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By M. Fig, J. Brune, C. Strebinger, G. Bogin

"A fundamental understanding of flame propagation characteristics through and around obstacles is needed to accurately model methane driven longwall coal mine explosions originating or propagating in the gob. Experimental investigations of methane flames in horizontal cylindrical reactors with simulated gob (i.e. rock piles) were carried out alongside coupled Computational Fluid Dynamics (CFD) and combustion simulations. Stoichiometric methane-air mixtures were ignited in semi-open reactor vessels of 5cm, 9.5cm and 71cm diameter, all with a fixed length to diameter (L/D) ratio of 8.6. This was done both with empty reactors and also with a rock pile placed at the open end of the reactor. The rock pile length to reactor length ratio was fixed at 0.3, and the rock pile height to reactor diameter ratio was fixed at 0.33 for all reactors. The smaller two reactor experiments were modeled with ANSYS Fluent in 2D. Experimental results indicate that for this geometry a similar acceleration mode occurs across scales: that the flame speeds up an average of 40% as it passes over a rock pile with this profile. The model is able to capture several important features of the experimental results, including the significant increase in velocity, the speedup ahead of the rock pile, and the leveling off of the empty tube flame front propagation velocity. INTRODUCTION Explosions in underground coal mines are among the largest industrial explosions, known to result in the rapid combustion of 20m3 of fuel gas or more [1,2] Coal beds hold methane gas under pressure, and when the pressure is relieved through mining activity some of this methane is released. The methane then mixes with ventilation air and, if not sufficiently diluted, may form a combustible mixture, which may result in an explosion. Several large coal mine explosions have occurred around the world recently. These include the 2014 Soma Mine disaster in Turkey that killed 301 people [3], and the 2009 Heilongjiang Mine explosion in China that killed 108 [4]. Other recent mine explosions, including the 2010 disaster at the Upper Big Branch mine that caused 29 fatalities [5], have demonstrated that explosive gases can accumulate and ignite within and around the gob area of a longwall coal mine and then expand into the active mining face and nearby areas, endangering workers and equipment. If enough combustible gas is involved, the initial flame can accelerate, eventually transitioning from deflagration to detonation [6]. Researchers are developing a fundamental understanding of the evolution of the explosion process from the laminar kernel to the fully turbulent regime, and its propagation through obstacles such as those found in the gob. Researchers also studied the initial development of methane flames and the potential for the development of a detonation."

Jan 1, 2018

By Al. Valero

This paper quantifies in universal units (energy units), the annual decrease in the mineral endowment of the planet. This is done for some important extracted non-fuel minerals, namely aluminium, cobalt, chromium, copper, gold, lead, uranium and zinc and is compared with the depletion figures of conventional fossil fuels. The results of this study reveal that each year, the decrease of the global non-fuel mineral bonus provided by Nature is 2 to 3 orders of magnitude greater than the loss associated to the burning of fossil fuels. Particularly for 2008, the depletion in mineral wealth of the studied commodities was about 20 times greater than that of fossil fuels. The assessment methodology is based on the Second Law of Thermodynamics. It quantifies the useful energy (exergy) required to concentrate a mineral from a completely dispersed state in the crust, to the conditions of composition and concentration found in the mines. Exergy can be a useful measure for quantifying the mineral depletion caused by man, as it takes into account the main physical features that make minerals valuable: composition and concentration. This analysis enhances and puts numbers to the importance and necessity of material reuse and recycling.

Jan 1, 2011

By H. Köse, C. Tatar, C. Helvaci, F. Simsir

The Çayirhan coal basin is located 124 km (77 miles) west of Ankara,Turkey. With approximately 520 Mt (570 million st) of lignite reserves, the Neogene Çayirhan basin is one of the important coal districts of the central Anatolia region. The Çoraklar formation consists of crossbedded sandstone, channel fill conglomerates, mudstones, carbonaceous shales and volcanoclastic pebblestones, which are fluvial in origin. The lower and upper lignite seams occur, respectively, in the lower and the uppermost parts of the Çoraklar formation. The lignite deposits are in the Çayirhan and Koyunagili portions of the Beypazari Neogene basin. The Çayirhan coalfield consists of lower and upper lignite seams. The lower lignite seam does not outcrop at the surface. Its lateral discontinuity and relatively low sulfur content, plus sedimentologic and stratigraphic features of the associated sediments, indicate a fluvial origin. Thus, the lateral spreading and geometry of the lower lignite deposits were controlled by the channel, flood plain and well drained marshes of a fluvial system. The mining method employed at Çayirhan is the fullymechanized, retreat, working longwall with caving system. Due to ventilation, haulage and tectonic conditions, panel lengths from 0.6 to 1.7km (0.4 to 1.1 miles) are chosen, and 220-m (720ft) face lengths are used. The annual coal production is 2.2 Mt (2.4 million st).

Jan 1, 1994

By Jeffrey J. Schwoebel, Jianliang Li, Daniel J. Brunner

A United Nations (UN) administered degasification technology transfer project, funded by the Global Environmental Fund (GEF) is underway at the Shihao Mine of the Songzao Coal Mining Ad- ministration in the province of Sichuan, Peoples Republic of China. This mine exploits multiple seams at depths ranging from 300 to 600 m below surface. In-seam boreholes and frequently spaced in-mine vertical boreholes, developed from underlying galleries constructed specifically for this purpose, currently degasify the seams in advance of mining at the Shihao Mine. Because of ventilation system constraints and the in-situ gas con- tent, longwall mining of the coals at this mine could not proceed without some form of pre-mining degasification. This paper presents a simulation based degasification plan of long, in-seam horizontal boreholes for the Shihao Mine. Simulations with a coalbed reservoir program assessed time dependent degasification characteristics of both vertical and in-seam horizontal boreholes. The simulations used input data from reservoir and desorption tests conducted at the mine site. The results produced system design nomograms to assist mine engineers in defining the appropriate borehole spacing necessary to degasify the seam in the time available for pre-mining drainage. The predicted effectiveness of the current vertical degasification scheme was compared with that for a horizontal borehole program and served as the basis for the recommended in-seam borehole configuration for the project at the Shihao Mine. The horizontal borehole degasification program requires substantially less gallery and borehole development than the present vertical degasification scheme.

Jan 1, 1997

By Leonhard Schmid

INTRODUCTION In the region of Zurich several of the Swiss Interstate Highways meet and have to be linked to form a continuous network. The subalpine glacial topography with hills, ridges and lakes requires the construction of many tunnels (Figure 1). The Milchbuck Tunnel forms part of the inner arterial highway system of the city of Zurich. It passes underneath the ridge separating the Limmat and Glatt valleys. In its final configuration the tunnel will consist of two parallel three-lane tunnels (Figure 2). For the time being only one tunnel is constructed. This tunnel will be operated with two outbound (climbing) lanes and a single inbound (descending) lane (Figure 3). The owner, the Canton of Zurich, awarded the contract for the construction to a joint venture with the following three contractors: Locher & Cie AG (leader), Prader AG, A. Brunner's Erben, all located in Zurich. The actual freezing was performed by subcontractor Philipp Holzmann AG, Mannheim, West Germany. Electrowatt Engineering Services Ltd, Zurich, was design engineer and performed the construction supervision.

Jan 1, 1981

By J de Cuyper, E. J. Parkins, H. L. Shergold, W. Freyberger

The paper is divided into two parts. The first part describes an investigation of the effect of temperature on the conditioning and flotation of an ilmenite ore with a 1:l oleic acid-fuel oil mixture as collector. During conditioning the pulp underwent characteristic changes of flocculation, deflocculation and dispersion which were monitored by measuring the power consumption of the conditioner motor. Optimum flotation results were obtained at the end of the deflocculation period. High ilmenite recoveries were obtained at high temperatures and high concentrate grades at low temperatures. The second part of the paper describes a study of the effect of temperature on the adsorption of oleic acid at the ilmenite/water interface. At high adsorption densities it was chemical and exothermic. Contact angles showed that the hydrophobicity of the collector-coated minerals increased with an increase in temperature.

Jan 1, 1976

By Erwin K. Roesner

The difficulties encountered while sinking deep shafts for Potash Mines in southern Saskatchewan have been the subject of several papers in the past. Geological and hydrological conditions of the strata overlying the potash deposits require special techniques for ground and water control during shaft sinking. The easily soluble potash ore requires the lining of these shafts to be virtually watertight to assure long term and safe operation. This paper describes the construction of the most recently completed potash shaft for the Potash Corporation of Saskatchewan. The shaft was designed and constructed by Thyssen Mining Construction of Canada Ltd. and it is located near Lanigan, approximately 110 km east of Saskatoon.

Jan 1, 1980

By John E. Dreier

The Pachuca-Real Del Monte district, Hidalgo, Mexico (Figure 1) has produced roughly 1,500,000,000 oz Ag., 6,000,000 oz Au. and minor Pb., Zn, and Cu from about 100,000,000 tons of ore since discovery early in the 16th century. Production has come from epithermal vein deposits that have been up to 8 km in length, 650 m in vertical extent and 45 m in width but which averaged 200-400 m in length and vertical extent and 2-4 m in width. Ore deposits occur through-out an area about 12 km E-W by 10 km N-S (Figure 2) and between the elevations of 2000 and 2800 m above sea level. The deposits occur as shoots in the veins and terminate laterally where the veins narrow, upward where the veins pinch out and downward where the veins decrease in silver con-tent to below the cut-off grade; the veins are known to extend 500 m below the bottoms of the ore bodies and probably extend to much greater depths. The district lies wholly within a mid-to-late Tertiary volcanic rock sequence that is made up principally of andesite and dacite lava flows and flow-breccias. Although the bottom of the sequence is not exposed in the district, stratigraphic constructions indicate the volcanic rocks to have an aggregate thickness of 2000 to 2500 m. Structurally, the area is characterized by gentil warping and normal faulting of the volcanic rocks. Pre-ore modifications to the volcanic rock sequence consisted mainly of faulting along west-trending, south-dipping normal faults and north-trending high-angle faults.

Jan 1, 1978

By T. V. Shockley

The Gulf Coast, from New Orleans, Louisiana to Brownsville, Texas, is one of the largest high energy consuming areas in the United States. This region has areas of very high industrial density. The lower Mississippi River from Baton Rouge past New Orleans has a high industrial density. Lake Charles, Louisiana, the Orange-Beaumont-Port Arthur area, Houston (4 separate areas) and Corpus Christi all have the same high industrial density. This situation developed due to good transportation, good labor conditions, good weather and the abundance of cheap energy-gas and electricity. Obviously the latter had the greatest impact. The availability of cheap natural gas made Gulf Coast sites very attractive to energy intensive industry such as metals and petro-chemicals. The area was also very attractive to refinery development due to the large supply (endless?) of crude oil available. As we all know, the energy situation has changed dramatically in the last five years. The cost of a MMBTU has risen from the 17¢ to 19¢ level to a price of $1.95 to $2.10. The price of interstate gas, as defined by the National Energy Plan recently passed by Congress, was approximately $1.98/MMBTU escalated to October, 1978. It goes without saying, that this has had a major impact on doing business in the Gulf Coast. As fuel prices soared, different companies responded in different ways; but overall, industrial energy consumption along the coast was reduced 20% to 25% from 1974 to 1975. Since 1975 production and energy use has been increasing, however, production at some plants is still significantly below plant capacity.

Jan 1, 1979

By James F. Lemons

The potential production of cobalt from nickel sulfide deposits in Canada, from nickel laterite deposits in the Pacific Islands, and from the copper deposits of Zaire and Zambia will be a function of the cost of recovery of the primary nickel and copper products. This cost of production varies significantly for these deposits and is related to the differences in the cost of labor, energy, and supplies, to production technology, and to the grade and recovery of nickel, copper, and cobalt. This Bureau of Mines paper investigates these cost and technology differences as they relate to the cost competitiveness of the deposits in Canada, Zambia, Zaire, and the Pacific Islands.

Jan 1, 1984

By L. A. Obasi, C. Obasi

Investigations were carried out to determine the effects of changing metamorphic conditions on the formation of magnetite from the Itakpe iron ore deposit. Various magnetite grain sizes from ferruginous quartzites from different zones were determined and analyzed statistically. The results reflect the reaction of mineral individuals. In particular, the granulometry of magnetite changed with changes in the mineral formation conditions in the deposit and correlate with the mineralo-geochemical zones. This is interpreted as part of a readjustment of the mineral to the prevailing conditions. Because granulometry is a prebeneficiation parameter, this work will be, no doubt, of importance to the exploitation and beneficiation of the quartzites and rich ores.

Jan 1, 2000

By L. E. Beverage

In 2006, the Mine Improvement and New Emergency Response Act (?2006 MINER Act?), Pub. L. No. 109-236, 120 Stat. 493 (2006) was enacted in a bi-partisan move to strengthen the 1977 Mine Safety and Health Act. This action followed several underground coal mining accidents at the Sago and Aracoma Mines in West Virginia and the Darby Mine in Kentucky. The focus of that legislation was, in part, to force technological development and implementation. It involved the recomposition and training of rescue teams. Requirements for sealing worked out areas of mines were changed when MSHA invoked its Emergency Temporary Standard (?ETS?) authority for the first time in many years. Increased penalty amounts were established for certain types of violations for all types of mining, and minimums were set for unwarrantable failure violations issued under Section 104 (d)(1) and (d)(2); 30 U.S.C. Section 814 (d)(1),(2). The entire 30 C.F.R. Part 100 penalty criteria was revamped in a rulemaking, effective in April 2007. The visions were ambitious and noteworthy and those in industry and government have spent the last four years working through the aftermath of intended and unintended consequences of these changes. The penalty structure arrived at in 2007 has proven unwieldy and has contributed to the increase in contested caseload now before the Federal Mine Safety and Health Review Commission. In essence, litigation under the Mine Act ground to a virtual halt when the number of cases increased but the budget for Administrative Law Judges, who hear the cases, and the Solicitor?s office who represents MSHA, was not increased. Addressing the backlog effectively was one of the major challenges when Joe Main was confirmed as Assistant Secretary in early 2010.

Jan 1, 2011

By P. R. La Pointe, H. C. Ganow

The production of both over- and undersized coal fragments is a constant problem to open pit operators in the Powder River Basin. Operators strive to achieve production blasts that economically minimize the weight percentage of over- and undersize coal. However, natural fractures influence blast fragmentation, and can impose limits on the final fragment size distribution. ARCO&apos;s Anaconda Minerals Company studied the limits placed by natural fracturing as part of a wider geotechnical study of the Wyodak Coal in the eastern Powder River Basin, Campbell County, Wyoming. Measurements of fracture orientation, size and spacing were made at ARCO&apos;s Black Thunder Mine. These data were used to form statistical distributions for natural fracture size, spacing and orientation. An algorithm was created to select fracture properties at random from these distributions and to form hypothetical blocks. The blocks were then numerically "sieved" to derive pos- sible particle size distribution curves. These curves are compared to fragmentation results from samples taken from three test blasts. All test blasts yield very similar lognormal fragment size distributions. The median particle size varies from 1.25 to 2.0 in.(3.2 to 5.1 cm), the mean from 4.0 to 8.5 in. (10.2 to 21.6 cm). The standard deviation was about 1.6 in. (4.2 cm). Coal fines (fragments < 0.25 in. or 0.64 cm) are about 15%. Calculated fragment distributions for the natural fractures predict the median size well but underestimate the variance. Algorithm modifications to account for processes known to occur in the comminution zone near the blast hole significantly improve the match in the fine coal size range. The match suggests that spacing of fractures, rather than fracture length, controls the formation of fine- and medium-sized fragments. On the other hand, the oversize coal is controlled by the fracture lengths, rather than the spacing. Data from subsequent test blasts support this idea. By increasing delay times from 8 msec to 17 msec, engineers were able to reduce fines to 7% - 10% but could achieve no further improvement, despite changes in shot pattern geometry, decking and hole size. The hypothetical fragment distributions show that, even without blast enhancement, about 5% of the natural coal blocks are fine-sized.

Jan 1, 1986

By D. R. Dolinar, J. Pablic, D. C. Oyler, T. P. Mucho

At a mine in central PA, high horizontal stresses have caused long running roof falls resulting in hazardous conditions for the miners and the premature abandonment of panels. Because of these conditions, the mine requested assistance of the National Institute for Occupational Safety and Health (NIOSH) in utilizing the "advance and relieve" method to mitigate the affects of horizontal stress on the mine roof. "Advance and relieve" mining involves the removal of a pillar or a portion of a pillar during development, thereby creating a cave along one side of the panel. Following cave development, the horizontal stress is relieved over the workings adjacent to the cave in the active panel. The mine has used this system in three panels with a significant reduction in stress damage and no large roof falls.

Jan 1, 2001

By Ahmad Rahbar-Kelishami, Zahra Karimi

When alumina is extracted from bauxite ore, one of the environmental pollutants created is known as red mud (RM). This study clarifies that the RM obtained from the Iran Alumina Company has a significant proportion of iron oxides (24%), alumina (19%), silica (17%), and calcium (21%), as well as trace amounts of other minerals. The elements in the RM can be removed and utilized again to reduce environmental pollution. Acid leaching is one of the best ways to selectively exclude some minerals from the RM. In this research, the RM is exposed to different inorganic acids, including HCl, HNO3, H2SO4, and H3PO4, and their binary mixtures. By comparing the results obtained from XRD, EDX, and SEM, it was discovered that CaSO4 crystals are formed by exposing the RM to sulfuric acid. Besides, phosphoric acid was only able to destroy the surface of RM particles. The XRD analyses of acid-washed residues demonstrated that except for the residue of HCl 5 N, all residues contain hematite, showing that inorganic acids cannot easily extract hematite from the complex phases of red mud. While the dissolution of RM with HCl or HNO3 will remove most of the calcium content of RM texture, increasing its iron oxide percentage, which may subsequently be utilized to make colors and pigments.

Mar 29, 2024

By Dapeng Zhang, Brij Moudgil, Shibo Zheng, Chunhui Feng, Wenyi Song, Wending Xiao, Patrick Zhang

Separation of dolomite from phosphate is the most challenging problem in phosphate mineral processing. Over 50% of the future phosphate reserve in Florida contains too much dolomite to process using the current industry practice. The current phosphoric acid production practice requires less than 1% MgO in the phosphate concentrate as the feed material. The Florida Industrial and Phosphate (FIPR) Institute has collaborated with worldwide experts in the field to address this issue. As a result, the industry is now offered three feasible options. Option 1 offers three methods for reducing MgO content in the concentrate from the Crago process, including adding a dolomite depressant in the rougher flotation step, dolomite flotation of the cleaner concentrate, and scrubbing the cleaner concentrate in quartz sand. These methods could reduce MgO content in the final concentrate by 20–40%. Option 2 involves crushing and grinding of high-dolomite phosphate pebbles followed by dolomite flotation at slightly acidic pH using a new collector that does not require phosphoric acid as a phosphate depressant, achieving a final concentrate analyzing less than 0.9% MgO at about 87% P2O5 recovery. Option 3 is a gravity separation technique using an innovative separation jig, and its full potential remains to be demonstrated.

By G. Orhan, C. Arslan

The possibility of producing metallic chromium from Cr2O3 via the aluminothermic route, with no external energy supply, was the subject of this laboratory-scale research. The experimental study focused on investigating the individual effects and quantitative optimization of the charge contents, i.e., the additions of CrO3, Al powder and CaO (or BaO). The highest chromium recovery of 98% was attained with the additions of 12% CrO3 and 1.2 times the stoichiometrically required amount of Al powder. The optimum CaO addition giving the highest chromium recovery was found when the CaO/Al weight ratio in the charge was equal to 0.3. When BaO was used, however, 95% Cr extraction efficiency was obtained at a BaO/Al weight ratio of 0.15.

Jan 1, 2000

By Dale S. Preece

INTRODUCTION The Waste Isolation Pilot Plant (WIPP) is a research facility located in Southeastern New Mexico. The WIPP is being developed by the U. S. Department of Energy (DOE) to demonstrate the safe storage of defense-related radioactive wastes in bedded salt. Since the WIPP is a research facility. a number of large-scale in situ experiments have been planned and are currently under construction (Munson, 1983). These experiments were designed to study various aspects of nuclear waste storage in bedded salt such as mechanical responses and creep closures of drifts, thermal response due to heated canisters, and thermally-induced fluid migration. One purpose of the WIPP is to develop and demonstrate a general predictive structural analysis capability for a bedded salt repository. One set of experiments, called the Geomechanical Evaluation (Room G), is heavily instrumented to study the creep around several rooms with different configuration. A Layout of the Geomechanical Evaluation room is shown in Figure 1. One portion of it consists of wedge shaped pillar where two drifts intersect at an angle of 7.5 degrees. The pillar can be seen at the bottom of Figure 1. One purpose of the wedge pillar experiment is to study progressive pillar failure in the tip region. Another is to determine how nonuniform pillar thickness affects creep closure of the drifts. An important aspect of the experiments is the correlation between experimental data and corresponding pretest finite element analyses of the site. The finite element simulations serve two purposes. First, the computer simulations aid in understanding the experimental results by providing calculated stress. strain and displacement fields that cannot be measured directly. Second, comparison of calculated and measured drift closures serves as a method for validating or improving the finite element models and the constitutive models employed. The wedge pillar geometry required a 3-D finite element creep calculation. Results from these 3-D calculations will be presented in this paper. A 2-D plane strain double drift model which approximates the wedge pillar geometry at a slice perpendicular to the drift has also been performed and will be compared to the 3-D results in this paper. FINITE ELEMENT COMPUTER PROGRAMS Two finite element computer programs. JAC (Biffle, 1984) and JAC3D (Biffle. 1986), were used. JAC is a 2-D finite element program developed for quasi-static analysis of non-linear solids. It employs the conjugate gradient iterative technique to obtain a solution Spatial integration is performed using a single gauss point in each four node quadrilateral element. An hourglass viscosity technique is used to control the zero energy modes that occur with single point integration. The single point integration combined with the explicit nature of the program and exploitation of CRAY-1 computer architecture results in very efficient execution J4: results were compared to results obtained with eight other 2-D structural creep computer codes in the second WIPP benchmark exercise (Morgan, 1981) JAC3D was derived from JAC to treat 3-D finite element models and has many of the same characteristics including single point integration and hourglass viscosity. These characteristics have made 3-D creep analyses more reasonable by significantly reducing computation time The first exercise of the creep capability

Jan 1, 1986

By Sandeep Kumar Asarapalli, Sunil Kumar Bisoyi, Bhatu Kumar Pal

Spontaneous heating of coal is one of the major concerns in the coal mining industry. Hundreds of millions of tons of coal are lost each year because of spontaneous heating. If necessary arrangements are made, many fires due to spontaneous heating may be avoided. Therefore, protective measures have become essential to prevent coal from spontaneous combustion. A large amount of coal reserve can be saved by the assessment, suppression, and prediction of spontaneous heating of coal, which also helps in betterment and efficient coal production. The use of chemical retardants can act as inhibitors for the liability of coal toward spontaneous heating by increasing its ignition temperature, thereby, increasing its incubation period. The coal-chemical mixture can be used for whitewashing the exposed coal in galleries as it creates a layer between coal and oxygen in the atmosphere, delaying the oxidation process and ultimately inhibiting the spontaneous heating liability of coal. This work examines the effect of chemicals such as sodium chloride, calcium carbonate, potassium iodide, sodium nitrate, and potassium chloride on the spontaneous heating of a coal sample. Thereby, it suggests a better chemical for inhibiting the liability of coal toward spontaneous heating. The experimentation involves flammability temperature (FT), crossing point temperature (CPT), and differential thermal analysis (DTA). The ignition and oxidation temperatures were found from the above experimental methods for Lingaraj open-cast coal mine samples, with and without adding chemicals. The results are cross-checked and verified through DTA. Correlation analysis was carried out among the results obtained from CPT, DTA, and FT, and better chemical retardants that effectively inhibit coal’s tendency toward spontaneous heating were suggested.

Dec 23, 2023

By David Marsh, Mark W. Johns

Carbon-in-pulp (CIP) is a preferred method of gold recovery from cyanided pulp. However, the resin-in-pulp (RIP) process is considered to have several advantages for the recovery of gold. Mintek therefore undertook a research programme to develop a commercially-viable RIP process. The MINRIP RIP process and a novel gold­selective strong-base resin, Minix, were developed. The process has been successfully demonstrated at a scale of 100 000 t/month. Continuous countercurrent tests using synthetic solutions indicate that the relative performance of an adsorbent depends on the composition of the solution. Minix resin yielded a higher gold loading than that of carbon, while maintaining an acceptable barren value. Batch tests on a number of gold-bearing materials indicated that Minix has potentially a higher capacity than carbon, and loads gold faster than carbon. An economic appraisal that consolidated the countercurrent results and the economic study indicated that the capital and operating costs of the Minrip process are considerably lower than those of CIP. The amount of the cost advantage depends on the gold content of the feed and the throughput.

Jan 1, 1993