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By Archie W. Fletcher, R. J. Wesely, Nathaniel Arbiter, A. D. Zunkel

In contrast to pyrometallurgy's six thousand year history in the production of metals, that of hydrometallurgy is of relatively recent origin. The earliest reference to it at all was in the 16th century, with the first applications to copper in the 17th and 18th. In the 19th century, increased demands for pure metal resulted in development of electrolytic refining, and early in this century electrowinning. The rapid growth in wpper production in the present century, paricularly in the United States and Chile, stimulated the development of new technology for leaching, and for the recovery of copper from leach solutions. Solvent extraction has become a major factor during the past quarter century by permitting novel leaching technology which produces dilute or complex solutions. In addition, solvents other than sulphuric acid, and chemical methods for precipitating copper metal are now of increasing interest. These are trends which should grow in importance in the future with the need to process lower grade and more complex materials. The evolution of copper hydrometallurgy is reviewed briefly and key factors in recent major developments are presented with details of specific operations and with trends for the future indicated. The relative importance of copper hydrometallurgy is compared to that of pyrometallurgy in the light of probable changes in ore supplies and character.

Jan 1, 1993

By A. MacG. Robertson

INTRODUCTION The tailings, or solid waste, remaining after uranium has been extracted from an ore and the liquid wastes associated with it contain both radioactive and other substances which, if released to the environment, may have a detrimental impact on man and his environment. Although the radioactivity of the waste is of natural origin, the mining and milling process results in bringing the radioactive ore to the surface, changing its chemical and physical form, increasing its mobility and, therefore, enhancing the potential radiological exposure to man. Exposure to radionuclides released from a tailings impoundment, while small as applied to any one generation, can be made large by counting far into the future, large enough to be the dominant source of exposure from the nuclear fuel cycle, Cunningham (1978). Increasingly it is being found that where the prime concern was initially the radionuclide releases, the release of other pollutants and contaminants may be of equal or greater concern. While there is a definite benefit, at least to present generations, resulting from the recovery of uranium, current and long-term concerns require that consequential present and future releases be kept as low as is reasonably achievable. Design practice, to minimize this release, is currently passing through a technical revolution; precipitated by public and institutional concerns. New techniques and methods are, therefore, being actively sought and continuously implemented. Because of the complexity of the pollutant release mechanisms and the sitespecific nature of each impoundment site and tailings product, a wide variety of site selection and design options have been implemented or considered. It is often possible to design a number of satisfactory tailings disposal schemes which differ widely in nature and cost. This paper outlines the principal areas in which options are available and discusses some of these options. Both operating and post-decommissioning conditions are consi-

Jan 1, 1980

By J. B. Rubinstein, V. J. Badenicov, S. T. Hall

A simulation technique of the flotation process and models for the solution of various problems are developed. A modular model of column flotation is constructed taking into account the kinetic relationship of the process and the hydrodynamic regime in the cell. Based on this, a technique of calculating the column parameters based on laboratory tests is developed (scaling-up), and applied for calcetest results is developed (scaling-up), and applied for calculating the design of commercial-scale columns.

Jan 1, 1996

By Fathi Habashi

THE MOST important arsenic minerals are shown in Table 6-1. The recovery of arsenic from arsenic sulfides is treated in Chapter Four. Arsenical ores may be either leached directly, or first smelted to volatilize as much arsenic and sulfur as possible, and the resulting product, called speiss, is then leached. A speiss is mainly a complex mixture of metal arsenides, but its [Table 6-1. Arsenic minerals. Arsenides Niccolite NiS Smaltite CoAs2 Skutterudite CoAs3 Sulfarsenides Cobaltite CoAsS Enargite CuaAsS4 Arsenopyrite FeAsS Arsenic sulfides Realgar As4S4 Orpiment As2S3] composition varies widely, depending on the type of ore treated. A speiss usually contains 15-35% arsenic. Methods of leaching are describedd in the following paragraphs.

Jan 1, 1970

Historian and storyteller, Duane Smith, will be the keynote speaker at the National Mining Hall of Fame's 10th anniversary induction banquet on Saturday, Sept. 6,1997 in the Museum Convention Center at Leadville, CO.Smith is a professor of history and southwest studies at Fort Lewis College in Durango, CO. He is also an award-winning author of 28 books about the West and mining. Hall of Fame Board Chairman Richard Moolick said the induction banquet event will mark the National Mining Hall of Fame and Museum's 10th anniversary in its Leadville facility, a century-old Victorian schoolhouse. Karl Elers, chairman of Battle Mountain Gold in Houston, TX, will be the master of ceremonies. He is a member of the National Mining Hall of Fame and Museum's board of directors. The six inductees into the National Mining Hall of Fame will be enshrined by Thomas Falkie, president of Berwind Natural Resources of Philadelphia, PA. He is also chairman of the Mining Hall's board of governors. The six inductees will join 132 mining greats who were previously honored. The black-tie (optional) banquet will be highlighted this year by guests who prefer to don 1890s dress for the occasion in the old silver-mining boomtown. A cocktail reception and open house will precede the banquet, with tours of the district and special events to follow on Sun- day, Sept. 7.

Jan 1, 1997

By E. Bane Kroeger

Plane failure in rock and soil slopes is usually caused by the intersection of a discontinuity plane with a slope face. Normally, these discontinuities are weaker than the surrounding intact rock and provide a surface along which movement can occur. The discontinuities are typically analyzed to determine the stability of a particular slope. One problem that arises when evaluating the stability of a planar feature is that the method for planar analysis is two-dimensional and has difficulty dealing with planes that are oblique to the slope face. Several researchers have stated in the past that planar failures are a special case of wedge failure. Wedge failures occur when two planar discontinuities intersect in an unfavorable manner. Sliding can occur along the intersection of the planes. Wedge failures are very common in rock slopes and can often be problematic. Wedge stability analysis methods are typically three-dimensional and can analyze planar features that are very oblique to the slope face. Wedge failure analysis can also be used to determine the stability of planar features with good success. One advantage to using wedge analysis over plane analysis is that a tension crack can be both non-vertical and oblique to the slope face in the wedge analysis. This allows the engineer to more closely match field conditions. It also negates the need for the engineer to have two separate software packages to analyze a single slope, saving both time and money.

Jan 1, 2002

By H. Richard Eisenbeis, Donna M. Watkins

Many technical professionals (tp)* desire to occupy upper level management positions. But career paths for most scientists and engineers do not extend beyond their specific disciplines. This is unfortunate. Our technical frontiers are expanding so rapdily that it is difficult, if not impossible, to make sound top management decisions without understanding the technical complexities involved. Technical professionals often are not considered for upper level management positions because they lack the managerial and interpersonal skills necessary to become successful administrators. You've heard this before, but a key component of these skills is the ability to communicate. Technical professionals are often unable to communicate as well as they should with nontechnical professionals and nonprofessionals within the organizations that employ them. Communication is important for managerial success Communication is the network of interactions whereby knowledge and understanding are conveyed from one social set to another (Flippo and Munsinger, 1982). In order to be successful, managers must not only be "good" communicators, they must be "effective" communicators as well. Good communication occurs when managers are able to formulate and transmit their messages in such a way that they are received and understood. Effective communication goes one step further: It occurs when recipients accept messages as legitimate and respond to these messages in the manner desired. Before promotion into upper level positions, managers must have developed organizational skills (planning, decision making, organizing, and controlling) and interpersonal skills (directing, influencing, and motivating). Applying these skills effectively is difficult without a highly refined ability to communicate. Effective communication, then, is basic to managerial success. Nowhere, perhaps, has the importance of being able to communicate effectively been emphasized more than in Mintzberg's landmark study of managerial roles (Mintzberg, 1973). Mintzberg's results indicate that executives typically averaged 36 written and 16 verbal contacts a day. These contacts were both important and trivial. They generally occurred in a random manner. Time spent on each varied. Scheduled meetings averaged over an hour. Desk work, telephone calls, and unscheduled meetings required an average of 15 minutes or less. Why technical professionals have difficulty communicating Three reasons why technical professionals do not communicate well are: • The work motivational patterns and personal attitudes of technical professionals are not conducive to effective communication. • Students in technical professions are not encouraged by educational institutions to develop their communication skills. • Organizations do not insist that all technical professionals be able to communicate in the language of business. The work motivational patterns of most technical professionals are indicative of internals and high achievers (Hunt, Salisbury, and Whittington, 1968). As internals, they believe they control their own destinies. As high achievers, they believe that task accomplishment is a primary indicator of success. To ensure a task is completed in the manner desired, tp's attempt to structure and define work situations so they alone are responsible for results. TPs consider the task accomplished when they, and perhaps other tp's, are satisfied with the results. From the tp's perspective, the task may have been completed. From a communication standpoint, two other factors may apply. First, solving the problem required very little interaction (and thus, communication) with others. Second, the tp's, considering the task accomplished, have little concern for how their "technical" answers will be translated to nontechnical persons needing

Jan 8, 1987

By Thomas E. Krakowski

INTRODUCTION This paper presents a method of calculation of internal moments and thrusts in tunnel liners of any material. The method is intended for hand calculation, but as it is numerical in nature it can be programmed for use in computers. The information required for design or analysis is presumed active internal and external pressures, the effective moment of inertia and cross-sectional area of the tunnel liner, the liner's modulus of elasticity, and the coefficient of subgrade reaction of the material surrounding the tunnel. Starting with active external and internal pressures and following the procedure described herein using the structural properties of the liner and surrounding medium, external passive reactions and internal moments and thrusts are calculated. The method is intended for use by design engineers. GENERAL Experience has shown that flexible tunnel liners have less internal bending stresses than those calculated using classical structural theory applied to free-standing arches. In fact, liners which are very flexible in relation to the surrounding soil or rock have virtually no bending moments when compared to free-standing arches supporting equal active loads. In order for this phenomenon to occur, the original active pressure diagram must be "modified" by additional external reactions (passive pressures) from the surrounding material, so that the thrust line within the lining follows the centroid of the tunnel arch more closely than that of a similar free-standing arch. These passive pressures are reactions developed through outward deflection of the tunnel liner. Thus, the outward moving portions of a

Jan 1, 1979

By R. C. Freas

Limestone is a basic raw material in the production of cement, lime, a wide variety of industrial products, and a significant percentage of the crushed stone produced in the United States annually. It is used in fluxes, glass making, mineral fillers, environmental applications such as flue gas desulphurization and water treatment, soil conditioners, animal feeds, and as a construction aggregate. This presentation provides an overview of limestone distribution in the United States, it’s production, the variety of products produced, and a brief review of the primary uses for limestone.

Jan 1, 2006

By Fernando Concha, Arturo Barrientos, María Cristina Bustos

Manufacturers referred to high capacity thickening as a filtration operation rather than thickening in spite of the fact that it is performed in thickeners and that conventional thickeners can be operated as high capacity thickeners by changing the feeding level and operate it in a different manner. In this work we derive a phenomenological model for high capacity thickening based on mass and momentum balances. The difference with a conventional thickening is the presence of a surface source within the variable domain. The model can be used to design, simulate and to develop control strategies.

Jan 1, 1995

By G. V. Basham

"Environmental audit" is a phrase that can raise the blood pressure of otherwise cool and calm corporate personnel. There is widespread concern that any organized effort to find environmental problems will do so and may result in the imposition of substantial liability against the business that engages in such activities. However, such audits can reduce rather than enhance possible liability. Relevant issues include: the role of the attorney in the process, liability risks associated with environmental audits, steps to maximize confidentiality of audit results, reporting requirements and use of audit results in a proactive manner.

Jan 1, 1995

By R. W. Smith

Though generally rather non-selective in nature long chain collectors nevertheless function in different ways in accordance with their own particular physical characteristics. Altering various parts of their structures such as chain length, type of chain, etc. can therefore substantially alter the adsorptive behavior of the collectors in a set environment. The effect of such structural differences of the collectors on physical parameters such as solubility, critical micelle concentration, acid or base strength, tendency to be expelled from the aqueous phase is discussed, as is also the effect of these parameters on flotation behavior.

Jan 1, 1989

By Arthur J. Borst, Joseph P. Gildner

In a recent National survey, Seattle topped the list for having the worst daily traffic congestion. To address this problem, Sound Transit is planning to build 40km (24 miles) of light rail, including ten kilometers (six miles) of twin tunnels with four subway stations 40 m (130 ft.) to 65 m (210 ft.) deep. The overall schedule is very aggressive and Sound Transit is preparing four separate heavy civil construction contracts for simultaneous underground construction. Three of these contracts are being considered for design-build. Final design will start in March2000 and all underground construction must be completed by the end of 2005.

Jan 1, 1999

By E. Piesch, M. Urban, G. M. Hassib

INTRODUCTION In radon dosimetry diffusion chambers with passive [a]-detectors are now in current use to investigate the long-term accumulated indoor exposure of radon and daughters. For the diffusion chamber developed at Karlsruhe the electrochemical etching technique (ECE) was applied to reveal [a]-particles in polycarbonate plastic detectors. Compared to conventional etching, the main advantages of the ECE are the large track diameter, simple track counting in a single field of about 1 cm2, stability of the latent tracks to humidity and temperature and ability for a long-term accumulation up to 1 year. The electrochemical etching system was designed to etch in one run about 101 foils by using a 200 W high voltage generator. The commercial available radon dosimeter system is applied for a country wide program of measuring radon in dwellings. Because of an increasing interest of radon monitoring in mines, environmental monitoring and personnel dosimetry the properties of several track etch detectors have been studied. In the comparative study, Makrofol E, LR 115 and CR 39 were used in the diffusion chamber to investigate the etching techniques, the relative efficiency, the measurable [a]-energy range, and the counting statistic for the measurement of radon concentration. THE KARLSRUHE DIFFUSION CHAMBER The design of the Karlsruhe diffusion chamber is presented in Fig. 1. The upper part of the chamber is closed by a fibreglass filter to separate radon from aerosols, heavy dust particles and radon decay products. Inside the diffusion chamber [a]-particles from radon and daughters are detected by two passive radon detectors, one on the bottom of the chamber and the other in front of the filter. With the fibreglass filter applied the diffusion time is about 1 minute for radon. Therefore, also short-term variations in the radon concentration are recorded by the track detector. Mainly because of the short halflife of thoron (56 s) only about 7 % of the thoron concentration is expected in the diffusion chamber. Radon monitoring provides the estimation of the long-term accumulated mean value of the radon concentration with a lowest detectable concentration of 0.1 pCi/1 after 3 months accumulation by using polycarbonate track etch detectors, an electrochemical etching technique and track counting in a single field of 1 cm2. The diffusion chamber was optimized for the polycarbonate track detector with respect to chamber geometry and detector position [1]. Table 1 presents data for 3 different diffusion chamber designs. The radon sensitivity of the diffusion chamber depends on the [a]-energy discrimination and the angular response of the [a]-track detector. The difference between foil No 2 and foil No 1 can be explained by an additional plate-out effect of radon daughters on foil No 3. The high sensitivity of foil No 3 compared to that of foil No 2 is caused by an increase of the effective volume and the effective area for [a]-particle from radon and from plated-out decay products, respectively. Additional experiments have been performed in order to investigate the electrostatic properties of the plastic material and the properties of the diffusion filter [1]. The properties of bare a-detectors were compared with those inside the diffusion chamber. In contrast to laboratory results, dust particles deposited on the detector surface or in the environment of the detector obviously affect the reproducibility of the bare detector significantly. After 4 months exposure in dwellings the scatter of 10 dosimeters exposed in the same room exceeds a factor of 3 compared to 15 % for the diffusion chamber. COMPARATIVE STUDY OF TRACK ETCH DETECTORS Detector types and evaluation technique In the comparative study the properties of the following plastic track etch detectors have been applied: - LR 115 from Kodak Pathé, France, is a red dyed cellulose nitrate layer of 13 µm thickness on a 100 µm thick polyester support. The holes appears as bright spots in a dark red background. In an optical microscope counting of through etched [a]-tracks which must penetrate the detector layer - CR 39 from Pershore, England, is an ally1 diglycol carbonate plastic of about 300 m thickness. The normal etched [a]-tracks are counted by an optical microscope and the ECE [a]-tracks by a microfiche reader.

Jan 1, 1981

By Warren E. Fife

This paper will discuss the application of a continuous miner using a fixed drum milling type cutting head for the underground mining of hard rock and salt ores. Continuous mining machines of the ripper chain cutting head, oscillating milling cutting head and boring arm designs have been used in rock and salt applications with various degrees of success. The large boring arm miners have been successful in potash, trona and salt, but they have not been successful in mining rock materials like iron ore. The main method used in underground mining rock materials is the conventional drilling and blasting the ore from the solid. This is particularly true for the harder, more abrasive copper and iron bearing ores. The softer salt based ores of potash, trona and rock salt can use several underground mining methods depending on seam conditions. Several of these methods use underground coal mining equipment that has been extensively redesigned to adapt it for use in mining noncoal materials. Conventional mining methods employ the use of a universal cutting machine to undercut or topcut the ore body before face drilling and blasting takes place to produce a smooth parting of the ore. The boring arm continuous miner is widely used in underground mining of potash and trona ores. It produces a tunnel with a smooth semicircular contour which results in good rib and roof stability. The ripper chain continuous miner is also widely used in mining the salt based ores of potash, trona and rock salt. They are used more frequently in Europe than in the United States and Canada. Some reasons for using the mechanical mining machines as opposed to the conventional drilling and blasting techniques for mining hard rock ore bodies are the resulting improved rib and roof control, facilitates selective mining of the ore body, and requires less man-

Jan 1, 1974

By Jack Garrity

The Asarco Mission Complex includes two milling operations around a large open-pit copper mine in southern Arizona. The ore body was discovered in 1953 and the complex has been in operation since 1959. The mills provide the concentration operations of crushing, grinding, flotation and filtering processes involved in processing copper ore. Smelting and other downstream processing are accomplished at other Asarco locations. The mine pays a smelting charge to the smelter, which is seen as a service to the concentrators. The higher the concentration of copper to the smelter, the lower the smelting charge is to the mine.

Jan 1, 1995

By Yannis Faitakis, Brenda M. Wright, Gail Powley, Mark Hamblin, Randy B. Paine

A major problem in the ore extraction process is the high degree of variation in the mix of materials that make up the mined ore. The mix of materials makes it extremely difficult to characterize and predict the behavior of the ore when it is processed. The Quality Production Database (QPD) tool was successfully used in order to predict and transfer information regarding the quality characteristics of the ore being delivered to the extraction and hydrotransport unit operators. This paper describes the use of QPD in the prediction of various ore characteristics at the Syncrude Canada Ltd. processing facility.

Jan 1, 2000

By H. J. H. Pieterse

This paper highlights the mineralogy of the Barrick Goldstrike Mines Inc. area. The mine is located at the north end of the Tuscarora Spur and is part of the Bluestar/Goldstrike subdistrict of the Carlin Trend. The Betze, Post, and Meikle Mine are major deposits located in the area. The deportment of gold, its leachability, and various process options are also evaluated. Particular emphasis is given to the practical and economic considerations of ore control, and routing of ore to a process option.

Jan 1, 1993

By Thomas H. Koenning, William E. Bruce

Determination of the state of a mine fire is an important function during firefighting and during rescue and recovery operations. It is imperative that an accurate, up-to-date assessment of fire conditions be available for persons directing such activities in order to avoid unacceptable risk to mine rescue teas and/or fire fighters. Many indicators which consist of ratios of the concentrations of fire gases have been developed over the years for determining the state of a mine fire. Results from numerous gas sample analyses are necessary for determining the trend of the fire. Some indicators are preferred because the influence of sample dilution, a frequent problem, is said to be eliminated. Definitions and examples of indicator6 found to be useful in diagnosing recent western U. S. coal mine fires are presented. Mine gas explosibility is an important subject also requiring rapid assessment. Example explosibility calculations are presented applying one widely used method. Establishing limits for withdrawal of personnel are discussed.

Jan 1, 1987

By H. D. Freeman

The Pacific Northwest Laboratory (PNL) is developing cover technology for uranium mill tailings that will inhibit the diffusion of radon to the atmosphere. As part of this cover program, an improved radon flux measurement system has been developed. The radon measurement system is a recirculating, pressure-balanced, flow-through system that uses activated carbon at ambient temperatures to collect the radon. With the system, an area of 0.93 m2 is sampled for periods ranging from 1 to 12 h. The activated carbon is removed from the radon trap and the collected radon is determined by counting the 214Bi daughter product. Development of the system included studies to determine the efficiency of activated carbon, relative calibration measurements and field measurements made during 1980 at the inactive tailings pile in Grand Junction, Colorado. Results of these studies are presented.

Jan 1, 1981