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By M. A. Cocquerel

INTRODUCTION Davy McKee have developed and patented a combined mixer settler (CMS) which has undergone extensive trials and has now been installed in two commercial uranium plants in South Africa. Substantial capital and operating cost savings can be realized over conventional mixer settler in uranium extraction, especially from dilute feedstocks containing approximately 200 ppm U308. Pilot plant work has also been undertaken on other metal extraction systems and the results are very encouraging in most areas of interest. CONVENTIONAL MIXER SETTLERS The conventional plant in use at many uranium recovery facilities consists typically of a mixer box in which the aqueous and organic phases are contacted and a settler in which the two phases separate. The mixer box must allow sufficient residence time for the mass transfer kinetics to be satisfied for the particular species involved. The settlers are usually rectangular and take the form of shallow tanks of large cross sectional area.

Jan 1, 1984

By G. A. Doyle

Until the suspension of conventional operations in 1996, the White Pine Mine was the second-largest active underground copper mine in the United States, underlying an area of approximately 30 km2 (13 sq. miles) in the Upper Peninsula of Michigan. The mine operator intends to initiate in-stope solution copper mining by circulating a solution (lixiviant) of mine water, sulfuric acid and ferric iron through rubblized ore. As planned, the solution would be retired in the mined-out stopes following completion of the solution-mining activities. Investigations into the fate of the retired solution indicated that the solution, through time, would change from an acidic, metal-rich solution to a near-neutral, reducing solution containing much lower concentrations of metals. Investigations included reaction-path modeling (EQ3/6) and laboratory and in-mine tests. The combination of neutralization and reduction will result in precipitation of most metals, primarily as metallic sulfates, chlorides and sulfides.

Jan 1, 1997

By D. A. Kramer

Seawater and natural brines accounted for about 51percent of U.S. magnesium compounds production during 2004. Dead-burned magnesia was produced by Martin Marietta Magnesia Specialties from well brines in Michigan. Caustic-calcined magnesia was recovered from sea-water by Premier Chemicals in Florida; from well brines in Michigan by Martin Marietta and Rohm and Haas; and from magnesite in Nevada by Premier Chemicals. Intrepid Mining and Great Salt Lake Minerals recovered magnesium chloride brines from the Great Salt Lake in Utah.

Jan 1, 2005

By Z. D. Hora, W. N. Hamilton

Introduction Some unique opportunities exist for industrial minerals in British Columbia and Alberta. The region's diversified geology, particularly in British Columbia, offers favorable environments for a rich variety of mineral resources. Many minerals have been produced for years. For some, however, the level of production is far less than the potential. Others have had production in the past, but are not currently produced. Still others are known to exist and may have been actively prospected. But they are not yet developed. In addition, a number of speculative possibilities have recently come to light. The potential significance is not fully confirmed, but is suggested in showings in favorable geologic settings. Location and geography British Columbia and Alberta are the westernmost provinces in Canada (Fig. 1). The region overlaps two major physiographic divisions of the country, the Cordillera and the Interior Plains. It also takes in a small segment of the Canadian Shield on the east. The entire territory is greater than 1.6 Mkm2 (618,000 sq miles). Most of British Columbia lies within the Cordillera, a mountainous belt some 800 km (500 miles) wide. The belt is made up of three main physiographic components, the Eastern, Interior, and Western subdivisions. The Eastern subdivision embraces the rugged, linear ranges of the Rocky Mountains, elevations between 2600 and 3300 m (8530 and 10,800 ft). They form a 100-km (62-mile) wide band straddling the BC-Alberta border and extending northwest across northern British Columbia. The Interior subdivision includes several ancient mountain ranges but is dominated by an intermountane plateau area of low relief (average elevation 1200 m or 3900 ft). The Western subdivision is dominated by the Coast Mountains (elevations between 1800 and 4000 m or 5900 and 13,123 ft). These form a band about 175 km (110 miles) wide into which are sculptured the spectacular fiords of the BC coastline. Alberta lies largely within the Interior Plains, a prairie region of low to moderate relief (elevations between 200 and 1200 m or 650 and 3940 ft) formed of nearly horizontal bedrock strata. The Plains surface rises gradually to the southwest toward the deformed belt of the Rocky Mountains, where the bedrock strata are upturned, folded, and faulted. To the east, the Plains merge with the Canadian Shield, which exposes the Precambrian crystalline basement of western Canada. The total population of the BC-Alberta region is about five million people. Minerals, forestry, and agriculture are the primary industries here. It has well developed infrastructures to service these industries. British Columbia is third among the Canadian provinces in metal mining - $1.1 billion in 1985 - and first in forest products. It is also second in hydro-electric power development. Alberta leads all provinces in total mineral production, largely due to its extensively developed petroleum and natural gas resources - $26.2 billion in 1985.

Jan 12, 1987

By W. K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating the electrochemistry of mineral flotation. A significant need in this area is greater reliability of sensors. The USBM is testing electrolytic methods to clean and condition redox-sensing electrodes to improve the reliability and extend the service life of these instruments in the harsh physical and chemical environment of mineral processing slurries. A novel method for removing scale from fouled electrodes has been developed that includes anodic polarization to 1.2 V versus the Ag/AgCl reference potential, followed by brief potentiodynamic conditioning. Laboratory results show that this technique removes calcarious deposits from gold sensing electrodes and returns the electrode to useful service within approximately 10 min. Mechanical abrasion to remove the scale is thereby avoided.

Jan 1, 1994

By Robert B. Hopler

For many years the explosives industry was a technological enigma: it was at the 'cutting edge' of some technologies and in the backwaters of others. For example, for at least the past 85 years, the industry routinely measured time to one-millionth of a second for determining the detonation rate of explosives. At the same time, however, formulations were usually hand-written in 'formula books,' such as the alchemists may have done. Also, due to the fact that the equipment had proven to be safe, many of the mixers and packing machines in use until recently were those patented in the 19th century; improving efficiency was not worth the possible risks that might be encountered. In recent years, the wide availability and portability of computers and their adaptation to specialized applications have revolutionized the explosives industry, much as it has many others. With the advent of the water-based emulsions and slurries (water gels), and the necessity to design totally new processing and delivery equipment, the opportunity arose to apply modern techniques to many aspects of the business. Table 1 lists some computer applications currently in use by explosives manufacturers and end users. The use of high-tech production controls, equipment design aids, field measurement devices and other computer applications is so pervasive in the industry today that any brief article such as this must be considered only as a broadbrush overview of the subject.

Jan 1, 1994

By S. Di Muzio

Sulphate Reducing Bacteria (SRB) are hetero-trophic anaerobic micro-organisms that can be used to remove sulphates and heavy metals from Acid Mine Drainage (AMD), heavy metal-bearing streams with high iron and sulphate contents and low pH, generated by sulphur bio-oxidation in abandoned mine districts. After the preliminary chemical precipitation of iron with carbonate stones (I step, chemical precipitation) SRB can be used to reduce sulphates to sulphurs then favouring heavy metal removal as sulphur precipitates (II step, biologically mediated precipitation). In this work the experimental results of heavy metal and sulphate removal from column tests were reported. Sulphate and heavy metal abatement in fixed bed column was performed using chemically pre-treated samples of synthetic AMD. Attenuation of toxic effects of treated samples was also ascertained by toxicological tests of germination and radical growth with Lepidium sativum.

Jan 1, 2006

Semiautogenous (SAG) ball mills are being increasingly used today for the coarse grinding of a range of ores, including gold, copper and iron. Larger mines are demanding mills with larger throughputs. This has led to some remarkable developments in mill diameters and installed powers. Conventional design principles - mills with trunnion bearings - have reached their limitations. This article describes one SAG mill with a slide-shoe arrangement and Krupp Polysius' Combiflex twin drive. In August 1997, the world's largest SAG mill with a slide-shoe arrangement was commissioned in Queensland, Australia, operating as a wet mill. The inside diameter is 10.4 x 5.1 m (34 x 17 ft) effective grinding length. The 1.36-ktlh (1,500-stph) SAG mill is driven by two Combiflex drives (twin drives with 2 x 5,500-MW or 7,375-hp installed motor power) in conjunction with a girth gear (outside diameter 11,890 mm or 468 in.). Commissioning of the SAG mill was completed with no notable technical difficulties. The plant runs continuously except for planned maintenance stoppages and process-specific reasons. As this article is written, the machine has been in operation for about 8,000 hours without major problems.

Jan 1, 1998

By Salama

In the conventional approach, the separator feed incremental masses are assumed to be concentrated at the midpoints of the density or size intervals and subjected to a model partition function. The resulting separation predictions would change if the locations of the incremental masses were changed. As a result. the predicted results depend on the choice of locations where the feed incremental masses are concentrated in the density or size intervals. A technique that utilizes the cumulative-mass-distribution of the circuit feed and the derivative of the partition (separation) function relative to density or size variables is proposed. The proposed technique eliminates the dependency of the predictions on choice of where the feed incremental masses are concentrated within the density or size intervals. Since the proposed technique is based on the cumulative masses at the upper limits of the density or size intervals, the technique produces a single prediction whereas the existing techniques produce predictions that depend on where the incremental masses are concentrated. In fact, it has been demonstrated that the existing conventional technique, in which the incremental masses are concentrated at the midpoints of the density or size intervals, is a first-order approximation of the technique proposed.

Jan 1, 2002

By H. Haas

European coal mines are facing a very difficult situation. Despite a steadily increasing world energy consumption, the sales of European coal mines have been going down and production has to be adapted. The reason is the collapse of energy prices aided by the decreasing rate of U.S. $ to Deutschmark in the last few years. The problems are not due to the development of European mines themselves. Assured energy supplies are an important condition for the health of a nation's economy. Contribution of domestic energy production ensures some degree of independence from world market fluctuations as to supply volumes and price, and maintaining jobs and should be achieved within the framework of economic constellations. Governmental energy programs are planned towards meeting this end.

Jan 1, 1989

By Kenneth A. Gutschick, Harry L. Francis

A large number of minerals and chemicals (Table 1), some mineral-derived, are used in the treatment of both potable water and domestic sewage waste water and solids (Anon., 1990). In water treatment there are ten principal process uses as shown in Table 2 (Anon., 1990), which also lists the major chemicals in each process. Since lime (calcium oxide, calcium hydroxide, and dolomitic lime) is the largest chemical (by tonnage) used in water treatment, this chapter will deal primarily with this product. Note that it is included in five of the process uses shown in Table 2, and that indirectly it is also used in at least one other category (taste and odor control, where lime is used with potassium permanganate to provide optimum pH condition). POTABLE WATER TREATMENT Water Softening The biggest use for lime in water treatment involves water softening, where it serves to reduce carbonate hardness caused by dissolved bicarbonate and carbonate compounds. Currently there are more than 1000 domestic water softening plants (Table 3) located in most sections of the country, but particularly in Ohio, other midwestern states, Florida, and Texas, where limestone bedrock abounds (Anon., 1990). Among the other uses for lime in water treatment are coagulation, disinfection, and removal of heavy metals due to high pH softening, removal of certain radioactive and organic compounds and fluorides, neutralization of acidic water, removal of silica, particularly with dolomitic lime, and removal of color. Most of the above advantages accompany water softening, although at some plants lime is used specifically for one purpose, such as silica removal with dolomitic lime, minimizing pipeline corrosion by addition of lime to correct an aggressive water, and others. Hardness in water comprises two types - carbonate hardness, caused by dissolved calcium and magnesium carbonates and bi- carbonates, and non-carbonate hardness caused by dissolved non- carbonate salts, particularly calcium sulfate, calcium chloride, magnesium sulfate, and magnesium chloride. Total hardness is the sum of the carbonate hardness and non-carbonate hardness. Waters are classified as soft (0 to 75 mg/L as CaCO,), moderate (75 to 150 mg/L), hard (150 to 300 mg/L), and very hard (above 300 mg/L). Most water plants strive to reduce total hardness to about 100 mg/L, although in recent years the tendency in some cities has been to allow a little higher value in order to reduce both chemical costs and the amount of water softening sludges produced. There are four basic types of softening plants: lime softening, primarily to reduce carbonate hardness; lime-soda softening, for reduction of both types of hardness (in some plants caustic soda is used in place of soda ash, but it is more costly); split lime-zeolite, where a base exchange mineral is employed in place of soda ash (this system also requires salt [sodium chloride] to regenerate the zeolite mineral); and finally zeolite softening, which is generally used in small systems for private houses and small municipalities. Principal disadvantages of the latter system are its relatively high cost and the salt requirement, which introduces considerable quantities of soluble salts into the waste water discharge system.

Jan 1, 1994

By Gurses Oner

In situ leaching is a relatively old mineral extraction method; however, historically only a small portion of copper has been produced from small scale operations. Recently, in situ leaching technology because of its intrinsic advantages over conventional mining and milling is being considered as a viable option for recovering copper from both low grade oxide and sulfide deposits. This paper presents the application of computers to investigate in situ technology using large whole core leaching experiments. Computers were applied to three different areas: (1) experimental control and data acquisition, (2) non-destructive evaluation of samples using x-ray computed tomography and image processing and (3) mathematical modelling and data analysis.

Jan 1, 1992

By Kenneth A. Rogers, Richard F. Hill

Introduction A number of processes for deriving more convenient liquid and gaseous fuels from coal are commercially available or in final stages of development. Generally, synfuels from coal processes have efficiencies ranging from 50 to 70%. Considerable engineering design and development work are necessary to bring forth commercial plants using the various technologies-but technological breakthroughs are not expected or needed. Gasification While a variety of solids handling, gas contacting, and gas quality upgrading techniques may be employed in the various gasification processes, the primary goal is the same-to convert a sulfur-containing solid to an essentially sulfur-free gaseous product. The gaseous product may be a mixture of hydrogen and carbon monoxide with nitrogen. Definitions are not rigorous, but high-Btu gas is generally over 900 Btu/scf(33 534 kJ/m3) and low-Btu gas is generally below 350 Btu/scf(13 041 kJ/m3). Medium or intermediate gas falls between these values. High-Btu production is more difficult, as it requires additional upgrading of a low- or intermediate-Btu gas stream to produce a commercially acceptable product. The carbon/ hydrogen ratio is adjusted either by rejecting a portion of the carbon, increasing the hydrogen, or a combination of both. The chemical processing steps include production processing gas containing carbon oxides and hydrogen by the reaction of carbon and steam (gasification); reaction of hydrogen and coal to form methane (a hydrogasification process); reaction of hydrogen and carbon monoxide to produce methane (methanation); and the removal of impurities. The gasification processes share a number of common techniques. The coal received at the plant site must be further cleaned and crushed or ground before it can enter the gasifier. Conventional cleaning methods are used to remove extraneous materials such as metal, rocks, etc. For some processes the coal must be finely ground so it may be fluidized or entrained in a flowing gas stream. For other processes crushing and sizing only are required. Agglomerating coals may be pretreated by heating, mild oxidation with air, or other procedures to assure smooth gasifier operation and to avoid reactor plugging. Nonagglomerating coals Such as lignite and subbituminous coal normally do not require pretreatment. Feeding a solid material such as coal to a higher pressure reactor is a difficult task. Dry feeders using a series of pressurized lock hoppers, or wet systems in which a slurry is pumped into the reactor, are used. The gasification step is the heart of the process. Here, the solid feed material is contacted with synthesis gas (carbon monoxide and hydrogen). The coal is devolatilized and a portion of the fixed carbon converted to methane. The gas-solids contacting methods used include fixed beds, fluidized beds, moving beds, entrained beds, and free-fall systems. The gasification process, overall, is endothermic and the heat required to maintain reaction rates is usually supplied by burning a portion of the coal feed. External heat sources such as electric resistance heating, molten salt or solid heat carriers, and the introduction of a hot hydrogen stream also have been tested. Following the gasification step the particulate materials and heavy hydrocarbons contained in the reactor effluent are removed by a water quench and solids separation system. If low-Btu gas or synthesis gas is the desired product, the raw gas is scrubbed to remove carbon dioxide and sulfur compounds and then is used directly. However, if high-Btu gas is desired, methanation is necessary. In most gasification processes, the hydrogen content of the gasifier

Jan 2, 1980

By Allen Pratt, Guy Deschênes, Mike Fulton, Hai Guo

Calaverite is a gold telluride species, with the composition, AuTe2. Calaverite is usually characterized by an exceedingly slow dissolution rate in a cyanide solution. Cyanidation of a slurry containing synthetic calaverite (P90 of 10 microns) was studied to determine the leaching kinetics and surface reactions. Alkalinity, dissolved oxygen, lead nitrate and sulphide minerals (pyrite and chalcopyrite) were among the parameters evaluated. The reaction products at the surface of calaverite were documented using X-ray photoelectron spectroscopy. High lime concentration with lead nitrate and injection of oxygen produced the fastest leaching rates. New gold leaching mechanisms were identified which appeared to be related to the parameters selected.

Jan 1, 2005

By Alden B. Carpenter

Oil-field brines have been collected and analyzed from Jurassic and Cretaceous rocks in the Mississippi Salt Dome Basin, from Jurassic and Lower Cretaceous rocks, southwestern Arkansas, and from Ordovician and Silurian rocks, southern Michigan. All of these brines are genetically related to evaporites and appear to be brines expelled from halite-bearing rocks, presumably during compaction. The brines in rocks closest to the halite-bearing rocks are uniformly low in lead and zinc suggesting that the metals in metal-rich brines are not acquired within evaporite sequences. The metals in metal- rich brines in Mississippi and in Russia appear to be derived from red beds and may have been originally associated with ferric iron oxyhydroxides. Reduction of these compounds by migrating hydrocarbons appears to release lead and zinc to the associated brines accompanied by the fomation of authigenic ankerite.

Jan 1, 1979

By Peter N. Calder

There is little doubt that the stability of both highwalls and spoil piles is essential to efficient strip mining. Accurate determination of the appropriate geotechnical parameters will pay dividends during mining, but only if the mine operation closely follows the engineering plans which have incorporated These factors. Productivity is invariably higher in mines where failure of highwalls and spoil piles does not occur. This is the result of the reduced rehandle and better working conditions found in stable mines. Control of the waste piles and highwalls also leads to better coal recover since failures can result in the burial of uncovered coal, which is then lost to mining. Safety is an important consideration. The importance of providing a safe working place for employees and of protecting costly mining equipment is hard to overemphasize. For miners, working in areas where instability exists, the degree of hazard involved in their occupation is increased particularly where night operations are involved. It is true, too, that there have been many cases where loading equipment has been buried and severely damaged by failures.

Jan 1, 1980

By R. Gorakhki, R. Stafford, A. Jung

Geosynthetic clay liners (GCLs) have been used widely as an alternative for compacted clay liners and covers in mine waste applications. The high swelling of bentonite particles in the GCL creates a uniform barrier layer that results in low permeability of water and mine waste leachate. GCLs must provide sufficient internal and interface shear strength stability, especially if GCLs are used in steep slopes under high normal loads. Peel strength is a common parameter that is typically correlated to internal shear strength properties of GCLs. The relationship between internal shear strength and peel strength of GCL at normal stresses of 287, 575, 862, and 1724 kPa is evaluated in this study. The data in this study was compared with the peel strength-internal shear strength relationships found in literature. The study concludes that the relationship between peel strength and internal shear strength is unique based on manufacturing, needle-punching density and the method with and without heat treatment of the geotextile end fiber bundles.

Feb 1, 2023

By Jessica M. Wempen, Dallan J. Coons, Bailey S. Simmons, Michael K. McCarter

Gate-road yield pillars are subject to increases in stress as the longwall face advances toward the pillars. Increases in pillar stress can be inferred by measuring roof/floor convergence surrounding the pillar. This paper presents a case study of convergence measurements surrounding a two-entry gate-road yield pillar in the head gate of a coal mine. Convergence was measured over a six-month period, as the longwall face approached and passed the pillar. Measurements were collected at eight locations surrounding the pillar: four locations in the travelway and four locations in the beltway. In addition to convergence stations, the pillar was instrumented with an array of seismometers. In future analysis, convergence measurements will be compared to seismic interpretations. This study reports on the geology and geometry of the longwall panel, the roof and rib support, the change in convergence over time, and the physical properties of coal and parting. Additionally, the convergence measurements are compared to pillar safety factor distributions derived from a finite element model. The convergence measurements contribute to the knowledge of when yield pillar abutment loading, caused by the encroaching longwall, is first detected. Knowing when abutment loading begins to yield the pillars can help define when standing secondary roof supports are required for head gate entry support.

By William J. Douglas

Critical path modeling (CPM) has been used widely as a tool to manage large-scale projects having many activities which are conducted in series or parallel. The construction industry is a regular user of critical path modeling as a planning tool. In this context, the method is used to provide an orderly schedule for all activities to forecast delays, slippages, and problem areas and to identify critical activities where resources should be directed. It also identifies others which have slack time, and provides information on the degrees of freedom and flexibility available in completing the project. The purpose of applying critical path modeling to an underground mining system is not primarily for scheduling, but as an analysis tool. In observing underground mining systems, it Is clear that repeated sequences of activities must take place for mining to proceed efficiently. Some of these activities must be sequential, while others be carried out in parallel. The fundamental difference between critical path modeling applied to mining versus a large-scale construction project are: (1) The activities in a mining system are cyclic in nature. (2) The location of the activity varies, and the entire process is not thought of as co-located, as is the case in a construction project. Another important aspect of the network development for mining systems is the degree of detail that is desired. One can be concerned with very macroscopic networks which represent, for example, an entire mine life cycle. Networks representing this problem would be more closely analogous to those of a large construction project. On the other hand, one might be interested in evaluating alternative ways of developing a property or of mining in a given section. More detailed networks representing the section activities are necessary to evaluate system parameters and their impact on long-term production.

Jan 1, 1978

By Y. C. Kim

Three rock fracture parameters define three points along empirical cumulative size (of rock fragments) distribution curves at Inspiration copper mine. These parameters are: rock quality designation (RQD), longest piece of intact rock and % of +1 inch. The RQD and the longest piece are actually measured on drill hole cores whereas % of +1 inch is visually estimated on the same cores. These size distribution curves are then utilized in a variety of engineering applications such as; slope instability analysis, blast design, copper recovery prediction from heap leaching, etc. The three rock fracture parameters for two dominant rock types (porphyry and schist) in the pit had to be estimated separately due to different rock fracture characteristics.' Both ordinary kriging (OK) with measured hard data only and soft kriging (SFTK) with hard and soft data were used to estimate each parameter. The cross validation of 100 measured sample values served as the-basis for evaluating the potential benefits of SFTK over OK. Use of subjective information during SFTK required obtaining (prior) probability distributions for all three rock fracture parameters. These distributions were obtained from the typical rock fracture parameters observed in drill hole cores falling inside the geologically interpreted structural domains with varying degrees. of fracture intensity and also through direct mapping along the exposed bench faces. Two different types of soft information were developed for this study; namely, Type "A" and Type "K". The former is based on sample distribution of fracture parameters whereas the latter is based on two step estimation designed to narrow the range of variation observed in data Type "A". The results of the cross validation were analyzed using a linear regression of actual values versus estimated values. The results confirm an improvement on the estimates made by SFTK with hard and. both types of soft data over those produced by OK with hard data only.

Jan 1, 1989