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By James E. Monsees, Wayne A. Carbiener, Michael R. Wigley

This paper illustrates an approach to quantitatively document the degree of technical conservatism to be incorporated into the design of a waste isolation system in bedded salt. It is anticipated that for an actual repository site the key performance constraints and/or design bases identified in this paper will be reviewed, and modified or supplemented as required. Ultimate acceptance of a repository will be dependent upon scientific peer input and scrutiny of the demonstrated conservatism inherent in each specific repository site and design.

Jan 1, 1981

By Z. B. Yin, R. W. Bartlett, P. R. Taylor

Tube furnace experiments have been performed to evaluate the lime roasting of pyrite in air. The sulfur volatilized was measured over time. Variables studied included: form of lime, sodium sulfate additions, temperature, air flow rate, lime to pyrite weight ratio and pyrite particle size. It was found that more than 98% of the sulfur can be retained at a reactor temperature of 650°C, with a slight excess of calcium hydroxide. The roast products are primarily hematite and calcium sulfate.

Jan 1, 1990

By M. Dale Slade, Gordon S. Bird, Robert S. Kelly

Gallium scrap is obtained from many different sources, therefore each lot received has to be evaluated and then processed accordingly. Some of the problem areas are separating small amounts of gallium from large concentrations of iron, eliminating trace amounts of gold, silver, copper, germanium, tin, and zinc from gallium, and having the flexibility to process each lot of scrap individually Following gallium from the raw scrap material to the final seven nines pure product requires stringent quality control and excellent analytical capabilities.

Jan 1, 1983

By M. S. Vernon, J. J. Kellar, W. M. Cross, R. M. Winter, F. J. Johnson, A. G. Pommer

Three substrates (MgO crystal, CaF2 crystal and Mg plate) were used to construct thin layers of Mg(OH)2. Various routes were used to modify these substrates, including surface hydration and sol-gel coating. In each case, it was found (by using Fourier transform infrared spectroscopy) that thin layers of Mg(OH)2 could be produced. In the case of hydrated layers, the surface morphology of the Mg(OH)2 resembles the bulk platelet shape of precipitated Mg(OH)2.

Jan 1, 2000

By Stavros A. Argyropoulos

The strides that have been made in recent years in applying Artificial Intelligence to pyrometallurgy, are reviewed. The computer reproduction of the way in which a human being reasons and calls on past experience and stored knowledge when faced with problem will be extremely helpful in pyrometallurgy. It is expected that Artificial Intelligence will be applied in all areas of human endeavor. Areas of pyrometallurgy that are most promising for expansion into A1 in the near future are presented.

Jan 1, 1990

By Cheng Zhengbing, Sun Baoqi

This paper summarizes several chemical purification methods used for producing high-pure industrial minerals These methods, mainly including alkali melting, acid leaching, oxidation-reduction bleaching, are respectively used to eliminate the impurities such as silicates in graphite and diamond, ferric oxides in quartz sand or other valuable silicate minerals, colouring impurities in kaoline, barite and other minerals which are required to have a high-whiteness. The fundamentals of the chemical purification methods and some practical examples in China are introduced in the paper.

Jan 1, 1995

By James R. Fahy, Lawrence A. Hansen, J. David Deatherage

A laboratory testing program was con- ducted to investigate the shear strength along specific soil-liner interfaces for five types of liners of varying thicknesses. Results indicated a bilinear relationship between shear stress and applied normal stresses ranging from 276 to 1000 pKa (40 to 145 psi). Friction angles along the soil- liner interface below the break point normal stress (7.5 to 19 degrees) were lower than those recorded above the break point normal stress (14.5 to 39 degrees ).

Jan 1, 1987

By P. Sanchez-Mejorada

Quimica del Rey, SA, a subsidiary of Industrias Peñoles, SA de CV, produces sodium sulfate from brines extracted from a playa of Laguna del Rey, located in the State of Coahuila in northern Mexico. The spent brine is used as raw material for the production of magnesium oxide. The brine, which contains ions of sodium, magnesium, sulfate, and chlorine, occurs filling intercrystalline voids of a lenticular evaporite deposit whose main constituents are glauberite (sodium-calcium sulfate) and blöedite (sodium-magnesium sulfate).

Jan 1, 1987

Aqueous pressure oxidation at low temperature, although desirable from a process engineering and operating point of view, presents unique problems when temperatures approach 160°C (320°F). In developing the pressure oxidation process for the Lone Tree Mine, elemental sulfur formation and agglomeration with pyrite proved to be a problem. This paper discusses some of the unique features of the Lone Tree sulfide deposit and its amenability to low-temperature oxidation. Problems encountered during pilot plant operation and their solutions are discussed.

Jan 1, 1995

By Mark W. Springett

The sampling of precious metal deposits entails inherent problems due to the low mineral abundances, high mineral specific gravities, skewed grade distributions and wide ranges of mineral particle sizes. Sampling practices and precautions are discussed with particular attention to each of the tripartite stages of sampling - sample acquisition, sample preparation and sample assaying. Practical examples of approaches to the sampling problem are given and some examples of significant sources of error are provided from gold and silver deposits in North America.

Jan 1, 1992

By J. Yordan, J. Zinterer

Effective removal of ink particles by froth flotation is of up-most importance in paper recycling. In this study, the potential use of talc particles as carriers of difficult-to-float fine ink particles is investigated. In order to accomplish ink particles removal, the interactions between talc and oily- ink particles in aqueous solutions containing flotation chemicals was studied by zeta potential distribution measurements and with the impinging jet apparatus. The chemical conditions under which talc-ink adhesion occurs are identified and reported.

Jan 1, 2003

By Daniel P. Coughlin, Robert C. Thomas, Christopher S. Romanek, Kristian W. Paul

Two separate constructed treatment wetland (CTW) systems receiving the same metal contaminated, acid sulfate water over different lengths of time and at different rates were evaluated for metal attenuation. Both wetlands are the alkalinity generator portion of a succesive alkalinity producing system (SAPS). Sequential extractions are employed to determine phases of metal removal. Results indicate that Fe, Al, Zn, Ni. and Cu accumulate in the organic substrate over time. Manganese accumulates initially, but is not retained in the system over time.

Jan 1, 2000

By Tim Wolf

The author has seen an increased use of shaft-mounted, right angle drive assemblies. These designs use the pulley shaft as its 'foundation" and can create significant overhung loads. To reliably perform, the pulley and shaft must be designed for these special requirements. This paper will focus on the development of overhung loads and their design effects. Special considerations to maximize performance will be presented and comparisons with other drive options will be made. Experience in heavy mining applications will be used throughout.

Jan 1, 2000

By Rudrajit Mitra, Wesley B. Johnson, Erik C. Westman

The ability to understand stress redistribution within a mine allows greater extraction efficiency with reduced safety concerns. Stress redistribution has been examined at the laboratory scale using ultrasonic tomography and numerical modeling using PFC3D. A data acquisition system was built to obtain tomograms as samples are loaded in uniaxial compression. Limestone samples were loaded to failure. Three-dimensional tomograms of the samples correlate to various stress distributions. The tomograms are compared to analytical and PFC3D results.

Jan 1, 2005

By M. R. Shahan, W. R. Reed, S. Klima, T. W. Beck, Y. Zheng

Testing was conducted to determine the ability of foam to maintain roof coverage in a simulated longwall mining environment. Approximately 27 percent of respirable coal mine dust can be attributed to longwall shield movement, and developing controls for this dust source has been difficult. The application of foam is a possible dust control method for this source. Laboratory testing of two foam agents was conducted to determine the ability of the foam to adhere to a simulated longwall face roof surface. Two different foam generation methods were used: compressed air and blower air. Using a new imaging technology, image processing and analysis utilizing ImageJ software produced quantifiable results of foam roof coverage. For compressed air foam in 3.3 m/s (650 fpm) ventilation, 98 percent of agent A was intact while 95 percent of agent B was intact on the roof at three minutes after application. At 30 minutes after application, 94 percent of agent A was intact while only 20 percent of agent B remained. For blower air in 3.3 m/s (650 fpm) ventilation, the results were dependent upon nozzle type. Three different nozzles were tested. At 30 min after application, 74 to 92 percent of foam agent A remained, while 3 to 50 percent of foam agent B remained. Compressed air foam seems to remain intact for longer durations and is easier to apply than blower air foam. However, more water drained from the foam when using compressed air foam, which demonstrates that blower air foam retains more water at the roof surface. Agent A seemed to be the better performer as far as roof application is concerned. This testing demonstrates that roof application of foam is feasible and is able to withstand a typical face ventilation velocity, establishing this technique’s potential for longwall shield dust control.

Jan 1, 2017

By M. R. Shahan, W. R. Reed, S. Klima, T. W. Beck, Y. Zheng

Testing was conducted to determine the ability of foam to maintain roof coverage in a simulated longwall mining environment. Approximately 27 percent of respirable coal mine dust can be attributed to longwall shield movement, and developing controls for this dust source has been difficult. The application of foam is a possible dust control method for this source. Laboratory testing of two foam agents was conducted to determine the ability of the foam to adhere to a simulated longwall face roof surface. Two different foam generation methods were used: compressed air and blower air. Using a new imaging technology, image processing and analysis utilizing ImageJ software produced quantifiable results of foam roof coverage. For compressed air foam in 3.3 m/s (650 fpm) ventilation, 98 percent of agent A was intact while 95 percent of agent B was intact on the roof at three minutes after application. At 30 minutes after application, 94 percent of agent A was intact while only 20 percent of agent B remained. For blower air in 3.3 m/s (650 fpm) ventilation, the results were dependent upon nozzle type. Three different nozzles were tested. At 30 min after application, 74 to 92 percent of foam agent A remained, while 3 to 50 percent of foam agent B remained. Compressed air foam seems to remain intact for longer durations and is easier to apply than blower air foam. However, more water drained from the foam when using compressed air foam, which demonstrates that blower air foam retains more water at the roof surface. Agent A seemed to be the better performer as far as roof application is concerned. This testing demonstrates that roof application of foam is feasible and is able to withstand a typical face ventilation velocity, establishing this technique’s potential for longwall shield dust control.

Jan 1, 2018

By R. Feenstra

In the course of time, an increasing number of investigations on jet cutting all kinds of material, such as rocks1, 2, 3, metals4, 5, and wood6 have been reported to serve various applications. This paper deals with one particular application of jets, viz deep-well drilling for hydrocarbon exploration and production. A number of papers have been published on this subject 7, 8, 9, some of which refer to jets purposely containing abrasives, termed 'jetted particle drilling'7. Since such abrasives complicate fluid handling considerably and do not appear to be absolutely necessary for making hole we have restricted ourselves to conventional drilling fluids. A large part of our investigation has been performed with the aid of three laboratory-type drilling machines, which permit tests on both micro-bits (12 in) and full-scale bits (62 - 9 5/8 in). In view of the application of jets in deep wells, care has been taken to simulate hydrostatic pressures as they exist in the field on the hole bottom. These have been found to have a major effect on the bit-penetration rate for various drilling fluids. Following experiments with single nozzles, laboratory bits have been designed, improved further and developed for field use. Field runs on 9 5/8 in bits, using conventional equipment and pumps, served to verify the feasibility of the jet drilling concept. Further efforts are evidently needed to evaluate the jet drilling method. It is encouraging that one of these10, a field test programme, is supported by a number of oil companies jointly. Such a combined effort is of paramount importance to evaluate and develop this new method of drilling to its full potential in a reasonable period of time. This paper aims to contribute to that ultimate goal.

Jan 1, 1974

By S. K. Kawatra, J. A. Halt

"Low-grade iron ores are finely ground and processed to recover iron-bearing minerals. However, the iron-rich powder is too fine to be used directly in blast furnaces and most direct reduction furnaces, and must be agglomerated or pelletized into a usable product called “pellets.” Bentonite clay has traditionally been used as a binder to make iron ore concentrate pellets, but it is expensive and contaminates the pellets. Organic binders may be a viable alternative to bentonite clay. This manuscript reviews organic materials that have been used to make iron ore concentrate pellets. Included are discussions on the development of organic binders, common pros and cons to organic binder use, organic binder structure and its effects on agglomeration, and additives to organic binders.IntroductionIron ore agglomeration turns finely disseminated, low-grade iron ores into a usable product, called pellets. During pellet production, fine-grained, iron-rich minerals are liberated from low-grade ores, concentrated, and agglomerated into round balls that are thermally hardened or cold-bonded to form pellets. Pellets are then transported to blast furnaces or direct reduction operations where they are used to produce iron; iron is further refined and shaped into the wide variety of steel-based industrial and consumer products in use today.Over the years, pellet production has become increasingly more prevalent with the increased exploitation of low-grade iron ores and increased iron and steel consumption around the world. In 2010, world iron ore pellet production was 388 Mt. It could be argued that the current pellet production process has been enabled by the use of binders – practical experience has shown that it would be nearly impossible to agglomerate iron ore concentrates using rotary drums and discs without using a binder."

Jan 1, 2015

By C. Bryce

Rhenium is primarily recovered as a byproduct from molybdenum roasting circuits. However, rhenium is also present in copper heap leach solutions at very low concentrations, and this represents a potential new rhenium source. Freeport-McMoRan (FCX) has developed a new process using carbon adsorption followed by ion exchange or solvent extraction to concentrate rhenium from less than 1 ppm to 15 g/L. The product is compatible as a feed to an existing rhenium processing plant. A pilot plant operated at Freeport-McMoRan?s Sierrita Mine has demonstrated the technical and financial feasibility of this new process. Copper heap leaching dissolves more than just copper from the copper ore. Several metals can be identified in leach solutions at concentrations of financial interest, rhenium in particular. Rhenium spot prices ranged from a yearly average of $1,070/kg ($483/lb) in 2005 (Magyar, 2008) to $10,400/kg ($4,706/lb) in 2008 (Polyak, 2013). The spot price in September 2013 was approximately $3,000/kg ($1,357/lb) of rhenium (Metal Bulletin, 2013). Several facilities at Freeport-McMoRan have very low rhenium concentrations in their copper leach solutions, ranging from 0.1 to 0.7 mg/L. The large quantity of solution available, if coupled with an attractive rhenium price, means that the rhenium contained in leach solutions may represent a significant value if a method of extraction could be developed. Testing has confirmed that rhenium adsorbs onto activated carbon much more selectively than other metals in the pregnant leach solution (PLS). A 100-gpm pilot plant was constructed to verify the lab-scale results on a larger basis and establish operating parameters for a full-scale operation. This report summarizes the initial technology development and pilot plant operation.

By B. M. Eiter, J. Hrica, D. R. Willmer

"Mineworkers are routinely tasked with making critically important decisions about whether or not a hazard presents an imminent danger. Researchers from the U.S. National Institute for Occupational Safety and Health collected formative data to investigate mine safety professional perspectives on workplace examinations, which revealed a potential gap in how mineworkers are assessing risk. During interviews, participants revealed not having a systematic methodology for mineworkers to use to determine if a hazard is considered imminent danger. In this paper, we identify and describe three distinct categories of imminent danger complexity and discuss potential steps that could lead to improved identification of imminent danger situations. Finally, we identify potential practices to incorporate into risk management efforts, including feedback, communication and specialized training, to increase awareness of imminent danger situations. IntroductionIn recent years, the metal and nonmetal mining sector, as categorized by the U.S. Mine Safety and Health Administration (MSHA), experienced an increase in the number of fatalities occurring at mine sites. From 2013 to 2015, 69 mineworkers were fatally injured, twice the number of fatalities in each of the previous two years (MSHA, 2015a). As a way to address this increase, MSHA issued its P15- IV-01 program policy letter, suggesting that “miners would benefit from rigorous workplace examinations conducted by experienced and trained examiners” (MSHA, 2015b). The goal of these examinations is to find hazards in the field and mitigate them before they cause injury or death to mineworkers. While it is important to identify all hazards in the workplace, it is critically important to identify those hazards that are considered imminent danger because they require an immediate response to avoid a severe or even fatal injury."

Jan 9, 2018