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By K. N. Han, H. C. Cho, R. Kim

"As an extension of the work on the effect of OH- on various cations in hydrometallurgical systems, the effect of Cl-, Br-, I- and CN- on cations such as Ag+, Cd2+, Hg2+, Cu+, Cu2+, Co2+, Zn2+, Pb2+ and Sn2+ has been examined in detail. The Newton-Raphson technique has been used to determine the amounts of various metal species as a function of the concentration of anions. Some practical implications of various metal complexes in metal separation and removal from solutions have been examined and discussed.IntroductionUnderstanding the role of anions in hydrometallurgical processes often determines the success of an operation. The successful choice of concentration and type of anions not only leads to an effective extraction and removal of metals (Esmaeili et al., 2005; Brbooti et al., 2011; Wei et al., 2005; Jeppesen et al., 2009; Al-Tarazi et al., 2004), but also to assisting effective separation of various metals, whether it is a solvent extraction, ion exchange operation or even a simple precipitation (Farha et al., 2011; Sevenich and Fritz, 1983; Rashid, 1974).This paper continues the discussion of the role of anions in hydrometallurgical systems beyond the role of OH-, which was the topic of a previous paper (Kim et al., 2014). Table 1 lists various anions that are frequently used in conjunction with metal ions to be selectively separated or precipitated. As seen in the table, many anions are used frequently in hydrometallurgical practices. Some of the more frequently used anions include OH-, SO4 2- and CO3 2-. The halogen elements, Cl-, Br- and I- , as well as CN-, are also used in hydrometallurgical applications, especially in relation to noble metal recoveries (Meng and Han, 1994; Zhang et al., 1996; Sun et al., 1996; Starovoytov et al., 2007)."

Jan 1, 2015

By Paul A. Rittenhouse

First of all, I want to thank John Dunlap for asking me to this AIME meeting in Denver. I was first introduced to Denver and The Rocky Mountains more than ten years ago and immediately decided it was one of the most attractive spots in the world. I've come back many times since and still welcome any opportunity to return, even if it means I have to prepare and give a paper on potash. When John Dunlap gave me this assignment, he told me that the program would include papers on the geology of potash, papers on new discovered potash deposits and new mines and asked me to discuss potash from the commercial point of view. He also asked me to include a supply/demand outlook for potash. However, one thing he did not mention was "how far into the future he wanted me to look" and it seems to me the time element is a crucial factor to you who are both geologists and miners as well as to me. In your case, you have to look far enough into the future to give you time to explore, find, evaluate, develop, and bring into production a commercial deposit. My mining associates and friends don't agree on how long that takes but it's probably somewhere in the range of eight to fifteen years. But, they all agree on one thing and that is that the time required is continually getting longer. Now my time problem is just the opposite. It is "relatively" easy, and I stress relatively, to identify and evaluate the importance of the various factors that impact on both the supply of and demand for a commodity such as potash if the time period is today. It gets a little tough if one has to project into tomorrow or next week or next month. And when we start talking in terms of a year, five years or ten or fifteen years, things really get sticky and the old crystal ball becomes mighty cloudy. But we economists and forecasters are not known for our temerity so let me get on with the job at hand and take a look at the world potash supply/demand outlook.

Jan 1, 1978

By Terry O. Arney

Ore Reserve Models are well established evaluation and mine planning tools. BY definition, these models are made up of regularly sized blocks, arranged in a three dimensional matrix. Two dimensions correspond to north and east directions, and the third, to the depth or elevation. The dimensions of the blocks need not be equal, but generally at least two of the dimensions are equal. The blocks are located in space by coordinates which are generally translated into index values for computer applications. Each block will have quantitative attributes, such as grades, densities, rock characteristics, etc. assigned to it. The process of assigning values to each block in the three dimensional matrix is the process of ore reserve model development. One of several interpolation procedures may be employed to predict the value of a block, based on surrounding data. Block value models have several uses. The utilization of block models in ore reserve computations is quite common. Here, ore reserves may be calculated by level or by cross-section for the entire deposit. For each ore reserve calculation, multiple cut-off grades may be analyzed to determine the ore reserves under different cut-off conditions. The other major use of block value models is in mine simulation. Through simulation, profitable studies that analyze the effect of alternate ore removal sequences can be undertaken to determine economic optimality. Other studies that are undertaken in mine simulation problems include the evaluation of mine layout, pit slope effects, and the impact of varying cut-off grades.

Jan 1, 1974

By L. Alagha, M. Khodakarami

"This work focuses on the extraction of rare earth metals (REE) from aqueous solutions using stimuli-responsive polymers. Various parameters affecting the adsorption capacity of the polymer, including pH, polymer concentration and REE concentration were studied. The interfacial behavior of REE in aqueous phase before and after polymer addition and the mechanism of the formation of metal-polymer complexes and their properties were investigated using UV/VIS spectroscopy. Results obtained would help to test the feasibility of employing stimuli responsive polymers in pre-concentration of rare earth elements associated with other elements in mineral aqueous streams prior to solvent extraction. The pre-concentration step would reduce the amount of organic solvents used for extraction and striping compared to conventional extraction processes. INTRODUCTION Rare earth elements (REEs) have become the foundation for several technologies and have been used extensively in many industries such as modern electronics, green energy, health care and transportation and defense [1-4]. As these industry sectors are growing, the global consumption of REEs is going to increase dramatically. The current global REEs demand is estimated to be 105,000 tons of rare earth oxides per annum with an expected annual growth of 5.6% [5-6]. Rare earth elements are produced from different sources (primary and secondary). China is considered as the largest producer of REE in the world, providing about 90% of the world’s mine production while the United States is second with 4% of the mine production [7]. High global demand for rare earth materials results in shortage of such materials in the near future. It should be considered that the term ‘‘rare’’ earth is not an accurate term, since they are abundant in some extent in the Earth’s crust, but are typically finely dispersed. Thus, nowadays looking for more efficient and cheaper methods for extraction, separation and purification of low concentrated REE ores and exploring secondary sources are essential. Rare earth materials are found in raw condition and require treatment that involves several processes, which can consume money and time. Recent improvements in extraction and recycling technology have made the extraction of rare earth elements from rare earth sources more feasible in terms of cost and time [8-10]. Physical and pyrometallurgical methods require high-energy and thus high costs. Moreover, due to environmental problems, environmental protection systems are required, and they are not as adaptable as chemical processes [11, 12]."

Jan 1, 2016

By David F. Becker

Two-dimensional, finite-difference elastic modeling aids in planning an optimum seismic-acquisition scheme to define the extent of subsurface cavities resulting from in situ gasification. To understand the seismic effects of a cavity, two models are compared and contrasted. Model A consists of a low-velocity layer (LVL) in a half space; Model B contains a rectangular water-filled cavity in the LVL. Amplitude differences are the dominant effect on the surface records for each model. Cavity resonance and diffraction effects are more definitive in vertical seismic profiles (VSP's) and in a "snapshot" of the wave field. Interpretation and subtraction of corresponding records for both models shows the need for pre- and post-gasification seismic recording. Also VSP data are more informative than surface records.

Jan 1, 1983

By F. Arslan

Gold extraction from refractory ores is still a problem. Gold losses in the cyanidation process are mainly due to the presence of sulfides and carbonaceous materials. Oxidation of carbon and sulfide minerals by sodium hypochlorite is a possible method to render the ore amenable to cyanidation, and earlier work by the USBM indicates that electrochemical generation of hypochlorite is promising. Laboratory work was carried out on the oxidation of pyrite and carbon in an electrochemical cell with a sodium chloride electrolyte. The results of preliminary tests are discussed in relation to the mechanism of electrooxidation of refractory gold ores and the estimation of current efficiency.

Jan 1, 1991

By Edward J. Harvey

Joplin, one of the most famous zinc mining camps of a bygone era, is today experiencing a healthy growth in manufacturing enterprises. Manufacturing requires water, and knowledge of its availability and quality often is the main factor in location of industry. For this reason in January 1964, on the suggestion of the former State Geologist, Dr. Thomas R. Beveridge, a study of the water resources of the Joplin District was undertaken as a cooperative effort of the Missouri Geological Survey and Water Resources now under the direction of Dr. William C. Hayes and the U. S. Geological Survey. The project area is in southwestern Missouri on the Springfield Plateau and is bordered on the west and north by the Osage Plains of Kansas and Western Missouri, (fig. l). Upland altitudes rise from 900 feet above sea level in the west to 1400 feet in the east. The countryside is rolling to moderately hilly and much is excellent farmland.

Jan 1, 1965

By F. W. Petersen

Slurry reactors are being used extensively throughout the chemical, biochemical and mineral processing industries. This paper describes the interaction between fine ore particles and granular porous adsorbents such as activated carbon and ion-exchange resins in a stirred tank reactor. Gold and silver cyanides were used as adsorbates to detect changes in the mass transfer characteristics of the adsorbents, which were ashed to determine the loading of ore particles. A simple kinetic model incorporating film diffusion, intrapanicle diffusion ~d the adsorption equilibrium, was used to interpret kinetic data and to estimate the effect of slurry conditions on the diffusion parameters. It was observed that the equilibrium loading of fines in the adsorbents was independent of their concentration in the slurry. Furthermore, the presence of these panicles inside an adsorbent decreases the effective diffusion of gold or silver cyanides into the adsorbent matrix. When fine suspended solids are present in the reactor, a decrease in the effective availability of the superficial surface of the pre-saturated adsorbent panicles for mass transfer from the liquid phase was observed. This newly defined surface availability factor was dependent on the concentration, panicle size, and the zeta potential of the fine particles in suspension.

Jan 1, 1993

By Alphonse C. Van Besien

It is doubtful if anyone knows precisely how many U.S. coal miners have been killed by roof falls. In 1931, 51 miners were killed by falls or rock in every 10-day period (Paul, 1). Roley (2) indicated that from 1882 to 1945, over 3,700 men were killed by roof falls in Illinois alone. During this 63-year period, roof falls accounted for 47.6 percent of the coal mine accident fatalities. Similarly, Price and Nolting (3) reported that during the 10-year period beginning in 1937, roof falls claimed over 50 percent of the lives lost in West Virginia coal mines. Over 150 miners died under fallen rock in West Virginia alone, in each of those years. Certainly, the statistics have improved over the years. The Theodore Barry Report of 1971 (4) indicated that during, the previous 4 years, fewer than 100 miners per year lost their lives to roof falls--in the entire United States. The improvement is less remarkable when it is realized that the accident rate has declined only as the number of miners employed underground has declined. The TRW Report (4) pointed out that although the number of fatalities in underground coal mining (from all causes) had been cut in half from 1956 to 1965, the fatality rate per thousand miners had remained virtually constant. The decreased accident rate was due not to a reduction in hazards but to a reduction in work force. Roof falls still claim approximately 50 percent of the lives lost in underground coal mines. Considering the increased underground production of coal which must result from our energy crisis, the environmentalists' pressure against strip mining, and our inevitably diminishing supply of strippable coal, it is apparent that some means must be found to reduce the number of lives claimed by coal mine roof falls.

Jan 1, 1973

By R. G. Swanton

The Bureau of Mines is investigating the leaching of phosphate values from Florida phosphatic clay wastes using sulfuric acid (H2SO4) as the leaching agent and methanol as the solvent. Acid-alcohol leaching studies were done using pure crystalline apatite to investigate potential causes for low extractions. It was found that a barrier layer formed on the surface of the apatite. Initial discovery of the barrier layer was made by analyzing pure apatite samples before and after leaching using an optical microscope. Subsequent Fourier Transform Infrared (FT-IR) analyses proved the coating was calcium sulfate hemihydrate (CaSO4-1/2H2O) and that unreacted apatite existed beneath the coating. Scanning electron microscope (SEM) photographs depict the CaSO4-1/2H2O morphology as long slender crystals adhering to the apatite surface. It was also shown that grinding the leached tailings and leaching again in the H2SO4-methanol system resulted in additional phosphate extraction.

Jan 1, 1991

By L. G. Austin

A program has been written to combine the Klimpel-Austin approximate model for liberation in a binary system with a mill model applicable to ball milling. The model applies for a system where the volume fraction of valuable B in host matrix A is small. The mill model is treated as an equivalent series of fully-mixed reactors. Twenty-three classes of material are considered: pure A; pure B; unchanged AB; 0-10.2 B in AB either as surfac- exposed B or as wholly-contained grains of B; 10-20% B in AB, surface-exposed or wholly- contained;etc.. to 90-100% /b ub /ABm syrface-exposed or wholly-contained. Illustrative cases are given making reasonable assumptions concerning relative rates of breakage and primary breakage distribution functions for each class of material.

Jan 1, 1986

By Jacques B. Wertz

However excellent the geologic map of an area is, it can only show what is exposed on the ground. It cannot and should not generalize the information nor complete the picture by inference: this is left to the examiner. Consequently, it becomes justified for him to use all expressions of geologic structure in order to gain an additional dimension in geologic interpretation, and particularly so in mineral exploration. In previous studies related to Arizona, the known faults were the starting points and a host of interpolated, supporting geologic factors described in earlier publications ascertained the presence of a series of structural trends and lineaments found to be rather continuous and persistent, even though unsubstantiated by geologic maps. In present studies pertaining to the humid environment, with the same aim of seeking major structural trends and lineaments, the starting points are morphologic expressions such as straight lakes and straight segments of rivers, among others, because there generally is not enough geology available. An example is given herewith for an area that straddles the International Border, north of Spokane. In both semi-arid and humid environments, one observes that mineral deposits quite often occur close to the intersection of a major fracture or lineament with some secondary trend.

Jan 1, 1971

By B. K. Mishra

Power draw of the mill has been accepted as an indicator of the performance of the mill, yet the problem of predicting power under a given set of mill operating conditions still remains to be solved. In the literature, this problem of predicting power is attributed to a lack of knowledge with regard to the motion of the charge. Here a DEM based model is used to analyze the motion of the charge. The resulting information is used to predict the power draw of the mill. A 16-ft diameter mill is simulated. A factorial design study of the variables-mill speed, lifter configuration and ball size distribution-as independent variables is taken up. The power draw as a response variable is analyzed to establish the best operating condition of the mill.

Jan 1, 1993

By G. A. Doyle

The White Pine Mine is the second-largest active underground copper mine in the United States, covering an area of approximately 13 square miles in the Upper Peninsula of Michigan. The mine operator intends to initiate in-stope solution mining by circulating a solution of mine water, sulfuric acid, and ferric iron through rubblized ore and recovering copper from solution. As planned, the solution would be retired in the mined-out stopes following completion of solution mining activities. Investigations into the fate of the retired solution mining fluid indicate that the solution, through time, will change from an acidic, metal-rich solution to a near-neutral, reducing solution containing much lower concentrations of metals. Investigations include reaction path modeling (EQ3/6) and laboratory and in-mine experiments. The combination of neutralization and reduction will result in precipitation of most metals, primarily as metallic sulfates, chlorides, and sulfides.

Jan 1, 1996

By Alan R. Grant

Interpretation of presently available geological information indicates that most of the periods of significant metal deposition in the Washington Cascades Range are, at least in part, genetically related to late Cretaceous -Tertiary intrusive episodes. Chemically, the most favorable environment for base metal deposition is high in potassium. Characterizing the advanced stages of these chemical alteration conditions are the silicate mineral assemblages orthoclase and/or secondary biotite. Wall rock alteration includes both deuteric and hydrothermal processes, the intensity of which primarily depends upon the degree of fracturing in the country rock prior to the introduction of secondary material. Broadly speaking, the primary physical controls for the distribution and concentration of sulfides appear to be a series of structural couples involving both northwest (paralleling regional trends) and northeast--striking systems. Meaningful base metal exploration in the Washington Cascades demands a basic understanding of the various geologic factors related to the distribution of the sulfide deposits. Any geologist contemplating Cascade work should be well grounded in the fundamental concepts of petrology and structure.as these constitute two of his most beneficial aids. The acquisition of the detailed data necessary for this understanding may seem a bit academic, yet it has been demonstrated in numerous instances that a fair economic appraisal of a particular property or mining district depends primarily upon the ability of the geologist to recognize the subtle environmental differences which could lead to the discovery of a major ore deposit.

Jan 1, 1971

By E. R. Drevdahl

It has been suggested that we at the University of Arizona present a paper covering the origin, philosophy, and results of the College of Mines program in the field of computers and operations research. I have worked with the program since its beginning, and I will try to outline the developments as they have taken place. The formal development of the educational and research program in the field of Operations Research and Computer Applications at the College of Mines, University of Arizona, began in early 1957. During the year, the University offered its first formal instruction in computer programming. This was my first introduction to computers, and it did not take long to realize that this new tool had a potential that could be profitably utilized by the mining industry. In March 6f 1957, the University Computing Center began operations with its IBM 650 computer. This machine was the only computer of this size in the local area at this time, The first programming effort was in machine language and the programming cost could only be justified for repetitive-type of problems. The progress in the computer field moved very rapidly and with the development of the many compiler and assembly programs and the addition of sub routines to the computer library, the scope of problems that could profitably be investigated by computers expanded rapidly.

Jan 1, 1963

By A. G. Oppegaard

Most iron ores treated by the R-N direct reduction process yield metallic iron products considerably lower in titanium, manganese, and chromium oxides and alkaline metal sulfates/sulfides than were contained in the original ores. These metallic iron products are suitable as feed stock for the open hearth and electric steel-making furnaces. The elements which are rejected in part are acceptable in the product since the product is designed to by-pass the blast furnace. R-N reduction conditions (PCO+H2-1 atmosphere, 1830° to 2150° F.) are adjusted for each ore. The iron ore which is reduced to 90 to 95 percent metallic iron is then subjected to the conventional beneficiation techniques. Under these conditions, 55 to 80 percent of titanium oxides, 75 to 95 percent of manganese oxides, 60 to 90 percent of chromium oxides and up to 97 percent of alkaline metal sulfates contained in the ore are rejected with the gangue to the non- magnetic tailings. The metallic iron products illustrated in this work contained 89 to 96 percent total iron, one to five percent TiO2, 0.2 to one percent MnO, 0.3 to 1.6 percent Cr2O3 and/or up to one percent alkaline metal sulfide. Usually only one of these components was present. Recoveries ranged from 80 to 96 percent of the iron in ore.

Jan 1, 1958

By R. Merkl

Since the 1940s, decanter centrifuges have become more important for increasingly complex solid-liquid or solid-liquid-liquid separation processes. Sometimes processed industrial or metalliferous minerals are abrasive or are treated with corrosive chemical agents. Traditional mining applications include the processing of coal, gravel and other products, where low-speed decanters, as well as screen bowl decanters and filters, dominate. These have been increasingly replaced by high-speed decanters during the last decade. Decanter centrifuges also started to play a key role in applications such as drilling muds, processing carbonates and separating SX crud in copper platinum ore concentrations of nickel and gold. Communication between machine producers and mineral processing engineers is vital for the right choice of materials and the design of the right decanter centrifuge for the individual process.

Feb 1, 2012

By Michael M. Kimberley

Stratiform uranium deposits occur in Canada along the north shore of Lake Huron near the base of the Middle Precambrian Huronian Supergroup. Outcrop of the Buronian Supergroup extends for over 400 km from Sault Ste. Marie in the west eastward through Sudbury and then northeastward to Cobalt. Maximum stratigraphic thickness exceeds 5 km. The predominant Huronian rock type is metamorphosed sandstone (quartzite), with sub- ordinate argillite, conglomerate, mixtite (possibly tillite), volcanic rocks, and minor limestone, Much of the quartzite is highly feldspathic. Substantial uranium ore was first discovered in Huronian rocks in 1953 and has been exploited continuously since the initial mine-mill plant was constructed at the Pronto ore body, 30 km south of the present townsite of Elliot Lake. Only one ore body remains in production, however. It is shared by Rio Algom and Denison Mines 14 km north of the town of Elliot Lake.

Jan 1, 1980

By E. J. Sullivan

This study seeks to define the mechanism of oxyanion sorption onto surfactant-modified zeolites. Zeolites which have been treated with hexadecyltrimethylammonium bromide (HDTMA) surfactant to produce a hydrophobic surface are capable of sorbing both organic compounds as well as oxyanions such as chromate, selenate, and sulfate. Simple ion exchange and charge-balancing mechanisms do not fully explain this unusual phenomenon. The sorption of HDTMA surfactant appears to be partly ion exchange and partly sorption to non-ion-exchangeable sites. Sorption of chromate is a simple exchange mechanism with bromide, which co-adsorbs with HDTMA to form a surface precipitate. Information from this study will be used to design on-site and in situ treatment systems for contaminated water, such as filter beds and permeable barriers.

Jan 1, 1995