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By B Scheiner, D. A. Stanley

Introduction Treatment of ores to recover metal and mineral values results in waste materials usually in the form of dilute slurries. The US Bureau of Mines (USBM) investigated a technique for dewatering phosphatic clay waste by flocculating with polyethylene oxide (PEO) and dewatering the resulting floes on a static screen and/or trommel screen (Schemer et al., 1985). In the investigation, it was determined that PEO was far superior to polyacrylamide polymers for this type of dewatering. This paper discusses reasons for this superior performance. Comparison of PEO with polyacrylamides Dewatering experiments were conducted by adding PEO solution from a burette to a stirred clay slurry. The dewatering endpoint was characterized by rotation of the floc mass as a unit, a clear supernate, a maximum floc size, and a minimum floc volume. Additional water was removed from the floes by hand squeezing (Schemer et al., 1985). The clays investigated were sodium, potassium, magnesium, calcium, and aluminum exchanged montmorillonite and attapulgite. Nine commercially available (Superfloc) polyacrylamides were compared with PEO at two polymer concentrations. Results are summarized in Table 1. The solids content of the dewatered clays ranged between 24% and 33% and was highest for PEO-treated material. These results and the data in Table 1 indicate that PEO is superior to polyacrylamide in terms of polymer dosage required. Superflocs 16 through 128, like PEO, are nonionic and should give similar results to those for PEO if the flocculation mechanism is the same for both type polymers. Superflocs 204 through 214 are anionic with increasing anionic character from 204 to 214. Generally, the anionic polymers gave the best results for the polyacrylamides tested, but in terms of dosage they were not as good as PEO. Correlation between flocculation and dewaterability of waste slurries The overall mechanism for mechanically induced clay dewatering is not completely known, but certain observations can be made. For instance, when a polymer is adsorbed on a clay such as montmorillonite, the polymer desorbs interlayer water. Polymer adsorption is driven by favorable entropy changes associated with this water desorption. It is also known that the -CH2-CH2- links of the PEO chain are sufficiently hydrophobic to lead to physical adsorption of the polymer (Theng, 1979). For montmorillonite slurries, the sheet-like fundamental particles, called tactoids, consist of a small, variable number of aluminosilicate layers together with interlayer water and exchange ions. The flocculation process consists of adsorption of polymer on the tactoid. Loops and tails of polymer that extend into solution then adsorb on another tactoid, forming a bridge. Mechanical action, induced by hand squeezing or in a trammel, joins the bridged tactoids face-to-face and edge-to-edge to form regions of high density. Similar orientation effects are observed for the needle-like attapulgite crystals (Schemer et al., 1985). Proposed flocculation model Generally, statements concerning flocculation and dewaterability apply to both PEO and the polyacrylamides. However, PEO has additional interaction with the clay material when compared with polyacrylamides. PEO is a polymer with repeating -CH2-CH2-O- groups and interacts with montmorillonite through a water bridge whose strength is greatly influenced by the exchange ion. To obtain insight into this interaction, a series of experiments were conducted in which different ion exchange forms of montmorillonite and attapulgite clays

Jan 1, 1987

By Changjiang Li, Jun Yang, Qiang Fu, Xu Chang, Xing Wu, Yubing Gao

With the development of underground mining, the deformation of roadway floor has increasingly become a major constraint on the safe and efficient production of coal mines. To address the floor deformation that was caused by massive stress concentration in roadway, an innovative method based on deep-hole directional tensile blasting technology is put forward. By taking No.122108 working face in Caojiatan Coal Mine as engineering background and analyzing the mechanism of deformation, a numerical simulation and field test are carried out to verify the effect on deformation control of this technology. It is found that the deep-hole directional tensile blasting technology can actively control the fracture position of the roof in the gob area and cut off the stress transmission path, so as to relieve the stress in the roadway. And since different blasting parameters have different impacts on the stress relief effect, a numerical simulation is implemented and it is found that the stress relief effect is the best when blasting depth is set to be 32 m and the blasting angle be 60°. By applying the optimal blasting parameters to the field engineering test, it can be seen that the deep-hole directional tensile blasting technology could effectively reduce maximum stress value and stress field range of the both sides of the roadway, and make the stress field far away from the roadway, thus effectively controlling the deformation of the roadway floor. The deep-hole directional tensile blasting technology can effectively solve the problem of roadway floor deformation and can be safely applied to engineering sites.

Jun 13, 2023

By Stephen D. Hill, C. R. Ferguson, T. H. Jeffers, P. G. Bennett

The U.S. Bureau of Mines' Salt Lake City Research Center has developed porous polymeric beads containing immobilized non-living biological materials for extracting metal contaminants from waste waters. Immobilized biological materials include peat moss, algae, biological polymers, and other materials that demonstrate high affinities for heavy metals. The beads, designated as BIO-FIX beads, have distinct advantages over traditional methods of utilizing biological materials in that they have excellent handling characteristics and can be used in conventional processing equipment or low-maintenance systems. Toxic metals such as copper, cadmium, zinc, lead, and mercury are several of the many heavy metals effectively removed from mine waste waters using BIO-FIX beads, Continuous cyclic testing indicated that the beads continued to produce treated effluents which met National Drinking Water Standards (NOWS) after 150 loading-elution cycles. Adsorbed metals were removed from the beads using dilute mineral acids. In many cases, the extracted metals were further concentrated to enable processors to reclaim the metals, thus minimizing the generation of a hazardous sludge, Tests indicated that use of the beads in a low­maintenance system was particularly effective for treating remote acid mine drainage waters and small toxic seeps from hard-rock mining districts.

Jan 1, 1991

By Tom Ireland, Tony Rock

The proposed 1.83km long twin bore A3 Hindhead road tunnel planned for contruction in 2008 is being delivered under a Highways Agency Early Contractor Involvement (ECI) contract. The proposed construction methodology is progressive mechanical excavation of a horseshoe shaped tunnel with shotcrete installed close behind the face using robotic spraying equipment. The tunneling medium is a ‘soft rock’ sandstone for which there was little previous tunneling experience, requiring extensive geotechnical investigations and an innovative approach to lining design. A 240m long portal section though sandy material utilising a steel pipe umbrella is also required. This paper describes the development of the tunnel planning and design including the most recent developments in UK road tunnels, and the innovation included in the ‘permanent’ primary lining design.

Jan 1, 2007

By Edward S. Plotkin

The tunneling construction industry faces a new challenge in endeavoring to comply with the multitude of regulations and standards of the Occupational Safety and Health Administration and to work following accepted and experienced tunneling practices. Tunnel inspections appear to be gaining in priority. The national OSHA inspection activities reported for the year 1976 in the construction industry are as follows: 989 Inspections 45 As result of Accidents 186 As result of Complaints 605 General 153 Follow Up 34% Were found to be in compliance 714 Citations were Issued 1,825 Violations were found (201 of which were serious; 1573 were non-serious; 51 were imminent danger. There were no recorded failures to abate a violation in our industry.) The five general priorities by which a company would be scheduled for an inspection in descending order are: imminent danger situations, reports of fatal accidents or catastrophies, inspections in response to valid employee C( taints, inspections of work places covered by National Emphasis Program NEP, (OSHA's NEP has been designed to impact on any industry having a very high injury or illness rate) and finally random inspections of work places covered by OSHA. The following criteria in selecting companies for random inspections is used by OSHA.

Jan 1, 1979

By T. Mudder, R. Cellan, R. Waterland, J. Whitlock, B. N. Nelson

The effectiveness of anaerobic in-situ biological treatment for the immobilization of selenium, molybdenum, and uranium in an alluvial aquifer was examined using long-term column tests. A series of organic substrate and nutrient combinations were tested to determine removal effectiveness, optimum supplement concentrations and ratios. Final column testing was conducted to determine the chemical stability of the treatment by-products/treatment compounds by dosing the columns continuously with elevated redox untreated alluvial groundwater.

Jan 1, 2002

By A. Pezzuto

"Pipes are used on mine sites in a variety of applications including transport of slurry, conveying clean and processing water, and in mine dewatering. Mine waters and slurries can cause pipe wear and failures via several mechanisms (or combinations thereof) such as abrasion, scaling, and corrosion. Polyethylene (PE) pipe materials have grown in popularity over the past several decades due to their chemical and mechanical properties (e.g., inertness, flexibility, relatively low density) and low cost. While PE is generally resistant to corrosion, it is subject to abrasion. To combat this, a novel, rubber-like liner is in development. In addition to comprehensive abrasion testing, however, the liner must be evaluated to see how it performs under other conditions. Here, a brief field study is described that tested PE pipes with the new liner against traditional PE pipes to specifically assess mineral scale buildup. The study was conducted in the Reiche Zeche study mine in Freiberg, Germany in six different locations with varying water qualities and flow conditions. INTRODUCTION Water and slurry conveyance are major operations on and around mine and mill sites, from mine dewatering, to tailings transport, to water treatment processes. Conveyance systems in such applications can include great lengths of pipe materials along with pumps and monitoring instruments, and thus represent significant capital investments. Due to the variability of the physical and chemical properties of water and slurries, pipe materials are subject to a wide range of conditions. These can cause pipe wear and eventually failure leading to serious economic, environmental and social, consequences. While pressure-induced pipe failures (e.g., ruptures or ""bursts”) can be immediate, most failure mechanisms involve gradual processes. Scaling and sedimentation can present major problems for pipe systems conveying highly mineralized waters. Sedimentation generally refers to the deposition of suspended solids, such as sand, clay, silt, or organic matter onto pipe surfaces. This phenomenon can occur due to a decrease in water velocity or particle collisions with the pipe wall. Scaling, on the other hand, commonly refers to the deposition of precipitated mineral salts (including oxides and hydroxides) onto pipe surfaces. Mine waters often have extremely high ion concentrations (i.e., high dissolved solids content) due to their interaction with enormous surface areas of minerals, which are exposed during mining and processing operations (Brown and Barley, 2002). As these waters are transported, slight changes in temperature, pressure or chemistry (e.g., pH or ORP) can cause instability with respect to ion solubility such that salt precipitation begins to occur. “Seed” crystals can rapidly grow and attach to pipes, either due to local surface phenomenon near the pipe wall (e.g., which can promote coagulation) or sedimentation of the precipitated solid. Whether due to suspended or precipitated solids, as the solids begin to stick to pipe walls, “aging” or hardening processes can commence; and the build-up of scale can become self-perpetuating as the scale itself provides an attractive “nucleus” for further attachment of particles or crystal growth (Muryanto et al., 2014). Over time, scale-buildup reduces the effective pipe diameter, which can ultimately result in decreased flow velocity, clogging and, in some instances, bursting (Dirany et al., 2016)."

Jan 1, 2017

By Spencer R. Titley

Nearly three decades of intense research, corresponding with a period of unparalleled discovery and the advent of scientific advances and hypotheses of ore formation, has resulted in a great body process-focused research concerning how ore deposits form. The development of process models and their application has proceeded more or less in step. Discoveries have been made in mineralized regions such as provinces and districts but generally without a comparably developed understanding of why provinces and ore bodies exist and, except in general terms, where ore deposits are within districts and regions. The process of discovery is still referred to as search and exploration budgets are heavily weighted toward exploration drilling.

Jan 1, 1995

By P. I. James, M. R. Baker

Este artículo analiza la nueva producción de cobre a partir de "minerales de desecho" de baja ley usando la tecnología de Blue Planet Strategies DEMET™ (Dynamic Electrode Mining Effluent Treatment, por sus siglas en inglés), que tiene como objetivo salvar la brecha de procesamiento entre la solución débil de lixiviación en operaciones de extracción por solventes/electrowinning (SX/EW), removiendo electroquímicamente los metales a partir de corrientes débiles y a la vez generando productos concentrados en metales objetivo en un análogo funcional de extracción por solventes (SX). Se estudió el tratamiento de la débil solución de lixiviación pregnant (PLS por sus siglas en inglés) y se usó para estimar los impactos económicos y de producción para una hipotética lixiviación en pilas de cobre brownfield y una operación aumentada DEMET usando SX/EW para tratar el "mineral de desecho." Se presenta la remoción de cobre a un 86% de eficiencia en las placas por debajo de 0,1 g/L de cobre con un consumo de energía de 0.55 kWh/lb de cobre y una concentración del producto mayor a 10 g Cu/L. El modelamiento arrojó aproximadamente $2/ lb para la producción total de cobre y costos de tratamiento menores o iguales a $1/lb con un inmediato aumento del margen bruto de operación del 12% para el brownfield incrementado. Se indicó también un aumento de la vida de la mina con un margen bruto promedio de 38% en la producción aumentada de "mineral de desecho" con valores de cobre de $3.25/lb.

Jan 1, 2014

By James H. Boettcher

In the second quarter of 1979, ASL Inc. inquired whether Crocker National Bank ("CNB") would provide $4 million in term loan financing to help ASL acquire the outstanding shares of the S&S Coal Company in West Virginia. ASL had, prior to approaching CNB, sought financing with the assistance of a financial advisor from a number of commercial banks without success. A summary of the initial terms requested by ASL is shown in Table I compared with the actual terms the transaction closed with. It is not difficult to note that the two sets of terms differ significantly. This is often the case when financing requests based on the expectations and vision of a mine developer are juxtaposed with more pragmatic requirements of a commercial bank. The "art" and fun of structuring financing plans for mining ventures (highly leveraged acquisitions or grass roots) comes in working with mine developers to arrive at a final financial structure that meets their objectives and constraints as well as those of the bank or other financial institution providing much of the financing. This article briefly describes the process we went through with ASL beginning with the terms they requested initially and ending with the ones on which the transaction was finally closed.

Jan 1, 1981

In the screening process, used to prepare particles for many applications, shape is known to have a significant effect. The degree of flakiness of construction aggregates has been considered particularly important. The objective of this research was to find values of operating parameters that optimize the separation of flaky from non-flaky particles by slotted screens. Thus an investigation was conducted to experimentally determine the influence of the particle size and thickness on the screening process. The Response surface method was employed for modelling and analysis of the data. Experiments employing a central composite design were performed on a pilot-scale, rectangular-aperture, vibrating screen to examine the effects of the screening variables the mass recovery of flaky and non-flaky particles to the oversize product. The SAS statistics package was used to fit a second-order model to each response and to analyze the fitted surface to determine the optimum levels. The optimization associated with a dual response system was then considered. The results of this study should provide a basis for optimizing screening conditions to obtain maximum recovery of non-flaky particles to the screen oversize while minimizing the recovery of flaky particles, which should be of interest to the aggregate industries.

Jan 1, 1999

By L. J. Nicks

The current U.S. Bureau of Mines research program is addressing the recovery of flake graphite from kish, a steelmaking waste product, and the use of zeolites from abundant domestic natural deposits for efficiently cleaning up mining industry wastewater. The United States is almost totally dependent on imports for its graphite needs, but this may change depending upon the results from a pilot plant being constructed by industry using Bureau technology. Standard mineral processing techniques were applied by the Bureau to recover high-quality flake graphite from kish. It was considered innovative enough to receive an R&D 100 Award in 1992, and its commercialization has the potential to supply the total U.S. demands for graphite many times over. Zeolites have ion exchange properties similar to ion exchange resins, but are less expensive and available in large quantities. Samples of naturally occurring zeolites were tested for their efficiency in removing metal ions from synthetic and industrial waste solutions. The tests focused on defining their selecting, loading, eluting, and regenerating characteristics, and on developing a method for recovering the metal ions as added value products. The results showed that the removal of metal ions with zeolites from acid rock drainage (ARD) solutions is technically feasible and that this technique has the potential for being used in an integrated chemical treatment systems approach either as a primary or secondary cleaning step.

Jan 1, 1995

By Kim Lapakko

Increasing public concern over the welfare of the environment has placed demands on the mining industry to evaluate the environmental impact of mining development. This is a difficult task and involves considering the influence of a multitude of variables on complex processes over a long time period. Few studies which focus on the evaluation of the environmental impact of mining have been conducted and, therefore, there is little past experience to rely upon. This article describes some of the work done to evaluate the potential environmental impact of mining development in Minnesota. Interest in developing the major copper and nickel sulfide deposits near the wilderness areas of northeastern Minnesota aroused concern regarding the environmental impact of mining development in the region. As a result laboratory and field studies were initiated to investigate the potential for trace metal leaching and acid generation due to dissolution of Duluth gabbro. Chemical equilibrium computer modeling was conducted to aid in data interpretation. The goals of the study included the investigation of leaching mechanisms and rates of release (1, 2).

Jan 1, 1980

By Herschel H. Potter

While preparing this paper, I soon realized I had a problem in defining what injuries should be classified as "personal." Admittedly, in some cases, falls of persons, sprains and strains, pulling and pushing injuries, and back injuries may have been caused by the individual. But, I believe the number of injuries directly attributed to an individual's carelessness is relatively small in comparison to the total number of injuries in those categories. For discussion purposes, the injuries most often considered to be personal, that is, caused by individuals are those classified as back injuries. My paper will be devoted to back injuries because this category represents the greatest number of injuries occurring in coal mining. A man's best friends are his wife, his back, and his dog. The back, however, has a reputation of not being as faithful as his other two friends.1 "Industrial back injury is one of the major occupational health problems plaguing industry to- day. According to national surveys, back injury accounts for more lost time than any other occupational injury and costs companies thousands of dollars in compensation, medical fees and over- time pay."2 A study conducted by USA Today found that back ailments afflict an estimated 75 million Americans, have totally disabled about 2.5 million adults, lead to as many as 200,000 required surgeries each year, are a leading cause of absenteeism and disability, are the second leading cause of hospitalization, are responsible for 18 million doctor visits a year and cost about 93 million work-days annually. The cost to industry is estimated at $14 billion a year.3 During the past 30 years, a great deal of accident prevention education has been directed toward the reduction of back injuries. However, this effort has not produced any great change in the incidence of the injury. Back injuries should be of the utmost concern to everyone here today. I don't need to tell you what the incidence rate is for back injuries, nor will I use any statistics to inform you of the incidence rate for the coal mine industry or any specific mine. It is only important to know that the number of back injuries is excessive. Back in- juries resulting from lifting have been and continue to be one of the most constant and undiminishing problems in the occupational environment. The fact is, we use our backs to per- form work that the back was not designed to do. Historically, manual materials handling related accidents have consistently accounted for the largest percentage of all industrial accidents. In fact, over 25 percent of all industrial accidents are related to handling of materials.4 In underground coal mining operations, material handling accidents account for even larger percentage of lost time injuries. In 1983, for example, they accounted for 34 percent of all lost time injuries and 32.6 percent of all non-lost time injuries. 5 I want to use one example of a task that will illustrate what I have just said: the building of a concrete block stopping. Each solid concrete block will weigh from 60 to 70 pounds. To build a stop- ping 6 feet high and 20 feet wide will take approximately 80 blocks. On the average, these 80 blocks will be handled at least four times from loading into the conveyance for transportation to being placed while constructing the stopping. This generally requires repetitive lifting from ground level. The next three slides demonstrate the lifts

Jan 1, 1986

By F. Aurelian

The Banat district in Romania was an important uranium mining area for the last 45 years until its closure in 1997. Uranium was present as finely dispersed pitchblende into solid bitumen lens and layers. Due to the mining activities, radioactive wastes have been disposed of in different places of the Banat area. These sites contain uranium, radium and radon and exhibit high contamination potential for environmental receptors (soil, air, waters, sediments and vegetation). Therefore the risk for human health through external and internal irradiation is considered high. The main pollution sources in this uranium mining area are mine and surface waters, waste and low grade ore heaps, dumps as well as release of radon. In this paper studies concerning recognition of pollution sources, delimitation of maps, uranium and radium solubilization and migration from dumps as well as environmental contamination of specific areas related to exploitation and exploration are presented. The risk assessment is based on the relationship ?source-pathway-target? in order to assess environmental risks and identify targets for rehabilitation. The sources causing significant contamination problems were identified by examining the pollutant linkage. The remediation plan for the Banat uranium mining complex involves mine flooding, treatment of water and leachates, as well as modification of heap slopes, application of covers and establishment of vegetation.

Jan 1, 2005

By John Mastoris, Kostis Dragasakis, Kostas Kouklidis, Shkurtë Gashi, Halil Berisha, Jenuz Bulica

Titan Group’s environmental policy and Sharrcem’s Corporate Social Responsibility (CSR) are the driving forces behind the development and implementation of a comprehensive Rehabilitation Plan at Dimce Quarry, which is the main raw material source for Sharrcem Cement Plant since the 1970’s, located in the municipality of Hani i Elezit in Kosovo. Based on an Environmental Impact Assessment Study and the approved Mining Plan and also on the principles prescribed in the Guidelines on Quarry Rehabilitation, released by the Cement Sustainability Initiative of the World Business Council for Sustainable Development (WBCSD-CSI), Sharrcem has adopted a quarry operation and rehabilitation process in line with the best practices in the mining and cement sector. This paper discusses the background for the development of the rehabilitation plan and the results of rehabilitation activities, as have been implemented over the last few years. The main objective of the progressive rehabilitation plan at Dimce Quarry is to restore the depleted pit and return it back to the original land owners for resettlement. To date approx. 3,4Ha of former mining area has been restored by backfilling and levelling of the depleted closed pit and returned back to owners, who have built their houses and turned it into a living area again. This Quarry has turned out to be a real composition and practical example of preserving and returning back the natural resources in a state compatible with the surrounding environment and with respect to the needs of the local stakeholders. The motivation for business to engage in rehabilitation activities in the first place lies in the belief that the development and implementation of a progressive and practical Quarry rehabilitation plan and restitution of the land will deliver significant environmental and social benefits that outweigh the long-term rehabilitation costs, while maintaining the company’s reputation.

Jan 1, 2017

By E. R. Bauer

The ground control aspects and occupational safety concerns of extended depth-of-cut mining are presented in this U.S. Bureau of Mines (USBM) report. The scope of extended cut use and typical face operations while extracting extended cuts is reported. A comparative review of roof fall fatalities and a statistical analysis of accidents and injuries for both extended and nonextended cut mining is included. The views and opinions on extended cutting from a series of interviews with mine workers in five states are summarized. In addition, some of the problems and safety concerns of this extraction system are mentioned.

Jan 1, 1995

By William Gleason

The world has seen unprecedented economic changes in recent years, starting with the stock market collapse of 2008 and the great recession that followed. With these changes, the mining industry, like others, has been forced to find ways to adapt to the shifting and sometimes volatile conditions. It has been a bumpy ride that has not been easy. Prices for most commodities have been in a decline in the past several quarters ? albeit still well above the average prices of 10 years ago ? as the costs of production have been on a steady incline for the past 10 years. Adding to the concern was the report in April that China, which had grown at an average pace of 10 percent/year, for the past decade, slowed to less than 8 percent gross domestic product (GDP) growth this year, catching many off guard. Even gold, once the safe haven for investors during rocky times, stumbled in April of this year, losing 7 percent of its value in two days. So what?s an investor to do ? and how can companies still attract financing? For the first time in 10 years, SME, in conjunction with the New York Local Section of SME, attempted to clear the waters of the mining finance sector with a conference focused on ?Current Trends in Mining Finance.? Held at City University of New York, Graduate Center, April 29-30, the two-day conference attracted 148 attendees and was intended for senior executives and mining industry specialists, covering a range of important topics and trends through 17 panels with about 50 speakers. The presentations came from representatives from some of the most influential companies in the mining and financial sectors, including Citi, Nomura, Societe Generale, Caterpillar, Newmont Mining Corp., Ernst & Young, Export Development Canada (EDC), KPMG, HSBC, Tocqueville Asset Management, BNP Paribas, Revett Minerals, Royal Gold, Environ and ERM.

Jul 1, 2013

By J. F. T. Agapito, R. R. Goodrich

Yield pillars have been used for many years to help reduce stresses near mine openings and improve roof and floor stability. A yield pillar is often defined as a pillar that fails but retains residual strength. Stress transfer occurs through the roof and floor after the peak strength of the pillar is reached. High stresses are transferred from around the openings onto abutments that can be barrier pillars or unmined ground. This mechanism, often referred to as pressure arching, is possible as long as the width of yield pillars is less than the critical width above which stresses cannot be carried by the overburden. Significant stress transfer also can occur due to small amounts of pillar and/or floor yielding before the peak strength is reached. This is accomplished in a quasi-elastic manner with little or no visible roof and pillar fracturing or floor heave. Long-term stability may be achieved when stresses and mechanical properties are favorable to pre-failure yielding. This paper gives practical examples where improvements in stability and resource recovery were achieved with this mechanism. Yielding was assessed by comparing measured and calculated vertical pillar stresses. Results indicated that calculated stresses in the pillars were 25 to 40 percent higher than the measured stresses, demonstrating significant arching load transfer to the abutments. Pre-failure yielding is probably often present but unintentional in both development and production areas. Better recognition and use of this mechanism should lead to improved designs as mines become deeper.

Jan 1, 2001

By Hung-Kei H. Lam

Rubidium and cesium were discovered by Bunsen and Kirchhoff about 100 years ago. These two elements are by no means as abundant as sodium or potassium. Their occurrence in minerals is widespread, but usually as minor constituents. There is no known specific ore containing rubidium, but rubidium is found replacing the. other alkali metals in .some minerals.. Perhaps the highest concentration of rubidium found in one mineral is in lepidolite, KLi(OH,F)2A12Si3010, which contains from 0 to 3.5%*Rb20. 0n the average, lepidolite contains about 0.5% Rb20. Other sources of rubidium are carnallite, KMgCl3?6H20; pollucite, H20.2Cs20.2AI203.9SiO2; rhodizite, R20.2A1203-3B203; biotite, H2K(Mg,Fe)3A1(Si04)3; sea water, rivers, marine and fresh water organisms, soils, and plants. Cesium, even though it is the least abundant. of the stable alkalies, has a specific ore. Pollucites a hydrous cesium aluminum silicate, may con¬tain as high as 42.5% Cs20, although again, the average Cs20 content is about 25% among the handful of known deposits. Other cesium-containing minerals are lepidolite and carnallite. Rubidium and cesium are very much like potassium in chemical properties, consequently, they are hard to separate. Because of the difficulty in obtaining pure cesium and rubidium compounds coupled with the scarcity-of supply, prices were high and the two elements enjoyed little industrial use. Just before the Second World War, the world. supply of rubidium and cesium, from Germany, was a matter of tens of kilograms per year and prices were about

Jan 1, 1959