Search Documents

By C. V. Trang, V. T. Le, K. Enns, J. J. Byerley

The precipitation characteristics of copper and nickel cyanides from solutions continuing copper zinc and nickel cyano complexes are examined. Equilibrium precipitation calculations are presented as well as comparative experimental data. The practical significance of the precipitation data is discussed in the co·ntext of an initial step m an overall treatment strategy for mixed cyanide effluents.

Jan 1, 1998

By R. H. Mozley

It is not my intention in this paper to review recent developments in the mineral processing industry which might fall under the above heading, but to refer to some of the research that I have done over the past 25 years or so. To begin with then, my student days at the Camborne School of Mines, the year 1952. Equipment from the last century was still in everyday use at the local tin mines. At South Crofty Ltd a steam beam engine 100 years old was pumping mine water from 2000 feet, the motive force being conveyed from surface to the pump at the bottom of the mine by a 14 inch square pitch pine rod joined with forged iron straps, steam winders were still in use, and in the mills, stamps ground the ore, and the cassiterite was recovered by equipment with exotic names like "buddies, kievs, and round frames." And to equip us students for the brave new world, we included in our practical mineral dressing a day's test programme with a Californian stamp -- experience that I am still waiting to put to good use!

Jan 1, 1984

By R. E. Johnson, M. Schipper-Zablotskaja, B. R. Palmer, van Sandwijk A.

A procedure has been developed for the removal of zinc from acid solutions containing aluminum, silicon, calcium, magnesium, sodium, potassium and manganese ions and high concentrations of chloride ions. The first step of the procedure involves the precipitation of aluminum and silicon at pH 4.2. The second step, the removal of the zinc as zinc oxide, was studied in detail to get in- sight into the formation of oxychlorides. A diagram was developed giving the conditions at 75O C under which the formation of oxychlorides is avoided. Under optimal conditions a zinc oxide with less than 0.5 weight percent of chloride can be produced from 11 - 16 g/l chloride solutions.

Jan 1, 1993

By D. J. Bryden, J. W. Oberholzer

In response to the need for enhanced precautionary measures to safeguard mine workers in collieries from the consequences of methane ignitions in a heading, the coal mining industry has ex- pressed the desire for the development and testing of active on board suppression systems. As overseas systems cannot be used directly in the bord and pillar geometry it is necessary to adapt overseas and local technology to suit local mining conditions, as well as to test such developed systems for their compliance with the expressed needs. As the systems have to be tested in a specific roadway configuration, a facility was developed to enable the testing in South Africa. A surface test facility has been established which can be used to develop and test suppression systems on continuous miners and roadheaders. This facility consists of a tunnel wherein compliance tests can be conducted in simulated underground conditions. A number of methane explosion tests have been conducted in the test facility. The explosions conducted varied in CH,/air concentration (7,5 to 9 percent) and volume (26 to 88 m3). At lower concentrations there was a marked reduction in explosion strength and flame speed. Tests carried out with the Explostop system successfully suppressed the propagation of methane ignitions in both scenarios tested.

Jan 1, 1997

By D. E. Munson, H. J. Sutherland

Empirical methods for describing the shape of the subsidence trough over coal mines in Europe are tested against field measurements of subsidence over longwall panels in the United States. The graphical methods developed by the National Coal Board in the United Kingdom do not correlate well with the U.S. measurements; however, the profile functions typically used on the Continent give quite acceptable fits to the data. In the case of two longwall panels mined at Old Ben No. 24 in Illinois, a trigonometric profile function appears the best choice; in the case of two longwall panels mined at York Canyon in New Mexico, an error integral function is somewhat superior. Analyses of subsidence development curves show that rate effects occur. A comparison of fitting parameters establish influence functions as an important methodology for future analysis. In conjunction with the evaluation of empirical methods, an analytic model based on material failure and bulking was developed. A key element of the model is the void-volume distribution function which establishes a mechanism for transfer of significant amounts of the mined volume to the surface. Preliminary calculations demonstrate the features of the model and illustrate close correlation to physical observations in the field. Moreover, centrifuge models simulating the subsidence process have been used successfully to demonstrate the dominant or key failure modes necessary to the analytic model. General features of the centrifuge simulations and model calculations correlate well.

Jan 1, 1982

By Y. Numata

2-Mercaptobenzothiazole (MBT) is a heterocyclic-mercaptan and belongs to a group of molecules containing nitrogen and sulfur as electron donor atoms. MBT has been employed as a collector in flotation under names of MBT, Captax, and Flotagen. It is a major constituent of reagents in the 400 series of the American Cyanamid Co. Current applications of the reagent include flotation of copper minerals, tarnished or oxidized lead, copper activated sphalerite, and nickel ores. It has been used successfully in the flotation of pyrite in acid circuits in the range of 4 to 5.

Jan 1, 1990

By Leroy O. Gieseke, John B. Begley

If the particles produced and transported in your plant are as chunky as rough crushed coal or as fine as cement, there are probably several conveying and elevating systems suitable for your operation. The problem is deciding which is most suitable in terms of space, energy cost, allowable product degradation, productivity, and angle of movement. Each conveying and elevating method should be fit to the products it can handle successfully, to desirable economics, and to suitability for the overall operating scheme. Matching along these lines will result in selection guides that should be useful for many years, although design evolution is expected for the materials handling equipment involved. There are several common bulk material handling devices for moving solids: belt conveyors, screw conveyors, bucket elevators, chain conveyors, and en-masse conveyors/ elevators. En-masse conveyor/elevator equipment is commonly compared and contrasted with the other devices. These comparisons often involve en-masse versus all others. En-masse has developed into a versatile technique because the machines can move materials horizontally, vertically, or in closed circuit. Such machines unload, elevate, store, reclaim, and distribute materials-all without ancillary equipment except for chutes and gates. Bulk material can be carried, as with a belt conveyor or bucket elevator; pushed, as with a flight or screw conveyor; bumped, as with a vibrating conveyor; blown, as with a pneumatic conveyor; fluidized, as with a dense phase pneumatic conveyor; or by applying internal forces to it to induce "en-masse" flow. Conveying en-masse is analogous to the flow of a fluid in an open channel, and elevating en-masse is analogous to the flow of fluid in a pipe. In the case of a fluid, flow is caused by a differential in pressure. With en-masse movement, flow results from resistance to shear induced by the movement of chain and flights.

Jan 12, 1980

By G. A. Doyle

The quality of water in mine pit lakes depends in part on the physical limnology (Le. stratification, turnover, and development of anoxic conditions with depth) of the lake. Limnologic data collected from four existing pit lakes indicate that pit lakes develop a thermocline, or temperature stratification, in the upper 10m to 30 m of the water column. Two of the pit lakes (26 m and 55 m deep) undergo seasonal turnover of the entire water column, whereas two deeper pit lakes (110 m and 240 m) undergo seasonal turnover of only the upper portion of the water column. In the deeper lakes, seasonal mixing does not extend through the entire water column and a distinct chemocline develops with depth.

Jan 1, 1996

By P. D. Rao, D. E. Walsh

A pilot-scale study was performed to evaluate the potential for gravity concentration of gold from -13 mm (-1/2 in.) crushed ore from Ester Dome, AK. 9.04 t (9.94 st) of crushed ore were sampled and processed through a Pan-American jig-Wilfley table pilot plant. Plant products were sampled for assay and material balance calculations. Gold recovery through one stage of jigging and two stages of tabling was 17.4% at a concentration ratio of 615:1. Concentrate grade was 766.3 g/t (22.4 oz/st). The feed grade to the plant was calculated at 1.71 g/t (0.05 oz/st). Jig tailings, primary table tailings and secondary table tailings grades were 1.44 g/t (0.042 oz/st), 1.30 g/t (0.038 oz/st), and 5.47 g/t (0.16 oz/st, respectively. Significant coarse, free-milling gold values were shown to remain in the, jig tailings. Concentrate mineralogy is discussed.

Jan 1, 1992

By K. V. S. Sastry

Pelletization, sintering, and pressure compaction are the most common methods used to agglomerate ore concentrates. Over the last 20 years agglomeration has grown enormously in popularity and has become a standard unit operation in the nonferrous, cement, fertilizer, and ceramic industries. However, it is in the processing of iron ores and the preparation of blast furnace feed that agglomeration is used most and its application has grown fastest (Ball, et al., 1973; and Sastry, 1977). This chapter deals with an account of the current practices and future trends in the application of computers relative to an overview of the process design and engineering considerations of the unit operation of agglomeration.

Jan 1, 1979

By J. M. Kaufman

Recent mining regulations have increased the need for detailed engineering and environmental information pertaining to the hydrogeologic environment in mining areas. The cost of obtaining such hydrogeologic information has also increased. After mineralization of potentially economic grade ore and tonnage has been identified, and after completing preliminary mining feasibility studies (suggesting that development is merited), a second exploration phase can incorporate a simple, cost-effective baseline hydrogeologic data reconnaissance program that is linited but useful. Using exploration drill holes only, this program can provide a direct indication of where ground water is encountered. Also, reasonable estimates can be made on the relative production of water from various water-bearing strata, a composite potentiometric surface map can be prepared, and the general chemistry of the ground water can be characterized.

Jan 1, 1984

By James A. Barclay

Results of investigations over approximately the last 10 years by the Bureau of Mines and others on technology for recovering cell-grade alumina from domestic nonbauxitic resources such as clay, anorthosite, alunite, dawsonitic oil shale, coal ash, and coal shale are reviewed. It is concluded that, although many innovative techniques have evolved from this effort and have been shown to be technically feasible, energy and economic considerations will prevent any of the processes from competing with the Bayer process under normal conditions. Based on the Bureau's experience, some variation of clay-HCI leaching, HC1 gas sparging crystallization has the greatest potential as an alternative to the Bayer-bauxite process.

Jan 1, 1984

By B. Whitmoyer, J. Tian, J. E. Sneckenberger, M. A. Jerabek, C. A. Chandler

A computational procedure has been developed to determine the lung volume function for the upper airways of the human respiratory system. This analytical procedure computes a person's partial lung volume from an experimental two-microphone acoustic measurement of the upper airway passages obtained through a molded tubular mouthpiece. The theoretical transfer function for the two microphone signals as well as the related acoustic impedance and reflection coefficient for the upper airways are calculated using two-channel spectrum analysis techniques. An inverse spectrum analysis scheme then converts the reflection coefficient to an impulse response from which the airway area function is extracted using an area recovery algorithm. Numerical integration of the upper airway area function yields the lung volume function for the upper airways of the human respiratory sysytem. A software program to accomplish this computation of human upper airway volumes will be described in this paper. Application of this computational procedure to the measured tracheal acoustic impedances of 15 human subjects will illustrate the program's capability toward early detection of lung dysfunction using a prototype clinical facility.

Jan 1, 1991

By B. R. Green, Ms. M. H. Kotze

Ion-exchange fibres (IEF) were prepared by the ir­radiation grafting of styrene onto polypropylene, which was then subsequently functionalized. Strong- and weak-base exchangers were prepared and evaluated Tor their ability to extract gold cyanide selectively. The IEF prepared had loading capacities similar to those of the corresponding resins and they had good selectivities for gold cyanide when contacted with a mixed metal-cyanide solution. The expected advantage of IEF over granular exchangers, that of faster kinetics, was illustrated. The strong-base Iibre in particular seemed to be very effective for the extraction of gold cyanide from dilute solutions such as return-dam waters.

Jan 1, 1990

By I. Iwasaki

A low-grade copper-nickel deposit, with an estimated size of 4.6 billion tonnes and with average analyses of 0.6% copper, 0.2% nickel, occurs in northeastern Minnesota. In addition to copper, nickel, cobalt, and precious metals, the Duluth gabbro contains magnetite, ilmenite, olivine, plagioclase and biotite. It is estimated that the flotation tailings that would be produced by a concentrator of optimal size to sustain a smelter would amount to 20 million t per year. The flotation tailings, having already been ground, warrant a closer examination for the recovery and utilization of potential by-products. The residual sulfide minerals and fibrous minerals may also be isolated and treated separately for useful purposes or for disposal in an environmentally acceptable manner. Two flowsheets were developed; one involving preconcentration by low- and high-intensity magnetic separation and another involving preconcentration by gravity concentration. The concentration methods for recovering and purifying individual by-product minerals were investigated. From their chemical, physical and mineralogical characteristics, the potential areas of application and marketabilities of each product fraction were surveyed.

Jan 1, 1983

By Q. Xu

The adsorption behavior of gold in ammoniacal solutions on to activated carbon has been studied. The gold loading capacity of the activated carbon used in the system and the recovery efficiency by the adsorption were examined. The parameters affecting the adsorption of gold on to activated carbon included temperature, agitation speed, concentration of 'cation and anion as well as that of ammonia. It was found that the maximum gold loading on activated carbon used was about 10 kg of gold per ton of carbon. The recovery of gold by the adsorption from ammoniacal solutions was dependent upon the initial gold concentration in the solution. A recovery of 98% of gold was obtained on to the activated carbon under experimental conditions after 120 hour adsorption. It was also found that the initial adsorption rate was relatively fast compared to the whole period of the adsorption. The apparent activation energy for the adsorption was measured to be 15.8 kJ/mol. It was believed that the kinetics of gold adsorption on activated carbon was controlled by pore diffusion.

Jan 1, 1995

By E. B. Thorn

The production of portland cement requires that four basic elements -- calcium, silica, alumina and iron -- be ground to a fine powder, homogenized, and fed to the pyroprocessing unit, where it is burned to a cement clinker. The raw material must either be ground wet in a slurry form or dried and ground to a dry powder, with a fineness of approximately 85% passing the 200 M screen. According to the Portland Association's Plant Information Summary, approximately 38% of the U.S. capacity is ground wet and 62% ground dry. The following data is taken from the Portland Cement Association's 1981 Energy Survey: [Million BTU/Ton kW h/Ton Wet Process Plants 5.86 138 Long Dry Process Plants 4.97 123 Dry Preheater Plants 4.03 157 ]

Jan 1, 1984

By Martin G. Casto

Mixer-settler extractors, among the oldest forms of extraction equipment, have been used since the beginning of this century. Over the past years, a very large number of mixer-settler devices have been designed and operated. Both batch and continuous flow mixer-settlers have been used. The continuous flow mixer-settler extractor offers a great number of advantages over other extraction equipment. The main advantage of the continuous flow mixer-settler is that it is a compact device. A large number of stages can be assembled in a relatively small area, and more stages can be added fairly easily. Many improvements have been made in the design of mixer-settlers. These improvements occurred in almost every phase of mixer-settler' operation; interface control, mixer design, intrastage pumping, interstage flow of the two liquid phases, and stage construction. It is believed that Barstow1 used one of the first continuous mixer-settler extractors. This mixer-settler had concurrent flow within each stage and countercurrent flow overall. The flow for both phases took place by gravity. The Barstow device and other early mixer-settlers had no separate interface control for each stage, therefore, "tilting" of the stages was necessary. In 1934 Holley and Mott2 designed a mixer-settler in which the heavy phase was recirculated within each stage by the use of a valve controlled central line instead of by a pump. Gordon and Zeigler3 in 1939 were among the first to use an adjustable valve to control the interface levels in a mixer-settler, making tilting of the extractor unnecessary. In 1952 Coplan et al. 4 used a modification of the Holley-Mott idea to build a highly improved mixer-settler with flat common walls, and with the

Jan 1, 1971

By J. B. Hiskey, X. H. Jiang

The extraction of gold from chloride solutions by ion exchange is examined. It is shown that at initial gold concentrations between 1 - 5 ppm, 20 g/l C1- and pH 5, the kinetics of loading on weak base resins are slightly slower than those observed with activated charcoal. Equilibrium loading of auric chloride varies considerably as a function of pH from one resin to another. For all of the resins studied, nearly complete gold extraction was achieved between pH 2 and pH 6.5. Sodium hypochlorite was found to exhibit a slight effect on the equilibrium loading of gold chloride.

Jan 1, 1990

By James K. Grunig, Rodney J. Anderson

A process consisting of leach, continuous countercurrent decantation, resin-in-column ion exchange, evaporative crystallization of beryllium sulfate, and decomposition of the sulfate was developed for Spor Mountain, Utah, ores. The process is metallurgically sound, has a minimum of process steps, and is applicable to a wide variety of beryllium ores. The most novel aspect of the process is a resin system of ion exchange which is highly selective for beryllium and which rejects substantially all impurities except for minor amounts of aluminum, magnesium, fluorine, and sulfate in addition to beryllium. The oxide from sulfate decomposition meets specifications of potential users.

Jan 1, 1983