Search Documents

By B. Pesic, J. E. Wey

Introduction One important class of manganiferrous ores is manganiferrous-silver ores. They occur in the oxidized portions of the silver deposits of the western United States. Silver is often associated with manganese oxides, which in some ore deposits are dispersed through calcite, causing the black color of the host rock, known as black calcite. Black calcites can occur in carbonate rocks (0.3 to 50 kg Ag/t) and in volcanic rocks (less than 30 g Ag/t). Silver mineralization associated with manganese oxides and black calcites can occur in veins (Hewett, 1968) or as disseminations (Graybeal, 1981). In the US, silver-bearing manganese veins are located in a broad arc that extends from southern Colorado to southwest New Mexico, southern Arizona, and southeast Califor¬nia (Hewett, 1964). Areas of disseminated silver-manganese mineralization include the Creede and Silver Cliff districts of Colorado and the Tombstone and Hardshell districts of Arizona (Graybeal, 1981). These deposits are also characterized by significant amounts of silver halides - cerargyrite (AgCl), bromargyrite (AgBr), and iodargyrite (AgI). Black calcites are also common in these deposits. Oxidized silver ores containing the higher oxides of manganese are generally refractory to hydrometallurgical methods of treatment. In the past when these ores could not be smelted, they were treated generally by cyanidation at very low efficiency. The US Bureau of Mines (USBM) studied the problem of treating silver-manganese ores in the early 1920s (Clevenger and Caron, 1925). It was found that the refractory silver in the original ore was insoluble in all the common solvents for metallic silver and its salts. The conclusion was that to obtain the highest recovery of silver, all the manganese had to be dissolved or the higher oxides of manganese reduced to manganous oxide. More recent results from treating refractory silver¬manganese ores were given by USBM (Scheiner et al., 1973). The silver ores from Candeleria District, NV, and Round Mountain District, CO, were investigated. Electrooxidation experiments recovered only 34% silver with minor amounts of manganese dissolved. Sulfurous acid pretreatment followed by cyanidation revealed that silver extracted was proportional to the amount of SO2 used. A similar approach, using sulfurous acid pretreatment followed by cyanidation, was also proposed by Rhoades et al. (1984). Hazen Research Inc. performed extensive testing on silver and manganese dissolutions from Ag-Mn ores obtained from the Candeleria and Round Mountain ore deposits. The methods examined were direct cyanidation, pretreatment with sulfurous acid followed by cyanidation, malonitrile leach, and leaching with ammonium hydroxide-sodium thiosulfate under slight oxygen pressure. The results were not satisfactory. The importance of the vast reserves of Ag-Mn ores and the lack of an efficient method to recover these metals warranted a search for new technologies. One novel method for extraction of these metals is treatment of Ag-Mn ores with acidified thiourea solutions. Preliminary results of the leaching of silver and manganese from Ag-Mn ores were very encouraging (Pesic, 1984a) ; thus, it was decided to examine the new lixiviant in more detail. Experimental Ore from the Round Mountain District was studied. It was crushed, ground, and dry sieved into monosized fractions in the range of 16 to +400 mesh. The ore composition was about 90 g Ag/t and 3% Mn, depending slightly on size. The leaching experiments were performed in apparatus described elsewhere (Pesic, 1982 and 1984b). All experiments were performed at constant temperature conditions. The leaching residues were analyzed for silver and manganese. Atomic adsorption was used to analyze the solution samples and fire assaying to analyze the leaching residues (for silver). The standard experimental conditions are given in

Jan 1, 1987

By B. Moudgil, M. Bogan

A mathematical model, based on first-order kinetics, is derived to describe batch settling data. The model is used to predict the settling behavior of solid suspensions under different conditions. The potential benefits of this model to solid-liquid separation processes are discussed.

Jan 1, 1994

As noted by D.W. Fuerstenau in his Plenary Lecture at the Conference on Extractive Metallurgy of Gold and Base Metals, Kalgoorlie, Australia, "Com¬minution of solids is surely one of the oldest technologies that, even in this day and age of DNAs, chips and space exploration, continues to challenge our scientific acumen and engineering ingenuity." Thus, the fundamentals of comminution continue to receive a great deal of attention in the literature. This was particularly true in 1992 with the publication of the proceedings from the SME-sponsored symposium, Comminution Theory and Practice. Papers covering topics ranging from liberation to comminution fundamentals to novel size reduction techniques are included in this review. Liberation Liberation continued to be a prime area of research interest, not only in terms of liberation modeling, but also in understanding the basic mechanisms involved in mineral liberation. King (Comminution - Theory and Practice, pp. 3-15) described a method for determining the interphase area between mineral grains. He showed how the mea¬surement of interphase area before and after comminution could be used to determine the presence or absence of intergranular fracture. Lin, Miller and Cortes (Kona, Vol. 7) discussed the use of computed tomography (CT) as a nondestructive means of investigating three-dimensional particle composition. The use of this technique in constructing coal washability curves from CT data was presented.

Jan 1, 1993

By Bernard Scheiner

A number of wells were drilled at two phosphogypsum stacks, one at P-21 owned by IMC and the other at Agrico's South Pierce Stack. Each well was sampled, and composites representing 5-ft increments were leached with synthetic rainwater to determine the extent of metal and nonmetal migration. To simulate what was occurring in the stack, composite samples were placed in a column, so that the column represented the stack in miniature form. Leaching experiments showed that both metals and nonmetals moved down the column when water was added to the top of the column. Data obtained from P-21 showed that with time the concentration of metals and nonmetals reached equilibrium values. The concentration of Ca, SO4, F, Si, and PO4 were -600 ppm,~1,500 ppm, 32 ppm, 14 ppm, and 22 ppm, respectively. Column leaching of South Pierce material, representing 0 to 55 ft of stack, showed that after 355 in. of water, the stack was near equilibrium values down to the 33-ft level. With continued addition of water, the portion of the stack at equilibrium would continue to increase and eventually reach the values observed for P-21. The test showed that the sulfate concentration of the effluent from the stack would never reach the USEPA standard value of 250 ppm. During the leaching test, it was determined that the permeability of the phosphogypsum in the columns was 0.000103 cm/sec. This number was used in the modeling. The data obtained from the leaching experiments cast some doubt on the practice of entombment now being practiced for closure of phosphogypsum stacks. The data clearly shows that with time, the amount of material leaching from the stack is low in concentration, with only the calcium and sulfate at higher levels. When a stack is closed at an existing operating plant, allowing rainwater to fall on the stack and capturing the solution in the existing pond system would eliminate the need for covering the stack, since with time the closed stack would continue to leach and at some point reach the equilibrium values of the P-21 stack. Entombment means that the leachable material in the stack will always be there and will require monitoring forever. Allowing rainwater to decontaminate the stack may be the best environmental solution to the problem.

Jan 1, 1999

By Malcolm J. McPherson

There have been numerous recorded cases of mine explosions being initiated by falls of roof. The actual mechanism of the ignition has often been unknown. One possibility is incendive frictional sparking, particularly when the falling rock contains quartz. Another possibility that has received little attention is the increase in temperature of the air due to adiabatic compression under the falling roof. This paper analyses that possibility and concludes that falls which are extensive in plan area but not necessarily of great thickness of falling rock can, indeed, produce temperatures in excess of those required for the ignition of coal dust or methane.

Jan 1, 1995

Small-scale flotation tests have been conducted to examine the effect of froth stability on the column flotation of finely pulverized coal. The results of this study demonstrate that the upgrading of coal in a column flotation cell can be significantly improved when froth stability is properly controlled through the manipulation of appropriate operating variables. Several important correlations have been established from the test data. These relationships should prove useful for the design and ore ration of column flotation cells for fine coal processing.

Jan 1, 1991

By John Hayden

The nation runs on energy. It is essential for the economic growth and national security of the United States that the nation has an adequate, sustainable, environmentally acceptable and economically viable balanced supply of energy sources, (e.g., coal, petroleum, nuclear, natural gas, solar, wind, geothermal, biomass, hydroelectric power). Therefore, the allocation of mineral raw materials to the energy-producing sector of the economy must be a top priority that requires the total demand for energy-related materials be judged in terms of domestic supply (Fig. 1).

Jan 1, 2012

By T. J. Cox

The Red River is located within the Sangre De Cristo Mountain Range in northern New Mexico. An approximate 12-mile segment of the river from the town of Red River to the village of Questa (Questa) includes several hydrothermal alteration zones. Alteration ?scars? formed as a result of rapid chemical weathering and physical erosion of pyrite-rich hydrothermally altered rocks. Storm water runoff from the scar drainages contributes metal-laden, acidic water to the river and creates a visible plume of discolored water in the river. Acidic runoff reduces the river pH from 7 to the mid 3s for at least 2 hours during large storms and the low pH water continues downstream. Runoff from scar drainages increases some metal concentrations in the river from below chronic ecological criteria to as much as two orders of magnitude greater than acute ecological criteria, and results in acutely toxic conditions for macro-invertebrates. A general improvement in the river?s water quality occurs downstream due to dilution from tributary inflow from non-mineralized watersheds, the natural buffering capacity of the river, and storm water controls at the Chevron Mining Inc. Questa mine.

Jan 1, 2011

By James L. Noble

A small placer operation can be defined as one with a throughput capacity of 250 cubic yards an hour or less. The success of small placer operations after the values have been established, depend entirely on having the proper design. There are various types of placer deposits including marine, beach, desert, stream, bench, underground and even frozen placers. Each is unique and requires special considerations. Size distribution of alluvial placer ore varies from sand to large boulders. When boulders occur, they can become a problem to all types of excavating to a greater or lesser degree. Clay content and cementing are common in placer deposits. Some clay disperses easily in water while others, if not handled properly, will form clay balls that pick up gold and carry it to tailings. Overburden, depth of bedrock, vegetation, and ground and surface water must all be considered when designing a plant. Any equipment chosen should be capable of processing large volumes of material at a high efficiency. There are usually five steps to processing placer gravels, as follows:

Jan 1, 1992

By Young C. Kim

Determination of the minimum sampling requirements of the run-of-mine (ROM) coal is very important for the purpose of meeting contract specifications. It is also important for the purpose of meeting emission regulations at a coal-burning power plant, such as the one located at Homer City, Pa. The classical statistical sampling theory can be applied to this problem, if ROM coal samples are known to be spatially (or serially) uncorrelated. On the other hand, the estimation variance concept from the Matherson's geostatistics must be used, if the samples are spatially correlated. Conditional simulation technique combined with simulation of the existing mining method is used to determine under which circumstances ROM coal samples do not preserve the spatial correlation. Only after establishing the degree of correlation that exists among ROM samples, an optimal sampling scheme can be devised using either the classical statistics Or the geostatistics. The minimum required sample volume can then be calculated using the well-known Gy's formula. This paper describes the results of the above investigation using the Helen coal mine data of the Homer City Owners. Empirical guidelines for determining the degree of correlation are also provided for coal mine operators.

Jan 1, 1986

By Wendell R. Peters

Shallow underground voids resulting from early coal mining and other resource recovery activities over the past several decades are now being recognized as a significant cause of ground subsidence problems. Uncertain knowledge of abandoned coal mines also imposes potential hazards in current mining operations since water inundation or the release of methane gas is a serious hazard when mine excavation operations break into an abandoned mine. Requirements for detecting and mapping subversive man-made tunnels in previous work has led to the development of a surface- operated automatic earth resistivity survey system and associated computer data processing system for military applications. Field demonstration tests of this system have resulted in successful detection of tunnels at depth-to- diameter ratios greater than ten to one. Under the sponsorship of the Bureau of Mines, a similar high-resolution earth resistivity system was designed and constructed for use as a potential means of detecting coal mine workings. The hardware and software aspects of the new system are described together with applications of the method to the survey and mapping of abandoned coal mine workings. Field tests are presented showing the detection of both air-filled and water-filled mine workings.

Jan 1, 1981

By Cleophus Short

[Of the many occupations in and about the coal mines, those of the haulage crews are among the most hazardous. Statistics ship that the second greatest number of fatalities about the coal mines occur during haulage ion and through the use or misuse of haulage equipment. During the five year period between January 1, 1957 and January 1, 1962, the m stone mine had a. Sack haulage frequency of 4098 and mined 3, 541,939 toads per haulage fatality. Coal mire haulage is similar in respects to railroading. We gee very serious consideration to the instillation of tack and to the selection of the haulage crews. In doing this, we are attempting to have our coal mine haulage as. Safe as that of the railroads.]

Jan 1, 1963

By William E. Souder, R. J. Evans

From time to time, major technological innovations arise that alter the time-honored ways of doing things. Such innovations can dramatically benefit society in terms of new products, increased outputs, reduced costs and general modernizations. However, the advent of these types of technologies is likely to be resisted because of their uncertain potentials, and because they disrupt established routines and industry patterns. This paper reviews the case history of water jet coal cutting, and assesses its potential to become a major innovation within the next decade.

Jan 1, 1983

By Brian P. Canning

Ion exchange resin processes are receiving renewed attention in the mining industry for recovery;, of metals from solution. This interest has been inspired by the development of continuous countercurrent ion; exchange systems (CCIX) which are of much lower cost than the original, fixed bed contactor processes. With the countercurrent systems and new developments to process or upgrade the eluate product, ion exchange can now compete successfully with solvent extraction for treatment of uranium ores. The low concentration of U308 obtained in the CCIX strong eluate is generally upgraded by solvent extraction methods in sulfuric acid systems. Resin loadings of up to 120 grams per liter of U308, however, have been produced experimentally by recycling of eluate (HIM-IX process) and further developments may be expected in the near future. New developments in resin technology are bringing forth products of greater strength, loading capacity, selectivity and density. Densities up, to 1.35 spgr have been claimed by some suppliers. The process is not a new one and has taken years to advance to the present state of development. The earliest system to gain widespread acceptance was the resin-in-pulp system applied to uranium recovery. Ion exchange, however, later lost acceptance in favor of solvent extraction in the 1960's due to problems in resin degradation, resin contamination and resin-pulp separation, in addition to the development of improved solvent extraction reagents and techniques. The resin-in-pulp system continues to have application on high clay ores and has advanced in design. A number of other continuous ion exchange systems were also tried but never gained continued acceptance. In the current resurgence period the CCIX systems to gain acceptance were the Utah and Chem-Sep (Higgins Loop) systems. These processes are relatively simple in concept although require sophisticated controls. Fixed bed columns have also been designed into multistage systems in countercurrent operation but are not discussed in this paper. These systems remain competitive today for many applications. The most recent advancements however have been in the multistage contactors from,, which three are in current acceptance. These are the Himsley, Porter, and NIM systems. All industrial applications of these systems are relatively new, although pilot plant and in-plant development has been in progress over the last decade. Fur36ther developments should be expected in the near future.

Jan 1, 1979

By Errol vanHuyssteen

Old tailings from Zn, Au, Cu, and Ni mining operations were characterized. Their mineralogical variation in depth is compared with matching pore water and solids chemistry. A geochemical model was used to predict minerals precipitating from pore water solutions. These are compared with actual secondary minerals occurring. The degree to which the precipitation of secondary minerals controls the sulfate and iron concentration of the pore water was also investigated. The results obtained are related to the selection of the most appropriate modes of tailings deposition.

Jan 1, 1998

By Martin Oatman, Lawrence Lenahan

The West Seattle Tunnel is part of a regional sewer conveyance system located in Seattle Washington. The tunnel was constructed for the Waste Water Treatment Division of the King County Department Of Natural Resources, from June of 1995 through the first quarter of 1997. The Geologic setting for this soft-ground tunnel consists of glacial, interglacial, glacio-lacustrine, and alluvial soils. This paper, prepared jointly by the owner and con-tractor, will describe project-related site geology, engineering considerations, construction, and dispute resolution/avoidance practices.

Jan 1, 1997

Over the last two decades, the mining industry has spent considerable time and effort in installing sophisticated control systems (including expert systems) to regulate and improve the performance of AG/SAG mills. Yet the need for these systems is often overlooked – unmeasured and uncontrolled variation in the feed material. With AG/SAG mill technology replacing rod and ball mills as primary grinding equipment, the need for careful and thoughtful feed preparation has gone. To maximise mill throughput, operations need to better understand the ore characteristics affecting AG/SAG mill performance. Industrial operating data will be used to illustrate these ideas and concepts. It is often quite surprising which ore characteristics that are the most influential on mill throughput.

Jan 1, 2004

By Tien H. Wu, Pinnaduwa H. S. W. Kulatilake

The concepts of conditional probabi1ity and geometrical probability are used to establish a relation between the probability density of the trace length and the probability density of the discontinuity diameter. The discontinuity is represented as a thin circular disc. A numerical solution scheme is used to obtain the probability density of the disc diameter from the probability density of the trace length. An example was used to illustrate the possibly large difference between the mean discontinuity diameter and the mean trace length.

Jan 1, 1986

By Stanislaw Nawrat, Waclaw Trutwin, Waclaw Dziurznski, Janusz Roszkowski

In recent years attempts have been made to fight open and intensive mine fires by the use of special extinguishers, which are able to produce great volumes of inert gases directed into the fire zone. These extinguishers are derived from turbo-jet engines used in aircrafts and adopted for operations in mine conditions. The purpose of this paper is to draw the attention to a computer simulation method, enabling studies of dynamical behaviour of mine ventilation processes disturbed by open fires, which are also influenced by measures taken during fire fighting actions i.a. the mentioned operating extinguishers. The first part of this paper gives an account of the principles on which the computer simulation program, concerning the non- steady mine ventilation process, the fire as a heat source and the extinguisher as a source of inert gas and moisture has been based. The next part of this paper deals with simplifying assumptions and the subsequent limitations of the derived simulation pro- gram. Finally, from an example of a computer simulation, the results will be presented and relations shown between parameters characterising the ventilation process during the fire fighting action.

Jan 1, 1997

By Chaoxun Zhao, TAIYOU LI, JIAQI JIN, Jan D. Miller, Chen‑Luh Lin

A large portion of the energy consumed in copper concentrators is used to reduce the particle size of the feed by crushing and grinding. The cost of metal production could be reduced if low-grade particles of cm size were removed prior to further processing. Two copper sulfide ore samples (3 × 1 cm) from Arizona were analyzed by micro X-ray computed tomography (Micro-XCT) to determine the grade of copper sulfide in each particle. For copper ore sample A, a significant number of particles contained very low amounts of copper, while some particles had copper sulfide grains of mm size. Based on Micro-XCT, it was expected that 85% of the copper for sample A could be recovered at 65% of mass rejection during preconcentration by sorting. However, in sample B (a different copper ore), distribution of copper sulfide was dispersed primarily in each ore particle, so for the particle size class of 3 × 1 cm, liberation of copper sulfide and gangue minerals was not significant. In view of the XCT results, dual energy (DE) X-ray radiography was used as a basis for sorting. Previous DE X-ray radiography of a drill core sample demonstrated that this rapid detection method can be used to identify rich or poor Cu-bearing coarse particles. Pilot scale X-ray sorting of sample A (10 × 1 cm) showed 31% rejection of a 0.08% Cu gangue product with a corresponding recovery of 90% copper.

Nov 30, 2021