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By Harold B. Goldman

On the basis of tonnage, the sand and gravel industry is the second largest nonfuel mineral industry in the United States. In 1990, the production of sand and gravel was 927 Mt valued at $3.4 billion. California, which leads the nation with more than 126 Mt, together with Texas, Washington, Michigan, and Ohio, account for 36% of the total production in the nation (Table 1). In commercial usage, sand applies to rock or mineral fragments ranging in size from particles retained on a No. 200 Sieve (0.074 mm openings) to those passing a No. 4 Sieve (4.76 mm openings). Gravel consists of rock or mineral fragments larger than 4.76 mm, ranging up to 88.9 mm maximum size. The construction industry consumes 97% of the sand and gravel produced; the remainder is sand used for specialized products such as glass (see chapter on Industrial Sand and Sandstone and Glass Raw Materials). Utilization The building industry uses sand and gravel chiefly as aggregate in portland cement concrete, mortar, and plaster; the paving industry uses sand and gravel in both asphaltic mixtures and portland cement concrete. Aggregate is commonly designated as the inert fragmental material that is bound into a conglomerate mass by a cementing material such as portland cement, asphalt, or gypsum plaster. Sand and gravel is also used as construction fill, road base and subbase, and decorative material. Portland Cement Concrete Aggregates: Portland cement concrete consists of sand and gravel surrounded and held together by hardened portland cement paste. Concrete mixes commonly contain 15 to 20% water, 7 to 14% cement, and66 to 78% aggregate. Sand and gravel used as concrete aggregate have to meet many requirements (Goldman and Reining, 1983). Premature deterioration of concrete has been traced in many instances to the use of unsuitable aggregates. Asphaltic Aggregate: Asphaltic mixtures used predominantly for paving consist of combinations of sand, gravel, and mineral filler (material finer than 0.076 mm), uniformly coated and mixed with asphalt produced in the refining of petroleum. Sand and gravel used as asphaltic aggregate must meet the same general physical requirements as materials used for portland cement aggregate. GEOLOGY General Requirements of Aggregates Construction aggregate has many requirements that are difficult to meet if only unprocessed material from natural deposits is used. Suitable material is composed of clean, uncoated, properly shaped particles that are sound and durable. Soundness and durability are terms used to denote the ability of aggregates to retain a uniform physical and chemical state over a long period of time so as not to disintegrate when exposed to weathering and other destructive processes. Individual particles must be tough and firm, possessing the strength to resist physical stresses and chemical and physical changes, that may cause swelling, cracking, softening, and leaching. The aggregate should not be contaminated by excessive clayey material, silt, mica, organic matter, chemical salts, and surface coatings. Physical Properties: The quality of aggregate depends upon its physical and chemical properties. These, in turn, may be inherent mineralogical and textural features of the rock or may be the effects of later changes such as tectonics, mechanical or chemical weathering, or incrustations. The physical properties most significant for concrete use are: 1) abundance and nature of fractures and pores, 2) particle shape and surface texture, and 3) volume changes which may occur because of freezing and thawing or wetting and drying. An aggregate is considered to be physically sound if it is adequately strong and capable of resisting the agencies of weathering without disruption or decomposition. Minerals or rock particles that are physically weak, extremely water absorptive, and easily cleavable are susceptible to breakdown. The use of such materials in concrete reduces strength or leads to early deterioration by promoting weak bond between cement and aggregate, or by inducing cracking, spalling, or popouts. Severely weathered, soft, micaceous, or porous materials may cause localized stresses to develop in concrete by swelling and shrinking during wetting and drying or freezing and thawing cycles. Physical Suitability of the Various Rock Types. Sedimentary rocks have a wide range in physical and chemical qualities. Sand- stones and limestones, if hard and dense, are ordinarily satisfactory, but many sandstones are friable and excessively porous and commonly are clay-bearing. Shales generally make poor aggregate material, being soft, weak, and absorptive. Most igneous rocks are satisfactory, being normally hard, tough, and dense. Tuffs and certain flow rocks may be extremely porous and have high water absorption and low strength. Metamorphic rocks differ in character. Most quartzites are massive, tough, and dense. Fine-grained marbles are usually durable, but coarse-grained marbles have low abrasion resistance. Gneisses are ordinarily very tough and durable. Some schists contain micaceous minerals that are undesirable because they are soft, laminated, and absorptive. Micaceous minerals are susceptible to splitting along cleavage planes and thereby impair particle strength and durability. Some schists and slates in particular are thinly laminated and tend to assume flat slabby shapes that lack strength-and do not pack well. Any or all of these rock types may be rendered undesirable because of harmful exterior coatings. Weathering processes, particularly the action of ground waters, deposit these coatings. The most common coatings are calcium carbonate, clay, silt, opal, chalcedony, iron oxide, manganese oxide, and gypsum. Particles with these coatings are undesirable as aggregates because the bond between particle and coating may be weak, and decreasing the strength of the aggregate-cement bond.

Jan 1, 1994

By T. F. Torries

The primary criteria used by the mining industry to judge the merit of a project is internal rate of return (IRR) rather than net present value (NPV), although NPV is favored by academicians. This paper discusses the problems of IRR and NPV and compares the multigoal nature of the decision¬makers and their need for informa¬tion having the characteristics of NPV and IRR. The conclusions reached are that both NPV and IRR can be used for investment ranking, that NPV suffers the same multiple root problem as does IRR, and the use of conventional incremental IRR to reach NPV¬consistent project ranking is mis¬leading.

Jan 1, 1999

By F. Gray

Diamond tool fabricators expect strong growth in most applications for 1995 and 1996. Overall growth projects range from 8% to 10%. Diamond grinding is forecast to grow between 5% and 8%, while cubic boron nitride grinding should grow between 10% and 12%. A strong automotive industry is a major factor in this projected growth, as is continuing demand for other durables

Jan 1, 1995

The transfer of Langmuir-Blodgett (LB) monolayers of collector molecules to the surface of mineral crystals is an excellent method for the study of collector adsorption phenomena and is of particular significance in the understanding and development of improved flotation separations. The fatty acid/fluorite and amine/sylvite potation systems were investigated by the Fourier transform infrared/internal reflection spectroscopy (FT-IR/IRS) examination of transferred LB monolayers of collector molecules at the surfaces of the mineral crystals. The [ir]-A isotherm study of fatty acid and amine, typical anionic and cationic collectors, showed the different packing trends dependent upon the pH and/or type of subphase. This result clearly reflects the effect of pH on compound formation and dissociation of the collector molecules. Identification of the collector adsorption state and confirmation of the validity of the FT-IR/IRS adsorption density equation were included in this research effort. This allowed for a detailed discussion of collector adsorption phenomena. As a result of these experiments, it is possible to relate the hydrophobic character of a surface to the nature of the adsorbed collector structure and thus describe flotation behavior in greater detail. For example, it appears that in the case of oleate/ fluorite the equivalent of an LB monolayer can form spontaneously during adsorption from solution, and this structure is known as a self-assembled monolayer (SAM). Such a state is significantly more hydrophobic than the oleate structure which forms on the calcite surface at an equivalent adsorption density.

Jan 1, 1996

Conventional logging tools such as density, neutron, and acoustic have ranges of investigation of tens of centimeters. The borehole gravimeter, however, has a range up to hundreds of meters. For example, from the center of a cylindrical ore body 0.20 g/cm3 denser than its surroundings, one can detect the boundary of the ore body at a radius as large as five times its height. More complex structures can be investigated with computer programs. We can predict the usefulness of proposed gravity surveys, or decide which suggested structure is most likely to have caused the results of existing surveys.

Jan 1, 1988

By John L. Bolles

The mineral processing engineer must have some knowledge of mineral identification, and the greater his knowledge in this field, the greater will be his potential to do his own specialty well. Most metal-bearing ores and industrial minerals require processing of some kind to produce a salable product or a material suitable for further processing. The types of treatment are many, but each one is aimed at separating a mineral or family of minerals from others. Obviously, then, it is basic to all mineral processing to identify the minerals present in the raw material and in intermediate and final products resulting from processing. Very often the mineral processing engineer will enter planning while exploration of a mineral prospect is going on. He will examine hand specimens, drill cores and cuttings, bulk samples, and materials in place. He must identify the valuable minerals, their occurrence and associations with other minerals, and the identity of diluents or host rock. An exact and detailed knowledge of the raw material will usually suggest the treatment processes that should be investigated in the development of the most suitable scheme for that particular raw material in that particular location. Physical properties of a mineral often lead directly to a process for separating that mineral from others. Some well-known examples of these are: magnetic separations for such minerals as magnetite, rutile, ilmenite; gravity separations for gold, silver, galena. cassiterite; flotation separation for most sulfides; distillation of mercury from cinnabar; and selective dissolution in specific solvents such as halite or sylvite in water, gold and silver in cyanide solutions, copper oxides, carbonates, sulfates and silicates in dilute sulfuric acid. These processes and many others are described in detail elsewhere in the Hand¬book and so it is not appropriate to give details here, except to emphasize that processing is aided greatly by complete mineral identi¬fication. Developing a treatment scheme for a new mineral discovery is an exciting assignment fag the mineral processing engineer, but much more of the usual work relates to quality control in existing plants. Here too, mineral identification is important. Some processing is aimed toward producing an end product which will meet exacting specifica¬tions regarding purity or allowable diluents. In this situation it is vital that contaminants be identified so that the process can be adjusted

Jan 1, 1985

By Song Xiaotian

Studies have been carried out to optimize the VCR's mining sys- tem on the basis of synthetic analysis at Fankou Pb-Zn mine in Southern China. The synthetic e- valuation method is proposed for selection of mining alternatives and stope dimension optimization techniques. Theoretic calculation and computer optimization of the fragmentation of rock blasted by multispherical explosive charges are discussed. The mathematical and optimal fragmentation models are built. The optimum model is built for the main mining operations such as drilling, blasting and haulage. Lt can be used to evaluate VCR?s mining projects, select mining parameters and provide design fundations. From the point of view of system research on the geomechanical process, stoping technological process and benefit, the complex method of optimization is proposed for VCR's mining. Using computer simulation, based on this model, the optimal parameters are established and analysed. An effective approach is provided for research on the mining method optimization and getting better economical benefits from the application and improvement of VCR's method.

Jan 1, 1986

By R. F. Kovar, R. N. Torbin

Foster-Miller has recently developed a new concept for a highly specialized shaft lining system. This innovative shaft lining system uses a continuous slip forming placement technique, lining the shaft from the bottom up such as in a raised bored shaft. Although this part is not unique, the concept is designed to use polyurethane foam instead of concrete for the liner material. Furthermore, the concept is designed to attain rates of advance of 30 m/h (98 fph). The polyurethane foam liner is designed to be thinner (100 mm or 4 in.) than a conventional concrete liner (300 mm or 12 in.). It will eliminate the high cost associated with the erection and operation of an on-site concrete batch plant. The system will be designed to operate remotely, requiring few personnel for its operation. This system (or parts of it) may be appropriate where fast construction speed is required or where a jointless liner is needed.

Jan 1, 1990

By H. G. Linge

The Australian gold industry currently contributes some $4bpa to the national economy [l]. Some 40% of the total gold is produced in the region centred on Kalgoorlie known as the Eastern Goldfields of Western Australia. This region is the largest single centre of production with an output of some 100 tpa of gold [2]. In the Eastern Goldfields, refractory arseno­pyritic gold ore is an increasingly significant source of gold, feeding several operations utilizing bio-oxidation as the pre­carbon in pulp/leach (CIP/L) treatment process [1]. This paper desribes an alternative pre-CIP/L treatment option for use in the Eastern Goldfields based on the chlorination of arsenopyrite by chlor-alkali technology [3] using the salt resources available from saline water present in abundance in the region.

Jan 1, 1995

By Donald S. Clarke

The Umuna epithermal precious metal deposit has provided the target for a simulated rock geochemistry exploration program, directed at bedrock exposed in the drainage system of eastern Misima Island. A geochemical halo to the deposit is readily recognised in the mafic meta-volcanic country rock. This halo is defined by anomalous results for both major (K, Na, Ca, Mg) and minor (Au, As, Sb, Cu, Pb, Zn, Ba, Rb, Sr, Cs, Bi, Ga, S) element geochemistry, extending further than 1km from the deposit. Such halos are sufficiently extensive to provide adequate exploration targets in the search for epithermal mineralisation, complementing mineralogic and secondary media geochemical investigations.

Jan 1, 1989

By A. Bruce Waugh, W. W. Wen, Kevin N. Clark, Neville C. Lockhart, Bruce A. Firth

Australia is the world's largest coal exporter, and technological advancement is a key element of the coal industry strategy. The issues include: increased recovery of saleable coal; enhanced quality, i.e. lower ash, moisture, fines, phosphorus (sulphur is a relatively minor problem for Australian coals); better quality control; higher throughputs/lower costs; improved handling and transport; and reduced environmental impacts. In process terms, many coal preparation operations, particularly fine coal circuits, are relatively inefficient, and all circuits must also be matched and integrated for optimum overall operation. A holistic approach to technological improvement is desirable. This paper summarises research and development efforts, within CSIRO and its collaborators, across the unit operations as outlined in the title.

Jan 1, 1995

By K. A. Natarajan, Namita Deo

Strains of Bacillus polymyxa, preadapted and grown in the presence of corundum, were found to be capable of the efficient separation of hematite from alumina. Results of tests performed using binary hematite-corundum and ternary he- matite-quartz-corundum mixtures in the presence of cells and metabolic products separated from the adapted bacterial culture indicated that more than 99% of the hematite could be efficiently separated through selective flocculation after desliming. It was found that alumina-specific bioproteins and other nonproteinaceous compounds were secreted by bacterial cells after adaptation to the mineral. The utility of this bioprocessing is demonstrated in the removal of iron from bauxite ores through selective

Jan 1, 2000

By Hassan El-Shall, El-Sayed A. Abdel Aal

The major goal of this study is to decrease iron content in wet-process phosphoric acid. Reducing the amount of post-precipitated sludge in the acid is another important objective in this investigation. In order to achieve these goals, research efforts have focused on bench scale testing of an iron-chelating reagent to remove iron from phosphoric acid produced from South Florida high-iron and -magnesium phosphate concentrate, and plant testing using freshly produced concentrated acids for reducing the post- precipitated sludge. The data obtained in the above studies suggest that the addition point of the precipitating reagent is very important, as the precipitated iron compound has higher solubility at higher P2O5 concentrations. Up to 60% Fe2O3 removal efficiency is achieved depending on the amount of the reagent, concentration of acid used, and operating conditions. The addition of precipitating reagents to freshly concentrated phosphoric acid leads to a decrease of up to 84% in sludge volume percentage depending on acid type and clarification conditions. Decreasing the volume percentage of the sludge facilitates acid handling as well as decreases the adherent water- soluble P205 leading to lower total P2O losses.

Jan 1, 2002

By P. Somasundaran, Brij M. Moudgil

All the major interfacial technologies encountered in mineral processing involve adsorption of surfactants and/or polymers. With the need for processing low grade complex ores it is imperative that conventional techniques such as flotation and flocculation be extended to meet the challenge of treatment of fines. Addition of surfactants or polymers is indeed not limited to the solid-solid separations but extends to particle size reduction in the form of grinding aids and dewatering operations as well. Although progress has been made in recent years to understand the science involved in various interfacial processes, more challenges and opportunities exist today than ever before in processing of the low grade finely disseminated ores. A brief review of the recent advances and the challenges in mineral processing, especially, those related to the interfacial technologies is presented.

Jan 1, 1989

By Robert R. Munro

Introduction Traditional aggregate sources - riverbeds and alluvial fans - located close to developing urban centers are being foreclosed to mining. As sand and gravel reserves are depleted, nearby production plants cannot secure additional, adjacent reserves and are being forced to close down. The sand and gravel industry, in many respects, is its own worst enemy. It promotes development, street paving, home building, and industrial and commercial centers. Economics make us favor developments close to our operations. Thus, we encourage development by our neighbors, who soon become our detractors. Current Aggregate Mining Problems Urban development is not compatible with sand and gravel mining. Neighbors dislike the view of pits and quarries, and they complain about dust, noise, and trucking. In general, the neighbors are not happy being close to an aggregate source. This is reflected in land use or zoning laws. In most localities, mining requires a special-use permit. Public hearings are required before a legislative body. If a large group of opponents show up, legislators will often deny the land use. Urban areas are seeing traditional close-in sand and gravel sites becoming no longer available for industry. A parallel situation is also developing in most urban areas. That is, the not-in-my-backyard attitude toward landfills. As urban areas mature; a significant amount of change takes place in the physical makeup of a city. Streets and parking lots deteriorate and need repaving. Curbs and gutters need to be relocated. This necessitates a place to dispose of excess, or old, paving and structural material. Since landfills have become at least as difficult to permit as sand and gravel sites, they are becoming remote from urban areas. A significant portion of the structural material that needs to be disposed of is concrete and asphalt. This material is heavier than other materials. Thus, the cost of moving a large volume of very heavy material to a landfill becomes very expensive. In California, dump truck transportation is regulated by the State Public Utilities Commission through minimum rate tariffs. A rule of thumb for estimating the cost of such transportation is once the material is loaded, the extra kilometer (mile) costs $0.09/t ($0.08 per st). Thus, to haul an 18-t (20-st) road an extra 32 km (20 miles) will cost about $32. Because of its remote location, the cost of hauling aggregates to the point of use in an urban area becomes excessive - about the same as hauling the material to a landfill. Here is a classic example for synergism. If we could save the transportation cost of heavy demolition material by disposing it relatively close to the central city (its source), and at the same time provide an aggregate source close to the central city (its point of use), two difficult economic situations can be solved. Thus, the develop¬ment of recycling concrete and asphalt. Mining Concrete and Asphalt There are two methods of mining concrete and asphalt. The first is to pick up the old pavement in pieces. Thin, cracked pavement can usually be lifted from the grade with a front-end loader. It will break up into manageable-sized pieces. With heavier pavement, it is sometimes necessary to intentionally break it up with a stomper or heavy ripper. The pieces are loaded into heavy dump trucks and shipped to the crushing site. Again, a front-end

Jan 7, 1984

By Shoung Ouyang, Pinnaduwa H. S. W. Kulatilake

Available literature on the topic is reviewed. Methods are suggested to improve the presently available techniques to perform probabilistic modeling of shear strength parameters for rock discontinuities. The Mohr-Coulomb model and a power law model are used as strength criteria to model shear strength of rock discontinuities. Use of various regression techniques for point estimation of shear strength parameters from direct shear data are discussed. Goodness-of-fit tests for bivariate beta and bivariate normal distributions are developed, and the applicability of them to represent the distribution of shear strength parameters is tested through examples. Both distributions seem to have potential to represent the statistical distribution of strength parameters.

Jan 1, 1986

By Wan-Kyu Choi, Arpad E. Torma

The electrochemical reactions involved in a zinc sulfide flotation concentrate leaching with sulfuric acid in presence and absence of Thiobacillus ferrooxidans, as well as with ferric chloride - hydrochloric acid containing media, have been investigated. The cyclic voltammetric measurements revealed that many intermediate electrochemical reactions are involved in the zinc sulfide leaching. Using chronoamperometric and chronopotentiometric techniques, it was found that the leaching process is controlled by solid - state diffusion. The activation energy of solid - state diffusion process was determined by the Price's approach to be 21.3 kJ. The leaching mechanism is discussed in terms of solid - state properties (energy bondings) of the high energy gap solid zinc sulfide semiconductor and energy density states of redox systems of acidic leach media. A generalized model for the mechanism of zinc sulfide oxidation is present.

Jan 1, 1990

By Leonid P. Ni, Askar M. Kunayev

It is well known that processing of the high-silicon bauxites for obtaining alumina by the hydrochemical Bayer process is irrational due to the significant losses of alumina and alkali with red mud. The main source of losses of the mentioned compounds under the conditions of leaching by the Bayer process is the formation of difficultly soluble sodium alumosilicate of the composition Na20 .Al203, 2Si02 . n H20. A conventional method of an extra recovery of alumina as well as of regeneration of alkali out of red mud is the high-temperature sintering of the latter with soda and limestone with the subsequent leaching of sodium aluminate from the sinter by water or soda solution. A sequential version of the Bayer-sintering flow chart recommended for the prosessing of bauxites with an increased content of silica is based on this method. However, the sintering method is not the only alkaline method allowing to make an extra recovery of alumina likewise of alkali from red mud. Our investigations showed/I/, that the components mentioned can be recovered by a pure hydrochemical method of treating red mud with concentrated alkaline solutions, with lime (Ca0) being present, that was earlier succesfully used in the development of the hydrochemical method of processing nepheline rocks/2/. The possibility of extracting alumina and alkali from red mud is based on the reactions which can be schematically represented in the following way:

Jan 1, 1984

By B. Andersen, P. Somasundaran

An accurate knowledge of the interactions among mineral particles and between such particles and dissolved and precipitated species is important in developing efficient separation processes. In this investigation, interactions relevant to dispersion and selective reagent adsorption (the two main prerequisites for selective flocculation) within Florida phosphatic clay Waste were studied. Initial studies with artificial slimes, consisting of pure clay and phosphate minerals, showed dispersion of artificial slimes to be relatively easy. The problems that were encountered during selective flocculation of the artificial slimes were due to unselective polyacrylic acid adsorption on clay, which was caused by the presence of multivalent calcium ions on the exchangeable cation positions on the clay surfaces. This problem could be solved by exchanging calcium for sodium, which reduces the interaction between the polymer and the clay surface. This procedure, however, was not successful for mineral mixtures. Natural slimes were found to be much more difficult to disperse. This was attributed to the presence of cementing materials such as humic substances and Al and Fe (hydr)oxide precipitates. Selective removal of these cementing materials resulted in good dispersion and partial separation. A further increase in the separation of natural slimes is most likely determined by the presence of calcium on the clay surfaces, as was found for the artificial mixtures.

Jan 1, 1994

By Jack W. Murphy, Kent J. McGrew, Rudolph H. Jacobson

Introduction Maximization of profit consistent with environmental protection is the principal goal of new applications development for any conventional or in-situ mining technique. Efficient evaluation of all the parameters that contribute to mining costs and production hinges on proper design and evaluation of testing programs and data. The program discussed herein utilizes several field and laboratory procedures to estimate ore deposit characteristics and optimize lixiviant compositions. The ore characteristics and lixiviant compositions are then used in a long path leaching test (stream tube test). The stream tube test data are analyzed by mathematical models with computer assistance to predict such well-field rate parameters as target metal production, lixiviant consumption, and restoration. When these predicted rates are combined with market values for target metals, capital expenditures, prices of lixiviant chemicals, and other economic variables such as labor costs, power rates, licensing fees, and others, an assessment of the relative feasibility of various proposed mining plans is possible. The flowsheet in Figure 1 illustrates this process.

Jan 1, 1984