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By S. S. Cook, S. E. Paulson

The US Bureau of Mines is conducting core leaching experiments with sulfuric acid on oxide copper ores from the Cyprus Casa Grande and Asarco/Freeport Santa Cruz deposit in Arizona to further the understanding of the leaching process in supergene copper ores as it relates to in situ mining. Leach solutions from atacamite mineralization contained 5 to 30 g/L (0.05 to 0.28 oz/gal) copper and few extraneous ions. Leachant from chrysocolla ores, with grades similar to the atacamite, contained 2 to 9 g/L (0.02 to 0.08 oz/ gal) copper and abundant extraneous ions. Quartz and K-feldspar had no impact on leach solution composition at any acid concentration up to 40 g/L - (0.39 oz/gal) while illite and sericite had minimal impact. Biotite, calcium-rich clay, and limonite have a significant impact on solution chemistry when there is abundant free acid in solution. High acid concentra¬tions increase acid consumption in ores with abundant biotite and limonite gangue. High acid concentrations can be used in ores with quartz, K feldspar, and sericite gangues without increasing acid consumption per unit of copper removed.

Jan 1, 1990

By G. E. S. Valadão

This paper is concerned with studying the dewatering behavior of three samples of iron ore products. The objective is to improve the industrial filtration performance by taking into account the laboratory results. Mineral samples came from the Iron Ore Quadrangle in the state of Minas Gerais, Brazil. These samples represent products from the industrial processing of hematitic ores. The samples have almost the same chemical and mineralogical compositions, but they have different size distributions and different specific surface areas. The filtration tests were performed using a modified Büchner funnel apparatus. The results indicate that size distribution and specific surface area have significant influences on dewatering behavior. For Sample 1, the addition of flocculant and/or surfactant was not essential to improving filtration performance. For Sample 3, the cake porosity and the cake thickness were influenced by the addition of the flocculant. On the other hand, the simultaneous addition of flocculant/surfactant decreased the cake formation time and reduced the cake moisture. For Samples 2 and 3, it was also observed that the industrial operation could be improved by taking into account these laboratory results. Key words: Dewatering, Iron ore, Hematite, Filtration, Flocculation, Surfactant

Jan 1, 2003

By Yixian Zhao

Although many ultimate pit limit design algorithms have been developed for the past one- quarter century, only the well known Lerchs-Grossmann's (LG) algorithm is capable of producing a truly optimum ultimate pit limit today. This paper presents a graph theory oriented algorithm for optimum ultimate pit limit design. This algorithm produces a true optimal solution and maximizes the total undiscounted net profit for a given 3-D block mine model. The algorithm performs much better than the well known LG algorithm, in terms of the reduction in computation time and computer memory requirements. More importantly the new algorithm is easier to understand and implement than the LG algorithm. Specifically, this paper discusses: 1) the computer representation of arcs and the rules of arc generations which dictate the formation of trees in the graph, 2) the mechanism of joint support and re-allocation, 3) the properties, the general procedures of the algorithm, and the suggested specific steps to implement the algorithm, 4) comparison between the new algorithm with LG algorithm, and 5) some experience in implementation of the algorithm and two case study results.

Jan 1, 1992

By Brian Fulcher, Matthew Bartlett, Jarrett E. Carlson

This paper discusses the challenges to complete the construction of two large underground Metro stations and connecting tunnels in the Tren Urbano system. The completion work includes the installation of specialized mechanical and electrical systems, extensive architectural finishing as well as coordination with systemwide power and controls installed by others. A unique feature of this project was the simultaneous design and construction of the structural/civil/architectural/mechanical/electrical works by KKZ separately from the power and control systems under the management of the Owner, its consultants and other contractors. Completion of this project comes after almost six years of continuous design and construction in a dense urban environment. The project was confronted by many challenges that could only be met with the combined efforts of the Joint Venture team in close cooperation with the Owner and its System wide Contractor. This paper will also address many of the major design and construction changes implemented to suit the Owner’s requirements.

Jan 1, 2003

By D. R. Spears, D. A. Stanley

The US Bureau of Mines investigated the fundamental aspects of shear-flocculation using a rapid, in-situ particle size analyzer. Silica was stirred in the presence of an aliphatic amine to determine the effects of collector coverage, stirring speed and solids concentration on the kinetics of shear-flocculation. The results showed that shear flocculation is a two-stage process. In the first stage, which occurs during the first 1-2 min. of the reaction, the mean particle size increases rapidly, and in the second stage, an equilibrium is set up between the rates of floc growth and floc decay. Collector dosage affected the position of the equilibrium by altering the number of surface sites for particle-particle attachment. A minimum stirring speed was necessary for shear flocculation, which was dependent on solids concentration and collector dosage. This stirring speed was the minimum necessary for particles to overcome the electrostatic energy barrier, and that results in keeping the conditioned particles dispersed. Larger particles flocculated more rapidly. At very high stirring speeds, large flocs became unstable, resulting in a narrowed particle size distribution in the slurry.

Jan 1, 1995

By J. Jordan, D. K. Denton, D. Tesarik, D. F. Scott, T. J. Williams

Personnel from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health integrated the results of studies from a seismic tomographic survey, a finite-difference analysis, laboratory measurements of compression wave (ultrasonic) velocities in rock cores, and site geology to evaluate the use of seismic tomography for identifying induced pressures in an underground pillar at the Edgar Mine, Idaho Springs, CO. The key findings were that (1) the seismic tomograms showed that seismic velocities in rock adjacent to mine openings were low, (2) a difference tomogram in which in situ stresses on the east and west sides of the slot were compared showed that velocities increased west of the slot but decreased east of the slot, (3) geologic features (rock types and a fault) identified through geologic mapping were recognizable in the seismic tomograms, (4) ultrasonic velocity measurements on the rock cores agreed with seismic velocity measurements in the tomograms, and (5) results from a finite-difference analysis compared well to the seismic tomograms west of the slot but not east of the slot. The significance of this research is that seismic tomography is a useful tool for determining relative stress in underground pillars.

Jan 1, 2004

By Boris M. Vorobjev

The paper in question discusses a wide range of topics on the coal mining environment in general and on computerized coal mine environment systems in particular. The emphasis is being made on methodological aspects of coal mine environment with reference to computerized monitoring systems Classification of computerized coal mine environment monitoring system is suggested by the author with specific reference to coal mining operations. Coal quality control system at all levels (coal face to regional levels) is also discussed briefly hereunder, since coal quality is one of the major factor for environmental management. An integrated coal mining economic and environmental management super-system is presented in this paper Review Of the UN/DTCD, UNDP European Regional project "Computerized Coal Mining Systems" is presented here. Conceptualization of a new European Regional project on Coal Mining Environment and Economic Management is also a topic discussed in the paper.

Jan 1, 1992

In analyzing cost performance, managers must initially consider the issue of scope. Is the analysis for a single responsibility center or multiple centers? For a single period or a number of periods? If multiple responsibility centers are being examined, how can managers compensate for differences in their sizes? Several techniques have been developed to analyze the relationships in a set of financial statements at a single point in time and the trends in these relationships over multiple periods. Cross-sectional techniques focus on the first of these, and time-series techniques look at the latter. Although this text focuses on cost performance, these methods also can be used for revenue-related analyses.

Jan 1, 1999

By S. Mathur

Future Florida phosphate reserves contain higher MgO than presently mined deposits. The high MgO content is contributed by dolomite and Mg-rich clay, palygorskite. Selective flocculation was attempted to reduce the MgO content of apatite in synthetic mixtures of apatite with dolomite and palygorskie. Mixed mineral selectivity was predicted in the apatite-dolomite and apatite- palygorskite systems with Poly(ethy1ene oxide) (PEO) flocculant. Loss of selectivity in the mixed mineral systems was primarily attributed to heteroflocculation, which was minimized by addition of a Site Blocking Agent (SBA), a lower molecular weight fraction of PEO, prior to addition of the flocculant. A 80:20 mixture of apatite-dolomite (or palygorskite) was upgraded as 95% apatite at more than 80% recovery level in the product fraction.

Jan 1, 1995

Since first introduced, the coal mine roof rating (CMRR) has been widely accepted as a tool for geologic characterization and mine planning. This paper discusses the application of the CMRR to another practical ground-control problem: extended cuts. Extended cuts, i.e., cuts greater than 6 m (20 ft) in length, are commonly used with remote-control continuous miners. Extended cuts can greatly increase productivity, but they have been associated with a number of fatal roof-falls. When extended cuts are attempted in weak roof material, the roof may collapse before it can be bolted Until now, it has not been possible to predict where conditions may not be suitable for extended cuts. In this study, data on the CMRR and extended-cut experience were collected at 36 mines in seven of the United States. It was found that, when the CMRR was greater than 56, deep cuts were routine in nearly every case. When the CMRR was less than 37, extended cuts were almost never taken, and, when the CMRR was between 38 and 56, extended cuts were sometimes, but not always, feasible. The data also show that extended cuts are less likely to be stable if either the entry span or the depth of cover increases.

Jan 1, 2000

By Rashi Tiwari, George Danko, Jeremy Knowles

A control technique is described for enhancing the efficiency of materials handling and other mining operations. The concept involves human-operator and robotics control interactions to assist in mining operations. Many mining tasks require a human operator to coordinate the motion of several machine links by simultaneously manipulating multiple joysticks or other control devices. The new control architecture allows for automatic coordination of multiple machine joints. The machine movement may follow a computer-optimized, learned coordination pattern, while the operator still retains the master control of the overall trajectory and velocity parameters. Examples are described for a surface mining front shovel.

Jan 1, 2005

By L. M. English, K. A. El-Nagdy

The mine characteristic curve represents the relation between the airflow in a system and the pressure drop across the system. In a single fan system, this relation can be easily drawn by assuming different values of the airflow and calculating the corresponding pressure drop according to Atkinson’s law. In a multiple-fan system this cannot be done for each fan simultaneously. However, an alternative mathematical method for plotting subsystem characteristic curves on subsystem quantity coordinates is outlined here that achieves this objective. The Hardy Cross algorithm has been combined with a switching-parameters technique and has been used to trace subsystem characteristic curves. An example using four fans in a complex network is presented here. This example illustrates the nature of the problem and the difficulty of detecting unstable conditions in this type of network.

Jan 1, 2001

By A. Iordanidis

Ieropigi Fe-Ni deposit is located in northern Greece, in Kastoria?s prefecture near Albania?s borders. A laterite profile exposed by opencast mining and placed near the basement of the mine was chosen for sampling. Ten samples, representing ?pure? Fe-Ni ore, ophiolite-bedrock, ?red? ophiolite and ?enriched? ophiolite were collected, based on macroscopic observation. The samples were analysed by X-Ray powder Diffraction (XRD) for the determination of the mineral phases. Iron and Nickel concentrations of the same samples were also determined by X-Ray Fluorescence (XRF) methodology. The Fe-Ni ore samples consists predomi-nantly of hematite, goethite, chrysotile (serpentine), saponite and quartz. ?Red? ophiolite samples consists mainly of chrysotile, hematite, quartz, calcite and small amounts of paragonite and goethite. Bedrock and ?enriched ophiolite samples are comprised of chrysotile, hematite, calcite, quartz, nontronite, paragonite and sepiolite. The Fe content ranges between 13% and 49% in Fe-Ni ore samples and between 7% and 10% in ophiolite samples. The Ni content ranges between 1% and 3% in Fe-Ni ore samples and between 0.3% and 4.5% in ophiolite samples (the higher content is observed in the so-called ?enriched? ophiolite). A correlation between Fe-Ni concentrations and mineral assemblages is being attempted in order to evaluate the nickel-rich mineral phases. It is shown that the nickeliferous minerals are serpentine, hematite, goethite and saponite.

Jan 1, 2006

By Alec G. Richardson, S. H. Chiang, Ralph W. Lai, McMahan L. Gray

The potential of coal cleaning by selective agglomeration was examined for a Pittsburgh seam bituminous coal using isooctane as an agglomerating liquid. The effects of particle size, pH, degree of mixing, and dosage of isooctane on the pyrite and mineral matter removal from finely ground coals were investigated. The role of shear-enhanced-hydrophobic-association in the flocculation of fine particles was examined. The degree of liberation of pyrite from coal at different grinds was examined using an automated petrographic image analyzer. The effect of dispersant on slurry rheology during grinding was studied. The results indicate that over 95 percent of the pyritic sulfur can be removed from the coal. Final products containing less than 0.9 percent ash at a combustible recovery in excess of 90 percent have been obtained with multiple stages of cleaning.

Jan 1, 1989

By J. W. Leonard, C. L. Jiang, B. K. Parekh, X. H. Wang

The selective depression of pyrite from the Kentucky No. 9 coal seam was systematically examined using various kinds of inorganic and organic chemicals. Most of the organic chemicals tested showed little selectivity in pyrite depression. It was found that both orthophosphate and pyrophosphate were effective for the selective depression of coal pyrite in coal flotation using fuel oil as a collector. At substantially low concentrations of pyrophosphate, the flotation of coal pyrite was completely depressed over a wide pH range, while the coal flotation remained unaffected. The mechanism of the selective depression of pyrite by phosphates was explained with the help of thermodynamic calculations of iron-phosphate-water systems and zeta-potential measurements. It was shown that pyrophosphate reacts strongly with the iron ions of pyrite to form stable hydrophilic iron pyrophosphate complexes on pyrite surfaces.

Jan 1, 1999

By T. Ko, K. N. Han, C. S. Park, N. S. Kim, C. Yoon, H. Yoon

Quantitative analysis of Platinum Group Metals from ore samples and industrial materials using Inductively Coupled Plasma-Mass Spectrometer (ICP-MS), Inductively Coupled Plasma-Atomic Emission Spectrometer (ICP-AES), Atomic Absorption Spectrometer(AAS), and X-ray Fluorescence (XRF) techniques was conducted and the performance of various techniques was compared. The effects of different matrices in the sample materials were compared and discussed for each analytical technique. The ICP-AES technique exhibited better accuracy than AAS but showed limitations in its application due to strong spectral interference in the presence of common matrix elements such as iron. The ICP-MS showed the lowest detection limit and less spectral interferences than the previous two techniques. The XRF technique was also applied to examine the total amount of PGM from industrial materials. Results from each analytical method on various sources were presented and discussed.

Jan 1, 2003

By J. M. Keane, C. K. Chase

Critical to successful dump and heap leaching of copper is an adequate evaluation of applicable parameters. This paper deals with methods to establish optimum conditions for dump and heap leaching copper so that commercial operations can proceed. Discussion is also offered of ore occurrences and preparations for dump or heap leaching.

Jan 1, 1988

By Yeonuk Choi, Gus Van Weert

cyanide control in effluents is becoming a critical environmental issue for the gold extraction industry. Silver impregnated carbon removes free cyanide effectively to the ppb level from solution in high throughput columns. By re-calcining the cyanide saturated carbon, the impregnated silver is restored to activity and the cyanide destroyed outside the effluent stream. Many gold mills already have an activation kiln on site, which could make retrofit relatively easy.

Jan 1, 1993

By Patrick R. Taylor

The hydrometallurgical fundamentals review did not arrive in time for publication in the May issue. Papers presented at the SME Annual Meeting, in Phoenix, AZ were available as preprints. The EPD Congress 1992 from The Metallurgical Society had several papers related to hydrometallurgy. Minerals Engineering 1992 was published in Minerals Engineering and contains several papers related to hydrometallurgy. In addition, a conference was held to honor Ernie Peters. The proceedings contains a large number of hydrometallurgy papers. Precious metals Gold extraction in the potassium cyanide-primene JMT sulfate-Xylene system was studied by Caravaca and Alguacil (Hydrometallurgy). Adams, Friedl and Wagner presented results on the mechanism of gold cyanide adsorption onto activated carbon (Hydrometallurgy). Adams also studied the adsorption of silver cyanide and used an IR method to evaluate adsorbed aurocyanide species on activated carbon (Hydrometallurgy).

Jan 1, 1993

By D. C. Seidel, W. K. Tolley

Supercritical water alters the structure of common sulfide minerals by partially removing sulfur from the mineral structure. This discovery has been applied to the treatment of pyritic gold ores to improve precious metal recovery without generating or utilizing environmentally sensitive products such as S02, chlorine, or cyanide. Pretreating pyrite concentrates in supercritical water under mildly oxidizing conditions provided by certain metal oxides or oxygen improved gold leaching using thiourea. The pretreatment differs from chlorination or roast pretreatments in that elemental sulfur rather than sulfuric acid is the major product. A pyritic ore containing 58 g/mt Au was pretreated with oxygenated supercritical water at 24 MPa and 400°C, then leached with 20 g/L thiourea. With pretreatment, gold recovery was 90%; by contrast, gold recovery was below 10% without pretreatment.

Jan 1, 1990