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By J. A. Brierley, S. N. McIntosh, C. L. Brierley, E. G. Baglin, E. G. Noble, D. L. Lampshire

The U.S. Bureau of Mines investigated column bioleaching as a means of recovering manganese from a domestic low-grade oxide ore. Manganese was solubilized from the ore using indigenous heterotrophic microorganisms and molasses as the nutrient source. The effects of medium flow rate, molasses concentration, and frequency of medium replacement on the rate of manganese extraction were examined. Results showed that flow rates between 0.4 and 8.1 L/min/m2 had little impact on manganese extraction, while an increase in the total amount of molasses applied during leaching directly affected the extent and rate of manganese extraction. Manganese extractions of more than 90% were achieved in 12 weeks of bioleaching in column tests using 500 g charges of ore. Sugar utilization by the microorganisms and formation of organic acid metabolites were monitored by high performance liquid chromatography (HPLC). Two methods were evaluated to recover manganese from the sugar- depleted bioleaching medium: (1) adsorption onto weak cation exchange resin, followed by stripping and precipitation techniques; and (2) direct precipitation of the manganese as MnCO, using ammonium carbonate. Both recovery methods removed at least 95% of the solubilized manganese from the medium as a carbonate salt. The stripped molasses medium was replenished with fresh molasses and recycled back through the bioleach column, successfully leaching more manganese.

Jan 1, 1993

By R. D. Begley, A. W. Khair

This paper presents an assessment of modeling techniques in predicting subsidence over longwall areas. Extensive instrumentation has been made, both at the surface and subsurface, at three longwall mines in northern West Virginia. Ground movements were monitored during a three- year period until subsidence ceased in these areas. A comparative analysis of empirical subsidence prediction techniques including graphical (NCB), profile function, influence functions (USBM, Bals', Knothe's, and zone area) will he presented. A brief geologic and topographic description of each site, along with the instrumentation and monitoring program, will also he presented.

Jan 1, 1990

By John A. Shuster

Case histories are reported for several soft ground shafts ranging from 6' to 40' in diameter and 50' to 230' in overburden depth for which ground freezing was employed to provide temporary ground support and groundwater control during shaft sinking through the overburden. Cases reported emphasize dealing with difficult site and ground conditions such as working within existing buildings, through very soft, running and bouldery soils, in the presence of substantial lateral groundwater flows, and into salt dome deposits requiring special considerations. Construction procedures, schedule, and relative costs are discussed for each case.

Jan 1, 1985

By P. R. McOllough

The Colorado Department of Highways awarded a contract to construct the Second Bore of the Eisenhower Tunnel in August, 1975. The contract was completed June 29, 1979, nine days ahead of schedule, with¬out major claims or delays. The tunneling involved complex construction through difficult ground conditions. The contract, plans and specifications were specifically planned to more equitably share the risks involved and to minimize adversary relationships. The Department produced a detailed tunnel design and maintained responsibility for the design. The contract employed some new provisions; e.g., a review board for settlement of claims and disputes; escrow documents (contractor's bid documents) to determine the contractor's basis of bid when determining adjustments. The tunnel contract, plans and administrative efforts employed by the owner and contractor were very successful in this project.

Jan 1, 1981

By Joseph Lynch, John DiPonio

This report refers to the Chicago Deep Tunnel Contract 13A, which was the first contract let in the City of Chicago requiring the construction of deep drop shafts for the transportation of high level sewage to the deep tunnel system. The basic contract required the contractor to construct certain drop shafts designed to deliver surface and high level sewage to the deep tunnel system approximately two hundred feet below. The design of the drop shafts was in a degree affected by their proximity to the existing deep tunnel. The tunnel, approximately three and one-half miles long, was to have five shafts dropping sewage at five locations. Four of the drops were approximately one-half mile apart and spaced from the dead end of the tunnel. One shaft divided the remaining two miles from the existing work shaft at the southeast end of the tunnel wherein a 220' deep pumping station was to be built. The existing tunnel had been built some time previously and all dewatering had stopped, allowing the tunnel and main shaft to fill with water. According to the plans, the drop shafts were all between fifty and ninety feet north or south of tunnel center line, and located in heavily built-up residential and industrial property. This then defines the problems: How do we control the water. If we excavate from the top down, how do we handle the slurry and the muck from five locations. How shall we construct the connecting tunnel between

Jan 1, 1997

By Takashi Sakaguchi, Akira Nakajima

Some attempts were made to recover and remove heavy metal elements, such as uranium, copper and chromium, from aqueous systems by using several phosphate compounds. The phosphorylated derivatives of polysaccharides, chitin phosphate, chitosan phosphate and cellulose phosphate, have high abilities to accumulate heavy metals, such as uranium, copper, manganese, cobalt, cadmium, zinc, nickel and chromium, compared with non-phosphorylated polysaccharides. In order to obtain basic information on the recovery and removal of uranium that may be present in industrial effluents, mine waste water and seawater, the adsorption of uranium by chitin phosphate and chitosan phosphate was investigated in details. The adsorption of uranium by chitin phosphate and chitosan phosphate was much greater than copper, cadmium, manganese, zinc, cobalt, nickel, magnesium and calcium. The adsorption of uranium was very rapid and was affected by pH of the solution, temperature. granule radius and co-existence of carbonate ion. The amounts of uranium adsorbed on the adsorbents increased linearly as the external uranium concentration increased. Uranium adsorbed on chitin phosphate easily desorbed with diluted sodium carbonate solution. On the other hand, uranyl and cobalt ions were separated from each other by using chitin phosphate. Along with these fundamental research, some attempts were made to recover uranium from seawater.

Jan 1, 1993

By H. Soto, J. Jara, F. Nava, J. B. Hiskey, B. J. Scheiner

Laboratory tests showed that ozone can destroy free cyanide and weakly complexed cyanide (copper and zinc cyanides). The iron cyanide complexes were resilient to ozonation but they were effectively eliminated by precipitation with Fe (II) ions under controlled pH conditions. Tests carried out with effluents from a number of gold mills confirmed the results obtained previously in the laboratory. The industrial samples contained cyanide in the form of free cyanide and also complex copper, zinc and iron cyanides. Solutions that contained up to 184 mg/L total cyanide, after the ozone treatment analyzed only 2-3 mg/L dissociable cyanide and 50-90 mg/L CN(t) (accounted for by iron complexes). After precipitation with ferrous ions total cyanide was reduced below 1.5 mg/L. For most solutions ozone consumption ranges from 3 to 6 g per g of cyanide destroyed. However, certain impurities (such as SCN and S203 ), present in some effluents, increase ozone consumption and make it more difficult to reduce copper concentration to satisfactory levels.

Jan 1, 1993

By Yeonuk Choi, Patrick R. Taylor, Lyle Cunningham

Laboratory experiments have been performed to evaluate the potential for metal removal and recovery from river bed tailings by ferric chloride leaching. The lead, zinc, silver and other metals in the river bed occur due to the old method of dumping mill tailings into rivers. This was practiced prior to the introduction of tailings impoundments. The effects of the leaching method, leaching time, pulp density, ferric chloride concentration, and leaching temperature on the rates and recoveries of lead, zinc and silver were studied. The effects of pulp density and leaching temperature were significant on the extraction rates of lead, zinc and silver. The lead content in the leached tailing was reduced to 0.023 percent, when using an 353O K leaching temperature and 0.384 g of FeC13/1 g of sample.

Jan 1, 1992

By Regina N. Tempel, Timothy E. Eastep, R. Craig Ford, Bryce R. Roming, Geoff Clothier, Maggy F. Lengke

The Climax Mine, near Leadville, Colorado treats acid drainage in a lime neutralization chemical treatment system. Chemical treatment has been successful in reducing the concentration of metals to below surface water discharge effluent limits, but lime usage has not been optimized. A geochemical modeling approach has been developed to increase the efficiency of lime neutralization. The modeling approach incorporates two steps: (1) calibration, and (2) calculation of amount of lime needed to increase pH and remove metals. Results of our work quantify the lime treatment process and improve our ability to predict overall water quality.

Jan 1, 2000

By Vanessa M. Torres

Diagnostic leaching tests provide a good indication of gold deportation in its various occurrence phases. With the results of these tests, possible flowsheets for difficult ore treatment can be established for further evaluation and plant operation can be optimized. The use of this technique can be extended, including heap leach evaluation and complex copper-gold ores. The results on the use of diagnostic leaching tests in gold ores from Companhia Vale do Rio Doce (CVRD) are presented and discussed, as well as the methodology to select steps and interpret results used at CVRD Technology Center (Sutec).

Jan 1, 1998

By Don W. Murphy, Don M. Larsen

Advanced process control has been implemented at the Jerritt Canyon Mill. Plant production prior to 1997 was limited by grind circuit capacity. The installation of additional mill horsepower and an optimizing supervisory control system achieved a throughput increase in excess of 12 percent. The controller application utilized a seamlessly integrated fuzzy logic expert system for real-time mill control coupled with a neural network predictor for closed-loop feedback of particle size constraints. In late 1998, a second supervisory controller was installed to operate the fluidized bed roasters. The second controller optimized roasting conditions, increased plant throughput and improved metallurgical recovery.

Jan 1, 2000

By Jean-Luc Cornet

As modern conveyors are increasing in size and complexity, their control requirements are becoming more and more critical. In addition to the safety and equipment protection requirements, control systems are now called to implement intelligent drive controls derived from dynamic analysis modelling, as well as to provide fast and accurate diagnostics while keeping operator controls simple. These requirements led to the development of a new and innovative approach to control system development. This paper describes the control philosophy used by Conveyor Dynamics, Inc. (CDI) and some of the key features of our approach to the architecture of control systems.

Jan 1, 1993

By A. K. Bakshi, Komar S. Kawatra

A plant trial of a new on-line pressure vessel rheometer for slurries, developed at Michigan Technological University, was carried out at a nearby copper concentrator. The rheometer measured the flow curves (shear stress vs. shear rate) of chalcocite slurries. Viscosity of non-Newtonian slurries changes with shear rate and so, for such slurries viscosity measurement at a single shear rate (often seen in the literature for grinding and classification studies) cannot be correlated to process performance. For these slurries, viscosity at various shear rates can be measured from flow curves generated by the pressure vessel rheometer. Other rheological properties, such as flow type and yield stress can be determined by this rheometer to better characterize the slurries. The slurry at the copper concentrator consisted of ground chalcocite ore. The solids content in the slurry varied between 30-60 % by weight. Top size of the particles was 125 micron, and 80% passing size was 34 micron. Measurements by the pressure vessel rheometer showed that most of the slurries had pseudoplastic flow at shear rates below -3000 sec-l, where the viscosity of the slurry decreased with increase in shear rate. Above -3000 sec-l, like a Newtonian fluid, the viscosity of the slurry remained steady. Flow curves and viscosity from the pressure vessel rheometer were verified with a Brookfield viscometer and a vibrating sphere viscometer, and the results were found to be accurate.

Jan 1, 1997

By P. Bevilacqua, G. Vallebuona

Empirical models are now used for predicting the performance of hydrocyclones in terms of capacity. cut size (d50.c), water split and partition curve. These models (such as the model by Lynch and Rao and the model he Plitt) were developed and checked for hydrocylones with diameters larger than 4 in. However, for smaller-diameter hydrocyclones, little empirical modeling has been done. This paper reports on an extended experimental research program on small hydrocyclones. For these cyclones, the suitability of existing empirical models was investigated and their accuracy was compared. To improve the predictive capability of these models to small cyclones modifications to the equations are proposed.

Jan 1, 1996

By Harold E. Goetzman, Blair R. Benner, Shaolin Zhong, Rodney L. Bleifuss

A commercial high pressure roller press (KHD 90125) was installed at the Coleraine Minerals Research Laboratory for testing in October, 1994. Pilot plant evaluation of the high pressure roller press has shown that it can be used as an alternative to the rod mill for the comminution of taconite. A series of pilot plant tests were run to compare roller press products to rod mill products in a simulated taconite flowsheet using magnet separation and closed circuit ball milling. Further investigation of a hybrid grinding system, roller press crushing followed by ball mill grinding, indicate that the combination may represent the most energy efficient system for taconite processing.

Jan 1, 1998

By Daniel L. Hanson

This paper presents case histories of the construction of four large diameter circular shafts using reinforced concrete ring beams as the primary internal support system. The case histories pertain to concrete ring beam systems which have been successfully used in shafts up to 130 feet in diameter and 75 feet deep. Soldier pile and lagging, and driven steel piling earth retaining systems using ring beams, are discussed together with the cost savings associated with using concrete ring beams. Soil conditions encountered at the case history sites are discussed together with the development of design criteria for each shaft. Instrumentation data obtained at one site are also presented.

Jan 1, 1987

By W. Kennedy Gauger, Tim Oolman, Debra L. Bisson

Radian Corporation (Radian) has developed a process for treating Cr(V1)-contaminated soils that involves: 1) soil washing using an alkaline extractant, 2) biological reduction of Cr(V1) to Cr(II1) in the soil wash effluent, and 3) separation of Cr(II1) from the biologically treated effluent. Biological treatment has been demonstrated for immobilized cells in fluidized bed bioreactors and suspended cells in slurry bioreactors for Cr(V1) levels ranging from 30 to 600 mg/L which have been reduced to non-detectable levels (< 0.05 mg/L; method detection limit [MDL]) during hydraulic residence times as short as 12 hours. The resulting Cr(II1)-containing effluent stream was chemically treated to precipitate chromium hydroxide for removal by physical separation.

Jan 1, 1995

By P. L. Webster, S. D. Thompson

The Coal Mine Belt Capacity Simulator (CMBCS) was originally developed to provide an improved belt capacity simulation through more detailed, flexible and realistic modeling of belt loading. While this model offered improved capacity design for conveyor belts and surge bins, it lacked the capability to simulate some key protection and segregation applications for bunkers. Recently, CMBCS was extended so that these latter bunker applications could be considered. In addition, a fear minor extensions were made to improve the model&apos;s flexibility and of efficiency. These various extensions and the steps taken to verify and validate them are described. The associated modifications in the model&apos;s input and output as well as the model&apos;s current requirements and availability are also discussed.

Jan 1, 1992

By J. A. Brierley, Arpad E. Torma, Victor C. Storhok, C. L. Brierley, Batric Pesic

Chemical and electrochemical studies were performed during bioleaching of cobaltite concentrate with Thiobacillus ferrooxidans. The two principal minerals present in the concentrate were pyrite and cobaltite (CoAsS). During chemical studies, the effect of pH on dissolution rates was examined under uncontrolled and pH-controlled conditions. It was found that in the pH range 1.5-3.0 there was no pH effect if the initial pH was not controlled (maintained). When the initial pH was controlled, the leaching of Co, As, and Fe depended strongly on pH. Electrochemical studies were performed by using cyclic voltammetry and constant potential techniques. A sequential reaction mechanism was proposed for dissolution of cobaltite.

Jan 1, 1993

By J. C. Norman

The United States was the world&apos;s largest producer and consumer of boron compounds during 1994. According to US Bureau of Mines (USBM) estimates, boron mineral concentrate and chemical production in the United States totaled about 1.05 Mt (1.15 million st), yielding 560 kt (617,000 st) of B203, for a total estimated value of $370 million. This production level was about 2% less than 1993 revised figures. The United States continued to provide nearly all of its own boron supply while maintaining a strong position as a source of sodium borate products and boric acid for export. Domestic employment in the mining and beneficiation of boron products during 1994 was 900 people, about the same as in 1993. USBM estimated total world production of boron of about 2.3 Mt (2.5 million st), yielding 1.1 Mt (1.2 million st) of B203. World production during 1994 was about the same as during 1993. USBM estimates US reserves to be about 210 Mt (231 million st) of ore and world reserves to be about 630 Mt (694 million st) of ore.

Jan 1, 1995