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By M. C. Williams, T. P. Meloy

For over thirty years the Population Balance Model, PBM, has been the mainstream modeling method for comminution unit operations and comminution circuits. For commercial comminution circuits the method is based on erroneous physics and dubious numerical mathematical methods leading to non unique solutions that have little extrapolative value and faulty control strategies. In short the PBM is wrong. Given is a detailed analysis showing a number of non trivial flaws in the linear PBM. Moreover, a simpler model is presented that leads to a solution of the comminution circuit predicting the size distribution output over a variety of conditions. Because the linear PBM is firmly entrenched, an award is offered, $10,000, to any researcher that can use the linear PBM and its present numerical methods to predict the typical straight line, self similar, output of wet mills over a variety of grinding times.

Jan 1, 1992

By Ruiren Jin

In alkaline pulp, galena is depressed by sodium carboxymethyl cellulose (NaCMC), while Cu(II)-activated sphalerite exhibits a high flotability so that satisfied separation can be achieved. In addition to hydrogen bonding, chemical bonding of NaCMC with galena is confirmed by IR; only hydrogen bonding is involved between NaCMC and Cu(II)-activated sphalerite. It is also found that the greater the degree of substitute and polymerization of NaCMC, the stronger the depressive effect of NaCMC and that lower stirring speed favors the depression.

Jan 1, 1987

By M. Plesha, A. Zubelewicz, K. Connor, T. B. Belytschko, O&apos

INTRODUCTION The Northwestern University Rigid Block Model (NURBM) has been extended to explicitly model dilatant behavior of rock joints. By incorporating dilatancy, the resistance to shear displacement and slip, which previously was limited to simple Coulomb friction, along edge-to- edge contacts is now provided by contact roughness as well as frictional resistance. The explicit formulation is based on concepts presented by Plesha (1985) in which a plasticity-based phenomenological approach was used to model dilatant joint behavior. This approach has been modified to allow for joint closure upon reversal of shear deformation. After presenting a brief description of the new joint constitutive relationship, model behavior will be illustrated with two examples. The first involves a simple two-block model to simulate a cyclic direct shear test of a single joint. The second example involves simulation of a large cavern in a moderately jointed rock mass subjected to cyclic excitation. It will be shown that in- creasing joint roughness increases cavern stability by interlocking of adjacent blocks. JOINT CONSTITUTIVE RELATIONSHIP Within NURBM adjacent two-dimensional rigid blocks interact along their common edge-to-edge contact with contact forces transmitted at the contact midpoint. The contact constitutive relationship was originally restricted to a Coulomb friction yield criterion with no tensile stresses permitted along the smooth contact surfaces. The local coordinate system for any contact is described as shown in Figure 1 with the elastic stresses and displacements related by the linear- elastic constitutive law: [ ] The contact microstructure has been modeled as Patton-type saw-tooth surfaces such as shown in Figure 2. Sliding can be active along the right asperity with angle aR and length lR or along the left asperity with angle a and length lL. In general, aR and aL will difkr as will lR and lL but for purposes of this paper it has been assumed that these angles and lengths are identical. By a simple transformation, the microscopic asperity stresses can be expressed in terms of the macroscopic contact stresses [ ] If Coulomb friction is assumed along the asperity surfaces, the plastic slip condition will be [ ] where µ is the friction coefficient with the convention that compressive stress is negative. When F is negative, the behavior is elastic and when F is zero, slip can ensure. When plastic slipping does occur, it is assumed that the relative tangential and normal displacements between the two contacting rigid blocks are additively composed of recoverable elastic parts and nonrecoverale plastic parts, [ ]

Jan 1, 1986

By I. Pordea

The materials used for the construction of buildings contain natural radionuclides of the U238 and Th232 series and are ? 50% due to land radioactivity. Another component of natural radioactivity is K40, with ? 40%. The presence of these radiopollutants in the final products (i.e. bricks, concrete) due to body irradiation is by two pathways: external irradiation and internal irradiation. External irradiation is due to gamma radiations emitted by Pb214 (RaB) + Bi214 (RaC) from the U238 series, by Ra228 (Mezothoriu I) + Ac228 (Mezothoriu II) + Tl208 (ThC??) from the Th232 series and by the K40 radionuclide. Internal irradiation is due to inhalation of radon (Rn222) and Rn220 (Tn) plus short life descendents (Po, Pb, Bi), radionuclides which are present in concrete. A fraction from radon present in concrete enters into a house leading to internal irradiation by inhalation. In Romania, the maximum concentration of radon allowed for new buildings is 200 Bq/m3.

Jan 1, 2008

By Y. A. Attia, D. K. Sengupta, H. A. Hamza

Increased recycling of waste paper has been emphasized in recent years in both the United States and Canada for environmental and economic reasons. Removal of ink particles from waste paper pulp is therefore necessary. One of the most promising methods for ink removal is froth flotation. This study investigated the feasibility of a simplified flotation scheme and found that about 90% to 92% ink removal can be achieved. Also, a 95% to 97% ink removal is achievable if a hydrophobic polymer is used ahead of the flotation stage. Clean paper pulp recovery was over 90%. The effects of pulping pH, flotation pH and concentrations of flotation and polymeric reagents are discussed in the paper.

Jan 1, 1995

By Paul D. Chamberlin

There are many unit operations applicable to the processing of gold/copper ores. Deciding which are most applicable to your ore can be done using a series of tree diagrams. The diagrams show generalizations, not definitive rules. And the listing of process alternatives on the diagrams is very limited although there are dozens to choose from. Three questions help point the way to proper process selec-tion: 1. How much gold is in the ore? 2. How much copper is in the ore? 3, What is the cyanide consumption when leaching the ore?Halogens can also effectively leach gold ores and gold/cop

Jan 1, 1996

By Glenn Mallory, Margarete Kalin, Ben Romanin

A waste management area of a copper zinc mine which is expected to be generating acid exceeding 1000 years is used as a research facility to develop a passive treatment approach to decommissioning the site. One of the processes proposed to be implemented in a lake with a one million cubic metre volume is biological polishing. To determine the expected performance of the process, model is constructed from experimental data collected in the lake. The model results and the field data represent a weak fit, but the discrepancies are useful indicators of key factors affecting the process, such as iron cycling.

Jan 1, 1995

By S. Meng, R. Jin, W. Hu

In alkaline pulp, galena is depressed by sodium carboxymethyl cellulose (NaCMC), while Cu(II) -activated sphalerite exhibits a high floatability so that satisfactory separation can be achieved. In addition to hydrogen bonding, chemical bonding of NaCMC with galena is confirmed by infrared (IR) spectra; only hydrogen bonding is involved between NaCMC and Cu(II)-activated sphalerite. It is also found that the greater the degree of substitution and polymerimtion of NaCMC, the stronger the depressive effect of NaCMC and that lower stirring speed favors the depression.

Jan 1, 1988

By Annan Cook

Cyprus Metals' Sierrita mine is located in the Pima Mining District, Pima County, Arizona (Fig. 1), which is one of the largest known porphyry copper districts. The ore body is part of a large mineralized system that includes Cyprus' adjoining Esperanza mine. The copper and molybdenum grades being mined at Sierrita make it one of the two lowest grade porphyry copper mines in the world Mineral production from the district was first recorded in 1876. Copper from replacement deposits in carbonate rocks and copper¬-lead-zinc from veins in volcanic rocks were mined from several deposits. However, it was not until 1957 that the district commenced to become a major copper producer with the beginning of production from the Pima mine, which was the first open pit operation. Since that time, seven other open pit mines have come into production. Because of the variable copper prices and high operating costs, not all of the mines are operating today. A map of certain outcrops, plutons, and open pits, as well as older underground mining operations, in the Pima district is shown in Fig. 2.

Jan 1, 1991

By Victor F. Hollister

Porphyry copper deposits can be categorized into three models for purposes of prospect evaluation: Breccia-pipe, modified Lowell and Guilbert, and diorite models. The modified Lowell and Guilbert model is normally associated with a quartz-bearing intrusive and a potassic, phyllic, argillic, and propylitic alteration sequence. Variations can occur in the alteration zones of this model that range from orthoclase-rich (Kalamazoo, Silver Bell, and Mineral Park) to ortho- clase-deficient (Petaquilla and Bougainville) potassic zones. The unifying features of the model are the presence of a phyllic zone and a quartz-bearing intrusion. The breccia-pipe model (Toquepala) is characterized by structure and alteration related to or controlled by breccia. Where tourmaline occurs in the breccia, the identity of the model is usually clear. However, if tourmaline is not commonly developed in the breccia (La Caridad), the deposit can be misidentified as to model. Porphyry copper deposits associated with quartz-deficient intrusives, whether these are calc-alkalic diorites or alkalic plutons, are characterized by alteration suites distinct from those of the modified Lowell and Guilbert model. These have been generalized as diorite model porphyry deposits. Because alteration and mineralogical development in diorite model deposits is distinct from that of the modified Lowell and Guilbert, ore guides and exploration tactics differ for the two models. The reprint that follows describing the three prospecting models summarizes their features. It is to be emphasized that these are models used in exploration for specific deposit types and are not genetic, tectonic, or geographic models. Porphyry copper deposits can be metamorphosed. Gibralter is an example of a Lowell and Guilbert model deposit that has undergone regional metamorphism.

Jan 1, 1991

By S. Chander

The effect of pretreatment potential on the response of a gold electrode for Eh measurements in sulfide solutions was examined in terms of measured Eh values and electrode response time. The electrode response time is defined as the time required for the electrode to reach a steady-state value. The relationship between measured Eh values and the hydrosulfide ion concentration is established. The effect of pH, the reversibility of the gold electrode in the sulfide solutions, and the reproducibility of measurements are also investigated. A mixed potential theory is proposed to explain the observations.

Jan 1, 1989

By Derek J. McCracken, William G. Holroyd

Emery is a rock that at one time held a large share of the abrasives market. The introduction of synthetic abrasives, however has forced it to settle for only certain niches in the marketplace. This loss of market share is due mainly to the higher amounts of impurities and weaker internal structure that naturally occurring minerals have compared to manmade materials. The use of rocks and minerals as abrasives dates back to early man, who used flint, quartz, and other natural materials to fabricate various tools. During the 19th century, with the Industrial Revolution imminent, the character of the abrasives industry was changed forever as synthetics were introduced. Frank B. Norton is credited with producing the first manmade abrasive when, in 1855, he manufactured a vitrified grinding wheel using emery grit and clay. Before Norton's accomplishment emery had been the only commercially available abrasive. The latter part of the 20th century has seen synthetics capture an increasing share of the abrasives market from natural materials. The term emery is believed to have been derived from the words emeri (French), smeriglio (Italian), and smiris (Greek). The term corundum, for the principal mineral of emery, seems to have originated from kauruntaka, the Indian name for the mineral. GEOLOGY Emery is a gray to black, granular rock comprised of various minerals including corundum (A1,0,), an iron-bearing mineral (usually magnetite-Fe,O,, hematite-Fe,O,, or hercynite- FeAI,O,), and several trace impurities such as mullite, titania, silica, and magnesia. The hardness of emery normally ranges between 7 and 9 on the Mohs scale, depending on its mineral com- position and level of impurities. Corundum, the hardest mineral in emery, typically has a hardness of 9. The specific gravity of emery ranges from 3.2 to 4.5, also depending on mineral composition and purity. The crystallography of each mineral contained in emery differs somewhat. Corundum exhibits an hexagonal crystal structure, whereas magnetite forms within the isometric system, frequently as octahedral crystals. Hercynite, an iron spinel, is also isometric. Hematite has an hexagonal structure but often is found as botryoidal and reniform masses. Principal deposits of commerical emery are found in the United States, Turkey, and Greece. In the United States two emery producers in the Westchester County-Peekskill area and one in the Cortlandt County area of New York closed their mines in the late 1980s. Commercial production in the United States now comes only from the western Cascade Range in Oregon. The emery in New York has a typical A1,0, content of 41.5%. Most of the rock is not true emery because it contains a mixture of spinel and magnetite but very little corundum. The deposits are of Late Ordovician-Early Silurian age and consist of veins in which emery is mixed with olivine, pyroxene, and hornblende. The veins evidently were formed by contact metamorphism and are surrounded by Precambrian schists that contain mica, sillimanite, cordierite, garnet, and quartz. The deposits in Oregon were formed during Miocene time by the contact metamorphism of ferrunginous bauxite by intrusive lamprophyric dikes and plugs. Emery is found in thin layers bordering these tabular dikes, which are usually oriented perpendicular to bedding, and in "surficial placer deposits. The emery deposits in Turkey occur as small, massive, lens- shaped bodies and as surficial placers. They are believed to have formed during Permian and Triassic times. In Greece the principal site of emery production is at Cape Emeri on the Island of Naxos. These deposits consist of lenticular masses of emery surrounded by marble. They originated during Mesozoic time, evidently by metasomatic replacement. Smaller deposits on several other Aegean islands were formed by the metamorphism of bauxite or other alumina-rich materials.

Jan 1, 1994

By B. Mishra, A. Staley, D. Kirkpatrick

The major waste product of the alkaline extraction of alumina from bauxite (Bayer Process) is known as red mud. Approximately one ton of red mud is produced for every two tons of bauxite mined. The red mud produced from Jamaican bauxite is rich in hematite, alumina and titanium oxide. It has been shown that more than 90% (by weight) alumina can be recovered from red mud by soda ash sintering and caustic leaching. Hematite can be carbothermically reduced with a degree of metallization of more than 94%, resulting in attempts, for magnetic separation. These separations are desirable because there are no waste products generated. Consequently, there is an opportunity for complete utilization of the waste material. Conversely, the preseparated material could be charged through the tuyeres in an iron blast furnace, or it could be smelted to produce pig iron. If smelted, the concentration of titanium oxide in the slag would be high enough to justify its recovery by an established acid-leach process. This paper describes the results of alumina recovery and the plans for titanium oxide recovery from red-mud. In addition, the situation of ongoing efforts in iron extraction, particularly, the method of magnetic separation of the reduced material. The problems associated with the use of reduced red mud as an alternative to direct-reduced iron (DRI) is also discussed. A critical assessment of the recovery sequence chosen for the products is described based on economics. Key words: Red mud, Waste product utilization, Alumina recovery, Titanium oxide, Iron

Jan 1, 2003

By W. A. Rickelton, A. J. Robertson

The ability of triisobutylphosphine sulfides to selectively recover silver from acidic sulfate solutions containing zinc and copper is described. Selectivity is explained in terms of the concept of hard and son Lewis acids and bases. Silver is stripped from the solvent using a novel strip feed (thiosulfate salt), and the recovery of metallic silver from the strip liquor by electrolysis or cementation is suggested. The high selectivity of extraction for silver and the utility of the stripping reagent are demonstrated in continuous, countercurrent, mini-plant tests. Important reagent properties, such as hydrolytic stability and low aqueous solubility, are discussed.

Jan 1, 1988

By Kenneth R. Dickson, I. Michael Gowring, Gary M. Davey

The Kemano Power Tunnel is currently being constructed by a joint venture of Atkinson, Kiewit, and Commonwealth. The 5.73 m diameter, 16.1 km long tunnel is part of the Kemano Completion Project in British Columbia, Canada which is being developed by Alcan Smelters and Chemicals Limited. The discussion includes the refurbishment and development of Robbins TBM 189-229 previously used at Calaveras (RETC Proceedings, 1987), the logistics of conducting a tunneling operation in a remote area with adverse weather conditions, in addition to a description of the work and the performance details in the various geological conditions encountered to date.

Jan 1, 1991

By P. M. Soupios

The study of soft soil (wastes above the rock bed) an issue of great importance in civil engineering, is usually addressed by drilling boreholes. This method is rather expensive and time-consuming and although the information obtained is usually accurate, on the other hand it is much localized. Recently published researches have demonstrated the ability of the combination of geophysical exploration methods to estimate the thickness of deposited wastes, which provides the layered structure of the study area and certain, method depended, mechanical parameters as well. By theory, the frequency of resonance of an upper layer is a function of its thickness and the average shear velocity in it. Furthermore, the application of H/V spectral ratios of micro-tremors is a fast, straight forward and cost effective methodology, yielding the determination of the main resonant frequency of the soil. Based on this framework, 20 microtremor measurements have been carried out in a Landfill in Heraklion-Crete. Some of these measurements were deliberately close to drilled sites, where the basement had been reached. Three electrical resistivity tomographies were also used, in order to define the landfill structure such as, thickness, determination of different wastes distribution in the study area and other parameters. In addition, estimation of predictive Vs using empirical relationship between shear velocity and penetration resistance (SPT?s) were also conducted. Knowing the thickness and the resonant frequency, we estimated the shear (Vs) velocity of the waste cover. The final Vs model was confirmed using the results from the Vs-SPT correlation. The combinative implementation of the above mentioned geophysical and geotechnical methods have successfully defined geometrical and geotechnical/geophysical characteristics of the area under investigation in a fast and cost effective way.

Jan 1, 2005

By T. Weimer

Gasification of carbonaceous energy carriers with simultaneousCO2 removal is a new and interesting alternative e.g. ZECA [1],HyPr-Ring [2], AER [3]. In the ZECA process lime supported Hydrogen generation from Methane is a basic process unit and the Hypr-RING process investigates Hydrogen generation from hard coal with addition of lime. Here the main objective is a further development of the AER process. High energetic efficiencies for gasification in the range of 90 % can be achieved if the humidity of the energy carrier is already sufficient for steam reforming reaction. The aim of the overall process is upgrading coals and biomass yielding into three valuable products: • A fuel gas ready for power generation • A CO2gas stream containing >95%, ready for transportation to disposal or chemical fixation • A pre-calcined feed for cement clinkering consisting ofCaO and coal ash Thus power generation and gasification are independent. A promising industrial application is the combination of gasification and cement production. Then only one additional reactor is required and the precalcination mass flows have to be increased.

Jan 1, 2004

By W. Kemp Wait

Electronic ore sorting is a coarse particle beneliciating process which performs a function which in the past was primarily achieved through the use of hand picking belts. Photometric ore sorting is capable of separating waste from mineral bearing rock having a distinct difference in surface light reflectance levels. This type of ore sorter can be applied to gold and silver ores which are contained in quartz veining. Photometric ore sorting has been used at gold mines in South Africa as well as the Black Pinc silver mine in Montana. A new ore sorter has recently been developed with precious metal ores in mind. This ore sorter is capable of sorting ores on both photometric and conductivity sensing parameters. The first production machine has been installed at a gold mine near Beardmore, Ontario and currently is being used to process low grade waste dumps.

Jan 1, 1998

By W. R. Bush

Radiation protection in uranium mines and nuclear reactors is compared, with the objective of determining if any radiation protection practices which have worked well in one area can be adapted to the other area, especially from reactors to mines since radiation protection is more highly developed in reactors. Several areas are identified where improvements can be made in radiation protection in mines, the most important being improvement in ventilation at the workplace, greater attention to special monitoring during upset conditions, and a need for a substantial increase in radiation protection staff. It is concluded that, although considerable room exists for improvement, the general approach to radiation protection presently being followed seems appropriate for the circumstances encountered in mining.

Jan 1, 1981

According to the Balandin's (1) "multiplet theory of catalysis", adsorption can occur only if atoms of the reactant molecules are congruent with surface atoms of the catalyst. Such a condition calls for certain definite geometrical relationships between the reactant molecules and the atoms at the surface of the catalyst. If such a match or geometrical 'fit' is not provided, the surface reaction will not take place. An appropriate analogy to this may be the lock and key theory that enzymes should fit a substrate just as a key fits a lock. Similar geometrical considerations in adsorption studies were made in connection with the flotation of minerals. Gaudin(2) and Gaudin and Preller (3) proposed that if the dimensions of collector ions are in registry with the mineral lattice, an ordered layer of adsorbed species is formed. They explained that the structural fit is one reason for good flotation of galena with xanthate. In another study, Bachmann (4) attributed the selective flotation of KC1 from NaCl with amine to the fact that the lattice parameter of the amine collector is closer to that of KC1. Schubert(5) investigated the flotation of various nonmetallic minerals with amine and pyridine, and related the dimensions of the collector ions with the anion distances of the mineral surface. He concluded that good flotation is obtained when the tolerance is within 20%. The geometrical theory has also been used by Groszek (6) to explain the preferential adsorption of n-paraffin onto the basal plane of graphite. The geometrical theory has thus been found useful in explaining adsorptive properties of an adsorbate relative to the substrate structure. The purpose of the present work is to examine the possibilities of a geometrical fit between sodium dodecyl sulfate and Cu(OH)2 surface, and to construct a crystallographic model of the surface compound.

Jan 1, 1974