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By L. W. Ashton

Geochemical exploration guidelines were developed from a study of 460 rock chip samples collected at nine disseminated gold deposits in Nevada. Obtaining high grade Au samples is difficult because gold content is extremely variable, even over 8 m (25 ft) distances. For reconnaissance sampling, pathfinder elements are reliable indicators with threshold values of 100 ppm As, 1 ppm Hg, and 50 ppm Sb. Arsenic is the most reliable of the three elements, being significantly enriched in all deposits. If the pathfinder threshold levels are reached with low Au content, more samples should be collected. Successful disseminated gold exploration requires large numbers of samples.

Jan 1, 1990

By Jozef S. Stachulak

INTRODUCTION Conveyor belt fires represent a serious hazard in underground mines. This fact is well understood in most mining countries. The statistical data for Ontario mines (1) indicates that the majority of the conveyor fires occurred at the head pulley of the conveyor belt. The main emphasis for fire prevention and detection should then be concentrated at the drive pulley of the conveyor designed to transport non-combustible material. In the case of conveyor belt fires, it is of utmost importance to detect the hazard at an early stage, when the overheating has not yet reached the ignition point. Thermal noise detection sensors were installed in 1987 at several conveyor sites at Inco mines. PRODUCTS OF COMBUSTION THERMAL DEGRADATION OF CONVEYOR BELT Various investigations on conveyor belt fire hazards have been made in the past (2, 3, 4, 5, 6, 7). Several belt samples (6, 7) were subjected to thermal oxidative degradation. The belts used in these tests were neoprene, polyvinyl chloride and styrene-butadiene rubber (6). About 70 different compounds were identified in the volatile thermooxidative products. As expected, hydrogen chloride was the major toxic product formed, accompanied by relatively low quantities of other toxic compounds such as carbon dioxide, carbon monoxide, sulfur dioxide, carbon disulfide, hydrogen sulfide, benzene, chloroprene, cresols, chloroethanol, formic acid and C8 hydrocarbons. The research investigation (8) performed by the USBM indicated that "smoldering combustibles generate a very low level of CO compared to the level of smoke produced". The cited publication (8), states that, "During smoldering combustion, typical mine combustibles produce about 2.5 times more smoke than CO. As fires develop to their flaming stages, the trend reverses and about eight times as much CO is produced as smoke." The reader is referred to several significant sources of additional information pertaining to emission products that can be found in references (8), (9), and (10). ANALYSIS OF FIRE HAZARDS U.S.A. AND ENGLAND Nearly 15 percent of all underground coal mine fires in the United States involved ignition of conveyor belts (7). In many cases, the fires propagated through thousands of feet of belt entry and created losses in the millions of dollars. Some of these fires consisted of rubber belts. Some involved polyvinyl chloride and neoprene belts that were classified "fire resistant". Typically, a belt fire begins after the conveyor is stopped. The fire is initiated by burning coal dust and grease accumulation around defective rollers or belt drives that have become heated by friction (7). An analysis of 113 conveyor fires (11) showed that 41 originated at the driving pulleys, 32 at the defective rollers, and 40 elsewhere on the conveyor system. The severity of the fire, which can spread along a conveyor road, has been emphasized by the disaster at Creswell Colliery, Derbyshire, on September 26, 1950, when 80 men were overcome and killed by toxic fumes from the fire (12). The fire started from smoldering caused by friction, and developed into a flaming combustion, propagating along the roadway containing the rubber belt at an estimated speed of 40.2 m/s (90 mph), and travelling a total of 650 m (2100 ft) THE INFLAMMATION OF CONVEYOR BELTS THE MECHANISM OF IGNITION Defective operation of a conveyor belt may start a fire in several ways: - Friction of the belt on the drive pulley. - Jamming of a guide roller, and others.

Jan 1, 1991

By B. Birol, M. N. Saridede

"Slag density is a significant factor in determining the process efficiency of the electroslag remelting (ESR) process, where calcium fluoride (CaF2)-based slag is formed synthetically to refine metal ingots. Although there are some former studies investigating the density of CaF2-containing slags, the prediction models focusing on them are applicable only to some specific systems. The present study aims to build a model to predict density for a wide range of CaF2-containing ESR slags. To investigate density for various slag compositions, CaF2-Al2O3-based and CaF2-Al2O3-CaO-based slag compositions were prepared. Additionally, some minor constituents like FeO, MgO and MnO were added to a 5:3:2 CaF2-Al2O3-CaO slag in order to investigate the effects of these constituents on the slag. The volumes of the prepared slags were measured in a tube furnace at 1450-1550 °C using the sessile drop technique, and their densities were calculated. The results showed that for the slags, density is related to optical basicity, and therefore a prediction model based on an Arrhenius equation was built. The model was tested with data from literature, and its limitations and validity are discussed.IntroductionThe electroslag remelting (ESR) process is a refining method in which a metal ingot is remelted under a synthetic slag. These synthetic ESR slags are mainly composed of calcium fluoride (CaF2), calcium oxide (CaO) and aluminum oxide (Al2O3). Other constituents like iron oxide (FeO), magnesium oxide (MgO), manganese oxide (MnO) and chromium oxide (Cr2O3) are added to this system in relatively low amounts, according to the type of steel ingot to be refined. The prediction of slag properties, such as electrical conductivity, viscosity and density, is crucial for the selection of the synthetic slag in order to obtain the required process parameters, like temperature, the passing time of the molten metal droplet through the slag, and metal-slag separation (Akbari, Reitz and Friedrich, 2009; Hara and Ogino, 1981; Mattar, El-Faramawy and Fathy, 2002; Mehrabi, Rahimipour and Shokuhfar, 2005; Presoly, Korp and Schneider, 2008).As slag density affects metal-slag separation in the ESR process, predicting the density of an ESR slag is important for appropriate refining and improved product quality. Although there are many studies investigating the density of slags (Akbari, Reitz and Friedrich, 2009; Aune, Hayashi and Sridhar, 2005; Hara and Ogino, 1981; Matsushita, 2011; Mills and Keene, 1987, 1981; Seetharaman et al., 2013; Shu, 2007; Shu and Chou, 2013; Sikora and Zielinski, 1974; Xu et al., 2012; Zhang and Chou, 2010), the prediction models built are generally valid for oxide-containing slags (Aune, Hayashi and Sridhar, 2005; Bottinga and Weill, 1970; Mills and Keene, 1987; Seetharaman et al., 2013; Shu, 2007; Xu et al., 2012; Zhang and Chou, 2010). These models were built on either the molar volumes of the constituents (Bottinga and Weill, 1970; Mills and Keene, 1987) or the thermodynamically calculated enthalpy or free energy of mixing, which can be applied to a system containing constituents sharing an ion, such as an O- ion for oxide systems (Aune, Hayashi and Sridhar, 2005; Hillert, 1980; Persson et al., 2007). Some recent studies modeled the density of some oxide slags on their optical basicity (Shu, 2007; Shu and Chou, 2013; Xu et al., 2012; Zhang and Chou, 2010)."

Jan 1, 2016

By R. D. Ellison, D. K. Shukla, D. E. Stephenson

Seals for man-made penetrations into or nearby nuclear waste repositories require several unique capabilities not common to seals for conventional underground activities. Design criteria include long functional use, extremely low permeabilities of the seal zone (including adjacent disturbed rock), and the potential for retarding radionuclide travel. This paper summarizes comprehensive seal programs being conducted by D'Appolonia for the Office of Nuclear Waste Isolation (ONWI) at Battelle, Columbus. The program schedule requires the first detailed conceptual design for a bedded salt site to be completed in 1982. Conceptual designs for other host media will follow as site exploration data becomes available. The design program is supported by a variety of office, laboratory, and field activities being conducted by ONWI subcontractors. An example is provided to illustrate the variety of efforts directed toward determining the extent of disturbance adjacent to penetrations as a result of in-situ and excavation methods. Also, the current "working design" for the shaft and tunnel seal system at the candidate Los Medanos thick salt site in southeastern New Mexico is presented.

Jan 1, 1981

By Pierre Longtin

"Replacing the aging roadway access to the iconic Golden Gate Bridge, thereby ensuring traffic safety and robustness in case of seismic occurrences, provided an opportunity for major design improvements as well as the development of a parkway that would include the construction of four new tunnels. With an eye to the future, the Doyle Drive replacement project aimed to meet the highest standards for environmental stewardship beyond regulatory requirements. Understanding that lighting equipment is the tunnel‘s subsystem that uses the most energy, the operator was looking for a sustainable solution to light the tunnels. An Intelligent Lighting Control System (ILCS), designed specifically for road tunnels, was acquired to individually control the almost 2000 luminaires lighting the four tunnels. This paper will show the results in terms of energy and operational savings generated over the nine months of operation between the commissioning and the conference in April 2016. INTRODUCTION Electrical & mechanical (E&M) equipment represents an average of 10 % of a tunnel total construction cost. Once the civil infrastructure completed, E&M equipment drives the main part of the expense during a tunnel useful life. Table 1 below describes the impact of various types of energy consumption and their cost impact in tunnels of less than 500 m. It is clear that lighting is the sub-system that requires the most energy. A good lighting strategy is the key to reducing energy consumption due to lighting and a viable solution that will bring important savings in tunnel operations.With a price of $0.14/kWh in California and a planned increase between 3% and 6% per year during the period 2013-2040, the tunnel operators could not afford to overlit the tunnels—particularly when they have to operate it for the next 30 years. However, they also need to maintain the right lighting level to ensure driver safety all the time. The Presidio Parkway project includes the Battery tunnels, which are 240 m (790 feet) and 230 m (750 feet) in length, and the Main Post tunnels, which are 280 m (920 feet) and 315 m (1030 feet) in length."

Jan 1, 2016

By Christof Brewka

Los Pelambres, 200 km north of Santiago, Chile, is the latest in a series of mega-projects developed in this part of the world. While most of its predecessors are spread over open desert, the Los Pelambres mine is nestled inside a narrow alpine valley high in the Andean Mountains. To handle the daunting task of transporting the mined copper ore more than 12 km and 1,400 vertical meters downhill to the concentrator plant, a gigantic belt conveyor system (capacity of 8700 mtph, 1800 mm wide ST 7800 steel cord belt, 2.5m diameter pulleys, an elaborate braking system including a mechanical failsafe and large reducers with a total installed drive power of 25,000 kW) has been employed. Many of these components have pushed the limits of conventional belt conveyor design.

Jan 1, 2000

By Pat DeWilliam

The Yakobi nickel-copper deposit is located essentially at tidewater in the east-central part of Yakobi Island, about 16 1 airline km (100 airline miles) west of Juneau, and can be reached by float plane and boat from Juneau and Sitka. The fishing village of Pelican, population 400, is situated 14.5 km (9 miles) to the east. An unimproved road, approximately 4 km (2.5 miles) long, connects a dock site at Lisianski Strait with the main part of the deposit known as the Basin Area (Fig. I). Other mineral occurrences are known as the Takanis, Flapjack, and Beach Areas. Another smaller nickel-copper deposit is located about 32 km (20 miles) to the south on Western Chichagof Island and is known as the Mirror Harbor nickel-copper deposit. The original discovery of the Yakobi deposit was made by S.H.P. Vevelstad about 1920 and a 47.5-m (156-ft) long adit was driven on the southwest side of the deposit in the Basin Area. The deposit was examined by J.R. Van Fleet of Union Carbide in 1930 and by J.G. Fairchild in September 1931. Stanley and Yates of the International Nickel Co. of Canada (Inco) visited the property in August or September 1937. In 1942, the controlling interest in the deposit, covered by 124 unpatented claims, was said to be held by Vevelstad and associates

Jan 1, 1991

By John Litz

The term "refractory gold ores" refers to a wide number of ore types which are not readily amenable to direct cyanidation. A number of processes have been used commercially, and a number of others have been proposed and in many cases pilot tested. The selection of the appropriate process for an ore should not be arbitrary. Ore grade may preclude some processes, but a good understanding of the ore mineralogy can guide the selection. Many present gold operations and many potential gold operations have faced or are facing problems with refractory gold mineralization. We at Hazen Research have had the opportunity to perform bench testwork and in some cases, pilot plant testing on a number of refractory ores. The data included in this paper are excerpted from the testing of fifteen ores which cover a wide range of mineralogical compositions. This paper is not intended to be a treatise on the processing of refractory gold ores. In many of these gold projects, not all of the standard process alternatives were evaluated, nor was adequate mineralogical work performed. Such is the dilemma of contract research. "If I believe that I don't need it, why should I pay to have it done." The intent of this presentation, therefore, is to show how different ores respond to the various processes, and to demonstrate that one must have an open mind when developing a process for a specific refractory gold ore.

Jan 1, 1998

By F. J. Klingler, K. M. Swaffar, M. M. Rabbaig

The Detroit Water and Sewerage Department has undertaken a $1.2 billion effort to capture and treat combined sewage overflows from various outfalls along the Detroit and Rouge Rivers in Detroit, Michigan. This program is planned to include a 455,000 m3 (120 million gallon) storage and treatment tunnel which will capture overflows from 19 outfalls along the Rouge River. The tunnel is currently in the conceptual design phase, with the bid date planned for mid-year in 2001,and completion planned for August 2005. The total design and construction cost is currently estimated to be approximately $450 million. Current concepts are for the storage and transport tunnel will be 6.1 m (20feet) in finished diameter, with a total alignment length of approximately 12,200 m(40,000 feet). The main tunnel will extend through the Traverse and Antrim Shalerock formations, while approximately 5,500 m (18,000 feet) of various diameter connecting tunnel will extend through both rock and soft ground. The project will include a total of 10 drop shafts, 13 riser shafts, various connecting structures, and a 455,000 m3/day (20 mgd) pumping station. This paper will present a discussion of the design philosophy, subsurface conditions, the various planned components, and the expected design and construction considerations for the proposed Upper Rouge Combined Sewage Overflow Tunnel.

Jan 1, 1999

By Allen D. Graham

The coal industry in South Africa is briefly outlined. Test- work carried out on bulk samples of coal in the laboratory and used in the design of the Van Dyks Drift washery are described. Factors affecting the selection of equipment and the designed capacity of the plant are discussed. A description of the crushing plant, washery and load out section is given together with performance data obtained in the final acceptance tests. New features incorporated in the Van Dyks Drift plant and in more recent plants of the Group are outlined.

Jan 1, 1982

By Daniele Martinelli, Rodrigo Winderholler, Daniele Peila

"This paper presents a technical description of an experimental procedure developed for the geotechnical characterization of granular soils conditioned for EPB tunneling using a modified direct shear box. As the main concerning parameters of the conditioned soil mass were their undrained properties, in order to preserve its pseudo-fluid characteristics, a watertight direct shear apparatus was constructed. A comparison between the results obtained under dry, saturated and conditioned conditions is presented. INTRODUCTION EPB shield machines have been used for tunneling excavation in many different types of soils thanks to the use of soil conditioning agents. These modify the properties of the soil into that of a plastic paste, thus permitting the homogeneous flow of the excavated soil from the tunnel face through the bulk chamber, the screw conveyor and finally the conveyor belt. Moreover this technique allows controlling the face pressure and its regulation in the bulk chamber, preventing water inflow when tunneling below the water table. Further advantages are a drop of the cutter head and screw conveyor torque and reduction of the friction between metallic parts and the soil, consequently reducing wear phenomena (Merritt & Mair, 2006; Vinai et al., 2007; Borio et al., 2010; Thewes & Budach, 2010; Herrenknecht et al., 2011; Barbero et al., 2012; Peila, 2014). Several studies have investigated the possibility of conditioning and the chemical materials to be used in different types of soils, mainly subdivided into three groups: cohesionless soils (sand and gravel), silts and clays, and rock masses. This various researches have set up several laboratory procedures for these achievements before and after soil conditioning, as stated in Thewes & Budach (2010) and Peila (2014) (for cohesionless soils), in Thewes & Burger (2005), Hollmann & Thewes (2013), Zumsteg et al.(2012) (for clay), in Peila et al. (2013) and Martinelli et al. (2015a) (for rock mass). Such tests should be simple to execute, reliable and easy to interpret at the in-situ excavation step. The reduction of shear strength is necessary in EPB operations, since it allows an effective transmission of the pressure from the material itself to the front. In some cases the slump is not sufficient to return a reliable result on the shear strength reduction, as in some cases some materials are behaving differently. Therefore this research is aimed to study this aspect more in detail, in order to show the effectiveness of the soil conditioning process on the material to be excavated."

Jan 1, 2016

By Howard J. Brown

The Lucerne Valley limestone mining district is in the San Bernardino Mountains, one of the major ranges in the Transverse Range Province of southern California. Several large limestone mining operations are present along the north range front in Lucerne Valley, and the area is one of the premier limestone mining districts in the country. Resources are contained in Paleozoic carbonate rocks that are part of a thick late Precambrian and Paleozoic sequence that uncomformably overlies crystalline basement. The district has been affected by multiple episodes of metamorphism and deformation, as well as by a complex sequence of late Cenozoic structural events. Detailed studies, however, have demonstrated that these rocks can be divided into formations correlatable with late Precambrian to Permian strata of the Cordilleran miogeocline. The district is the leading producer of white, high-purity calcium-carbonate products in western North America. Pluess-Staufer (California) Inc. mines and processes high-purity white limestone from extensive deposits, and is one of the largest producers of high-quality limestone fillers and extenders in the western United States. Major factors influencing the genesis of economic carbonate deposits in the district include depositional environment, post-depositional processes such as diagenesis, dolomitization and/or silicification, regional and/or contact metamorphism and associated intrusive activity, faulting, folding, uplift and erosion, and preservation from erosion. Regional geologic studies, detailed geologic mapping, intimate knowledge of stratigraphy, and recognition of complex structural relationships have proven to be invaluable tools in the discovery of high quality calcium carbonate deposits in the district.

Jan 1, 1987

Production reporting is a natural computer application and is often one of the first applications implemented by new computer users. Automation of a manual reporting system is a good place for new computer users to gain computing experience because generation of basic reports - is fairly straightforward, and automation can often be justified easily on the basis of clerical cost savings. Computers are particularly well-suited for reporting applications which generally satisfy the criteria for effective computerization. Three characteristics must be present to effectively utilize a computerized system: 1) The potential application must be precisely definable. If an algorithm for data processing cannot be developed, data cannot be processed. 2) The operation to be performed must be repetitive. If a particular function is only going to be performed once, computerized systems development is probably not justified. 3) The volume of the data to be processed must be relatively large. If only a few items of data must be manipulated, manual methods are probably adequate. Although a computer can perform only a few functions (it can compute; it can make comparisons; it can rearrange data), it can perform these functions much faster and more accurately than a human being can. The ability to classify and reclassify data in a variety of ways and the ability to summarize data make the computer an ideal tool for production reporting. Production reports can be classified into three major categories, depending on their purpose. Reports can be used for (1) informative, (2) analytical, and (3) control purposes.

Jan 1, 1979

The Carlin Trend is North America's premier gold producing district. It is located in northeastern Nevada's Elko and Eureka Counties along a northwest trending belt about 65 km (40 miles) long and 8 km (5 miles) wide (Thorstad, 1989; Jones, 1989). This trend is the worldwide reference site for epithermal, sedimentary rock-hosted microscopic gold deposits. At least 19 deposits have been discovered to date, varying in size from 933 kg to 1.08 kt (30,000 to 35 million contained oz) of gold (Fig. 1). Newmont Gold Co. and its parent, Newmont Mining Corp., jointly constitute the largest mineral right holders in the district. They own or control more than 1000 km'- (386 sq miles) in and around the Carlin Trend and own all or part of 16 out of the 19 mines and prospects identified to date. Since the initiation of Newmont's exploration activities in the Carlin Trend in 1961, 2.24 kt (72 million oz) of cumulative gold resources have been identified. Cumulative production from all mines since the start-up of Newmont's Carlin mine in 1965 to the end of 1989 was about 202 t (6.5 million oz) (Jones, 1989). The incentive of sustained high gold prices and innovation in processing technology resulted in a significant acceleration of gold output over the last few years. Newmont Gold alone produced more than 43.5 t (1.4 million oz) in 1989. That is equal to 22% of the cumulative 1965 to 1988 output, and an almost 200% increase over its 1986 output.

Jan 1, 1991

By E. O. Strahl

In the search for economic mineral deposits, the need for efficient mineral or chemical assays is of prime importance. Costly analytical methods and long delays in obtaining assay results severely limit the effectiveness of an exploration program. The assay problem becomes acute once a potential ore body is located and large numbers of samples are generated in close interval drilling programs. In order to avoid the delays and high costs of extensive assays, the exploration geologist or mining engineer is likely to be required to curtail his drilling program, composite samples, or restrict the required analyses to a limited number of critical elements. As a result, the definition of the potential ore body may be less than needed for final economic evaluation. The assay requirements for bauxite exploration usually involve a considerable number of total elemental and empirical analysis. Since the Bayer process for extracting alumina from bauxite involves the selective dissolution and reaction of specific minerals from the bauxite, a direct chemical analysis for elemental composition yields only a portion of the data required to effectively describe the potential economic value of ore body or deposit. To fully characterize the economic value of a bauxite requires digestion, mud separation and mud settling tests under conditions approximating a commercial Bayer plant. A close approximation of the process behavior of a bauxite also can be calculated from a combination of the chemical and mineralogical analyses. By determining the elemental chemistry, mineralogy, and Bayer plant processing characteristics of a few samples of a given bauxite, correlations can be derived that permit defining a bauxite in terms of a given set of process conditions.

Jan 1, 1977

By Jan K. Wolski

Detection of the air recirculation branches within a large ventilation network may be difficult, therefore a PC computer routine has been developed to perform this task in an efficient and reliable manner. This paper describes the method illustrated using a network with complex multi-recirculation circuits. The fact that only the air flow directions and not the flow rates are used in calculations is of some interest. The air recirculation during a real mine fire is demonstrated using the PCVENT program, whose version 4.0 includes current information about any recirculation branches during network calculations or during a fire simulation. This paper also discusses some transient problems related to air recirculation, and gives examples.

Jan 1, 1993

By H. Huang, R. N. Gow

"EH-pH diagrams are useful tools in understanding how mineral surfaces react in solution and particularly how aqueous conditions can be changed to enhance mineral leaching processes. Successful application of these diagrams, however, requires that several considerations be kept in mind to prevent what had been termed as “gross errors” in their calculation and use. In this paper, the aqueous Cu-S system is used as the basis for explaining the mass-balanced method of calculating EH-pH diagrams with the STABCAL thermodynamic equilibrium software. A breakdown of the Gibbs’ Phase Rule and how it is used in STABCAL to modify the diagrams is included. The methodology was applied to the aqueous Cu-As-S system, and resulting diagrams were compared against examples of those generated using the predominant-ion method. The complexity of such diagrams increases with every additional component, and competition between species becomes more apparent, as can be seen by curvature in the resulting mass-balanced diagrams. The complete diagram for enargite (Cu3AsS4) is shown. It compares well with spectroelectrochemical measurements from Raman spectroscopy and cyclic voltammetry studies.IntroductionInnovation in the field of processing arsenicbearing copper ores has been of particular interest. Copper arsenic sulfosalt minerals such as enargite (Cu3AsS4) and tennanite (Cu12As4S13) are now frequently prevalent in ore bodies as the oxide and easily leachable sulfides become harder to find. These minerals, unless pretreated somehow, concentrate in copper sulfide flotation processes, in turn concentrating the arsenic levels. Increasing environmental restrictions on arsenic content for smelters makes the hydrometallurgical processing of these concentrates more favorable. While enargite is considered one of the more refractory copper sulfides, more so than chalcopyrite (CuFeS2), there are still several methods, both industrially proven and in development, that are capable of processing these ore types. Alkaline sulfide leaching can be used as a pretreatment method to solubilize arsenic selectively (Delfini et al., 2003; Anderson and Twidwell, 2008; Tongamp, Takasaki and Shibayama, 2010a, 2010b), or the entire metal content can be leached using acid-type leaches such as acidified ferric sulfate (Dutrizac, 1981; Hackl et al., 1995; Klauber, 2008), or the chloride assisted, CESL (McDonald and Muir, 2007) or nitrogen species catalyzed (Anderson, 2003) processes can be used.As development of these leaching technologies proceed, it is also important to develop an understanding of the mineral thermodynamics. To date, there are numerous studies on the Cu-Fe-S-H2O system, particularly as it relates to chalcopyrite leaching, yet few studies have done on the Cu-As-S-H2O system. Computer-generated EH-pH diagrams have been employed to illustrate the importance of thermodynamic calculations in providing insight into such a system."

Jan 1, 2016

By W. M. Ma, Daniel W. H. Su, K. Centofanti, Yi Luo, W. L. Zhong, Syd S. Peng

NTRODUCTION Surface subsidence monitoring is the most effective means for investigating the nature of, and developing the techniques for pre¬dicting the surface movement and deformation process. However, because of imperfection in survey equipment and field practices, the surface movement data collected from field survey are not error-free. Also due to lack of proper numerical techniques for computing surface deformation from the measured surface move¬ment data, a relatively large portion of the subsidence data col¬lected could not provide information other than surface movement. In a paper by Luo and Peng (1992), the sources and magnitude of errors in the measured surface movements using an electronic total station in subsidence survey are discussed. If the errors in the measured surface movement components are left untreated before calculation for deformation indices (i.e., slope, strain and curva¬ture), the errors will be carried over to the deformation indices and enlarged if improper numerical procedures are used in the calcu¬lation. It should be noticed that in protecting structures affected by ground subsidence, accurate surface deformation indices are much more important than surface movement. In order to improve the accuracy of the collected surface movement data and the calcu¬lated deformation indices, a number of numerical procedures are also proposed in the same paper. The proposed techniques include: a data smoothing technique for data pre-processing; and a number of numerical methods and/or procedures for calculating surface deformation indices from the measured surface movement data. DATA SMOOTHING Because of various factors, the measured surface movement data always contain errors, small or large. In order to better utilize the collected data, a data smoothing method is proposed to correct the errors in the measured movement data. The method uses the same concept as the influence function method (e.g., Knothe, 1957) on which many existing subsidence prediction methods are based. The data smoothing method makes necessary corrections on the measured movement for the point of interest according to not only the measured movement at this point but also those at the surrounding points. The contribution of a surrounding point in making the correction for the point of interest is inversely propor¬tional, in exponential form, to the distance between them. The new magnitude of a movement component at the point of interest (Zi*) is calculated by

Jan 1, 1992

Zirconium chloride is of great commercial importance as starting materials for production of ZrO2, Zirconium metal and other Zirconium compounds from its main resources (Zircon Sands). The present study concerns with preparation of pure ZrO2 from Zircon by direct chlorination technique. Different parameters affecting the chlorination process are studied viz. carbon, chlorine flow rate temperature and time. The chlorination extent is determined from the loss in weight and chemical analysis of reaction products. The maximum chlorination extent -92% are achieved at 1100°C for 30 min. Zirconium oxide is produced from the collected zirconium tetrachloride either by calcination at 900°C or by hydrolysis in water in presence of RCI with a purity = 99%. Evaluations of the products of the process are investigated microscopically and by X-ray diffraction. The apparent activation energy of the chlorination of Zircon is determined to equal 36 kJ/mole.

Jan 1, 1997

By Jameel Menashi

A process has been developed for recovering the refractory metal values contained in mixed secondary source materials such as contaminated grinding wastes, oxides and sludges. The wastes are calcined with sodium carbonate in air to convert the refractory metals to water soluble Na2CrO4, Na3V04, Na2Mo04 and Na2W04. The base metals, Fe, Ni, Co and Cu, are converted to water insoluble oxides. An aqueous leach of the calcine effectively separates the refractory metals from the insoluble base metals. Co, Ni and Cu can be recovered from the oxidic residue by conventional processing methods. The leach solution is purified and then treated to recover the refractory metals as Cr203, NH4VO3, (NH4)6Mo7024?4H2O and H2WO4. The purity of the products is sufficient for their use in many metallurgical applications. The Na+ values in the leach solution are recovered as Na2CO3(or NaHC03) and are recycled to the calcination step. It is shown that the process can accommodate a wide range of feed compositions and generates a minimum of aqueous effluents.

Jan 1, 1984