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By A. E. Desrosiers, R. L. Kathren, D. L. Haggard, J. M. Selby

INTRODUCTION The radiological health significance of thorium-230 stems from its tendency to separate from the uranium238 parent, concentrate in bone tissues, and to subsequently irradiate the radiosensitive tissues lining the bone surfaces and the bone marrow. Indeed, thorium-230 may be the radionuclide which contributes the major dose following intake of natural uranium (Hartley and Pasternack 1979). This is reflected by the most recent recommendations of the International Commission on Radiological Protection, which specify the limits shown in Table I for the annual intake of radionuclides by occupationally exposed workers (ICRP 1979). TABLE 1. Occupational Annual Intake Limits (microcuries per year) for Selected Uranium Nuclides and Daughters (ICRP 79) [Radionuclide Ingestion Inhalation] [Uranium-238 200 0.05 Uranium-235 200 0.05 Uranium-234 200 0.03 Thorium-234 300 200 Thorium-230 3 0.02 Radium-226 2 0.5] Clearly, the relatively low annual limit of intake for thorium-230 shows it to be of greater radiological concern than its parent radionuclides. Because of the greater toxicity and different metabolism of thorium-230, monitoring only for uranium-238 does not satisfactorily identify the possible hazard from thorium-230 nor does it provide any real indication of the metabolism or biodynamics of these two radionuclides. Thorium-230 has a half-life of 80,000 years and can be detected by direct counting of the alpha particles or photons emitted during its transformation to radium-226. The 4.69 and 4.62 MeV alpha particles are distinctive and specific indicators of thorium-230 and are emitted with abundances of 76% and 24%, respectively. The principal photon, a 68 keV gamma ray, is emitted in only 0.37% of the transformations and is, therefore, not useful for low level measurements. The other photons emitted have even lower yields, or, in the case of radium L x-rays, are non-specific and, hence, useless for quantification. High sensitivity measurements of thorium-230 currently are usually accomplished by wet washing of the sample substrate, quantitative chemical separation of thorium atoms, and, finally, direct measurement of the alpha particles emitted from a massless deposition. This procedure is complicated, expensive, and time-consuming, and subject to interferences from uranium, other actinides, and other thorium isotopes. Recently, the feasibility of low-level measurement of thorium-230 by neutron activation analysis (NAA) was demonstrated (Kathren, Desrosiers and Church 1980). Two principal variations of the NAA method were used in this study: 1) instrumental NAA technique and 2) post-irradiation radiochemical separations (RCS). Instrumental NAA procedure is a nondestrucive technique which is preferred because of its simplicity. The procedure is as follows: after irradiation with a known neutron fluence, the samples are transferred to a clean container and quantitative gamma spectroscopy performed. With the radiochemical separations procedure, the sample is initially treated as in the instrumental technique. However, after irradiation, a known amount of "carrier" is added to the sample. The element(s) of interest are then separated from the rest of the matrix by distillation, precipitation and extraction techniques. The resulting sample, now free of interferring elements, is then ready for gamma-ray analysis. The use of a "carrier" is to determine the loss of element-of-interest during the chemical separations process. The neutron activation cross section of thorium-230 has an epicadmium resonance value of 1,010 barns (Mughahghab and Garber 1976) and a thermal neutron cross section of 23 barns. The 25.52 hr thorium-231 produced releases two photons of significance: an 84 keV complex, (6.5% yield) and 25.6 keV (15% yield) (Lederer and Shirley 1978). The 84 keV complex is particularly useful for quantification since neither natural uranium, thorium, their daughters, or activation products emit photons in this region. However, the higher yield of the 25.6 keV photon may result in increased sensitivity if there are no other photons of similar energy emitted by other radionuclides in the sample. PRELIMINARY STUDIES Thorium-230 standard stock solution was prepared from a pure sample of the oxide purchased from Oak Ridge National Laboratory. From this stock solution a series of samples were prepared for irradiation in the TRIGA Mark I reactor at Reed College. Various dilutions were prepared as well as thorium-230 spiked urine samples. Irradiation times varied from 1 to 54 minutes in a neutron fluence rate of 1.84 x 1012 n/ cu m-sec. The neutron spectrum was abundant in thermal neutrons, having a Cd ratio of approximately 10. Treated urine samples were also analyzed by the NAA instrumental method. Analysis of untreated urine samples was not possible due to the high background

Jan 1, 1981

By B. Campbell

This paper will detail the successful construction methods of a 20- foot diameter wet well shaft, approximately 180 feet deep in overall depth and 150-feet below the water table, adjacent to Lake Nacimiento, in San Luis Obispo County, California. In addition to this, highlights will include the selection process in determining the most economical support of excavation, while minimizing risk of large water inflows as indicated in the Owner?s Geotechnical Baseline Report (GBR).

Jan 1, 2010

By Jindrich Fiala, Jirí Kout

The paper contains knowledge that have been achieved when the problem of airflow temperature and humidity changes prediction in mine airways was investigated. The substance of physical processes has been consistently applied. The methods of dry-bulb and wet-bulb temperatures calculations can be applied in any type of mine airway. The exceptionality of auxiliary ventilated airways is in the original solution of so called losing air flowing when a ventilation pipe is leaky. The combination of aerodynamics and thermodynamics solutions enable to determine climatic conditions on projected workplaces with a sufficient accuracy.

Jan 1, 1991

By Qinghua Tian, Zhipeng Xu, Dong Li, Xueyi Guo, Liu Zhu

Tellurium (Te) is an important scattered metal. Known as the vitamin of modern industry, national defense and cutting-edge technology, it is the supporting material for new high-technology materials. Currently, its separation and extraction from Te-bearing materials face problems such as long flowsheets and high reagent consumption, giving rise to an urgent need to develop new methods for its recovery.

By A. R. Rule

As part of the Federal effort to help maintain an adequate supply of fertilizer minerals, the Bureau of Mines is conducting research to characterize complex, low-grade western phosphate rock and to develop methods for economic recovery of phosphate. The rock varies from soft, friable, altered phosphatic shale to hard, tightly cemented, unaltered phosphate rock. To supplement current beneficiation by sizing, a flotation procedure was devised that included depression of phosphate minerals with H2SiF6 and anionic flotation of carbonate minerals, followed immediately by cationic flotation of silicate minerals. Application of the procedure to several different ores resulted in phosphate concentrates that ranged from 28 to 31 pct P20S in grade and from 60 to 70 pct in phosphate recovery.

Jan 1, 1977

By E. C. Grunsky

Spatial auto- and crosscorrelation assessment of variables can be carried out using quadratic function estimates. From the function estimates, multivariate relationships of the variables can be determined in the form of spatial factors. The calculation of the spatial factors requires computation of the corresponding amplitude vectors from the eigenvalue solution. This vector reflects the relative amplitudes by which the variables follow the spatial factors. Instability of some of the eigenvalue solutions requires that caution be used in interpreting the resulting factor pat- terns. A measure of the predictive power of the spatial factors can be determined from the auto- correlation coefficients and squared multiple correlation co-efficients which indicate which of the variables are significant in any given factor. The use of unconditional simulations provides a basis by which geological variables of varying spatial ranges can be modelled using the spatial factor technique. Simulations were generated for a variety of ranges and variables were created that form single or multiple combinations of the spatial patterns. The success of the spatial factor technique depends on the amount of associated noise, and the size of the neighbourhood relative to the spatial range of the variable. The predictive power of the components is dependent on these two factors. Problems with collinearity of variables can result in unrealistic eigenvalues and result in the failure of the method. Application of this method to spatial data in mineral exploration can assist in outlining spatially continuous zones of alteration associated with mineralization.

Jan 1, 1989

Most statistical and geostatistical methods of re-source and reserve estimation work extremely well for Normal (Gaussian) well-behaved information. However, most interesting mineral deposits exhibit far from this idealistic distribution of values. It seems that the more valuable the mineral, the less likely the data are to have a Normal distribution. Values tend to be "positively skewed" with a long tail into the high values. Using averaging techniques, such as inverse distance or ordinary kriging may result in consider-able overestimation of grades and tonnages unless such values are cut or otherwise modified. This paper presents some real case studies where distributions are (a) highly skewed and (b) the product of multiple phases of mineralisation. Practical methods are presented for solving such problems including combinations of indicator and log normal kriging methods. The emphasis of the presentation is on developing operational methods which can be used on project evaluation or grade control in producing mines.

Jan 1, 2000

By Ronald L. Wiegel

Success has been achieved in developing mathematical models of rod mills, ball mills and recently to a limited extent autogenous grinding mills. There is also considerable activity in the development of mathematical models of various mineral concentration opera¬tions, such as flotation, magnetic separation and electrostatic concentration. However, at present there is a technological gap which hinders the integration of both size reduction and mineral concentration models into an overall process simulation model. This gap exists because size reduction models have been aimed at describing the size of the product and have not dealt with the equally important problem of identifying the product composition in each size fraction. Without this information the concentration model is ineffective. This situation is especially critical in the simulation of the magnetite-taconite beneficiation process, where a portion of the ore is rejected from the process following each stage of size reduction. Consideration has therefore been given to the merging of a size reduction model and a mineral liberation model to permit prediction of mineral composition as a function of size. The results of this integration of size reduction and mineral liberation models are discussed from both theoretical and practical viewpoints using batch grinding data for a magnetite iron formation sample as a demonstration vehicle.

Jan 1, 1975

By K. Konialis

In the last twenty years, the mining industry has made marked efforts to improve its reputation in regard to its social performance. These efforts have been expressed in the 9th ICMM (International Council on Mining and Metals) principle as a commitment to contribute to the social, economic and institutional development of the local communities. Towards this goal, which has been increasingly highlighted because of its importance for sustainable development, a number of practices and methods have been developed. The international development literature describing these practices is full of so-called development buzzwords, such as stake-holder participation, empowerment, capacity building. This paper argues that none of these development catchwords are neutral, but contain assumptions based on a specific view of development. Since capacity building is a central task in development, the paper focuses on this concept and takes a critical look at the assumptions that underlie this concept and influence strategies employed by the mineral sector. It suggests that the notion of capacity building in some earlier approaches implies a set of asymmetric power relationships between developed and developing countries where capacity is transferred from the developed countries to the developing ones. The developing countries are seen as passive recipients while the experts, i.e. the developed countries through their mining companies ultimately control the capacity-building process. The paper also points out that the mainstream capacity development approach has been based on the assumption that local or indigenous communities are mainly made up of needs and capacity gaps. The goal of development projects should then be to address these needs, which are perceived and prioritized by the ?experts?. Critiques of this development model suggest that in order for the mining industry to embrace more successful and sustainable practices, it should rethink the notion of capacity building. It should move towards alternative approaches that see it as a two-way learning process which will serve to enhance not only the capacities of the communities, but also of the development practitioners and which will build on the strengths of the community, and move away from attitudes of superiority and practices of dependence.

Jan 1, 2007

By J. J. Kollé

A compressed-water hydraulic pulse generator (HPG) for nonexplosive blasting of rock and concrete is described. Energy is stored in the HPG by compressing water to ultrahigh pressure. A large, fast-opening valve discharges the compressed water, resulting in a high-energy impulse. The HPG can be used for small-scale bench blasting by discharging the water through a nozzle that is closely fitted into a borehole. A bench blasting system requires an HPG, a drill and an indexing mechanism to allow insertion of the HPG nozzle into a drilled borehole. Systems with discharge energies ranging from 40 to 250 kJ have been used to excavate hard rock, including andesite, granite and quartzite. The largest system can excavate 15 t/h (16.5 stph) of massive quartzite based on a 2-min cycle time for hole drilling. Blasting with an ultrahigh -pressure hydraulic pulse generator was demonstrated as an effective means of excavating hard, massive rock under the confined conditions of a tunnel opening or underground sloping panel. Hydraulic blasting provides a continuous mechanized mining capability that is well suited for deep-level mining and urban excavation sites where explosives are prohibited.

Jan 1, 1998

By Craig Smith

California is the nation's leading producer of diatomite products. The Lompoc Mining District in Santa Barbara County is the world's largest source of commercial marine diatomite. Grefco Inc. exploration has defined a large embayment of commercial grade freshwater diatomite in Shasta County. Exploitation of this massive deposit could substantially increase California's diatomite production.

Jan 1, 1980

In early 1970, General Mills Chemicals, Inc. announced the availability of en improved liquid ion exchange reagent, LIX® 64N, for the recovery of copper from various solutions, such as dump leach liquors. LIX 64N has been shown to be a considerable advance over LIX 64, and is presently in use in three commercial plants. Results have been very gratifying. For example, one of the plants was designed for operational production of 40,000 pounds copper per day, and in fact reached this output within the third week following startup of the plant. In addition to the operating plants, another is scheduled to come on stream this month with L D( 64N being used to extract and recover both copper and nickel. The chemical properties and operating characteristics of this reagent have been fully described in a previous paper. 1 LIX 64N is quite an effective and selective extractint for copper, even with copper contents as high as 15 g/l, but the reagent is somewhat limited in pH range, and loses some of its extraction efficiency as the pH drops below 0.8. Liquors derived from vat leaching, electrolytic tankhouae bleed streams, or some of the new leach schemes derived to solubilize copper from sulfide concentrates are examples of the liquors that present major problems when treated via liquid ion exchange. LIX 64N could extract some of the copper from such streams, but recovery was limited to about 75 percent. Also, in some parts of the world there are streams which are relatively low in copper (-5 g/l) but which are very high in acid (25-50 g/1 H2SO4). Again, LIX 64N can attain only about 75 percent recovery from such streams. For effective treatment, these streams require a reagent which will maintain the excellent selectivity of LIX 64N, and will

Jan 1, 1971

By Mike Wardell-Johnson, Chris Campbell-Hicks, Craig Bitmead

Faster, simpler, cheaper and more accurate cyanide ex­tractable gold procedures are now available for grade control assay. Cyanide 'bulk leach extractable gold' or BLEG assays have previously been seen as desirable, due to the large sample size that can be treated, but not in common use due to the 24hr total assay time required. Sample sizes from 50g to several kilos can now be accurately assayed in less than 4 hours total time with the larger sample size increasing accuracy, without loss of precision, while greatly reducing the 'nugget effect' or coarse gold bias. Typical assay size is 200g, equivalent to 4 x 50g Fire Assays or 10 x 20g Aqua Regia Assays. Ongoing modifications and refinement of the procedures and reagents used also indicate applicability to the treatment of coarse gravity gold where substantial savings in both capital and operating costs for these circuits are possible. The successful use of this cyanide assay at the Bannockburn and Windine Well operations are cited to-gether with a compre­hensive comparative testwork program by Newcrest. Testwork at Gidgee and Lynas Gold operations is currently being initiated. Other operations using the method include Red Dome and Kidston; with Placer(Granny Smith) and PMA's Palm Springs operations to commence shortly.

Jan 1, 1995

By Sakai Kunito, Nigel B. Sugden

If an Earth Pressure Balance (EPB) TBM is operated effectively tunneling can be carried out producing negligible ground movements. Using the methods given in this paper face losses of the order of 0.5% and less are generally obtainable using an EPB. Operating the EPB TBM in this manner reduces the requirement for the building protection measures used to protect surface structures. This can result in a considerable cost saving for the construction of a tunnel under built up areas. This paper to give guidance on the causes of ground movements around a TBM and the methods of running an EPB TBM that will minimize those movements. Details of how this was successfully done during the construction of the Bangkok Metro are given. The paper is split into three parts as below. 1.Causes of ground movements due to TBM tunneling 2.Methods of controlling those movements using an EPB TBM 3.Case history Bangkok Metro (water main)

Jan 1, 2001

By Daniel P. Farjeat, Hector A. Canseco, Juan M. Schmitter

Since the early sixties, tunneling in the soft clay of Mexico City, has been done with the aid of open face shields and recently with compressed air. The use of pressurized shafts up to 1.5 kilograms per square centimeter, (147 kilo pascals) with vertical locks to launch the shields, have been used in two cases. After advancing almost 200 meters of tunnel, the same vertical locks were transformed into horizontal locks, to continue the work. Due to the high decompression times involved, it was necessary to install long locks, using the tunnel itself as part of the system. This article describes those cases.

Jan 1, 1981

By Angela K. Braden

Igneous rock exposures occupy only a minor portion of surface area (<18 mi2) in Arkansas, and are divided into two major groups: nepheline syenite (7 mi2) and syenite complexes (8 mi2), with various dikes and sills representing the remaining surface exposures. The syenite complexes have been the sites of major vanadium and minor titanium production during the past 50 years. Nepheline syenite exposures were important in the early production of locally used building stone; however, aggregate and roofing granules have now become the principal market for the production of nepheline syenite in Arkansas. Nepheline syenite intruded into a sequence of Paleozoic sedimentary rocks in Arkansas and is exposed in two areas: in Saline County near the town of Bauxite, and in Pulaski County at Granite Mountain, just southeast of Little Rock. Although the central Arkansas region had been investigated thoroughly for bauxite by the early 1950s, the nepheline syenite resources of the region have yet to be evaluated systematically by the state. Arkansas nepheline syenite was evaluated for its ceramic uses in 1952. Some recent industry interest has revolved around its potential use as a sand-blast abrasive. The largest exposed areas of nepheline syenite, located at Granite Mountain, currently are being mined by the Minnesota Mining & Manufacturing Company (3M) and McGeorge Contracting (Granite Mountain Quarry). 3M has been in operation since 1947 and mainly produces roofing granules. A fine powder produced by 3M during crushing that is marketed under the name Donnafill? recently has seen use as filler in self-compacting confined construction and as an additive (frit) in common brick. Since the early 1960s, Granite Mountain Quarries has produced a variety of aggregates, ranging from riprap to industrial sand, and recently constructed a computerized hot-mix-asphalt production facility. Approximately 4.5 million tons and 1.2 million tons of syenite were produced from Granite Mountain and 3M, respectively, during 1979. No production values are available after this date; however, combined production from both quarries is estimated to be at least 6 million tons annually.

Jan 1, 1999

By J. Willison

Over the past decade, the coal mining industry has faced the difficult task of remaining profitable in the midst of declining market prices. Historically, the industry has been quite capable of meeting this challenge by various means. As total costs to mine and market coal continue to increase, new methods of tackling the problem must be implemented. Studies have shown that although many options exist to influence both inby and outby costs, the greatest potential remains in addressing costs at the coal face. Mining operations can positively effect a change in their profitability by either reducing costs, or by increasing production to in turn lower their net cost per man-hour. Original equipment manufacturers can play a key role in both options through the introduction of new technology that permits higher extraction rates, as well as other advantages leading to lower cost coal. A leading advancement over the past 30 – 40 year period has been the advent of progressively higher voltages to operate the mining equipment. This advance enables higher power transmission for a given cable size, operation at lower amperages resulting in less voltage fluctuation, and reduced heat on the cable and electrical components.

Jan 1, 2003

By S. K. Kawatra, K. J. Shoop, T. C. Rao, T. C. Eisele

This study investigates the use of a horizontally- baffled column (7.6 cm inside diameter by 344.2 cm high) to reduce the ash content of a high ash bituminous coal. Tests were carried out to determine how the baffled column responded to changes in feedrate, reagent dosage, and feed quality, and to compare its performance with a conventional column installation in an operating plant. In this paper, the results of this investigation will be reviewed and discussed.

Feb 24, 1997

By Nicola Beltrandi, Andrea Pigorini, Holad Mohamed Dahir, Ezio Pedone

"Genoa is a very distinctive city located between mountains and the sea and infrastructural upgrading works often have to deal with the intersection of existing infrastructures. This is the case for the new railway tunnel construction between the stations of Brignole and Principe which under-cross two existing double-track tunnels in operation. The latter have been constructed with masonry bricks and the vertical distance between old and new tunnels is approximately 1m. Due to rock characteristics and the urban environment, stability and vibrations control are the main issues. Consolidation work with the fore-poling method and a specific sequence of excavation, primary lining and final lining support have been designed to assure stability and settlement control. A hard rock road-header has been used to assure vibration control. Finally, a real time monitoring has been implemented. The article presents monitoring and back-analysis results of the under-crossing of the existing tunnels. GENERAL LAYOUT OF WORKS The Genoa railway junction constitutes an integral part of the Ventimiglia-Genoa-Novara-Milan railway line route and it is included amongst the railway systems of the Tyrrhenian-Northern European multi-modal corridor (corridor of the two seas or corridor VII Genoa-Rotterdam). The main aims of the project concern the upgrading of the existing lines and the separation of the long-distance passenger and freight traffic flows from those of a regional and metropolitan type. The project includes: •,Completion of the connection with the port of Genoa Voltri and the Italy-France coastal route. •,Interconnection with the future Terzo Valico dei Giovi mountain pass route towards Milan. •,Upgrading of the Genoa Voltri – Genoa Brignole main line to four/six tracks. Rearrangement of the systems at the Genoa Voltri, Genoa Sampierdarena and Genoa Brignole Stations, reorganisation of the services in the Genoa Terralba area and interchangeability with the metropolitan system complete the design activities. The contract which includes civil and technology works is divided into four construction lots (ref. Figure 1):"

Jan 1, 2016

By J de Cuyper, S. R. Rao, J. Leja, K. S. Moon, W. Freyberger

A prolonged grinding of sulphide ores in steel mills appears harmful to flotation recovery and selectivity whenever xanthates are used as collectors. Particles finer than about 10um show a pronounced decrease in floatability. A supposition was made that the cause of the reduction in floatability of ground sulphides is the presence of metallic iron abraded during grinding and deposited on the ground particles. Electro- chemical measurements were made of mixed potentials developed by different sulphide-mineral electrodes (galena, chalcopyrite, pyrite, marmatite, pyrrhotite) in xanthate solutions, without a direct con- tact or in contact with a metallic iron electrode. These measurements showed that without a galvanic contact between the sulphide and the iron, the values of mixed potentials were in the vicinity of the xanthate/dixanthogen redax potential. When contact with iron was established, the mixed potentials shifted towards the more negative reducing or cathodic values, The shift was greater the higher was the ratio of the surface areas: iron electrode to sulphide electrode. Further, the shift in mixed potentials was greater the more reducing were the conditions on the sulphide electrode. Chemical analysis of reaction products produced on the surfaces of sulphides and in the bulk solution showed that less thiosulphate was formed in all of the sulphide-xanthate systems and that more elemental sulphur was detect-

Jan 1, 1976