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By K. S. Narayanan, Marcia L. Bartges, K. S. Venkataraman

The starting powders' physicochemical properties and consistency are essential for technical ceramic products to meet their performance specifications. The need for finer and more consistent powders has opened new technologies for synthesizing powders from atoms and molecules. However, submicron and near-micron powders obtained from conventional comminution and classification techniques are still competitive. This paper shows several examples from electronic ceramic applications of how we can use powder characteristics for micromanaging by design the ceramic properties such as the green and fired densities, slurry rheology, shrinkage during sintering, and the microstructure of the sintered bodies. The cross-disciplinary nature of the technology requires that the researcher not only should have a firm grip on the fundamentals of one or more disciplines, but also should be generally aware of the intricacies of other disciplines as well.

Jan 1, 1992

By Steven H. Brown

Ore bodies which were once uneconomical to mine by conventional methods such as tunneling or open pits, have become attractive due to the development of nonconventional techniques, involving considerably less capital expenditure. Technologies such as uranium solution mining or in-situ leaching, have enabled commercial scale mining and milling of relatively small ore pockets of lower grade, and may make a significant contribution to overall U.S. uranium supplies during the next 20 years. Commercial size solution mining production facilities have operated since late 1975. Solution mining involves the pumping of ground water, fortified with oxidizing and complexing agents into an ore body, leaching and solubilizing the uranium in-situ, and then pumping the solutions to the surface where they are fed to a processing plant. Processing involves ion exchange, precipitation, calcining, and packaging operations. This paper presents an overview of the solution mining process and the health physics monitoring programs developed over the last four years at several production facilities as a result of the radiological character of these processes. Although many radiological aspects of the process are similar to that of conventional mills, conventional-type tailings as such are not generated. Some special monitoring considerations are presented which are required due to the manner in which radon gas is evolved in the process and the unique aspects of controlling solution flow patterns underground. An overview of the major aspects of the health physics compliance and monitoring programs that have been developed are discussed.

Jan 1, 1981

By J. C. Watts

Ball mill grinding circuit control has received increasing emphasis in the past few years due to such factors as declining ore grades, increasing production costs, and advances in analytical devices and minicomputer technology. Since ball mill circuits have been a traditional bottleneck in mineral processing plant throughput, control systems often improve through- put without requiring additional processing equipment. In addition, much of the variability of the grinding product size and consistency is often removed, allowing better process operation downstream. Among the problems which arise in designing and implementing a process control strategy for ball mill circuits are circuit constraints imposed by processing equipment and local management, proper instrument selection, installation and maintenance, and use of calculated or inferred variables for process measurements. This paper discusses these problems and attempts to identify valid approaches to their solution.

Jan 1, 1979

By B. C. Paul, R. Q. Honaker, K. Ho

Recent research has shown that froth flotation is not effective at treating fine coals (-28 mesh) containing a large portion of middling particles. Due to their relatively large density differences, middling particles can be separated more efficiently using gravity-based processes. The ability of gravity separators to treat fine particles has been limited by the lack of particle inertia relative to the surface drag forces. However, particle inertia can be enhanced by the application of a centrifugal field. A commercial-scale centrifugal Falcon concentrator capable of treating a mass flow rate of greater than 1 tph continuously has been used to evaluate its feasibility for treating fine coal as an alternative to froth flotation. Tests conducted on a -28 mesh fine coal circuit feed have found the Falcon concentrator to be very effective at cleaning the 28 x 325 mesh size fraction. For an Illinois No. 5 coal sample, the ash content was reduced in the 100 x 325 mesh size fraction from about 18% to 8% while achieving a high combustible recovery value of nearly 97%. In addition, the total sulfur content was substantially decreased from 2.6% to 1.7%. The effects of the critical operating parameters on separation performance have been studied and their values optimized.

Jan 1, 1995

By B. R. Reddy, P. V. R. Bhaskara Sarma

A process for the separation and recovery of cobalt and nickel was optimized for a sulfate leach solution of Indian Ocean sea nodules containing 80 g/m3 cobalt and 730 g/m3 nickel using the sodium salt of Cyanex 272 as the extractant. Extraction of both cobalt and nickel increased with an increase in equilibrium pH and extractant concentration. The extracted species with respect to cobalt appears to be CoA2.3HA. More than 99.6% extraction of cobalt was achieved using 0.04M solvent in a three-stage counter current simulation at the A:O phase ratio of 3:2. The co-extraction of nickel was about 0.6% only. Two-stage countercurrent stripping of cobalt from the loaded organic at an A:O ratio of 1: 7 resulted in a pregnant electrolyte enriched by 0.8 kg/m3, thus enabling a ten times overall enrichment of cobalt. From the cobalt free raffinate, nickel extraction was carried out using 0.25M solvent in two countercurrent stages, and the extraction showed a 99.8% recovery. Stripping of nickel from the loaded solvent was carried out at an equal phase ratio with the advance electrolyte of pH 1.75 in two countercurrent stages. The nickel stripping efficiency was found to be 98.8%. The present studies indicated that complete recovery of cobalt and nickel was possible using nine counter-current stages.

Jan 1, 2002

By M. Alnot, J. A. Mielczarski, J. J. Ehrhardt, J. M. Cases

The flotation behavior of minerals depends on the balance between hydrophobic and hydrophilic species present at the surface of the minerals. The direct characterization of the interfacial products formed by the interaction of water and an aqueous solution of amyl xanthate with chalcopyrite, tetrahedrite and tennantite (the two former contain antimony and arsenic) were carried out by X-ray Photoelectron Spectroscopy (XPS) and infrared (IR) reflection spectroscopy. The experimental data collected from in-situ (IR ATR) and ex-situ (XPS, IR External Reflection) measurements have let us determine the types of the adsorption products and to propose mechanisms of interaction between the aqueous solution of surfactant and surface of the investigated minerals. It is shown that two major processes take place at the mineral interfaces: (i) the interaction with water and oxygen resulting in the formation of the oxidation products which are mainly hydrophilic (but also a hydrophobic product was found), and (ii) the adsorption of xanthate producing different types of hydrophobic surface products. The results obtained show differences in the composition of the outermost atomic layers of the investigated minerals which obviously will produce differences in the flotation behavior of these minerals. This work forms a good fundamental basis for a better separation between copper minerals containing arsenic and antimony, and chalcopyrite.

Jan 1, 1995

By R. W. Smith

Though generally rather non-selective in nature long chain collectors nevertheless function in different ways in accordance with their own particular physical characteristics. Altering various parts of their structures such as chain length, type of chain, etc. can therefore substantially alter the adsorptive behavior of the collectors in a set environment. The effect of such structural differences of the collectors on physical parameters such as solubility, critical micelle concentration, acid or base strength, tendency to be expelled from the aqueous phase is discussed, as is also the effect of these parameters on flotation behavior.

Jan 1, 1989

By Michael J. Martinson

A powerful methane explosion in the mid-shaft pump station of a main service and ventilation shaft killed several persons on the station; more workers were killed when a mancage travelling down the shaft fell to the shaft bottom under a pile of broken concrete slabs from a brattice wall destroyed by the explosion venting into the shaft and a tangled mass of twisted steelwork from the equipped compartment. The newly-commissioned shaft serves a recent extension of an established mine on the Orange Free State (OFS) goldfield in South Africa. After outlining the circumstances in which the paper was written, and reviewing the nature and extent of the methane hazard in OFS mines, the paper describes the physical layout of the shaft and summarises evidence given by witnesses at the official inquiry concerning events prior to the explosion. No attempt is made to apportion blame for the incident.

Jan 1, 1989

Iron ores may be upgraded by flotation of iron oxides or siliceous gangue using either cationic or anionic collectors. The electrostatic mechanism of adsorption can account for the complex chemistry involved. In industrial practice, only cationic silica flotation is used at present in North America. Some of the seemingly paradoxical phenomena of cationic silica flotation behaviors in meeting the demand for low silica concentrates are reviewed.

Jan 1, 1989

By R. S. Ondrey, R. A. Haney, T Tomb, R. T. Stoltz, Novakowski D. L. Chiz, E. J. Gerbec, D. J. Atchinson

Although the number of operating longwalls in the United States (approximately 100) has remained relatively constant over the last five years, longwall production levels have significantly increased and in some cases more than doubled. As a result of this production increase, control of respirable dust continues to be a problem. Therefore, the Mine Safety and Health Administration (MSHA), Pittsburgh Health Technology Center, Dust Division, initiated a study to investigate the availability and adequacy of technology for controlling dust on longwall mining operations. The study involved 23 longwall mining operations in three different Coal Mine Safety and Health Districts. Each operation was visited for a full shift. Respirable dust samples were collected on face personnel and at fixed locations along the face. Methods being used to control dust were noted, with special emphasis placed on obtaining quantitative data relative to ventilation, headgate dust controls, cutting drum sprays, external machine sprays and cutting sequence. Attempts were made to correlate dust control practices in place at the time of the visit to dust concentrations measured at the tail and on the tail shearer operator and to the average of all the dust concentration measurements from the occupations sampled. The methods used to control dust were also compared to the gamut of methods known to be available. This paper presents a discussion on the effectiveness of the methods being used to control dust and on the availability of technology for the control of dust on longwall mining operations.

Jan 1, 1991

By A. E. Hall, D. M. Mchaina

This paper outlines a proposed research project to investigate secondary sulphide ignitions. Sulphide dust explosions have resulted in loss of production and considerable capital and equipment replacement cost in Canadian mines. The practical application of laboratory test results to actual mine situations presents a complex problem and is a field requiring immediate investigation. The factors contributing to the outbreak of sulphide ignitions are not clearly understood. This indicates a need for future research to study the influence of blasting parameters, exhaust temperatures, and dust characteristics on secondary ignitions at source. The aim is to establish realistic quantities for each of the parameters and develop a model that will incorporate field and laboratory quantities. It may be possible to predict outcomes of sulphide ignitions when the parameters are known. It is also planned to study the techno-economic feasibility of the preventive and control methods. One aspect of planned future research requires quantification of some terms by obtaining measurements of pollutant concentrations and size distribution of the airborne dust in an underground environment immediately after a main blast. A blast-proof aerosol sampling package to measure the source term will be designed. This sampling package will consist of a sampling section and a shield which will be capable of withstanding a blast explosion. The accuracy in measuring the variables and combination of variables will be the main focus in this proposed study.

Jan 1, 1987

In 1988, at the request of members of the Society for Mining, Metallurgy, and Exploration (SME) Inc., the president of SME formed Working Party No. 79, Ore Reserve Definition. Its mission was to develop guidelines for the public reporting of exploration information, resources and reserves. These guidelines were published in the April 1991 issue of Mining Engineering,(pp. 379-384), and as a document entitled "A Guide for Reporting Exploration Information, continued on an ad-hoc basis until 1996. Working Party No. 79 was then renamed the SME Committee on Re¬sources and Reserves and became a standing committee. Since 1994, the Council of Mining and Metallurgical

Jan 1, 1999

By G. D. Schena

A decision support system for the management of the mineral resources of a developing country has been derived. The system allows the evaluation of the impact of a mineral project in a developing country in the broad context of its economy. The analysis permits the assessment of the overall socio-economic consequences of mineral prospects and allows incorporation in the evaluation of issues that are broader in scope than the pure financial objectives. The system is built around the Leontief framework of economic analysis. The original input-output model, enhanced to incorporate country-specific behaviour is integrated with cost-benefit analysis and shadow pricing. The analysis leads to synthetic measures of profitability at market and shadow prices. These measures are useful to direct the mineral policy of a developing country through the exploitation of those mineral resources which are most likely to bring about economic growth and social advancement.

Jan 1, 1992

By E. J. Peuraniemi, J. T. Yli-Penttilä, A. Jokilaakso, K. M. Riihilahti

Dust formation and the reaction mechanisms of copper matte particles were investigated in simulated flash-oxidation conditions. The granulated and ground matte consisted of 72% Cu, 4% Fe and 21 % S (by weight). Experiments were conducted by using a laminar flow furnace with a reaction-gas composition ranging from 20% to 75% O2 (by volume) in nitrogen. The particle feeding was carried out by a single-particle method, and samples were quenched after a specified reaction time ([~] 0.05 to 0.4 s) in a cold water film. Experimental temperatures ranged from 800o to 1,300o C. Chemical analysis was used to determine the degree of oxidation, and optical and scanning electron microscopes, combined with energy dispersive analysis, were used for characterization of the reacted particles.

Jan 1, 1999

By S. P. Mehrotra, P. C. Kapur

A phase-species classification is suggested for the mathematical models of flotation kinetics. Important models are discussed and the structure of their rate constants and parameters is analyzed. Split or enhancement factors are formulated for different kinetic models. The steady state dynamics of the flotation circuits can always be described in terms of these factors. For simulation of circuits, feed is characterized in a formal manner starting from a multivariate distribution of particles in flotation rate, size and mineral content. Synthesis of optimum circuits which simultaneously searches for the best process variables and structural parameters from a generalized master network is described. Trends in the areas of search algorithms, role of middlings and feed identification etc. are indicated.

Jan 1, 1989

By L. L. Newman, K. D. Ferguson

Traditional methods for mine waste management produces two waste streams and the construction of separate disposal facilities. Tailings impoundment design is usually controlled by physical stability problems. Alternatively. the waste rock offers high stability characteristics but hydraulic properties that create ideal conditions for oxidation. The problem of oxidation is significantly reduced for tailings due to a fine texture that augments water saturation. This paper introduces concepts for the co-disposal of tailings with waste rock and evaluates the physical behaviour of an integrated waste system. 'he potential benefits of co-disposal are shown for a typical mine such as Equity Silver.

Jan 1, 2000

By R. L. Wiegel

Several mineral process modeling and simulation packages are currently available for use in evaluating the performance of alternative process flow schemes. A critical link that has been missing from these packages is the ability to quantitatively model the effect of size reduction on the liberation of the valuable and waste minerals in the ore being processed. Although there have been several approaches taken to this problem over the past 25 years, none of them has led to a satisfactory conclusion. A technique was developed for measuring the effective liberation characteristics of magnetic taconite ores, and a program was constructed that makes use of these liberation characteristics in simultaneously simulating both size reduction and mineral liberation as it occurs in tumbling mills. This is an especially important step in the modeling of magnetic taconite processes, where magnetic rejection of low-grade wastes between grinding stages mandates that a predictive capability be available. The current application is specific to magnetic taconite, but it is possible that a similar approach could be used for other types of mineral systems. Key words: Modeling and simulation, Size reduction, Mineral liberation, Taconite, Magnetic concentrator

Jan 1, 2003

By V. T. McLemore

The Steeple Rock district in New Mexico is a major epithermal gold-silver district that exhibits district zoning. Five types of ore deposits occur within the district: •base-metal veins (with gold and silver) form the center of the district and occur along the Carlisle fault, •gold-silver veins along northwest-trending faults and outward from the base-metal veins, •copper-silver veins along the margins of the district, •fluorite veins along the margins of the district, and •manganese veins along the margins of the district. Areas of older acid-sulfate alteration occur throughout the district and also exhibit the following zoning: massive silica/chert zone (inner), silicified zone and clay zone (outer). This alteration overlies regional alkali-chloride (propylitic to argillic to sericitic) alteration. Synthesis of available data suggests the acid-sulfate alteration is related to a shallow, but older, epithermal hot-springs system. Subsequently, younger epithermal veins formed along faults.

Jan 1, 1996

By E. R. Bollinger, N. S. Tanious, R. D. Beckett

The US Bureau of Mines developed hand-made, steel-fiber-reinforced concrete (SFC) blocks for building mine cribs. To ensure wider usage of these cribs, US Steel Mining Co. initiated a joint development and evaluation program with Burrell Construction Co. to mass produce SFC blocks of reasonable dimension, weight, and cost. Small specimens and full-size cribs were evaluated to determine their compressive strength and post failure characteristics. After testing and adjusting of various concrete mixtures, a final formulation was selected that gave a nominal crib strength of 22 MPa (3200 psi) and a nominal modulus of elasticity of 6.9 GPa (1.0 x 106 psi.) These SFC cribs can support 6.4 times as much as a wood crib with the same load-bearing area. The SFC crib was proven to be an economical and effective roof support system through various underground installations.

Jan 1, 1987

By J. A. Brierley, C. L. Brierley, K. A. Prisbrey, R. W. Bartlett, J. G. Harrington

Bacterial oxidation of gold-encapsulating sulfide minerals in low-grade refractory ores was investigated over a period of one year. Crushed ore samples were held in wet, bacteria-inoculated, aerated columns. Sulfide mineral oxidation data were correlated with subsequent gold cyanide extractabilities. Experimental results for both sulfide conversion and gold extraction were compared with a biooxidation kinetics model that incorporates rock size, mineral grain size, and heterogeneous pyrite reaction kinetics. Using the model, extrapolations were made over three years for biooxidation of ore in large stockpiles. Ferric ion (oxidant) diffusion in the solution-filled pores of the rock matrix does not control the biooxidation kinetics of ore crushed to -25 mm.

Jan 1, 1993