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By William M. PhD. Schafer

The net acid generation (NAG) pH method is an important analytical tool that supplements static and kinetic tests for assessment of the acid generation risk of rock samples. This method is useful because it is simple, rapid and cost-effective; it combines features of the static and kinetic tests; and it can be conducted at mine assay labs. The NAG pH test is particularly effective for operational testing programs used to classify, selectively handle, and route potentially acid-generating waste rock. The NAG pH procedure is based on a 24 hour oxidation of a pulverized rock sample with hydrogen peroxide and subsequent measurement of the sample's pH. If the NAG pH is below a critical value, determined empirically, then the sample has the potential to generate acid in the field. The critical NAG pH value is typically within the range of 3 to 4.5, but the exact relationship between NAG pH and potential acid generation should be determined individually for each mine site, based on comparison with results of acid base accounting, humidity cell tests, and mineralogical analyses. Calibration and use of the NAG test for predicting ARD risk at several mines are described in this paper.

Jan 1, 2000

Coal fly ash and flue gas desulfurization (FGD) sludges can be returned to mine pits, fills and revegetation zones in Virginia by regulation if (and only if) a positive beneficial use can be shown. Utilization of alkaline fly ash for control of acid drainage from pyritic coal processing waste piles, and use as a soil amendment for revegetation, are the two dominant beneficial uses proposed over time. Both applications must be controlled by the basic chemical properties of the ash proposed for utilization. Currently, public concerns over long-term As and Se leaching from various applications are increasingly driving regulatory options for mine site utilization. Many fly ash materials are relatively low in inherent alkalinity or neutralizing ability, and certain ashes are actually acidic. Failure to add sufficient total alkalinity will result in strong acidification of the ash utilization zones, stripping heavy metals like Mn, Zn and Cu from the fly ash matrix. Similarly, if alkaline ash is loaded into non-acid forming coal wastes at high rates such that leachate pH is > 9.5, significant leaching of As and Se has been documented in large scale laboratory leaching columns. Utilization of fly ash and FGD as a mine soil amendment for revegetation is based upon combined liming and water holding capacity benefits, however, levels of soluble salts (primarily sulfate and borates) limit one-time application rates to 100 Mg/ha or less.

Jan 1, 2006

By Roger K. McLimans

Sphalerite in the ores is multi-banded. Based on color and textures, bands in samples separated by a few kilometers may be correlated. Darkness of color is directly related to iron content. Isotopic and fluid inclusion data indicate that temperatures of ore deposition were 225°C-50°C. The agreement between these two sets of data suggests that chemical and isotopic equilibrium were established. The salt content and hydrogen and oxygen isotopic compositions are similar to present-day values of oil field brines suggesting a similar mode of origin. Ore transport and deposition are not adequately explained by either chloride or bisulfide complexing. Necessarily, other mechanisms were involved.

Jan 1, 1979

By E. Topuz, J. Mastoris

The problem of defining the optimum final limits of an open-pit mine has challenged the mining industry for the last three decades. The difficulty results mainly from the great number of variables involved and from the sheer computational effort required in real-life applications. An actual lignite deposit is used in this study to introduce and apply a new methodology that can be used as a basis for surface-mine design optimization. A geologic-reserves model of the deposit is first developed with the use of an integrated geostatistical-modeling package. The model is transformed into an economic one through the use of flexible objective function formulation(s). The final open-pit limits are then optimized using a competent commercial optimizer, and comparative-sensitivity analyses are performed to study the effect of some basic mining and economic parameters on the optimal pit design. The conclusions drawn can develop useful guidelines for decision making by the mine operator.

Jan 1, 1996

The response of 174 domestic water supplies to longwall mining of the Pittsburgh coal seam was compared to various physical parameters. Sixty-four percent of domestic water supplies returned to service without the need for intervention, while thirty six percent required intervention to reestablish a suitable water supply. Domestic well response is strongly correlated with the topographic setting. Valley wells showed the least effect while hilltop wells showed the greatest effect. Well response was also found to be correlated to the location of the well above the mining with greater effects observed in zones of surface tension and compression, and fewer effects in zones which are stress neutral. Ground water supplies remained unaffected or were re¬established at 149 of 150 sites, indicating that ground water resources remain available to domestic wells after mining. Results of this study support the stress-relief model of ground water flow in the Northern Appalachian Basin. Longwall mining's effect on this system is to locally increase fracture connectivity in the near surface zone. This may shift the zones of saturated fractures to greater depths beneath hilltops and hillsides, and increase recharge and storage in valleys. General trends in well response are predict¬able utilizing the stress relief conceptual model, the topographic setting of the water sources, and their location over the mine.

Jan 1, 1986

By A. D. Davis

The former Homestake gold mine at Lead, South Dakota, has been selected by the National Science Foundation as the proposed host site for the Deep Underground Science and Engineering Laboratory. The deep laboratory and associated research campus will be developed at approximately the 7700-ft level. Plans also include the development of the Sanford Underground Science and Engineering Laboratory at the 4850-ft level. After the mine?s pumps were shut off in June, 2003, water levels rose to approximately the 4650-ft level by early 2008. Pumps in the 8150-ft deep mine were turned on again for dewatering in April, 2008. Instrumentation is being installed in the mine to measure water-level declines during pumping, for later analysis of permeability and related hydraulic properties of the formation. Pressure-sensitive transducers and data loggers will provide real-time information on water levels that will be available to interested parties. Quality of the water also will be monitored as it is pumped from the mine. I

Jan 1, 2009

By André Vervoort, Jef Caers

Compound lognormal distributions serve as new generalized distribution laws for analyzing and estimating ore value distributions or related properties such as the average ore grade. These models are an alternative to the well known lognormal distribution. They are the translation of general geological constraints on the genesis of the deposit cumulated in suitable statistical properties. In this paper a maximum likelihood framework is established for estimating the parameters of such laws or parameter functions thereof. It is shown that under certain conditions maximum likelihood estimation is accurate and efficient in estimating the mean value even when relatively few samples are available. The method is based on a numerical maximization of the likelihood function of these models given the data. Confidence limits on these estimates are set up using resampling techniques such as the bootstrap. By this a complete methodology is presented for inference on ore grade distributions such as is shown in an example of gold data from the Merriespruit mine (South Africa) and the diamond size distribution of the Bougban deposit (Guinea).

Jan 1, 1996

By K. Vanbroekhoven

An industrial site near the centre of a historical town in Flanders is characterized by chromium(VI) contamination of the groundwater. Since the potential for natural attenuation was not sufficient to control the groundwater plume as observed from different analyses like pH, Eh, soil oxidation and reduction capacity, the feasibility of site remediation based on in-situ bioprecipitation of chromium was examined in lab microcosm studies. By creating reducing conditions by addition of a carbon source in the groundwater, chromium(VI) can be biologically reduced to chromium(III), which can form an insoluble precipitate of chromium(III) hydroxide. Microcosms contained contaminated groundwater and aquifer samples that were collected and manipulated under anaerobic conditions. Three different carbon sources were screened for their effectiveness: molasses from sugar beet production, molasses form starch production (protamylasses) based on potato juice and lactate. The different concentrations of sugar molasses were used to determine the optimal conditions. A range of parameters was monitored at regular time intervals for a period of six months such as chromium(VI) and chromium(III), DOC, methane, pH, Eh. A rapid conversion of chromium(VI) to chromium(III) was observed for all conditions tested. However, extensive removal of chromium from the groundwater by precipitation was only achieved for a limited number of conditions. In general, lactate was found to be the most effective carbon source, slightly better than the lowest concentration of sugar molasses that was tested, which itself was more effective than molasses based on potato. Higher concentrations of molasses, although causing a steeper decline in redox potential, resulted in less effective Cr removal. Typically, the fermentation of molasses results in acidification and this drop in pH may hinder the formation of insoluble chromium(III)hydroxides. It may also be possible that certain components of the molasses form soluble complexes with chromium(III). For lactate, no significant drop in pH was observed. Following the laboratory microcosm tests, the stability of the chromium precipitates was examined by performing a sequential extraction on the microcosm materials. These were performed under redox conditions which were similar to the ones observed in the field. Since the outcome of these tests was positive, a pilot scale test was implemented in the field in April 2005. Two different substrates, the cheap waste product sugar molasses and lactate are being injected creating two different impact zones and typical parameters are monitored. Frequent re-injections were important to maintain reduced conditions and are carried out three-weekly up to now. To study the stability of precipitates formed, mesocosm socks containing aquifer material were installed in the monitoring wells and harvested at regular intervals. Results of this pilot test will be presented and compared to the laboratory results. Based on the success of this field test, a full scale process will be designed and implemented as remediation strategy.

Jan 1, 2006

By Pieter C. van Aswegen, J. A. Brierley, C. L. Brierley

The bacterial-oxidation (BIOX®) process for the pre-treatment of refractory ores for gold recovery is marketed by BlOMlN Technologies S.A. The process was originally developed by GENMIN who is still providing testwork, design and commissioning assistance to BIOMIN. Since 1986 three BIOX® plants have been commissioned by GENMIN. A further two plants will be commissioned during 1993 and 1994. The commissioning and operational experiences from these plants are described in the paper.

Jan 1, 1993

By Alan R. Grant

Interpretation of presently available geological information indicates that most of the periods of significant metal deposition in the Washington Cascades Range are, at least in part, genetically related to late Cretaceous -Tertiary intrusive episodes. Chemically, the most favorable environment for base metal deposition is high in potassium. Characterizing the advanced stages of these chemical alteration conditions are the silicate mineral assemblages orthoclase and/or secondary biotite. Wall rock alteration includes both deuteric and hydrothermal processes, the intensity of which primarily depends upon the degree of fracturing in the country rock prior to the introduction of secondary material. Broadly speaking, the primary physical controls for the distribution and concentration of sulfides appear to be a series of structural couples involving both northwest (paralleling regional trends) and northeast--striking systems. Meaningful base metal exploration in the Washington Cascades demands a basic understanding of the various geologic factors related to the distribution of the sulfide deposits. Any geologist contemplating Cascade work should be well grounded in the fundamental concepts of petrology and structure.as these constitute two of his most beneficial aids. The acquisition of the detailed data necessary for this understanding may seem a bit academic, yet it has been demonstrated in numerous instances that a fair economic appraisal of a particular property or mining district depends primarily upon the ability of the geologist to recognize the subtle environmental differences which could lead to the discovery of a major ore deposit.

Jan 1, 1971

By J. O. Costello

Marble is a preferred surfacing material in up-scale buildings. Its use increased in the 1870's with rising national wealth and declined in the 1950's when synthetic materials for these applications were developed. Natural marble is now limited to high-end domestic and commercial structures. Cultured marble is a paste of white marble dust and polyester resin cured in molds yielding fixtures of specific finished dimensions. Dyes incorporated at different stages in the mixing cycle mimic shades and veining of natural marble. This paper discusses the filler requirements for cultured marble production and reviews new techniques to cut and finish natural marble.

Jan 1, 1999

By O. Tsuge, G. Hoffman

ITmk3®(Iron Technology Mark III) is an innovative new ironmaking technology whereby high quality iron nuggets are produced directly from iron ore fines and coal in a rotary hearthfurnace1). The reaction mechanism has been investigated in detail through fundamental laboratory research2)3), and the ITmk3 process has progressed from the laboratory to commercialization by the success of the pilot plant tests initiated at Midrex’ Technical Center and at the Kakogawa Bench Plant (KBP) located at Kobe Steel Ltd. Kakogawa Steel Works4)5). Pilot operations have demonstrated rapid production of the iron nuggets with complete metal/slag separation at a relatively low operating temperature. The Kakogawa Bench Plant (KBP) in Japan has logged 21 days continuous operation during which high quality iron nuggets were produced directly from fine ore and coal. The operation technology and the engineering data obtained from these pilot tests were instrumental for the scale-up of the ITmk3 process for the Mesabi Nugget Corp. pilot demonstration plant, which is located at Cleveland Cliffs Inc. Northshore Mining iron ore pellet plant in Silver Bay, MN. The ITmk3 process is an ideally suited technology for siting at the iron ore mine, as it allows the economical production of a value-added merchant iron product.

Jan 1, 2003

By J. C. Willett, J. R. Sanfilipo, S. M. Podwysocki, P. D. Warwick

The U.S. Geological Survey is concluding an assessment of the major coal regions of the country. In this program, the quantity and quality of coals that are expected to be mined during the next 30 years are characterized. For the Gulf Coast region, the evaluation includes reviews of the stratigraphic setting, coal resources, and the quality of the Cretaceous to Eocene coals in four coal-producing areas. The coal-bed methane potential for these areas will also be evaluated. The results of these efforts will be a series of digital maps, text, and tables that will be published in a CD-ROM format.

Jan 1, 2000

By John M. Ackerman

In the spring of 1988, Freeport-McMoRan Resource Partners Ltd. Partnership, IMC Fertilizer Inc. and Homestake Mining Co., as joint venturers, were awarded the sulphur lease for Main Pass Block 299, lease number OCS-G 91372. This was one of 11 leases awarded to the joint venturers. Following the initial discovery wells in December 1988, delineation drilling confirmed proven sulphur reserves of 68 Mt (67 million long tons). Proven, recoverable oil and gas reserves are 6.2 Mm3 (39.4 million bbl) and 1114 Mm3 (7.2 billion cu ft), respectively. Development of the sulphur mine was given approval as a fast-track project in 1989. The oil and gas reserves were acquired from the original hydrocarbon lessee in 1990 and were also given fast-track status. Fast-track for these projects meant design and engineering would not be complete before construction began. Joint venture The Main Pass Joint Venture is one of 13 joint ventures formed between Freeport and three other companies - IMC Fertilizer, Inc., Felmont Oil Corp., a wholly owned subsidiary of Homestake Mining Co., and Texasgulf Minerals and Metals Co. Felmont has since changed its name to Homestake Sulphur Co. Texasgulf assigned its interests to its parent company. Texasgulf did not participate in the Main Pass 299 joint venture. Joint venture negotiations, anticipating a lease sale in mid-1988, began in December of 1987. This joint venture, the first of its kind, was created to acquire offshore leases, explore, develop and mine sulphur. The Interior Department's Minerals Management Service (MMS) announced a lease sale date of Feb. 24, 1988 on the first business day of 1988. This greatly accelerated the joint venture negotiations. Of the 13 leases the joint ventures bid on, 11 were awarded. Freeport holds its interest in all the leases through its ownership interest in Freeport-McMoRan Resource Partners, Ltd. Partnership. Resource Partners is the operator on all of the leases.

Jan 1, 1992

By S. Monette, D. B. Dreisinger, D. Vleeschhouwer, G. B. Harris, G. A. Kordosky

A new process for the recovery of pure (>99.95%) palladium and platinum is described. The process, which has been tested at the pilot scale, comprises (i) the simultaneous solvent extraction of palladium and platinum by a new Schering Berlin reagent, TN 1911, (ii) washing of the loaded extractant to remove co- extracted impurities, and (iii) differential stripping of first platinum at pH 3, and secondly palladium with strong hydrochloric acid, and (iv) precipitation of palladium and platinum salts, followed by reduction to metal. The process is, unusually, a non-ammonia one requiring only small amounts of ammonia at the end where final purification may be necessary for particularly complex feed solutions.

Jan 1, 1993

By R. E. Ray

As coal reserves at shallow depths continue to be exhausted, a number of US coal companies are developing seams previously considered too deep to mine economically. Because of increased cover load, mines operating in deeper seams face unique ground control problems. In addition, the volume of methane gas in coal beds increases with depth, and ventilation requirements are much more stringent for deep mines than for shallower mines. When the longwall mining method is wed at great depths, ventilation, ground control, and operational considerations all influence the design of longwall panels. This paper examines these influences, particularly ventilation and operational considerations, on the feasibility of two-, three-, and four-entry longwall development panels in Jim Walter Resources' four deep mines.

Jan 1, 1988

By N. K. Dumakor-Dupey, K. J. Bansah

"We made site visits to determine potential environmental issues caused by artisanal and small-scale mining (ASM) in the Tarkwa Mining Area (TMA) of Ghana. Activities of the diggers were observed to degrade vegetation, land and water. Improper handling of mercury was also identified as a major threat to people and ecosystem. Large abandoned pits and trenches posed fall traps to farmers, hunters and wildlife. We argue that lack of adequate monitoring and regulatory enforcement by Ghanaian authorities, together with inappropriate mining processes, probably due to lack of technical expertise are contributing factors to the environmental issues of artisanal and small-scale mining in the TMA. INTRODUCTION Environmental degradation caused by artisanal and small-scale mining (ASM) has been a major concern to many people and governments around the world. ASM is often associated with health, safety and environmental issues in communities where it is practiced (Kitula, 2006; Asiedu, 2013; Sousa et al., 2010). Some of the environmental issues that have been reported include land degradation, mercury contamination, cyanide release, and pollution of rivers/streams. These issues have been attributed to improper mining methods, inefficient technology, lack of technical training and environmental awareness, and lack of regulatory enforcement (Serfor-Armah et al., 2005; Bansah et al., 2016a; Hentschel et al., 2002). In Ghana, ASM typically occurs in rural communities, providing jobs to many people and contributing towards socioeconomic growth of the country (Banchirigah & Hilson, 2010; Bansah et al., 2016b; Osei-Kojo & Andrews, 2016). As a result of the environmental issues, many people have called on government to develop drastic measures to control ASM operations. It is in this regard that this paper examines potential environmental issues caused by ASM in the Tarkwa Mining Area in Ghana, and suggests mitigation measures to ensure environmental sustainability. ASM in the area comprises of registered (licensed) and unregistered (unlicensed) operations that adopt surface or underground mining methods to exploit gold-bearing materials. Surface operations typically involve clearing of vegetation, removal of overburden, excavation of mineral deposit, washing/grinding of excavated gravels and processing with mercury. Except grinding, washing and mercury recovery, underground operations are conducted below ground with limited impact on the surface. Alluvial mining is also commonly practiced in streams and along river banks. These activities can have devastating impact on biodiversity of the ecosystem. To achieve the objective for this study, field visits were made to ASM sites to observe operations and interact with diggers. Visits were also made to host communities of ASM and government officials to obtain their perspectives on ASM in relation to environmental impact. The study area (Tarkwa Mining Area) is located in the Western Region of Ghana (see Figure 1). It is endowed with natural resources such as gold and manganese. Hence, mining is the major economic activity in the area. ASM is widespread, with 15 registered operations and several unregistered mines. The environmental issues observed in the study have been grouped into three main categories: vegetation and land depletion; water quality and pollution issues; and mercury contamination issues."

Jan 1, 2017

By A. D. Davis

Limestone-based technology for arsenic removal from water is an innovative and promising method. The technology offers the potential for low-cost disposal of a stable waste product after arsenic removal, either in an ordinary landfill or by encapsulation in concrete. Leaching research described in this paper shows that the limestone waste, after encapsulation in concrete, passes the Toxicity Characteristic Leaching Procedure (TCLP) test. Leaching was less than 0.05 mg/L, which is 1/100 of the U.S. EPA?s standard for disposal of arsenic in a landfill. Disposal of arsenic-enriched waste is critical for commercial viability of arsenic-removal technologies. Low-cost disposal gives the limestone-based method an advantage that could help communities meet the new maximum contaminant level of 10 parts per billion for arsenic in drinking water. The ability to recycle the waste material in concrete could add a significant economic benefit, further reducing overall costs.

Jan 1, 2009

By P. J. Miranda, C. G. Anderson, L. G. Twidwell

Titanium is a metal of increasing worldwide strategic importance. The Center for Advanced Mineral and Metallurgical Processing (CAMP) at Montana Tech of the University of Montana is currently directing two titanium research initiatives. The first program, Titanium Extraction Mining and Process Engineering Initiative (TEMPER), is focused on producing low cost titanium through the identification and development of new mining, beneficiation and extraction technologies which will significantly reduce the cost of titanium production. This will directly benefit worldwide commercial applications. Secondly, CAMP is evaluating new technologies for fabrication of titanium utilizing the Free Form Titanium Fabrication (FFTF) initiative. These technologies may drastically reduce the cost and time to manufacture titanium components. Because of the high strength to weight ratio of titanium coupled with its superior corrosion characteristics, these programs will be of vital importance to expanding the commercial and strategic applications of titanium. An overview of these two new titanium initiatives will be presented in this paper.

Jan 1, 2005

By James McKelvey, Larry Drolet, Jason Swartz

INTRODUCTION When divers discovered that sections of a tunnel housing the pipeline that conveys wastewater from the Charleston Peninsula to the Plum Island Wastewater Treatment Facility had caved in, the Charleston Commissioners of Public Works(CPW) moved quickly to determine a long term solution for the city’s collection system, immediately focusing on the Ashley River sewer tunnel along the western boundary of the peninsula. Working with the Charleston community, as well as federal, state, and local officials, CPW developed a fast track yet long life design that can be used as a model for underground construction of tunnels in urban areas. The paper that follows summarizes key aspects of the Ashley River sewer tunnel project. HISTORICAL CHARLESTON Charleston, South Carolina is a culturally significant and historic city that was originally settled in 1670. There are over 100 buildings on the National Register of Historic Places within the Charleston area. Additionally, the first shots of the American Civil War were fired at Fort Sumter in the Charleston Harbor in 1861. As one can imagine, tourism generates significant business for the area with over 1.5 million people visiting Charleston each year. No project, especially one that requires digging, is done within the old city on the Charleston peninsula without careful planning. Many precautions are necessary to prevent damage or disruption to the historical properties. The Ashley River sewer tunnel project is exclusively in the old city. A lot of work was done during the design phase to minimize the impact to historical properties. Some of this work included: an archeological study (where pre-digs were monitored at all shaft sites by an archeologist); a building/structure assessment study (where structures near a shaft site were completely surveyed and cataloged); and an environmental study.

Jan 1, 2005