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By C. H. Bucknam, A. M. Raichur, M. Misra

Simultaneous dissolution of mercury along with gold occurs during cyanidation of gold ores. A method has been found for the efficient removal of mercury from the gold cyanide solution by treating with dithiocarbamates which form stable compounds with mercury. The mercury concentration in the leach solution can be brought down to low levels by adopting this treatment. Furthermore, it is also possible to stabilize the mercury in the ore heap itself by addition of this reagent so that mercury does not dissolve in the cyanide solution during heap leaching. Only trace amounts of mercury were detected in the pregnant solution obtained from a heap treated with dithiocarbamates. In this paper, process parameters are discussed in detail.

Jan 1, 1997

By S. R. Clifford

Organic contaminants can be removed from river sediment using conventional flotation methods. Organic contamination in sediments is one of the most significant pollution problems facing the Great Lakes region. Using conventional flotation, the majority of the organic contamination can be collected in a concentrate, leaving a "clean" tailings. This provides a cost savings by reducing the amount of material requiring further treatment. The concentrate can then undergo additional flotation stages, or other contamination removal procedures, to further remove the organic contaminants.

Jan 1, 1994

By Tong Deng, Yun Ma

Gold-copper ores have become important gold resources (von Michaelis, 1989), but the gold extraction from such materials posed a challenge due to the detrimental effect of copper species on gold cyanidation. Ammoniacal cyanidation process was rec­ommended (Muir et al., 1989) and practiced (Castello et al., 1992) for gold extraction from the gold ores which contain cop­per at moderate level mostly in form of oxide. This paper pro­vides an example to apply the ammoniacal cyanidation process to processing such a copper bearing gold ore.

Jan 1, 1996

By E Mutaz, M Bahaaddini, D J. Williams, M Serati

The contribution of the mining industry to the global economy has reached (and gone beyond) $1,800 billion in recent years that necessitates (more than before) the need to ensure workability, viability, health, and safety of mine sites and workers to meet the ever-increasing global demand for mineral resources. Amongst the many challenges facing the excavation industries, rockburst and spalling failures in deep mines in hard and brittle rock formations are yet happening that are still deemed as unsolved problems. During unconfined compressive testing of brittle rocks, microcracks initiate at approximately 0.3–0.5 of the peak strength (which is commonly known as the Crack Initiation stress level) mainly in the direction of the major principal stress, then grow unstably and coalesce to form macro fractures at approximately 0.7–0.8 of the peak load at a so-called Crack Damage stress threshold. From a stress-strain perspective, the crack damage stress threshold () is associated with the reversal point of the volumetric strain, which is also proved to be strongly affected by the intermediate principal stress. This paper extends the previous studies on the impact of true triaxial loading conditions on the CD stress level in high porosity rocks, and introduce a new Crack Mode-Changing Stress (CMCS) defined as the minimum principal stress required to change rock fracturing from splitting to a sliding failure mode. A large number of experiments on sandstone specimens were carried out at different true triaxial loading conditions and the effect of principal stresses on the CI and CD as well as CMCS were studied. The results show that not only the intermediate principal stress, but also the minor principal stress can significantly affect the CD and CMCS thresholds.

Apr 26, 2022

By Richard R. Klimpel

This paper discusses the use of froth flotation as a means of removing metal containing species from a variety of feed streams that generally fall into the classification of waste streams. The variability in solid composition, degree of oxidation, water chemistry, and levels of organic/inorganic contaminants associated with waste streams implies that the collector chemicals used in any flotation process must be much more selective than typically required in normal mineral ore flotation systems. Several examples of such work currently underway will be illustrated showing the potential of flotation to upgrade metal-containing waste streams.

Jan 1, 1992

By Caelen D. Anderson

An investigation of a hydrometallurgical method for the recovery of tellurium dioxide from cadmium telluride (CdTe) thin-film manufacturing scrap was conducted. Sulfuric acid/ hydrogen peroxide lixiviation was employed to selectively leach cadmium and oxidize tellurium to tellurium dioxide (TeO2). Experimental variables included solution pH, pulp density, oxidant (H2O2) concentration, temperature, agitation rate and residence time. After one hour of lixiviation, no noticeable increase in grade or recovery occurred; thus, all experiments were performed for one hour. Leaching results showed it was possible to recover at least 74% of the tellurium, while producing a 98% pure TeO2 product. Additionally, an apparent activation energy value of 12.1 kJ/mole (2.9 kcal/mole) was determined. This value, along with results from agitation rate experiments, indicated the reaction was primarily controlled by diffusion through the product layer. During lixiviation, partial dissolution of tellurium proved inevitable. Thus, a second step: ammoniacal precipitation was introduced to recover the aqueous tellurium as a precipitate. A statistical experimental design (DOE) was used to identify the significant effects from the residual effects. Experimental variables included precipitation pH, temperature, initial tellurium tenor and agitation rate. Precipitation results showed that it was possible to produce a low-grade (46% Te) precipitate, while recovering 98% of the aqueous tellurium species. The precipitation pH and temperature (°C) were determined as the significant effects for both the grade and recovery of tellurium. Agitation rate and initial tellurium tenor were determined as the residual effects and did not influence the grade or recovery of tellurium. An illustration of tellurium recovery, as a function of the significant effects, is illustrated in Fig. 1.

May 1, 2012

By A. G. Sciulli, G. P. Ballock, K. K. Wu

Waste disposal underground is the most effective method when viewed from an environmental aspect. As costs of other methods of disposal continue to escalate, the cost effectiveness of underground disposal during the mining cycle becomes increasingly attractive. The use of concrete for sealing abandoned mines has proved to be suspect when associated with a relatively incompetent adjacent strata due to its shrinkage characteristics. Complete failure of the plug has been known to occur in some instances. A more effective, cost competitive seal can be obtained using pneumatically stowed material and incorporating a polyurethane grout, which has greater adhesion characteristics than concrete. Injection of the surrounding strata and of the stowed material helps to ensure an impervious barrier and prevent the plug from moving when subject to high pressure heads. When properly placed, impervious seals cause the old workings to flood, raise the mine pool level, and thus eventually eliminate the potential for oxidation, which is the primary cause of acidity in the water.

Jan 11, 1986

By Y. J. Wang

A critical path approach is presented for the problem of mine ventilation net- works where regulators and fans are employed to control the airflow distribution which is preassigned. The problem is a classic one which arises in mine ventilation planning. By identifying the analogy between the network for controlled flow and that for CPPI, the applications of the well known CPM technique to the ventilation network problem become straight- forward. The mathematical formulation of the problem is presented and the solutions are illustrated with examples. The effect of booster fans on the total air power consumed in a ventilation network are also discussed.

Jan 1, 1981

By Peter Zhang, Daniel Su, Bo Kim, Zoheir Khademian

Building on the research results and knowledge obtained from the ongoing National Institute for Occupational Safety and Health (NIOSH) Gas Well Stability Research, researchers from the NIOSH provided detailed analyses on potential longwall mining and gas well casing interactions at an unconventional shale gas well pad in a West Virginia longwall mine. Following the recommendations from recent research findings, the 5-1/2-inch production casings in all five wells were left uncemented from 4,200 feet below the surface to the surface. Prior to the first longwall panel excavation, NIOSH researchers conducted sophisticated three-dimensional numerical modeling to predict longwall-induced deformations and gas well casing stresses, which were compared with post-first panel and post-second panel mining 40-arm caliper surveys. The pre-mining predictions and comparisons with post-mining 40-arm caliper surveys were presented to all parties involved, including the coal and gas operators, Mine Safety and Health Administration (MSHA), Pennsylvania Department of Environmental Protection (PADEP), and West Virginia Department of Mines (WVDOM), prior to the re-entry operation on December 13, 2022. To date, the re-entry operation is a resounding success.

Jul 1, 2023

By Harry M. Edenborn, Richard W. Hammack

Experiments were done to determine if a mushroom compost-based sulfate reduction system could be used to treat nickel-contaminated mine waters. Sulfate reduction systems were established in columns containing acid-washed mushroom compost. Simulated mine waters containing 2000 mg/L sulfate and 50 to 1000 mg/L nickel were adjusted to pH 4.5 and pumped through the columns at flow rates between 15 and 25 mL/hr. During the first nine days of operation, virtually all influent nickel was removed in the columns by sorption and ion exchange mechanisms. The nickel removal rate then dropped to 18 to 30 mg Ni/day (7.8 to 12.8 nmol/ g-substrate/day), probably due to low sulfate reduction rates. When sodium lactate was added to the inflow, a sustained and seven-fold increase in the nickel removal rate was observed. Bacterial sulfate reduction rates measured in mushroom compost-based wetlands exposed to coal mine drainage are 2 to 20 times faster than the rates observed in this study. Low sulfate reduction rates in the columns may have been due to the inhibition of microbial activity by high nickel concentrations and the removal of labile organic compounds from the mushroom compost substrate during acid-washing. Results of this study indicate that bacterial sulfate reduction can effectively treat nickel concentrations up to 500 mg/L if labile carbon is nonlimiting.

Jan 1, 1992

By Robert C. Dunne, Jeffery P. Vaughan

The Archean ores of Western Australia are in total the largest producers of gold in Australia. In addition to numerous small and medium sized deposits, the province also contains the giant Kalgoorlie Golden Mile deposits. A variety of different gold ore mineralogical associations has lead to the development of a number of different processing routes for both refractory and non-refractory ore types. Intense weathering and lateritization of Archean greenstones in the semi-arid Yilgarn region have resulted in the development of a deeply oxidized profile (60-100m) above most sulphide orebodies. Residual and re-deposited supergene gold within iron oxide/silica gangue of this zone responds well to CIP, CIL, heap and vat leaching techniques. Although gold is easily liberated in principal from oxidized gangue, in practice recoveries are sometimes affected by iron oxide coatings on gold grains, and by clay minerals which can interfere with plant performance. Refractory ore types in the Eastern Goldfields fall into three main categories - pyritic, arsenopyritic and telluride-bearing. Pyritic ores may be either free milling or require roasting. The difference appears to depend largely on whether gold occurs along grain boundaries or fractures, which can be liberated by grinding, or whether gold occurs as inclusions within pyrite grains and therefore cannot be satisfactorily liberated by grinding. Arsenopyrite bearing ores are not well understood and are complicated by what appears to be a variable degree of gold solid solution, in addition to included gold. Gold occurring in complex gold-silver telluride assemblages has traditionally been recovered by roasting in the Eastern Goldfields.

Jan 1, 1987

By A. Andreas

The transportation of mine products incurs a cost which can have a significant bearing on the competitive position of the product. This statement not only holds true for the transportation of the finished product but certainly as much for the in- plant haulage of the raw materials. Extensive literature is available both in North America and Europe on all aspects 02 these questions and to cite only a few of them: Pipelining of slurries, oil and gas, shipping of minerals and oil from the Arctic by icebreaking tankers, airlifting of metals or concentrates, etc. This paper is concerned with movable crushing plants as opposed to stationary and their influence on the in-plant transportation, that is trucks vs. belts.

Jan 1, 1973

By B. C. Paul, R. Q. Honaker, K. Ho

Recent research has shown that froth flotation is not effective at treating fine coals (-28 mesh) containing a large portion of middling particles. Due to their relatively large density differences, middling particles can be separated more efficiently using gravity-based processes. The ability of gravity separators to treat fine particles has been limited by the lack of particle inertia relative to the surface drag forces. However, particle inertia can be enhanced by the application of a centrifugal field. A commercial-scale centrifugal Falcon concentrator capable of treating a mass flow rate of greater than 1 tph continuously has been used to evaluate its feasibility for treating fine coal as an alternative to froth flotation. Tests conducted on a -28 mesh fine coal circuit feed have found the Falcon concentrator to be very effective at cleaning the 28 x 325 mesh size fraction. For an Illinois No. 5 coal sample, the ash content was reduced in the 100 x 325 mesh size fraction from about 18% to 8% while achieving a high combustible recovery value of nearly 97%. In addition, the total sulfur content was substantially decreased from 2.6% to 1.7%. The effects of the critical operating parameters on separation performance have been studied and their values optimized.

Jan 1, 1995

By Lj. Obradovic

The aim of this paper is to study the feasibility of copper and gold recovery from the old flotation tailing dam at Bor, Serbia. Laboratory leaching experiments were carried out using a composite sample taken by drilling from 16 - 40 m depth. Different oxidation agents as FeCl3, Fe2(SO4)3 and H2O2 were used. An H2SO4 solution with a pH less than 3 was used for leaching. The influence of a number of parameters on the recovery of both elements as temperature, pH, duration of leaching and concentration of oxidation agents was also studied.

Jan 1, 2006

By C. Flores, L. G. Twidwell, T. S. Jordan

It is well known that manguniferous silver ores containing manganese intimate) associated with silver are not amenable to conventional extraction methods. The segregation process has been applied primarily to the recovery of copper from oxidized and oxide-sulfide ores. A new alternative process, consisting of segregation roasting followed by flotation to recover the silver from refractory manganiferous silver ores, was studied using a 23-factorial experimental design. Laboratory investigations were conducted on a manganiferous silver ore analyzing 0.02% copper, 0.09% lead, 0.33% zinc, 12.55% manganese and 187 g/t silver. The investigation was designed to study the effects of the addition of salts, coke and copper (11) oxide on silver recovery. The results indicated that 79.3% of the silver can be recovered in the absence of copper oxide and 88.4% of the silver can be recovered with a copper oxide content of 1.5% at 750°C, 2% salt (NaCI). 1 % coke and 30 min of roasting. It was concluded that the addition of copper oxide improves silver recovery.

Jan 1, 1996

By Richard A. Bideaux

In mid-1975, the United States Borax & Chemical Corp., a member of the RTZ group, engaged Computing Associates, Inc. (CAI) in a continuing project to model their operating property at Boron, CA, with the goal of computerized assistance in medium- and long-range open-pit mine planning. Their property, 161 km (100 miles) northeast of Los Angeles, is the largest producer of borate minerals in the world. Because of unusual geological complexity, this unique deposit presents interesting problems in computer modeling, compared with the coal, uranium, and other metallic deposits with which CAI ordinary deals. Mine planning for Boron has historically been based on manually plotted contour plan maps and cross sections, with geological reserves derived from manual triangularization of the drilling pattern. Standardization and reproducibility of log interpretation, contouring, and reserve calculation were principal goals of using the computer. Additionally, it was desired to shorten both the time and cost of a planning cycle, while at least equalling the accuracy of the manual planning. The present recovery plant processes only water-soluble borates; at some time in the future it will be necessary to recover acid-soluble borate minerals as well. With computer assistance the economics of this changeover point can be more thoroughly evaluated.

Jan 1, 1979

By P. Koh

A novel approach incorporating computational fluid dynamics (CFD) and flotation modelling has been used for investigating flotation cell designs. CFD modelling has increasingly been employed to enhance understanding of the cell hydrodynamics in mineral and coal flotation. Opportunities for improving the flotation cell performance can be identify by modelling. The CFD-flotation model from CSIRO incorporates cell hydrodynamics that affect particle-bubble interactions. Information from the model includes velocities, turbulent dissipation rates, gas hold-up, particle-bubble attachment and detachment rates. The attachment and detachment rates have been found to be effective measures of cell performance for cell design.

Jan 1, 2011

By H. Ban

Triboelectrostatic separation tests were performed on a bench-scale, analytical separator using coal, coal combustion fly ash and mineral samples. Fractions of separated samples were collected and analyzed to characterize the performance of the separation. Particle size distribution and morphological characteristics for these samples were analyzed by optical microscopy, and scanning electron microscopy (SEM). It was found that smaller size fractions of a fly ash sample had better separation than the full sized parent fly ash sample, indicating interference or particle-particle interactions during the separation process. It was also observed experimentally that small kaolin particles attach to the surface of large silica spheres, causing charge neutralization and subsequent low separation efficiency.

Jan 1, 1997

By Drupad B. Desai, Bruce Chang, Jay L. Merritt

This paper reviews difficult ground conditions encountered along the alignment of large-diameter sewage tunnels for the City of Los Angeles. It offers a detailed one-of-a-kind solution to a unique problem for shallow urban underground tunnels in a seismic zone, using state-of-the-art materials, technology, and equipment. The following topics are discussed in detail: • Geotechnical Design consideration for tunnel traversing through an active fault zone. • Seismologist evaluation of possible fault-offset problems where a fault zone crosses the alignment, in the event of an earthquake of moment-magnitude 6.5. • Probability analysis regarding "recurrence interval." • Structural design of tunnel subjected to displacement, subjected to axial elongation or shortening, and capable of rotational freedom. • Special joint details.

Jan 1, 1989

By J. Iannicelli

A variety of domestic bauxites have been beneficiated to meet refractory grade standards by use of high intensity, high gradient, wet magnetic separation. Besides reducing the iron content to less than 2%, the Ti02 content of the bauxite was also reduced. The beneficiation can be accomplished by means of a simplified wet process flow sheet with an estimated cost comparable to that of water washed, filler grade kaolin. The process has been carried out on a small pilot plant and then scaled to produce 25 tonnes of calcined refractory bauxite meeting National Stockpile Specifications.

Jan 1, 1984