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By Davidtz. John C.

INTRODUCTION The effectiveness of collector type on sulfide mineral flotation is generally determined by the amount and type of functional groups of collector molecules that interact with surface and water at the mineral/collector/water/gas interface. The final interfacial state when bubble contact takes place is preceded by chemical and physical reactions that involve these gas/liquid/solid interactions. These interactions differ not only for different minerals, solution and gas composition, but also for different collector molecules. The purpose of this paper is primarily to summarize the developments and status of short (C2-C6) and long (C12) chain, aliphatic collectors that contain three sulfur atoms in their polar function. These are trithiocarbonates (TT'Cs). For purposes of comparison, similarities in molecules containing 0, N and S are compared. Mostly short chain ionic collectors molecules of dithiocarbonates (DTCs) and TT'Cs were compared. The studies, largely bench scale flotation and plant testing, were carried out on ores containing Cu, Ni, Au, and PGM's. Studies of long chain 'ITC collectors are reported on Ni, PGM and auriferous pyrite ores containing uranium. Under starvation dosage conditions, surface activity coefficients of short chain collector molecules and interacting water were calculated. Based on the UNIFAC group contribution method of activity coefficient calculations, the Gibbs Excess Free Energy

Jan 1, 2005

By Satid Therdkiattikul, Donald A. Dahlstrom

By oxidizing the pyrite matrix through biological leaching of precious metals ores or concentrates, better than 90% recovery of gold and silver is achieved. The paper develops three precipitation processes that eliminates arsenic and all other toxic elements in the resulting liquor after the biological reactors. In addition, the precipitates are highly crystalline and resist resolubilization. The latter must be tested for at least six months by EPA test procedures. The three systems are temperature (must be at least 120°C or higher) lime or limestone. A continuous pilot plant was employed for all three systems and complete recommendations are given to optimize Fe/As molar ratio, reaction kinetics (detention time) pH, temperature, wt % feed solids as well as resultant reagent consumption based upon continuous operation.

Jan 1, 1995

By H. G. Naidu, Raj K. Singhai, S. P. Singh

Introduction The economics of open-pit mining de¬pend heavily on the cost of overburden removal. It is necessary to maintain a pit slope as steep as possible. Steeper slopes lower the volume of overburden to be handled, thus lower the cost of material handling. There is, however, a limit to which the pit slopes in any given situation can be steepened. Steepening beyond this point could jeopardize the pitwall stability, ren¬dering it unsafe. It might even result in curtailment of pit production. Several factors affect the stability of pitwalls. Some are natural, such as topogra¬phy and regional and local geology. Others are man made, such as pit geometry, ground water management, equipment, drilling and blasting, and the type of excavation. Greater control can be exercised in the latter with proper planning and by following a set of procedures based on field experiences. This article deals with one such control¬lable factor - drilling and blasting. The eco¬nomics of steeper pit slopes is discussed, followed by a record of drilling and blasting practices in western Canadian surface mines. Microprocessor-based instrumentation and its application to blasthole drilling is also described. Economics of steeper pit slopes The economics of steeper pit slopes is not a new issue. It should be reinforced, though, that pit slopes must be as steep as possible to ensure maximum recovery of minerals at a minimum stripping ratio. For operating, economic, and safety reasons, different pit slopes are maintained during different phases of pit development. Figure 1 shows a hypothetical ore body, cylindrical shape, with a radius of 225 m (740 ft) and located 30 m (100 ft) beneath the surface. The mining operations are planned at two different slope angles of 25° and 40°. The ultimate pit depth was established on the basis of the criterion of "break even pit." The variation of the stripping ratio at differ¬ent mine levels is shown in Fig. 2. Table I summarizes the eco¬nomics involved for two pit slopes, 25° and 40°. Figure 3 presents the profits during the life of the mine for these two pit slopes. This study shows that steeper slopes for an open pit operation are far more advanta¬geous than flatter slopes. But, what is the optimum slope at any one point in the life of a moving pit? And how can the stable slopes be maintained over the short- and long-term? Canadian blasting practices A survey of blasting practices in western Canadian surface coal mines revealed that, at most mines, hard consolidated overburden is drilled and blasted. Blastholes are drilled with rotary crawler-¬mounted rigs using bits in the 220 to 310 mm-diam (8.5 to 12 in.-diam) range. Typi¬cal hole depths are 12 to 18 m (40 to 60 ft) to accommodate the pit bench heights of 12 to 15 m (40 to 50 ft). For a 12-m (40-ft) high bench, a typical hole will be 14.6 m (48 ft) deep including the subgrade drilling of 2.6 m (8.5 ft). Half of this hole will typically be a powder column and half will be stemmed. For a 15-m (50-ft) bench, a typical hole will be up to 18 m (66 ft) deep including the subgrade drilling. Drilling patterns are usually 9 m (29.5 ft) spacing and 9 m (29.5 ft) burden. De¬pending on local geology and hole diameter selected, drilling patterns of 8 x 8 m, 8.5 x 7.3 m, and staggered patterns of 11 x 5.5 m

Jan 1, 1989

By James I. Mathis

Should an arbitrary reduction factor be applied to laboratory compressive strengths when designing pillars? The answer is, as is the main contention of Peng's article, probably not. Many factors affect the strength of the material remaining in the pillar. On the other hand, outside influences will influence the strength testing results from the lab. This is not the first article, nor the last, to discuss the discrepancy between the two strengths. As was discussed in the article, actual pillar strength is affected by several factors. The two mentioned were: • The scale effect of discontinuities. How large must the pillar be so that the increase in discontinuity count with size will not decrease the strength. • Non-uniform strengths and lithologic units within the pillar. The scale effect of discontinuities is important. What size block must be tested so that the rock mass strength is actually measured? For a highly fractured rock mass, or coal with a high cleat density, this sample may be quite small. Conversely, if an unaltered, moderately jointed, quartz monzonite was examined, the sample block would likely be very large. This is the subject of ongo¬ing research. More to the point, if the tested sample is sufficiently large to model the rock mass strength, then no reductions should be made in the lab strength based on this factor alone. Non-uniform strengths and variations in lithologic units will also affect the pillar strength. I am not an expert in coal mines, having gained my experience in hard rock metal mining. These problems, though, are commonplace. However, strength sampling for pillar strength determination involves sampling material from within the lithologic unit that will form the pillar, not from pieces of material found on the floor. In addition, this sampling should cover the entire range of strengths of the material in the pillar-hard units (such as the partings described by Peng), as well as soft units. Testing results should then be included in the pillar design. Contrary to statements in Peng's article, at least one rock mass rating system (Laubscher, 1990) allows for the compositing of strong and weak units into a design rock mass strength that can be used for pillar design.

Jan 1, 1993

By Victor F. Hollister

The great increase in post-World War I1 use of molybdenum was made possible by discoveries of that metal in porphyry molybdenum and porphyry copper deposits. This section documents significant porphyry molybdenum discoveries of the post-war period. The most important discovery was Henderson in Colorado. It is not only one of the world's largest and richest, but it was found by a team of geologists who defined the hood model and tested it successfully at Henderson. Under the leadership of Stewart Wallace, these scientists established a set of criteria for exploration for Henderson-type de- posits that was copied by the industry. The discovery bf vertical cylinder type porphyry molybdenum deposits was less renowned. Boss Mountain in British Columbia and then Mt. Pleasant in New Brunswick were given relatively scant notice, compared with the Henderson discovery. However, these deposits have geometrics distinct from that found in the typical hood, which directly affects their exploration characteristics. Mt. Pleasant, included in this section, is a well defined, near vertical breccia pipe. Both the Henderson and Mt. Pleasant discoveries were made by relatively small groups operating independently of the bureaucracy that characterizes large corporations. The management role in each case was one of encouragement. In addition, Wallace had the beneficial experience of working for Climax, whose objective was the discovery of porphyry molybdenum deposits. Henderson was the natural outgrowth of the exploration effort by those who studied and understood the Climax deposit.

Jan 1, 1991

By Carl G. Bock

INTRODUCTION Rapid transit systems involving near surface tunneling in hard rock are becoming more numerous, especially along the northeast corridor of the East Coast. Tunneled systems are under construction in Washington, D.C. and are being planned for Atlanta, Buffalo and Baltimore. Near surface tunneling is defined for this paper as being that in which the crown is 100 feet or less below ground surface. For Rosslyn Station, the total cover ranged from 52 to 70 feet. The rock cover, however, ranged from 40 to 50 feet which is slightly less than the station height and about two-thirds of its width. Rosslyn Station (Fig. 1) is the only station excavated completely in hard rock in the Virginia portion of the 98.5 mile Washington Metropolitan Area Transit Authority's (WMATA) rapid transit system. The station site, oriented in a north-south direction beneath a main thoroughfare and flanked by multistory office buildings, was fixed by the need to serve a dense population center at a specific location and geologic conditions were a secondary consideration in siting. There was no previous underground rock excavation in the Washington Metropolitan Area of the size and scope of Rosslyn Station that offered a practical case history guide to the geologic conditions and excavation problems to be encountered. GEOLOGY The regional geology of the Washington Metropolitan Area is divided into two physiographic provinces by the northeast trending Fall Line (Fig. 2). Northwest of this boundary is the Piedmont Province

Jan 1, 1974

By V. A. L. Breguncci, A. H. Martins, C. P. Ribeiro Jr.

This work presents experimental results for the recovery of gold present in alkaline cyanide solutions by using the electroelution technique of strong-base anionic polymeric resins IRA 402-CL from Rhom and Haas-Brazil Ltd. loaded with gold. This technique of electroelution of anionic polymeric resins is based on the removal of metal ions adsorbed to the resin, resulting from a potential difference applied between the cathode and anode in an electrolytic cell. The electrolytic cell was composed of an aqueous solution with suitable chemical characteristics and an anionic polymeric resin bed loaded with gold. The resin used in the experiments was loaded using synthetic alkaline gold cyanide solution with 1.0 g/L of gold. The variables studied were electroelution time, cathode current density, distance between cathode and anode and the electrolyte chemical composition. Statistical methods made it possible to establish the optimum conditions that would achieve satisfactory gold recoveries by the electroelution technique. The statistically predicted response for the resin loaded with gold by percolation was 16.5% gold recovery, 2.0 A/m2 cathode current density, 20-mm distance between electrodes and 6.0 hrs electroelution time. For the centrifuging system, the statistically predicted response was 7.41% gold recovery under the following conditions: 0.25 A/m2 cathode current density, 1-mm distance between electrodes, 3.5 hrs electroelution time and 10.9% NaOH in the electrolyte chemical composition.

Jan 1, 2002

By B. V. Close

Surface mining regulations together with mine and reclamation planning require collection of large amounts of geologic and hydrologic data for both new and existing mines. Recently developed microcomputer software facilitates the integration of this information from computer databases into ground-water flow models. The databases are used to identify areas which require dewatering and/or depressurizing and for generating contour maps of aquifer parameters. Gridded versions of these contour maps are incorporated into finite difference ground-water flow models which are used to design dewatering and depressurizing well fields and to estimate the effects of ground-water pumping and pit progression on local ground-water levels.

Jan 1, 1988

By Haydn H. Murray

Common clay includes a wide variety of clay and other fine- grained rocks that are used in many ways. These clays are some- times classified as miscellaneous clay and shale. Most products made from them are fired and include such things as structural and face brick, drain tile, vitrified pipe, quarry tile, flue tile, conduit, pottery, stoneware, and roofing tile. Very large tonnages of these materials are bloated by firing to form lightweight aggregate, and large quantities are used in making portland cement (see the specific chapters in this volume). Uses not requiring firing of a finished product include filler for paint and other products and shale and clay used for packing dynamite in blastholes and for plugging oil and gas wells that are no longer in use.

Jan 1, 1994

By Jon Kellar, William Cross, Eric Swanson, John Starkovich

Zirconium tungstate (ZrW2O8) is a unique material with a negative coefficient of thermal expansion. In order to fully utilize this material as a filler, a surface treatment needs to be developed to better improve the wetting and dispersion capabilities of the filler. This paper describes an initial study to characterize the filler as well as investigate fatty acid and silane surface treatments for eventual compounding with thermosetting matrices. It was found that ZrW20, has a point-of- zero charge between pH 2.7-3.0, and that both fatty acid and organofunctional silane treatments appear to be viable surface treatments for this unique filler.

Jan 1, 2003

By Robert J. Guardia, James Rustvold, Robert A. Robinson, Christopher A. Robertson

In 1999, the Bonneville Power Administration (BPA) replaced approximately 730 m(2,400 ft) of damaged 42- and 36-inch concrete pipe by microtunneling Permalock pipe through sand and partly below groundwater. Microtunneling saved $3.5 to $5 million from the estimated cost of a shored excavation and avoided a railroad and contaminated valley fill. A slurry microtunnel boring machine (MTBM) was used for two segments where groundwater was present and a wheel excavator MTBM was used for one segment where groundwater was not present. This paper describes design and construction of this project that was completed within 2% of the bid and engineer’s estimate.

Jan 1, 2001

By B. Pregerson, M. Gaft, J. Rabinowitz

The main phosphate minerals, apatite and francolite, are characterized by intensive selective photoluminescence, connected with impurities of Eu2+, Ce3+, V4+, Mn2+ and (UO22+ ). The non-uniform distribution of phosphate minerals in lumps makes photoluminescence sorting possible. As result, an intermediate product is recovered which is enriched by P205 and has relatively small amounts of chert, dolomite, calcite, fluorite, etc. In the case of Zin Phosphate Plant coarse rejects, for example, it is possible to separate a product enriched by francolite, practically free of chert and with a lowered calcite content. This material is suitable for flotation, with a potential 6-7 % increase yield of concentrate.

Jan 1, 1993

By Roshan B. Bhappu

The extraction of gemstones, except for diamonds, continues to be a more or less handpicking type operation all over the world. However, considering the physical properties of gemstones such as density (sp.gr.), color, size, shape, luster, brilliance, reflection of light and the like in contrast to the relatively ‘dull’ physical characterization of the associated gangue minerals, it should be feasible to recover several gemstones using modern mineral processing techniques. This paper illustrates the unique physical characterization of several gemstones and suggests appropriate mineral processing techniques that could be used to recover these precious stones. Special emphasis is placed on the versatility of the Heavy Media Separation (HMS) process for processing of the gemstones. Finally, a few examples of commercially viable operations involved in the recovery of emeralds and rubies are presented.

Jan 1, 2005

By M. S. Celik, G. Onal, S. Atak, A. A. Abramov

An oolitic phosphate ore composed of phosphate (mainly francolite) and carbonates as gangue has been tested for the suitability of the reverse flotation process. The samples were first ground autogeneously followed by the reverse flotation process. While the carbonates were floated by sodium oleate the phosphate was depressed by phosphoric acid. The effect of particle size, reagents type and concentration on flotation recoveries have been investigated to determine the optimum conditions. By this process, a run-of-mine ore containing 16.72 % P205 was upgraded to 28.00% P205 with a recovery of 77.0% The mechanism of optimum flotation with phosphoric acid observed at pH 6.3 is explained based on a relationship involving surface potentials and the ratio of required collector concentrations for the respective minerals.

Jan 1, 1993

By Oliver Gutsche

High-pressure roll mill comminution of heterogeneous multicomponent feeds was simulated with artificial limestone-quartzite mixtures using a piston-die press. The influence of heterogeneous interactions between components of the mixture on grinding path, energy utilization and energy split have been examined. Primary fractures are governed by differential fracture strength and attrition resistance of the components at heterogeneous contacts; subsequent secondary and tertiary fracture events are governed by coarse-fine interactions in the particle-bed. The weaker component is preferentially ground out of the feed size fraction and concentrates in the fines. Energy split among the components in the mixture is a function of their relative fracture strengths. It doubles for limestone and decreases by a factor of 5 for quartzite over the entire range of the mixing ratio.

Jan 1, 1995

By J. Chilton

The fact that methane ignitions continue to occur at the mining face indicates that monitoring with machine-mounted methanometers does not always indicate the presence of high methane concentrations. Methane concentrations at the face change quickly due to changes in airflow. By measuring these changes in airflow, it may be possible to predict changes in face methane levels more quickly. Currently there are no techniques or instruments to accurately measure airflow inby the mouth of the ventilation curtain or tubing. Tests conducted in the NIOSH ventilation test gallery compare the data provided by one-, two-, and three-axis ultrasonic anemometers. The effects of changes in airflow direction and turbulence on instrument readings are discussed, and guidelines are given for selecting the type of instruments to be used for monitoring airflow near the mining face.

Jan 1, 2007

By John J. Peregoy, James E. Downes

INTRODUCTION The U.S. Department of Energy's Waste Isolation Pilot Plant (WIPP) is being constructed to provide permanent storage of radioactive TRU waste materials emanating from military weapons production. These wastes are contaminated with radioactive elements heavier than uranium, thus the name trans-(or beyond) uranic (Uranium wastes). The WIPP site, which is located 26 miles east of Carlsbad, New Mexico, was chosen thru a selection process after the National Academy of Sciences recommended salt deposits as a promising host strata for the storage of radioactive wastes. Throughout the United States numerous DOE facilities have produced and stored defense-generated TRU wastes. Once WIPP becomes operational in the fall of 1989, all sites may ship directly to this repository. A companion project has developed special shipping containers (TRUPACT) for safe transport of materials to WIPP. The WIPP facility is currently composed of surface buildings, three shafts, and underground storage and experimental rooms and tunnels. Frontier-Kemper Constructors, Inc. (FKCI) has nearly completed the construction of the fourth shaft, an intake shaft, to provide additional ventilation to the underground workings. PLANNED SHAFT EXCAVATION METHOD Full-face raise boring ( upreaming ) was the allowable method selected by Frontier-Kemper Constructors for the excavation of the shaft. After arrival of an oil-field type rotary drill rig in December 1987, a 9 inch diameter pilot hole was drilled from the surface to the mine level, a depth of approximately 2145 feet.

Jan 1, 1989

By E. J. Beckman, R. M. Enick, C. Shi

A novel liquid-liquid separation for the recovery of free or liberated gold from mixtures of fine particles was evaluated. Two inexpensive and environmentally benign fluids were selected for the study, water and carbon dioxide. The separation, which is conducted at 295 K and at the vapor pressure of carbon dioxide (6.0 MPa), is based on differences in wettability between the precious metals and other minerals. Contact-angle results indicated that, in the presence of water and liquid CO2, gold is slightly hydrophobic. The addition of CO2-soluble fluoroalkyl thiols or f uoroetherthiols increased the hydrophobicity of gold exposed to water and CO2 to a greater extent than alkylthiols. Minerals, including quartz, pyrite and magnetite, were hydrophilic. During the separation, an aqueous slurry of fine mineral and gold particles was mixed with liquid carbon dioxide. Pure gold particles (-325 mesh) were found to agglomerate at the H2O-CO2 interface. The minerals tended to remain in the aqueous phase. Despite these promising preliminary results, very poor gold recoveries were obtained when applying the procedure to an Australian gravity concentrate. This was attributed to the native gold particles in the concentrate being either too large, agglomerated in slimes or coated with minerals. Although this particular application was unsuccessful, this water-CO2 biphase technique may be applicable for other separations that require the removal of very fine, hydrophobic particles from an aqueous slurry.

Jan 1, 2000

An appropriate scale-up methodology is very useful for ball mill design and optimization of the grinding circuit. To date, the scale-up is based on the selection and breakage function method using lab mill data. However, a major drawback of that approach is that the charge motion in a lab mill is vastly different from that in a large industrial mill. Therefore, in the methodology proposed here, first the energy of individual collision in the mill is computed employing the discrete element method (DEM). Then the breakage of particles as a function of collision energy is studied in a separate experiment. Together, this information constitutes what is known as collision energy based population balance method. The appropriateness of this method is shown for 38-cm ball mill.

Jan 1, 1998

By Raj K. Rajamani

In ball milling the rates of breakage vary primarily with the size distribution of powder in the mill. In wet grinding viscosity of the slurry varies continually as size distribution changes and hence the breakage rates change. In this study a simpler estimation scheme is used to determine breakage rates in batch grinding. Using an approximate solution to the batch grinding equation, acceleration and deceleration of breakage rates of all individual size classes is determined when the grinding environment is varied. Experimental results with limestone and copper ore show time-dependent breakage rates under both dry and wet grinding conditions. In general the breakage rates increase for coarse sizes and decrease for fine sizes with increase in the fines present in the mill. Such variations have strong implications in closed-circuit grinding.

Jan 1, 1991