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By M. S. Safarzadeh, V. Agarwal

"The solvent extraction of cerium(III) and samarium(III) from mixed solutions of all rare earth elements (REEs) except promethium using PC88A (2-ethyl hexyl phosphonic acid mono-2-ethyl hexyl ester), an acidic extractant, was investigated. The effects of aqueous equilibrium pH, various acids (sulfuric acid (H2 SO4 ), hydrochloric acid (HCl) and nitric acid (HNO3 )), initial metal ion concentration and extractant concentration on the solvent extraction of Ce(III) and Sm(III) were systematically studied. From the experimental results, HNO3 and HCl were found to be the preferred aqueous media for the solvent extraction of both Sm(III) and Ce(III). The most promising experimental conditions of pH, PC88A concentration and metal ion concentration were identified for the extraction of Ce(III) and Sm(III). Separation results showed that H2 SO4 at pH 2 provided the best separation between Sm(III) and Ce(III). IntroductionIn recent years, demand for rare earth elements (REEs) has increased significantly because of their many commercial applications. REEs have especially important high-tech applications owing to their unique physical and chemical properties, and they are used in a wide range of areas such as catalysts, ceramics, magnets, lasers, glass, neutron absorption and alloys. As REEs have very similar physicochemical properties, their separation and purification from each other is challenging and gaining significant interest. Samarium (Sm) and cerium (Ce) are found in different REE minerals, including bastnäsite ((Ce,La,Nd(CO3)F), xenotime (YPO4) and monazite ((Ce,La,Nd,Th)PO4) at major production sites in the United States and China, as listed in Table 1 (Bleiwas and Gambogi, 2013). The most common acidic organophosphorous extractants used for REEs extraction and separation are DEHPA (di-(2-ethylhexyl)phosphoric acid), PC88A (2-ethyl hexyl phosphonic acid mono-2-ethyl hexyl ester), Cyanex 272 (bis-2,4,4-trimethylpentyl phosphinic acid) and Cyanex 301 (bis(2,4,4-trimethylpentyl)dithiophosphinic acid) (Sarangi, Reddy and Das, 1999; Surampally et al., 2012; Tian, Jia and Liao, 2013). Out of these extractants, PC88A is known for providing higher separation factors (Acharya, Mishra and Misra, 2015). El-Hefny et al. (2010) investigated the kinetics of the solvent extraction of Sm from chloride media using sodium salt of Cyanex 272 and reported the extracted species to be Sm(OH)A2•2HA. Lee et al. (2005) investigated the solvent extraction of Sm(III) with PC88A and saponified PC88A from chloride solutions and found the stoichiometry of the extraction reactions to be 1.5 with PC88A and 3 with saponified PC88A."

Jan 1, 2017

The only significant iron ore deposit in Hungary could be found in Rudabánya. The mine was closed in 1986. The area of Rudabánya was always the home of heavy mining activity. In former times, mainly silver and other non -ferrous metals were excavated.

Jan 1, 2011

By Lane White

In mid-April 1992, MINING ENGINEERING mailed a survey questionnaire relating to mining shovels and hydraulic excavators to 125 SME members working at surface mines or at the headquarters of companies that operate surface mines. The mailing was directed to individuals whose titles indicate that they have management or mine planning responsibilities for surface mining operations. A total of 56 usable surveys returned by June 17 are the basis of this report. Precious metals mines Eighteen precious metals mines or mining companies returned completed surveys in time to be included in this report. Of these, 14 use hydraulic shovels only for both ore and waste, I uses both hydraulic and rope shovels, and 2 use Caterpillar 988 front-end loaders for both ore and waste. (Of the latter 2, neither expects to be in the market for a shovel in the next three years. I of these 2 placed Harnischfeger P&H number one and O&K number two in response to the question, "Based on your current knowledge of their machines, which manufacturer would you likely chose to supply new shovels or excavators to a mine or mines operating under your responsibility, if you were in the market?") Another uses front-end loaders, make not designated. The latter does not expect to be in the market for mining shovels or excavators within the next three years. Of the final total of 14 precious metals mines using only hydraulic excavators to load ore and waste, 8 use Hitachi excavators only, 1 uses Demag excavators only, 1 uses Liebherr excavators only, 1 uses O&K excavators only, 1 uses Harnischfeger P&H and O&K excavators, 1 uses Harnischfeger P&H and Hitachi excavators, and 1 uses Hitachi and Demag excavators. Of the 14 precious metals mines using only hydraulic excavators, 7 use excavators in the 7.6 to 11.5 m; (10 to 15 cu yd) size range. Of these 7, 5 use only excavators in this size range, and they are used to load both ore and waste. 1 of the 7 also uses 11.5 to 17 m' (15 to 22 cu yd) excavators, and I also uses a 17 to 23 m3 (22 to 30 cu yd) excavator. Of the 7 remaining of these 14 precious metals mines that use only hydraulic excavators, 3 use 11.5 to 17 m' (15 to 22 cu yd), 2 use 17 to 23 m3 (22 to 30 cu yd), and 2 use less than 7.6 m' (10 cu yd) units.

Jan 1, 1992

By M. J. Laurila

On-line analyzers have made possible the use of fuzzy logic control (FLC) for local control applications in coal preparation plants. This includes FLC of heavy media vessels, cyclones and froth flotation. These circuits can be controlled in real time in a feedback control loop with an on-line analyzer. Control strategies can be developed using statistical process control (SPC) techniques that are first applied offline in manual mode through the use of control charts. This process is then brought on line using FLC in conjunction with an on-line analyzer to automate the circuit. The advent of programmable logic controllers into preparation plants has enabled the implementation of regulatory control. As shown in Fig. 1, regulatory control is the first level of process control as applied in a processing facility. This involves: ? The logic sequences for start-up and shutdown procedures and all the necessary interlocks for safety purposes. ? The systems to control individual parameters and individual units. Various sensors provide information that is useful to plant operators, while some can be used as signals to simple control loops (Couch, 1996). This is the foundation of process control. It must be performed well if there is to be any success in supervisory control (level 2). Supervisory control involves overseeing and directing the operation of unit operations, or of the whole plant. This includes more complex loops with cascade control. And it may involve feed forward and feedback systems. There have been some applications of this kind of control to thickeners and flotation circuits in coal preparation plants. In addition, there are supervisory controls on some dense medium circuits and, in a few cases, on jigs. These are implemented with proportional integral- derivative (PID) controllers that are available in the PLC or distributed control system (DCS) operating soft ware. In a coal preparation plant, there might exist 200 to 400 PID loops. In a coal-pro¬cessing plant, this number is increased to 2,000 loops or more. It is important to use the correct algorithm or function to control a process variable to the point where automatic control shows a markedly decreased variability over manual mode. This is where fuzzy logic and neural networks have an advantage over traditional model-based expert systems. Because dynamic models of coal preparation unit operations do not exist, model-based expert systems that are prevalent in minerals processing cannot work. Not enough is known about the dynamics of the gravity separation processes employed in coal preparation. Therefore, an artificial intelligence (AI) system consisting of a subset of fuzzy logic, genetic algorithms and neural networks must be applied in coal preparation plants if a supervisory control system is to be successful across a range of feed characteristics and variable set points.

Jan 1, 1997

By D. K. Gibson, A. I. M. Ritchie

The phenomenon of acid drainage is likely to occur whenever pyritic rock is broken up, permitting access of air and water. The basic chemistry of the oxidation process is described by the equations below:- FeS 2 +1120 + 7 02 ➔FeS04 +112S04 +1440k.J This reaction proceeds rather slowly, although believed to be bacterially catalysed to some extent. Once sufficient ferrous ions and acidity have been established the following two reactions take over, yielding the same net result but at a much greater rate. First, ferrous ions are oxidised to ferric; this is an extremely slow reaction unless bacterially catalysed.

Jan 1, 1991

By Daniel W. Kappes

This paper examines the issue of heap leach cash flow based on some recent operational examples. After the first six months of operation, single-lift continuous heaps produce into salable bullion only 70% of the total recoverable gold stacked. This compares with "batch" heaps and lab columns which achieve 100% in two to three months. Multiple-lift heaps often experience a second cash flow depression as a result of the holdup of gold in the heap. Heap leach projects seldom fail based Oil technical pe1for111ance, but they often fail in the sense that they gmerate cash flow at a much slower rate than expected.

Jan 1, 2000

By Arthur P. Chaves, John A. Meech, Vanessa M. Torres

Process choice for a refractory gold ore can become a controversial issue, especially at the early stages of a project. This happens since at preliminary stages, a simple economic comparison among the main process options is not possible as the differences are usually smaller than the precision of estimates. This paper presents a methodology to assess the suitability of each available technologies using a heuristic approach, were technical, economic, operational and environmental aspects are taken into account using a neural network methodology. This methodology is embedded in an expert system for gold ore process design, Intelligold, which is in the final stages of development.

Jan 1, 2000

By G. F. Willis

Gold mineralization in the Mesquite district is hosted by a series of Jurassic amphibolite grade metamorphic rocks which have been intruded by a Cretaceous leucogranite pegmatite. A series of northwest trending, high angle, normal faults have apparently acted as a structural locus for mineralized epithermal fluids and thus economic concentrations of gold in the Big Chief orebody. Late Tertiary fault reactivation has bounded the fault and fracture controlled mineralization. Popular theories of ore genesis call on, (1) Tertiary detachment faulting, (2) the Cretaceous intrusive, or (3) the opening of a dilational jog between regional dextral strike-slip faults as a source powering the gold bearing hydrothermal fluids.

Jan 1, 1988

By D. H. Davidson

In situ leaching (ISL) of copper has the potential of reducing both capital and operating costs for copper production. The ISL process combines surface facility (SX/EW) and wellfield operations, each of which must process the same total flow rate and pregnant liquor copper concentration. Commercial cost data are only available for SX/EW facilities. This paper discusses: the interaction between the principal wellfield costs associated with well modules, and wellfield start?up with SX/EW costs; how to estimate what the level of wellfield costs must be to optimize DCF/ROR; and how to relate these wellfield costs to orebody geologic and mineralogic characteristics.

Jan 1, 1988

By Dale C. Matthews

Pressure oxidation of refractory gold ores is becoming more popular in what has become an environmentally sensitive society. This article discusses some specific process problems and solutions involved with starting up and operating an autoclave circuit. The Getchell gold deposit is located about 72 km (45 miles) northeast of Winnemucca, NV. The deposit was discovered in 1934 and first production came about in 1938. The oxide portion of the ore body was mined and milled from about 1936 through 1950. Refractory arsenic-bearing sulfide ores had long been known to exist in the Getchell deposit. These ores had been mined concurrently with the oxides since 1938.

Jan 1, 1991

By C. A. Fleming, R. G. Williamson

Process development for Eskay Creek began in early 1990 at Lakefield Research, and was initially focused on producing a high-grade/high-recovery concentrate for sale. Owing to the significant base metal sulphide (Cu, Zn, Pb) content of the ore, such a product would have made an attractive feed to a copper smelter, while a gravity and/or flotation flowsheet would have circumvented many of the environmental permitting problems that were anticipated. In the event, it was found that neither gravity nor flotation (nor even a combination of the two) was able to produce a discardable tailing and, in late 1990, attention shifted to the development of a hydrometallurgical flowsheet.

Jan 1, 1995

By Ch. Roumpos

The present contribution investigates the way of applying benchmarking for large-scale open-pit mining operations based on sustainability indicators proposed by numerous institutions or groups of experts. These indicators have been developed taking into consideration the legal and regulatory framework that are in force. However, their scope is not only to declare the mining company?s compliance with all legal requirements but also to represent its economic, environmental, and social performance. In this way, sustainability indicators allow assessment of a company?s capacity to produce commodities, to meet the environmental quality requirements and to contribute to a long-term economic, cultural and social development of the local communities.

Jan 1, 2007

By David M. Shaw, John C. Franklin

A 32-channel warning system for high working level, fan operation, and airlock-doors has been constructed. The working level monitors have a microcomputer for accumulating the pulses, converting to working level, and triggering an alarm at a variable set point and at one working level. The system also detects when underground fans lose power or air doors are open. The system can detect changes in air velocity which indicate surface fan failures or changes in the ventilation system. Using this alarm system, the ventilation engineer will be alerted prior to excessive levels of radon daughters being reached so corrective action can be taken.

Jan 1, 1981

By X. Zhou

A novel flotation device, cyclonic static micro-bubble column flotation (FCSMC), was introduced in this paper. FCSMC has been widely applied for fine coal preparation in China, and its application has been further expanded to the mineral processing industry. The FCSMC system features a unique cyclonic structure which enhances the separation performance of the column. In this paper, the cyclonic separation mechanism of FCSMC process was investigated, and corresponding kinetics equations were established to probe the separation principle of this device. Some typical examples of using FCSMC to separate different materials including coal, copper, fluorite, etc., were presented. Key words: cyclonic static micro-bubble flotation column, cyclonic separation

Jan 1, 2008

By Jacques L. Mauboussin

The EUROPEAN ORGANIZATION for NUCLEAR RESEARCH (CERN) has undertaken the construction of a LARGE ELECTRON POSITRON COLLIDER (LEP), near GENEVA (Switzerland). The facility includes the main 27 km long tunnelled ring, 18 shafts, 20 experimental caverns and many auxiliary galleries. Roughly 800 000 cu.m were excavated in the molasse at 50-140 m depths, using roadheaders for caverns and auxiliary tunnels and 3 WIRTH, 4.5 m diameter, fullface TBMs for the main circular tunnel. Each TBM performs 25-30 m/day. Provisory lining behind them uses either precast concrete elements or shotcrete. Works a e being carried out by a joint-venture of European contractors led by FOUGEROLLE (France).

Jan 1, 1987

By W. G. Courtney

The prevention of frictional ignition with a ripper-type continuous mining machine using conical bits was investigated in the laboratory using cutter-drum-mounted water sprays. Results indicated that frictional ignition during dry cutting of sandstone with conical bits was readily obtained even at low drum rpm, while wet cutting with a carefully-designed water spray nozzle located behind the bit substantially reduced the likelihood of frictional ignition. However, the orientation and operation of the spray nozzle is critical and involves almost no margin for error. A Lee-Norse 265 ripper drum has been modified to include durable water seals and is presently being field tested underground.

Jan 1, 1987

By P. Bevilacqua, G. Vallebuona

Empirical models are now used for predicting the performance of hydrocyclones in terms of capacity. cut size (d50.c), water split and partition curve. These models (such as the model by Lynch and Rao and the model he Plitt) were developed and checked for hydrocylones with diameters larger than 4 in. However, for smaller-diameter hydrocyclones, little empirical modeling has been done. This paper reports on an extended experimental research program on small hydrocyclones. For these cyclones, the suitability of existing empirical models was investigated and their accuracy was compared. To improve the predictive capability of these models to small cyclones modifications to the equations are proposed.

Jan 1, 1996

By X. P. Zheng, H. K. Lin

During slow-cooling crystallization of iron-making blast furnace slags, most rare earth elements recrystallize in an artificial "mineral" identified as calcium cerite. Scandium (Sc) and europium (Eu), however, concentrate in a sheetlike "mineral." In this investigation, the mineralogy of this sheetlike "mineral" was studied. It was identified as being in the mica group and was called a rare earth-bearing barium fluorophlogopite. One of the objectives of this study was the recovery of this "mineral." The study indicated that it can be effectively recovered from the slag by flotation using dodecylammonium acetate or a combination of dodecyl-ammonium acetate and sodium oleate as collectors.

Jan 1, 1998

By H. L. Owens, J. W. Fredland, K. K. Wu

The Mine Safety and Health Administration (MSHA) is responsible for reviewing and approving the engineering plans for impoundments, of significant size or hazard potential, that are constructed on coal-mine property. Over the years, technical review criteria have been updated as the state-of-the-practice for dam safety has evolved. The evaluation of stability under earthquake loading, for example, has gotten much more sophisticated for impoundments built using upstream construction. Recent incidents where slurry has broken into mine workings have caused MSHA, mine operators, and design engineers to re-examine this safety issue. This paper gives an overview of MSHA’s impoundment plan review process.

Jan 1, 2003

By Ron Allum, Ed VanDerPas

The application of high speed tunneling in a deep underground copper mine is essential for an ambitious expansion project at Magma Copper Company's San Manuel Mine. At stake is the future of over 1,300 employees at the largest producing full gravity block caving copper mine in the world. A joint venture of Frontier-Kemper Constructor's Inc. and Deilmann Haniel GmbH is helping create that future through the successful application of tunnel boring technology. This paper examines the details required to assemble, deploy and operate a 4.62 m open main beam tunnel boring machine (TBM) in a 1048 m deep operating mine accessible only by shaft.

Jan 1, 1995