entrance loss at the top of the same compartment. Pressure differences were measured with manometers and trailing hoses, air flowrates with calibrated anemometers, and barometric pressures and wet-and dry-bulb temperatures were recorded for density determinations. Where possible, results are quoted as Atkinson friction factors, and relevant measurements are recorded in some detail to show the magnitude of fluctuations in observed pressure differences.

Jan 1, 1987

By Xinming Lu

In this paper, we use a new kind of fan charateristic curve instead of the common quadratic function, and give the existence and the uniqueness of the solutions to the ventilation network controlling equations, so that the existence and the uniqueness of the solutions for the natural air distributting problem can be conveniently given. We also give a conjugate gradient method with the global convergence to solve the equations having the unique solution. Because we adopt a very efficient technique of one dimensional search (or linear search) in this method, the method can quickly solve a lot of problems, especially in large scale problems. The second part of this paper is the establishment of the model of the constrained quadratic programming for the measurement adjustment of mine ventilation network. We give the algorithm to solve this model as well. The two algorithms given above have been realized in the mic-computer MC-68000 with Fortran codes, and the numerical results are satisfactory.

Jan 1, 1991

By Richard Engelmann

The mining industry, in particular the coal industry, has experienced the implementation of some major environmental regulatory programs during the past two decades. Over the coming decade the coal industry will probably experience only "fine tuning" of the regulatory programs they now operate under. The rest of the indus- try, however, appears to be on the verge of coming under a major new regulatory effort by the Environmental Protection Agency. Litigation and resulting court decisions will be the main force driving further changes in the SHCRA (Surface Mine Control and Reclamation Act) regulatory program. These changes are anticipated to be minor in compar- ison to earlier changes. EPA, however, is preparing a regulatory program which may carry as much impact to the rest of the mining industry as SNRA was to coal. Details of this program have yet to be worked out. Changes in the way EPAts Clean Air Program is applied to mining could also significantly impact the mining industry.

Jan 1, 1989

By Steven A. Bradbury

INTRODUCTION Passive dust control systems are quickly gaining acceptance in the bulk solids handling industries. The number of applications is increasing due to proven performance, especially in US power plants burning Powder River Basin coal. Air Control Sciences ®, Inc., of Boulder, Colorado, has over forty (40) patented Dustless Transfer ® systems in operation. All of the installations control workspace dust levels to less than 2.0 mg/m3, and in some applications reduced conveyor dusting by over ninety-eight percent (98%). Passive systems control fugitive dust emissions by minimizing the induced airflow in bulk material transfer and slowing its velocity. Traditionally, fugitive dust control in the mining industry was accomplished using either dust collection systems or dust suppression systems. The term passive dust control, indicates these methods don't use any active dust collection or suppression. Passive dust control systems are best suited to transfer from one conveyor to another. They can also be applied to transfers from feeder to conveyors.

Jan 1, 2004

By Lijun Xu, Ragula Bhaskar

The transport of dust particles from a turbulent air stream on to the surface of a mine entry is mainly due to the effect of diffusion, sedimentation and inertial impaction. While the literature in aerosol science contains many references on particle deposition, most studies apply to smooth surfaces in small, short tubes. The deposition data from those experiments may not be applicable to deposition in mine airways that have large areas of rough surfaces and extend several thousand meters. This paper describes the mechanisms of mine dust transportation and deposition, specifically, by estimating the turbulent deposition velocity for coal dust in mine airways. Data from in-mine experiments on ambient dust concentration and dust deposition along a straight entry were used. A statistical model for dimensionless turbulent deposition velocity was developed, and compared with the models developed by other researchers. The model shows that the distance from the dust source is an important factor in the turbulent deposition of mine dust.

Jan 1, 1995

By B. J. Arnold

With the passing of the 1990 Clean Air Act Amendments, many utilities are opting to switch to lower sulfur coal to meet new SO2 emissions requirements. This lower sulfur coal may be from new suppliers or it may be from current suppliers that modify existing cleaning plants or build new plants to produce this higher quality coal. New, sophisticated coal cleaning simulators are useful tools for optimizing cod cleaning circuit operating parameters to maximize the production of clean coal that meets more stringent specifications for SO2 emissions potential. The examples in this paper were developed using the Coal Cleaning Simulator (CCS), running under ASPEN PLUS™, that was developed under a Department of Energy project cosponsored by the Electric Power Research Institute. With advanced sensitivity analysis and optimization features, CCS allows a quick, efficient, cost-effective review of coal cleaning plant performance to meet current production goals and to plan future changes in plant operating parameters or circuitry configurations.

Jan 1, 1995

By Gerald H. Luttrell, Joe Shoniker, Jaisen N. Kohmuench, Christopher J. Barbee, Michael J. Mankosa

The HydroFloat technology was specifically developed to upgrade phosphate sands that are too coarse (>0.6 mm) to be efficiently recovered by conventional flotation methods. In this novel process, classified feed is suspended in a fluidized bed that has been aerated using an external sparging system. The air bubbles selectively attach to particles that have been made hydrophobic through the addition of a fatty acid collector. The teetering effect of the fluidized bed forces the low-density bubble-particle aggregates into the overflow, while hydrophilic particles are rejected as a high solids content underflow Since the HydroFloat is actually a density separator, the process can treat much coarser feeds than would be possible using traditional flotation processes. In addition, the high solids content of the teeter bed promotes bubble-particle attachment and reduces the cell volume required to achieve a given capacity. This paper presents test data from ongoing pilot-scale trials of the HydroFloat cell in the phosphate industry.

Jan 1, 2002

By F. N. Kissell, C. D. Litton

This study ranks the factors impacting survival during a coal mine fire. It has already been established that reducing time delays is the most important factor in saving lives. Consequently, every event during afire is measured in terms of its duration, and the effectiveness of any action taken to improve survival is measured in terms of the time it saves. By ranking actions according to time saved, these authors found that a combination of actions was most effective. This combination was: •installing lifelines, •moderately decreasing air leakage and •decreasing the fire growth rate. Changing ventilation leakage alone was much less effective, as was altering the CO (carbon monoxide), sensor alarm threshold. These results confirm an earlier fault-tree study on escape from mine fires. The fault-tree study had shown that, with the exception of delays, single-factor changes have minimal impact. Significant reductions in fire fatalities only take place with multiple factor changes.

Jan 1, 1994

By Richard Jr. Ray, Richard Druesedow

The Virginia Operations of Consolidation Coal Co. include a diversity of mine fan configurations which have been tested to quantify pressure losses through the inlet ductwork. Airflow and pressure measurements were taken at four shaft sites to calculate losses for the 90-degree bend at the top of the shaft and the self-closing dampers or closing doors located between the shaft and fan. Velocity contours were then developed from the test data to determine flow patterns in each fan system component. In addition, yaw and pitch angles of airflow through the fan annulus were measured to evaluate turbulence levels created by various inlet ductwork designs. The test results indicate that proper design of the shaft collar and ductwork arrangement for main mine fans can substantially reduce system pressure losses and air turbulence. BY minimizing the pressure drop experienced on the surface, these design improvements enable the bulk of the total pressure developed by the fan(s) to be utilized in the mine.

Jan 1, 1995