Search Documents

By Brajendra Mishra, Himanshu Tanvar

Niobium and tantalum extraction industries heavily depend on fluoride chemistry for metal oxide production. This study concentrates on developing a fluoride-free approach utilizing alkali treatment for selective dissolution of niobium and tantalum phases. The application of microwave heating in the alkali treatment of columbite significantly reduced the processing time, providing a higher reaction rate and recovery than conventional heating. A short duration of microwave exposure (6 min) elevated the sample temperature to more than 900 °C, resulting in the rapid formation of water-soluble niobium and tantalum complex. Metal recovery from the solution was attempted through direct precipitation using guanidine carbonate as the precipitating agent, resulting in a mixed oxide product with > 90% purity. On the other hand, solvent extraction was also attempted using methyltrioctylammonium chloride as an extractant, providing a niobium oxide and tantalum-rich mixed oxide with > 98% purity as the final product.

Mar 23, 2024

By Robert M. Dreyer

The first time that a geologist is confronted with the necessity of evaluating a lateritic ore deposit, he may feel that nothing could be easier. Why should there be any problems in making an economic evaluation of a relatively flat-lying, surficial ore body? After several hundred thousand dollars worth of frustrating work often culminating in a series of non-reproducible data - the evaluator may be a sadder and wiser man. This paper will try to illustrate why the evaluation of lateritic bauxite and nickel deposits is among the most difficult problems confronting an economic geologist - and, more especially, how this problem can be solved. Volumes have been published on descriptive and genetic studies of lateritic ores. Obviously, there is time today only for the briefest description of such an ore body. The laterite is a soil formed under tropical conditions and resulting in the concentration, within the soil zone, of certain tri-valent metals.- especially, aluminum and nickel. The soil zone is divided into two parts: (a) the true soil or lateritic zone and (b) the zone of, partially altered bed rock or saprolite. It is important to remember that, whereas bauxite generally is confined to the laterite zone, nickel deposits occur in both the laterite and

Jan 1, 1977

By James J. Scott

Friction Rock Stabilizers, trade name II Sp 1 it Sets'" have been under research and development by the author and the Ingersoll-Rand Company since February of 1973. The United States Bureau of Mines and the Mines Enforcement and Safety Administration as well as many mining companies have cooperated in field testing the device. Split Set rock anchors are distinctively different from the widely used mechanical rock anchors or fully grouted rock anchors. They control ground movement internally in a manner that allows controlled deformation during the early phase of the ground reaction curve but then, as secondary creep develops, anchorage per unit length increases and they serve to strengthen and stabilize the opening for long periods of time. The history of research and development of the Scott Split Set rock anchor system with accompanying laboratory and field test data is presented in this paper.

Jan 1, 1977

By Ayman A. El‑Midany, Hassan E. El‑Shall, Kerri‑Ann A. Hue

Modification of clays is necessary for the zearalenone (ZEN), as long-chain mycotoxins, removal. The organic-cations were usually used to modify the clay hydrophobicity to accommodate the large mycotoxin molecules. In this study, tri capryl methylammonium (TCMA) chloride and common corn oil were used in clay modification. Several characterization techniques such as XRD, FTIR, and TGA were used to identify the d-spacing changes after modification either by TCMA or corn oil. The results of applying the TCMA-corn oil-modified clays in ZEN removal indicated a noticeable improvement where more than 90% of ZEN could be removed in vitro at acidic and neutral pH values. The success of eliminating a high percentage of ZEN molecules is due to the expansion of intergallery spacing as a result of TCMA surfactant intercalation within the clayforming layers. The removal percentage does not depend only on pH but also on the amount of clay used. In addition, the ZEN removal in the presence of corn oil is better at acidic pH and small clay amount where the ZEN can be fully removed.

Sep 27, 2021

By R. D. Cook, J. L. Johnson

"Measuring mud bed level in a sedimentation device is an important control variable. Methods used to date for this purpose have had limited success providing continuous, consistent measurements at a reasonable price. This paper describes a new instrument for detecting the mud bed / liquor interface as well as bed density profiles. The state of the bed is measured directly with sensors located in the thickener. Data from bench-scale and full-scale tests show that the bed level is well defined and easily detected. In addition, full-scale testing revealed unprecedented information about thickener beds. Variation in bed density gave new insight into thickener bed dynamics, providing design and control opportunities never before possible. This novel instrument can significantly improve thickener control by providing reliable and consistent bed level measurements. It is also capable of measuring bed density profiles that can potentially identify significant operating problems early enough to take corrective action before experiencing costly shut downs. INTRODUCTION Numerous studies and papers have been devoted to the subject of thickener design and operation to achieve specified throughput and discharge densities. Mathematical models have been developed that present methods for sizing thickeners and predicting performance under varying process conditions. The compression effect of deeper beds on dewatering performance is a recognized phenomenon (Wilhelm and Naide 1981). This is one variable of many that are inter-related and influence thickener performance. For example in the steady-state, continuous operation of a thickener, if the solids feed rate increases and the bed level remains the same, the underflow discharge rate must increase with the result of solids concentration being lower. The interactions of these parameters are at the heart of thickener models. One such model (Burger and Narvaez 2007), predicts solids concentration profiles increasing downward and discontinuities between settling zones. This model uses sediment height (bed level) as a parameter that influences capacity calculations to achieve the specified solids concentration of the underflow. Knowing the bed depth is critical to maintaining stable thickener operation. Implicit in these modeling strategies are some basic assumptions such as homogeneous distribution of solids in the different settling zones, plug flow of solids through the settling zones and steady state operation of the thickener. The accuracy of these assumptions has not been verified because there has been little visibility inside the bed of full size operating thickeners. Testing of the instrument presented in this paper demonstrates that it provides a degree of visibility of the dynamics in a thickener not previously possible and indicates that the basic assumptions of the modeling strategies may not be completely accurate."

Jan 1, 2015

By M. R. Peterson, C. R. Ferguson, T. H. Jeffers

The ability of microorganisms such as yeast, bacteria, and various aquatic flora to sorb metals from dilute aqueous solutions is well documented. Although microorganisms have significant potential in decontaminating waste waters, techniques and equipment suitable for bioassisted decontamination are limited. The Bureau of Mines has investigated the use of microorganisms immobilized in porous polysulfone beads for extracting toxic and heavy metals from dilute waste streams. The minus 8- plus 12-mesh beads were fabricated from high-density poly- sulfone dissolved in dimethylformamide (DMF). Dried, thermally killed yeast, algae, duckweed, xanthan gum, and alginates were blended into the polysulfone-DMF, and spherical beads were formed by injecting the mixture into water. Microscopic analysis revealed microorganisms immobilized within the bead pores. The beads had excellent handling characteristics and were tested in stirred reactors, fixed bed columns, and fluidized bed columns for their ability to remove metal contaminants from several waste waters. The effluents resulting from these waste waters met or exceeded the National Drinking Water Standards for cadmium, copper, manganese, and zinc. Other heavy metal contaminants readily sorbed by the beads included arsenic and mercury. Elution of metal values from the beads was accomplished using dilute nitric acid or sodium carbonate.

Jan 1, 1989

By W. D. Hausel

The Wyoming craton in the western United States is a favorable terrane for diamond deposits. The craton hosts a variety of ultramafic, ultrabasic, and ultrapotassic rocks. Additionally, a few hundred 'kimberlitic' heavy mineral anomalies and some geophysical and remote sensing anomalies indicate the presence of undiscovered, mantle-derived, pipes in the craton. The Wyoming craton is separated into a Wyoming 'archon' known as the Wyoming Province, and the Colorado 'proton' known as the Colorado Province. The 'archon' underlies much of Montana and Wyoming and continues north into Alberta and Saskatchewan; the Colorado 'proton' underlies much of Colorado and a small portion of Wyoming. Although most exploration geologists would consider the 'archon' the most favorable terrane for commercial diamond deposits, the 'proton' has produced more than 120,000 diamonds, while the 'archon' has not been very productive.

Jan 1, 1996

By William Gleason

"What will the mine of the future look like? Will it resemble the current operations that supply the world with the products it needs to function, or will it be something totally different? How will the demands from the communities that are most affected by mining operations shape the mine of the future? How will technology and innovation be used to help miners reach deposits that are getting harder to access, and what are the dangers of this new world? Who will work at the mine of the future, and what will that work look like?These are questions that do not yet have definitive answers, but they are questions that need to be asked for the mining industry to move into a future that is as filled with uncertainty and challenge as it is with promise and opportunity.On Feb. 16, the 2015 SME Annual Conference and Expo and the 117th CMA National Western Mining Association conference began with a keynote address, "The mine of the future: Forecasting opportunities and challenges for the global mining industry." Panelists from five sectors of the mining industry participated in the session, which was followed by the conference and expo, that in large part, were also trying to answer the question of what the mine of the future will look like.In coming months, Mining Engineering will continue the discussions and answer some of the questions submitted by members of the 2,000-person audience during the keynote address in a monthly feature called, "Predicting the Mine of the Future," and in Thought Leaders Podcasts with the panelists and other industry experts."

Jan 1, 2014

By David S. Smith

Almost nine years after the assertion of enormous and pervasive federal control over coal mines by means of the Federal Coal Mine Safety and Health Act of 1969, 30 USC Section 801 et seq, as amended by the Federal Mine Safety and Health Act of 1977 (which basically increases the punitive powers of government) a brief assessment of some of the underlying causes, present status, and possible alternatives to governmental control is appropriate. In a governmental system based upon the principles of democracy and the protection of individual freedoms and constitutional rights the ultimate mechanism for abrogation of these rights is the creation and exploitation of fear. Machiavelli in rendering advice concerning the power over men provided by fear stated, "... it is much safer to be feared than loved .. fear preserves (the government) by a dread of punishment which never fails." The Prince. Within the context of the assumption of control by the government over industries or segments of our population - popular fear provides a convenient and almost necessary mechanism for the avoidance by law or regulation of democratic principles. The popular fear of coal mines has been successfully exploited by various goal oriented groups in the past and most recently by a Congressional constituency with a vested interest in controlling the mines through regulation.

Jan 1, 1979

By U. Paschedag

Today's modern longwalls have to produce high outputs with maximum availability and running time with the additional requirement of ever increasing panel width and length high-performance face conveyors require intelligent solutions for the integration of drive systems and chain tensioning devices into the overall longwall automation. The fully automated chain tensioning system allows the operation of an AFC with optimum chain tension at all times regardless of actual load on the conveyor. For the heavy-load start-up, the accurate load-sharing and an efficient overload protection of modern AFC's WESTFALIA and Dodge jointly developed the integrated WB/CST drive system.

Jan 1, 1995

By Hugh R. Rhys

The question of the desirability of recovering cullet from MSW in order to recycle it into the manufacturing of glass containers remains a controversial one. The main factors appear to be: 1. The position of the Glass Container Manufacturers Institute (GCMI), as the trade association for most container manufacturers, is that post-consumer cullet is a vital source of raw material. Present requirements are for: a) Flint cullet b) Non-flint cullet of known mix proportions c) Mixed unsorted cullet of known mix propertions c) Mixed or non-flint cullet of unknown mix proportions. A market balance for these products exists, and this might somewhat limit the outlets for (b), (c) and (d), or severely limit the outlet for (d) alone. 2. The color specifications are rather strict. With cullet admixtures of 20% of the melt or more, and the use of decolorisers in a flint furnace discouraged because their action is reducing in a process which requires an oxidising environment, color contamination in a flint furnace is serious.. For amber and green furnaces (reducing) it is less serious, but in order that the quantity of decolorisers may be controlled, the color balance (as a measure of the Fe and Cr content) of the admixtured cullet should be known. 3. Why not simply color analyze, either by a continuous on-stream or off-stream: photo-electronic analysis, or by systematic batch sampling (with some kind off electronic surveillance of the mainstream) and just send mixed, color measured cullet to only amber and green furnaces? The flint would-be simply included in the mix. This is probably technically feasible, but is subject to the market limitations noted in point1.

Jan 1, 1975

By İbrahim Çınar, Hakan Özşen

Mine workers in heavy and dangerous work are under several physical risk factors, for example temperature, humidity, noise, vibration, lighting and air velocity. Thermal comfort includes parameters such as air temperature, air humidity, air flow rate, radiant heat, metabolic rate and garment insulation. In this study, thermal comfort conditions were evaluated using thermal comfort indices defined as predicted mean vote (PMV) and predicted percentage dissatisfied (PPD) which were determined by measurements taken from an underground coal mine for approximately 100 days. Although the metabolic rate (light work) was kept at 2 met, it was found that predicted mean vote ranged between − 2.58 and 1.68. The predicted percentage dissatisfied index was found to reach 95%. According to the results, it can be seen that thermal comfort may have negative effects on occupational health and safety. The change in thermal comfort index values in the Soma Underground Coal Mine was investigated in detail and the reasons for the changes were determined. Furthermore, determining the optimal working environment for the mine workers was also an aim of this study.

By T. B. Jarboe

The 150 MWe circulating fluidized bed (CFB) power plant described in this paper is the product of recent Bechtel experience in the industrial power and steam market, where the economic feasibility of fluidized bed projects has been proven. The inherent ability of CFB boilers to burn low grade fuels makes it possible to also burn low ranking coals or coal wastes, including anthracite culm, coal mine rejects, and coal wash plant waste slurry. The impact of fuel characteristics on plant design is addressed. This includes solids handling, steam generation, sulfur capture, and auxiliary load requirements.

Jan 1, 1988

By Hendri Silaen, Charles Leatemia, Monang Napitupulu, John Kamarea, Arwin Edijanto, Riza Hasan, Avesiena Primadiansyah

The Deep Mill Level Zone (DMLZ) is the fourth panel cave mine in the East Ertsberg Skarn System, (EESS) which lies 500 m below the producing Deep Ore Zone (DOZ) mine and up to 1,700 m below the surface. The interaction between the DMLZ and DOZ is occurring as the DMLZ cave grows vertically toward the DOZ footprint. During this process, a rapid change in the global mine system stress is anticipated. This change is forecasted to drive substantial changes in the magnitude and direction of principal stresses in the DMLZ and DOZ mines at PT Freeport Indonesia. These changes will bring the mine system closer to the ultimate capacity of the excavations and can result in significant impacts to mine stability if not managed. Critical to this management, is understanding cave growth and locations, as well as how these changes will impact stress conditions.

Apr 26, 2022

By J. T. Carlson

Dolomite [CaMg(CO3)2] is an intolerable impurity in phosphate ores, due to its MgO content. The need to develop a cost-effective method for the removal of dolomite from high-MgO phosphate ores becomes increasingly important as high-grade reserves become depleted. The jigging process has been investigated as a method for the beneficiation of phosphate ores. A laboratory-scale jig was constructed and tested using a semicontinuous, ?through-the-screen? jigging process. Two types of sedimentary phosphate ore were used; a sample from Plant 1 in the 4.00 x 0.85-mm size range, containing 1.55% MgO, and a sample from Plant 2 in the 3.40 x 0.85-mm size range, containing 3.07% MgO. These were tested, using previously optimized jigging parameters, at high and low feed rates. For the Plant 1 phosphate ore, a phosphate concentrate that contained 0.89% MgO was achieved with a bone phosphate of lime (BPL) recovery of 32.0%. For the Plant 2 phosphate ore, a phosphate concentrate that contained 1.38% MgO was achieved, with a BPL recovery of 74.7%. Minimum achievable MgO grades were also determined by analyzing hand-separated phosphate samples.

Feb 1, 2012

By S. C. Schmelter

The destabilizing effect of water pressure on rock mass stability is examined quantitatively by the finite element method. A coupled code that accounts for the simultaneous effects of rock mass deformation and transient fluid flow is used for this purpose. The traditional soil mechanics assumption of an incompressible fluid is shown to be untenable for the analysis of porous, fractured rock slopes. A Mandel-Cryer effect, a transitory but elevated and potentially destabilizing water pressure following a cut, was not observed.

Jan 1, 1997

By R. L. Virta

Common clay is a natural, fine-grained material composed of hydrous aluminum silicates. Shale is a laminated sedimentary rock formed by the consolidation of clay, mud and (or) silt. Government and legislative programs The U.S. Environmental Protection Agency (EPA) invited industry to nominate representatives to a review panel that will help the EPA develop rules to regulate air toxics from the production of brick and structural clay products. The EPA was required to establish a review panel because these regulations will significantly affect small businesses. The regulation of air toxics falls under the Clean Air Act.

Jan 1, 2010

By B. A. Wills

With the increasing need to mine lower grade ores, high energy-related costs in comminution are of major concern. Very fine grinding is needed to liberate the very fine mineral particles in these ores. Not only is this expensive but it leads to greater losses in 'slimes'. In the early 1970's, 50% of the tin mined in Bolivia, 30% of the phosphate mined in Florida and 20% of the world's tungsten were lost in this way (Somasundaran, 1979). Gravity concentration techniques become unacceptably inefficient for particle treatment below 25-50µm, and even flotation fails in the ultra-fine range. Two approaches can be adopted to try to overcome this problem. The first involves increasing the efficiency of existing equipment or developing new slimes treatment processes. Gravity devices such as the Bartles-Mozley concentrator have been developed for this purpose and good recovery has been reported from 100µm down to 5µm. Such machines, however, have relatively low throughputs, so that large areas of plant space are generally required. Flotation is rapidly growing in importance for the treatment of ultra-fine minerals traditionally treated by gravity concentration.

Jan 1, 1986

By Jr. Koch

Since 1882, world zinc production has increased. In contrast, United States zinc production rose until about 1915, but since then has remained nearly constant, with a slight tendency to decrease. Production from the Tri-State district, the largest early source of zinc in the United States, has gone down steadily; this decline has been balanced by a growth in the rate of other districts. These changes in United States production are due to economic, not geological, factors. Recent exploration has located large mineable ore bodies; additional deposits will undoubtedly be found in the strata-bound carbonate rock and volcanogenic environments. A statistical analysis of the exploration effort in the Middle Tennessee district indicates that new discoveries can be expected there. Thus, the United States is in an early stage of the production cycle for zinc. Of major mining districts in the United States, only the Tri-State is exhausted under current economic conditions; large zinc resources of low-grade material, which would repay mining at higher prices or improved technology, are known to exist in that district.

Jan 1, 1980

By Carson Sharp Beltch

The determination of aqueous cyanide is accomplished by either detection in the sample as collected or by removal of the cyanide of the collected sample, followed by detection. The direct determination of the cyanide content of a solution can only be used in the simplest of systems, since many interferences can result in errors. Thus the most widely used method for total cyanide determination involve the reflux distillation of the sample using heat, acid and vacuum or air flow. The basic theory underlying this analytical approach is that by reducing the pH, the quality of molecular hydrogen cyanide will be in- creased and can be removed from the solution by elevating the temperature. The hydrogen cyanide is then collected in a caustic solution and analyzed. The general approach of removing the cyanide from the sample by distillation represented a major advance in this area of analytical chemistry. It enabled the determination of cyanide in many additional types of samples. When it became apparent that the tightly bonded cyanide complexes were not being detected by this approach, many methods fox complex ion destruction were proposed. These methods usually involved low pH adjustment with oxidizing mineral acids, coupled with the catalytic decomposition of the tightly hound complexes. All off the complexes except the strongest could he broken by these methods. The catalytic reflux distillation step has been found to have some negative aspects, since many materials that can be distilled with hydrogen cyanide will interfere with the color development step and result in a false positive reading.

Jan 1, 1981