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By B. P. Spigarelli

To meet the growing need for CO2 capture and storage technology, Michigan Technological University is researching CO2 capture and storage using carbonate solutions. The objective of the present study was to increase the absorption rate of CO2 into the carbonate solution without reducing the absorption capacity of the solution. This approach used a polypropylene glycol methyl ether (PPGME) as a surfactant to chemically alter the gas bubble size. Experiments were conducted to study the absorption rate of CO2 at varying surfactant concentrations of 0, 0.12, 0.24, 0.36, and 0.48 g/L. Results showed that as the concentration of surfactant increased in solution, the absorption rate also increased. The CO2 absorption rate increased from 3.45 mmol/min CO2 at 0g/L PPGME to 3.92 mmol/min CO2 at 0.48 g/L PPGME. This amounted to a 14% increase in the CO2 absorption rate with no decrease in absorption capacity of the solution.

Feb 27, 2013

By Jim M. Johnson

INTRODUCTION The facility water balance and maintenance of sufficient excess storage volume in the solution control system are often amongst the most critical facets of design and operation of heap leach facilities in cold, snowy climates. The purpose of this paper is to summarize and discuss climatic and operational factors which have a significant impact on heap leach water balance evaluations in high snowfall climates. Example water balance simulations are presented for proposed heap leach projects located in areas subject to high snowfall in the northwestern United States. The climatic data input to these simulations represent both net evaporative and net precipitation climates. FACTORS AFFECTING WATER BALANCE EVALUATIONS The combined effects of seasonal operations, re1atively low evaporative losses, and potentially large inflows to the solution control system from snowpack and spring storms require an enhanced awareness of the factors which impact facility water balance. Unlike operations at mines in more arid climates, seasonal excess water rather than a shortage of make-up water is the rule. A thorough understanding of a number of factors, including regulatory constraints, climatic influences, and impact of operating philosophy and techniques, is critical to successful development of an incident-free heap leach operation under high snowfall climatic conditions. A process water circuit schematic for a typical heap leach operation is shown on Figure 1.

Jan 1, 1988

By L. A. Weakly, D. A. Weiss, R. B. Crookston

A presentation of experience gained from using mechanical and conventional equipment for excavating shafts, raises, tunnels and other openings in various Colorado oil shale mining properties.

Jan 1, 1983

By Colin J. Douch

New Zealand has been a significant producer of gold for over a century. Total recorded production is over 850 tonnes. There were three major periods of production: the first and biggest was between 1860 and 1880, the second was between 1895 and 1920 and the third was between 1930 and 1945. After 1945 gold production fell continually until 1980 when the major upward adjustment in gold price led to renewed interest. There have been important new developments in each of the known gold-rich areas: Westland, Otago and Coromandel and exploration for gold in these areas and in previously unprospected regions has reached unprecedented levels. In Westland over 140 gold processing plants are each producing between two and six ounces a day from low-grade placers. A major gold dredging operation will soon be producing over a tonne of gold annually and other new dredges are proposed. There are still vast reserves of gold-bearing gravels in Westland and prospecting is continuing to reveal new resources. In the Reefton area there is renewed interest in gold-bearing quartz reefs which were the source of over a million ounces of gold between 1900 and 1951. New large opencast reserves are now defined.

Jan 1, 1988

By K. M. Stone, N. J. G. Masson, A. C. Woollett

The Jabali zinc deposit in Yemen contains at least 9.4 Mt (10.4 million st) of ore at a grade of 10.7% zinc, 2.2% lead and 77 g/t (2.2 opst) silver. The zinc occurs as smithsonite with minor hydrozincite. The Jabali ore does not produce a zinc concentrate of sufficient grade to be acceptable to a conventional zinc smelter, and it has been necessary to formulate a less-conventional development plan. This involves the construction of a mine and concentrator at Jabali and a metal production facility using a new flowsheet designed specifically for the treatment of oxide material at Yanbu, Saudi Arabia. To give the facility the necessary economies of scale, the Jabali concentrate will be supplemented by feed from other deposits, this may be either oxide or sulfide material. The paper outlines the geology and proposed mining and treatment operations at Jabali, presents the flowsheet for Yanbu and estimates preliminary costs for both operations.

Jan 1, 2003

By R. L. Grayson

Based on the relationships between severity measure vs. productivity and other factors, this paper presents a comprehensive analysis of US underground coal mine injuries in 1996 by mine size. From the 1996 data, it was concluded that, generally, the larger the mine, the more productive it is (in tons per employee-hour) but the more severe is its injury experience (r = 0.65). However, within very large, large and medium mines, the more productive the mine, the less severe is its injury experience (r = -0.43, - 0.36 and -0.26, respectively). For small and very small mines, a deeply nested analysis would be required to understand relationships. Other interesting relationships and comparisons are presented.

Jan 1, 2002

By Stanley M. Miller

Analysis of discontinuous rock masses for engineering design purposes requires information about fracture characteristics. For such studies, fractures or other elements of the rock fabric (bedding, foliation, etc.) should be considered in a statistical manner because they generally have high frequencies of occurrence and are discontinuous over the design area. A practical design procedure includes defining structural domains as those areas which contain fractures with similar orientation patterns. Within a structural domain, the statistical distributions of fracture set characteristics (spacing, fracture density, dip, dip direction, etc.) may be computed from mapped data and then used to quantitatively describe the rock fabric. These distributions can then be randomly sampled (using Monte Carlo techniques) to simulate the rock fabric and to help define potential failure surfaces along fractures. 1 The prediction of failure geometries is an essential part of stability analyses used in designing rock slopes or underground openings. In current probabilistic design procedures, Monte Carlo techniques that rely upon the iterative generation and analysis of deterministic instability models do not incorporate spatial aspects of the random variation in fracture set characteristics, 1,2 but consider the characteristics to be spatially independent.

Jan 1, 1979

By E. Suoninen, K. Laajalehto, L. Kartio

Efficient separation of pyrite from other sulfides is of great importance for the metallurgical performance of flotation processes. In this work Fourier Transform Infrared Spectroscopy (FTIR) and X-ray Photoelectron Spectroscopy (XPS) were used to study the surface chemistry of pyrite in depression, activation and xanthate adsorption under conditions of controlled potential. Modifications of pyrite surfaces after treatment with depressants (lime, sulfur dioxide, sodium cyanide) and after activation with metal ions (Cu, Pb) were studied. The principal adsorption product identified on pyrite was dixanthogen whose formation started at about +0.15 V and +0.25 V (vs, SHE) in ethyl and amyl xanthate solutions, respectively. Copper xanthate was formed on copper(II) activated pyrite. Activation mechanism of pyrite by copper(II) salts is likely to be electrochemical where copper occurs as copper(I) on the surface of pyrite. Effective depression is achieved by sulfur dioxide and sodium cyanide. Depression at high pH is due to formation of iron(III) hydroxides. Calcium ions do not affect the electrochemistry but adsorb on pyrite and reduce the surface sites for dixanthogen adsorption.

Jan 1, 1995

By S. Tavani, R. E. Browner, R. Dunne

Lead is used in CIP/CIL circuit to increase the leaching rate of gold from ores. At least four mechanisms have been proposed for the action of lead in gold leaching circuits: (I) precipitation of sulphides as highly insoluble lead sulphides preventing consumption of cyanide and oxygen; (2) su,face reaction on sulphide particles forming an insoluble lead sulphide layer peventing dissolution of those sulphides; ( 3) precipitation of lead sulphide, which undergoes further oxidation to soluble lead sulphate recycling the lead to solution,· ( 4) contact reduction of lead onto the gold szaface which then acts as a secondary oxidising agent. Rotating disc studies using a pure gold disc show that small amounts (5ppm) of sulphide ions are sufficient to significantly reduce the leaching rate of gold. Lead increased the leaching rate at small concentrations but at higher levels decreased the rate of leaching. The detrimental effects of lead were only found for a pure solution when leaching the gold disc. Ores mediate the amount of lead available by ads01ption/reaction, thus, reduced leaching rates from excess lead are not serious even when 500ppm of lead ions are added to the sluny. The detrimental effects of sulphide ions could be countered by lead addition during the leaching process. A penalty, in the form of reduced leaching rate, will occur the longer lead addition is delayed. A time lag was noted between the addition of lead and the increased leaching rate when a large concentration of sulphide ions was present.

Jan 1, 2000

By J. F. Kvitfkovich, R. L. Bate

Coal production in the Central Appalachian region has a long history, and it remains a major US coal-producing region. The coal industry consensus is that the region is in a state of decline as evidenced by the recent lower regional output. Are Central Appalachian coal reserves adequate for the region to continue as a major supplier of low sulfur coal? To answer that question, this paper focuses on the Central Appalachian coal reserve base estimates and production trends. Central Appalachian (CAPP) reserve evaluations face the difficulty that there are no publicly available databases that provide a thorough analysis of remaining CAPP reserves. Based on best available Energy Information Administration (EIA) data, a coal reserve estimate of 17.6 billion tons is developed. This estimate appears high according to industry perception. Recent United States Geological Survey (USGS), and other state agency coal reserve estimation projects are evaluated as alternative approaches to the re-serve estimation problem. Using the conclusions from these studies, the CAPP reserve base is estimated at 7.1 billion tons. Another perspective on the CAPP reserve base is provided by reserve holdings of major CAPP operating companies reported at 5.2 billion tons. A conceptual mining cost analysis indicates substantial price increases will be necessary to offset this deterioration in the economic viability of the reserve base.

Jan 1, 2004

By Stanley R. Riggs

The rocks exposed in the phosphate district are of Neogene age and consist of clayey quartz and phosphorite sands overlying phosphatic dolomite. The Bone Valley Formation is redefined as a marine phosphorite containing primary phosphorite and abundant terrigenous sediments. It contains a Middle Miocene vertebrate and invertebrate fauna and conformably overlies the Hawthorn Formation containing similar invertebrate fauna. A new, unnamed formation, with Pliocene and Pleistocene fauna and containing reworked phosphorite, overlies the Bone Valley disconformably. Its phosphorite is derived from the subjacent Bone Valley by post-Middle Miocene erosion and deposition in stream channels and marginal marine environments. The Bone Valley contains two main types of primary marine phosphorite. Orthocbemical phosphorite, a direct precipitate of microcrystalline phosphorite (microsphorite), occurs as a cement or binder in thin beds. Allochemical phosphorite consists of clastic phosphorite particles that were originally formed as microsphorite on another part of the shelf. Microsphorite was deposited in a very shallow open marine environment which had an abnormally high phosphorous content caused by upwelling currents. The mechanism of deposition is still in doubt, but organisms probably were a major factor. Soon after deposition, microsphorite was indurated, periodically torn up, and the resulting fragments transported and deposited elsewhere on the shelf. These processes account for a great portion of the clastic phosphorite in the Miocene deposits of Florida. The primary fossil skeletal material is of minor importance.

Jan 1, 1965

By Shallesh K. Patel, Richard M. Powers, Patrick Zhang

Perceived environmental impacts from flotation reagents used in the phosphate industry have been of concern for nearly a decade. A research program was initiated to determine the distribution, fate, and consequences of flotation reagents (fatty acids, fuel oils, and amines) within the environment. Therefore, laboratory investigations of biodegradation and soil attenuation of the reagents were conducted along with field flotation mass balances and groundwater investigations in clay settling, sand tailings, and undisturbed areas. Sample analysis and a reagent mass-balance model indicated that most reagents are distributed in clay settling and sand tailings areas. Groundwater analyses showed no fatty acids or amines in any of 19 surficial or intermediate aquifer water samples. In contrast, fuel oils were detected in the surficial aquifer at all sand tailings areas in concentrations ranging between 8.5 and 0.5 mg/L. Fuel oil was also detected in trace amounts (0.6 mg/L) in one intermediate aquifer well located in an active sand tailings area. All fuel oil concentrations detected were very low and, coupled with a biodegradation rate of approximately 10% per month, all concentrations should be within reference levels in six months. Based upon the results of this study, use of flotation reagents in the beneficiation process of the Florida phosphate industry present no long-term threat to the environment.

Jan 1, 1999

By Charles C. Y. Chen, Duane R. Skidmore

Batch leaching of Ohio #1, Ohio #4A and Ohio #5 coals was conducted with the thermophilic. sulfur, oxidizing microorganism: Sulfolobus acidocaldarius. Four different size fractions of each coal, with median sizes of 508, 200, 90, and 49 microns, were subjected for 10 days to leaching in a 5% coal-water slurry at 72°C and a pH of 2. Release rates and extent of sulfate and iron I1 and I11 ions from the coals during the leaching process and distribution of sulfur forms (sulfate, pyritic and organic) in the coal samples before and after treatment were determined. Data indicated that Ohio #1 coal, with an initial sulfur content of 0.6%, showed no significant changes with leaching in total sulfur content or forms of sulfur. The Ohio #4A coal, with initial total sulfur content near 5%, yielded product, for sizes below 200 microns with 90% reduction of pyritic sulfur while the extent of organic sulfur removal varied with coal particle size. Results similar to those for Ohio #4A were observed on the Ohio #5 coal, which had an initial total sulfur content of 3% and a final sulfur content near 1%. The findings were interpreted in terms of basic biological, chemical and physical mechanisms.

Jan 1, 1989

By Bruce B. Hanshaw

The Tertiary carbonate aquifer of central Florida is composed of about 2/3 calcite and 1/3 dolomite with minor amounts of quartz and apatite. The Mg content of the calcite is lower in the recharge areas than in the deeper confined parts of the aquifer system. Various geochemical lines of evidence indicate that much of the dolomite is of penecontemporaneous origin but that some may have been formed much later, possibly by ground water. Theoretical studies indicate that the Mg/Ca ratio in solutions is about unity for the three-phase equilibrium, calcite-dolomite-water. Solutions, such as ocean water and some subsurface brines, have Mg/Ca ratios higher than one and should represent dolomitizing solutions. In the areas of principal recharge to the Floridan aquifer, ground water is undersaturated with respect to both calcite and dolomite, and the Mg/Ca ratiois as low as 0.05. As the water moves downgradient, the Mg/Ca ratio systematically increases and approaches unity; saturation of the solution with respect to both calcite and dolomite also increases with length of travel in the system. Thus, in the zone of active potable-water circulation, the chemical process is one of dissolution of minerals until saturation is reached or exceeded. However, in the deeper brackish-water zones that underlie peninsular Florida, dolomite may be forming where the Mg/Ca ratio is greater than one. The necessary Mg may be derived from ocean water or brines recycled through the system as the hydrologic regimen is changed. The driving force may be simple mixing, relative fluctuations of sea level, or a combination of mechanisms.

Jan 1, 1972

By R. Matikainen

Since the Brundtland Commission in 1987, the use of natural resources has been an issue of global concern. Minerals are among the most important Earth resources and will definitely be essential for the development of societies also in future. Increasing scientific effort is needed not only to discover new deposits, but also to promote resource management in ecologically and socially sound way. Sustainable resource management is essentially a multidisciplinary challenge of developing life-cycle analysis and recycling of non-renewable resources from local to global scale. It offers great opportunities for geological surveys not only in EU, but all over the world to contribute positively to the welfare and sustainability of societies.

Jan 1, 2003

By F. Soumis

This paper describes an integrated procedure for the very short term production planning of an open pit and the execution of this plan: the truck dispatching. Integration of plan and dispatch means that the plan is realistic so that its objectives can be realized by the dispatch. This realism is obtained by supplying the plan optimization, which involves mixed integer programming, linear programming and non-linear programming, with experimental O.R. models of waiting and blending. The arrangement of these models in the computer programm has made it possible to obtain very short computing time for the planning in spite of the width of the optimisation. The dispatching of a truck is made by solving a classical assignment problem for each dispatch over a horizon of the expected*next 10-15 trucks to request dispatches. This deep-reaching dispatch procedure uses the continuously arriving information about trucks' positions and shovels situations and models by probability functions the expected waiting time of shovels and trucks. In this manner trucks and shovels are synchronized and last moments' opportunities for productivity gains can be obtained. The dispatch procedure takes .5 second on PDP11. This integrated planning and dispatch procedure gives high productivity while ensuring good blending. Results from the Mount Wright mine of the Quebec-Cartier Mining Co., where the integrated procedure has been installed on the existing computer equipment PDP11, are included.

Jan 1, 1989

By K. Chandrasekaran

Carbon-in-leach (CIL) is conventionally used in gold processing operations when preg robbing components are present in the ore. The CIL process is becoming attractive even in other situations when preg robbing is not a factor. This article discusses the situations in which the CIL circuit can be applied. The results of leach-carbon-in-pulp (CIP) and CIL circuits at Newmont Gold's Mill No. 2, No. 4 and No. 5 are presented for comparison: Mill No. 4 was initially designed for a throughput of 4.1 kt/d (4500 stpd). It is presently operating at an average throughput of 6.6 kt/d (7300 stpd) without significant changes to the original design. The design considerations of the Mill No. 4 CIL circuit are discussed. The design of any processing facility represents a series of decisions. The final design options should ultimately be resolved based on economic as well as technical considerations. Every design decision represents some sort of compromise. From the designer's view point, these decisions are made with the conviction that the final product represents the most prudent long-term expenditure. The design throughput rate is a decision reflecting a maximum return for the capital and operating costs that the plant will incur over the life of the mineral resource. The result is a plant that is not operator proof or maintenance free because it would be too costly to build. At some point, the incremental increase in the level of capital expenditure would not adequately compensate for the lower

Jan 1, 1991

By Gu Guohua, Hu Yuehua, Zhang Qin

The flotation behavior of pyrrhotite was investigated by using ethyl xanthate as a collector. Results showed that pyrrhotite had good floatability from pH 2 to pH 11, and poor floatability when pH was >12. The flotation of pyrrhotite was dependent on pulp potential on various pH values. The potential-pH range for pyrrhotite flotation was established. Cyclic voltammeny and FTIR spectroscopic analysis showed that the major adsorption product of ethyl xanthate on pyrrhotite was dixanthogen. The intensity of FTIR signals of dixanthogen adsorption on pyrrhotite and the anode current of a pyrrhotite electrode and flotation response of pyrrhotite are correlated with pulp potentials.

Jan 1, 2005

By S. Mathur, Pradip

Polyacrylic acid (PAA) was evaluated as a selective flocculant for the dolomite-apatite system. PAA with a molecular weight (MW) of 4 million was found to flocculate both dolomite and apatite. However, the flocculation behaviors of dolomite and apatite were significantly different with 450,000 MW PAA, which was found to be the lowest molecular weight fraction capable of flocculation. In single-mineral tests with a dosage of 2 kg/t PAA, 90% of the dolomite and 35% of the apatite flocculated. Selectivity was achieved in mixed mineral tests. From a feed consisting of an 80:20 mixture of apatite and dolomite, respectively, a concentrate containing 90% apatite was obtained with a 70% recovery. The dolomite rejection was about 75%, which corresponds to a 2% MgO content in the concentrate.

Jan 1, 1997

By Michael Chender

Introduction Clearly, many problems confront the minerals industry today. Yet, at the same time, there is too much energy spent bemoaning the negative effects of difficult economic circumstances, low metals prices, and adverse government policies. These are factors that cannot be altered by individual mineral company reactions. In fact, as we look to the future, the only thing we can be certain of is that we will continue to be faced with uncertainty. Thus, an area that demands close scrutiny and that can significantly affect a company's performance in the future is the posture it adopts to deal with uncertainty. This paper looks at how strategies are developing to deal with this issue. It also examines some of the implications that implementing such strategies have for the role of the individual explorationist. Elements of strategy Whether mineral company strategies are based on diversifying or retrenching, on emphasizing primary production or downstream integration, there seems to be increasing agreement that in the current environment strategies must have several features. They need to be information-based - developed out of access to timely and complete data and analysis about proposed directions and competitor activity, rather than simply following a current fashion. They need to be flexible - adaptable in light of changes in the marketplace and an unpredictable industry. And they need to be cost-efficient - making the most of limited resources. Whether a company is looking for gold financing opportunities, acquiring polymetallic prospects, or doing grassroots exploration for diamonds, these three elements are increasingly essential. They not only allow the company to pursue its current goals most expeditiously, but also open it to hearing and using feedback in the most constructive way. The company can then improve or change strategy as it proceeds. And it can be best positioned to take advantage of opportunities as they arise. These elements of strategy place great emphasis on the skills of the individual. The need for critical intelligence and the reduced amount of capital available to manage are making it more obvious that exploration is a "people" business. This is in accordance with a general trend in many sectors of industrialized economies, reflecting the widely discussed shift from smokestack to information-based industries. Increasing the odds There is a direct connection between successfully implementing the approaches to strategy discussed above and encouraging and improving the quality of work of the individual explorationist. To illustrate the importance of this, some commonly quoted figures on the odds of discovery success can be used. These figures are arbitrary but illustrative. Assume that one out of 100 exploration prospects actually turns out to be a promising ore body, and that one out of 1000 becomes a mine. Based on our research, chances are the most of those

Jan 1, 1986