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By R. Frim, S. D. Ukeles

The present U.S. production of bromine is from inland brines located in Arkansas and Michigan. The most concentrated domestic brines (up to 5,000 ppm bromide)are situated in Arkansas. Less concentrated brines(about 2,500 ppm bromide) are located in Michigan. The amount of bromine sold or used in the United States came from three companies operating in those two states. Its value was $191 million. In 2004, the estimated U.S. bromine production was 222 kt (244,000 st). That compared with 216 kt (238,000st) produced in 2003.

Jan 1, 2005

By M. G. Irish, E. E. Vidal, M. J. Jahraus, P. R. Taylor

An experimental system has been designed to monitor on-line variations of leaching parameters in a closed circuit of cyanide leaching solutions and gold bearing ores. Experiments performed to deter-mine variations in some important leaching parameters of the solution: pH, dissolved oxygen, free cyanide, oxidation/reduction potential, gold content, temperature, pressure and solution chemistry. By comparing results obtained when the leaching solution is allowed to become acid or kept basic, it was possible to infer the chemical reactions that occurred between the solution and the ores.

Jan 1, 2004

By Anthony G. Grice

This paper discusses the contribution that backfill is making to the Australian mining industry and provides some information on the largest operations together with some novel applications. Each of the three major backfill types; hydraulic, rock and paste are discussed in turn with a focus on new ideas and advances in understanding, technology and operating practices.

Jan 1, 2001

By Walter Shukin, Mark T. Olsen

An enormous quantity of tailings to be ultimately stored, unfavorable topography, severe climatic conditions, and an environmentally offensive red effluent all contributed to the challenge of designing an effective and cost efficient tailings confinement program at the open-pit iron ore mine operated by Quebec Cartier Mining Co. at Mount Wright in northeastern Quebec. The mine has been operating since 1976, but a detailed disposal plan was first initiated with construction of some channels and ditches during 1980. In the coming years, a system of dams, channels, and tailings confinement dikes will be constructed to accommodate tailings produced in the next 25 years. Careful consideration has been given to environmental effects, and the works under construction have been sized and situated to be extended as required to an ultimate mine life of 87 years.

Jan 8, 1981

By Roger B. Jr. Herbert

Surface water samples were collected from water accumulations at the surface of a neutral pH mine tailings deposit in Kristineberg (Sweden) where algal growth and iron hydroxide precipitates were observed. Ferric iron in the aqueous samples was determined by (adsorptive) differential pulse - cathodic stripping voltammetry. The analyses indicated that labile Fe3+ concentrations were in the range <20 to 337 nM, while total Fe3+ levels were much higher at 0.9 to 8.3 uM. The labile Fe3+ levels are more than two orders of magnitude greater than would be expected based on equilibrium with ferrihydrite. These results suggest that iron complexation with strong ligands in the surface water competes with iron hydrolysis, and that these ligands may be of algal and/or bacterial origin.

Jan 1, 2000

By S. Mathur

Future Florida phosphate reserves contain higher MgO than presently mined deposits. The high MgO content is contributed by dolomite and Mg-rich clay, palygorskite. Selective flocculation was attempted to reduce the MgO content of apatite in synthetic mixtures of apatite with dolomite and palygorskie. Mixed mineral selectivity was predicted in the apatite-dolomite and apatite- palygorskite systems with Poly(ethy1ene oxide) (PEO) flocculant. Loss of selectivity in the mixed mineral systems was primarily attributed to heteroflocculation, which was minimized by addition of a Site Blocking Agent (SBA), a lower molecular weight fraction of PEO, prior to addition of the flocculant. A 80:20 mixture of apatite-dolomite (or palygorskite) was upgraded as 95% apatite at more than 80% recovery level in the product fraction.

Jan 1, 1995

By J. P. Golightly

The structure and occurrence of nickeliferous laterite profiles are described and explained in terms of mineral solubility and drainage conditions. Complete profiles, from top to bottom, include: limonite zone; nontronite or silica zone; and saprolite zone. The middle zone is present only where drainage is sufficiently slow to allow saturation conditions to build up with resulting quartz or smectite precipitation. This precipitation may occur in any climate at a water table or in tropical climates with a long dry season. The degree of serpentinization of the laterite parent rock is important in determining the nature of the saprolite zone. Unserpentinized peridotite produces saprolite ores with hard residual rock cores, nontronitic or amorphous saprolitic rims, and fracture fillings of garnierite and quartz. Ser-pentinites yield relatively homogeneous serpentine saprolite, with minimal quartz or garnierite.

Jan 1, 1979

All coal preparation unit operations in which fine coal is handled depend to some extent on wettability of coal surface by water. The wetting results from interactions between the coal surface and water molecules that are determined by the composition of coal matrix (interrelated with coal rank) and heterogeneous constituents such as oxygen functional groups, mineral impurities and pores. The contact angle of water on an unoxidized, homogeneous coal hydrocarbon matrix is calculated to be 100o, and much lower values measured on real coal specimens result from contributions from the heterogeneous constituents. While the effect of wettability is critical in flotation and oil agglomeration, suppression of respirable dust, and coal water fuels, it has been shown to play a significant role also in coal flocculation with semi-hydrophobic and totally hydrophobic flocculants.

Jan 1, 1995

By Ian H. Clark

A series of numerical experiments were performed in order to elucidate the stress distribution, fracture strength and mineral liberation potential in single specimens of rock during crushing. Fracture strength was shown to reduce under eccentric loading conditions. Similarly, the presence of inclusions, both hard and soft, reduced the fracture strength. The predicted crack paths indicate that mineral liberation is unlikely to be preferential.

Jan 1, 1992

By Alden B. Carpenter

Brines (a solution containing more than 100,000 mg/l dissolved solids) in sedimentary basins are genetically related to evaporites in one of three ways: (1) dissolution of evaporite minerals, generally halite; (2) interstitial fluids in evaporites which are expelled from their source rock during compaction; (3) incongruent alteration of hydrous evaporite minerals (carnallite). Most brines of commercial interest originate as interstitial fluids in halite-rich rocks. These fluids are initially rich in magnesium, sulfate, and potassium but evolve in composition to an Na-Ca-Cl brine during their migration to their present host rock. A particularly important reaction in this process is: 2CaCO3 + Mgt+ = CaMg(CO3)2 + Cat (1a) This reaction reduces the magnesium content of the brine and ultimately converts it to a calcium-rich brine. The loss of sulfate occurs by two mechanisms. One of these is by direct precipitation as calcium sulfate (either as gypsum or anhydrite): Ca 2+ + SO4 2- = CaSO4 (2a) Additional sulfate may be lost from the brine by sulfate reduction: S042 + 1.33CH2 + 214- = H2S + 1.33CO2 + 1.33H20 (3a) The loss of carbonate species occurs by precipitation as carbonates: H2O + C02 + Cat = CaCO3 + 2H+ (4a) The net result of reactions 3 and 4 is: Ca 2+ + SO4 2- + 1.33CH2 = H2S + CaCO3 + 0.33H2O + 0.33CO2 (5a) The loss of potassium from brines is caused by the formation of potassium aluminosilicates: 2K+ + Al2Si2O5 (OH)4 + 4SiO2 = 2H + 2KAlSi2O8 + H2O (6a) The hydrogen ions produced by this reaction dissolve carbonates: 2H+ + CaCO3 = Ca 2+ + CO2 + H2O (7a) The net result of reactions 6 and 7 is: 2K+ + CaCO3 + Al2Si205 OH)4 + 4SiO2 = Ca2 + 2KA1Si3O8 + H2O + C02 (8a) A study of brines from central Mississippi has shown that the composition of these brines is related to the interaction of pore fluids from evaporites with minerals in the enclosing sedimentary rocks.

Jan 1, 1978

By Kenneth N. Han, Xinghui Meng

The leaching of gold and silver from various ores in ammoniacal solutions conta1mng various oxidants has been investigated. The samples tested included elemental gold, sulfidic as well as carbonaceous refractory ores, and tellurides. When pure elemental gold powders were used, the maximum amount of gold dissolved under the conditions studied was 16.3 ppm, 42.4 ppm, 82.0 ppm, and 152.2 ppm, respectively, at 140°C, 160° C, 180° C, and 200°C. Five different refractory ore samples were also tested. The recoveries of gold and silver from these refractory ores were typically 92% and 95%, respectively.

Jan 1, 1992

By Dan Kump

This paper provides an overview of Barrick Gold&apos;s Bullfrog underground mine backfill program. The Bullfrog underground mine was a gold mine that primarily used the underhand cut-and-fill mining method. The first portal was established June 18, 1991, and mining continued until Dec. 29, 1998. This paper begins with a discussion of the events that took place to reach about 1.8 kt/d (2,000 stpd) of backfill. It ends with a commentary of what was learned. The Bullfrog experience suggests that there are two essential factors to a successful backfill program: a well-graded aggregate supply and proper placing procedures.

Jan 1, 2002

By J. W. Wilson, Y. Ding

In the ultrafine coal-cleaning process, small coal particles (-400 mesh) are produced during the pulverizing operation. After the coal-cleaning process, these ultrafine particles are very difficult to dewater and create problems in coal transportation, storage and handling at utility plants. Research on ultrafine coal dewatering and briquetting resulted in the development of a single-stage operation that is potentially more effective and economical than conventional thermal drying and briquetting processes. The final coal product has a moisture content of less than 15% and possesses high strength and water resistance that satisfies coal transportation, storage and handling requirements.

Jan 1, 1996

By Jerry W. Danni, John E. Hardaway

Corporations today must comply with an ever growing number of complex and increasingly stringent environmental laws and regulations. An environmental audit program is an effective means in which to uniformly and systematically assess compliance, and to assure management that environmental liabilities are being minimized. This paper describes the design and implementation of Homestake Mining Company&apos;s environmental audit program, which has as its primary focus the objective verification of compliance with external requirements and internal good management practices. Major elements of the audit program discussed in the paper include: pre-audit preparation; on-site audit activities; and the post-audit report.

Jan 1, 1992

By Regina N. Tempel, Timothy E. Eastep, R. Craig Ford, Bryce R. Roming, Geoff Clothier, Maggy F. Lengke

The Climax Mine, near Leadville, Colorado treats acid drainage in a lime neutralization chemical treatment system. Chemical treatment has been successful in reducing the concentration of metals to below surface water discharge effluent limits, but lime usage has not been optimized. A geochemical modeling approach has been developed to increase the efficiency of lime neutralization. The modeling approach incorporates two steps: (1) calibration, and (2) calculation of amount of lime needed to increase pH and remove metals. Results of our work quantify the lime treatment process and improve our ability to predict overall water quality.

Jan 1, 2000

By Takahide Wakamatsu, Junji Shibata

Complex polymetallic sulfide ore deposits occur in Tohoku district, northern part of Honshu island, Japan. The ore is locally called "Kuroko” ( black ore ) and is compactly composed of fine grained sulfide minerals of such principal metals as copper, lead, zinc and iron. Currently one of Kuroko mill plants is producing such concentrates as copper, lead, zinc, pyrite, barite, and clay minerals, mainly employing differential flotation techniques. This paper describes briefly the progress of techniques in Kuroko processing over the past thirty years and also the present state of Kuroko processing and its challenges to be studied and overcome in the future.

Jan 1, 1989

By Odin D. Christensen

Gold deposits of the Carlin Trend occur within sedimentary rocks deposited across the Paleozoic continental margin. Lithologically dissimilar units, juxtaposed along the Roberts Mountains Thrust Fault system, constitute three distinct stratigraphic packages: autochthonous miogeoclinal carbonates, allochthonous eugeoclinal siliciclastic rocks, and an overlying coarse clastic overlap assemblage. Gold deposits occur within all three stratigraphic packages, with economic concentrations localized at structural and stratigraphic settings similar to those which host petroleum traps. Along structural breaks, gold is selectively concentrated within favorable stratigraphic units. Host stratigraphy controls the character of the ore, including average grade, grade variability, physical properties and metallurgical response.

Jan 1, 1989

By W. D. Diment

The concept of flying employees in and out of remote mine sites on a regular rotation basis, rather than establishing permanent support communities nearby, has gained increasing acceptance by mine operators, unions and regulatory agencies in Canada. The development of successful fly in/fly out programs and resultant compressed work schedules is dependent on meeting design requirements through comprehensive research of worker profiles to ensure the selection of suitable employees and the implementation of satisfactory working conditions. This paper presents an overview of Canadian mine industry practice with regard to the fly in/fly out mode of operation and compressed work schedules.

Jan 1, 1987

By Lawrence K. Nordell

Historical methods of designing steel cord belt splices are compared with modern finite element modeling (FEM) methods. Dependence of the belt strength rating on the splice dynamic fatigue strengths is reviewed. A number of splice schematics are examined, using simple spring theory and FEM methods. Steel cord wire rope design is discussed. The importance of the insulation gum rubber properties and their splice dimensional factors and tolerances are analyzed. Splice fatigue lie analysis procedure is reviewed. This may be used to predict splice life or time of failure, depending on how the conveyor belt is operated.

Jan 1, 1993

By R. K. Mehta, M. G. Bersch

Characterization of an ore or mill product is routinely performed by time consuming and tedious chemical analyses, sink-float separations, etc. Additionally, these types of tests do not provide data concerning the interrelations and interlocking of the mineral constituents. This paper discusses some of the applications and capabilities of the Minerals and Material Science Research Center at The University of Alabama. Back-scattered electron images of coal, oil shale, complex suldfide, and tantalium ores were acquired using a JEOL 8600 electron microprobe with a NORAN (formerly Tracor Northern] 8500 image analysis system. Methods of analysis and typical results are discussed.

Jan 1, 1992