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By Scott W. Beckman, Leslie C. Thompson, Joseph A. Kizis

Heap leaching of ore with cyanide is a common and economical means of extracting precious metals (gold and silver) from mined ore. The use of cyanide, and the heap leach process, can seriously impact the environment. In the worst case, catastrophic failure of containment structures can release toxic levels of cyanide into receiving bodies of water, resulting in toxicity to ecological communities and contamination of public water supplies. Furthermore, cyanide degradation products such as nitrates can also impact local streams, lakes, and aquifers. Even if cyanide can be removed, the crushed residual ore may generate acid solutions that can release toxic heavy metals into the environment. Pintail Systems, Inc. (Pintail) of Aurora, CO, in conjunction with technology partners Science Applications International Corporation (SAIC) and Fairmile Gold Corporation (Fairmile), have developed a microbially-based precious metal lixiviant that can be used as an alternative to cyanide. The microbial process, called BioLix, is Pintail's second-generation biotechnology product for the recovery of precious metals from ore. The BioLix process is based on the enzymatic induction of organic lixiviant compounds using proprietary inducing agents and microorganisms. The process operates at near neutral pH and ambient temperatures using non-pathogenic microorganisms and food-grade chemicals. Precious metal extraction is also enhanced through the employment of microorganisms that facilitate mineral-solution reactions such as surfactant generation (improved wettability), and oxidation of gangue minerals that expose mineral surfaces to leaching. In order to demonstrate the effectiveness of the BioLix process, results from laboratory bench-scale experiments and a column study are presented. In addition, new applications for this enabling technology are discussed and include re-leaching of spent ore heaps, in situ leaching, and cyanide replacement for heap leaching.

Jan 1, 2000

By Alex Harrison, K. Payne

Computer generated magnetic field reference signa- tures of steel cord belt splices are used to evaluate lay-up and fabrication irregularities of splices in operating conveyors. Used as a quality inspection tool, magnetic signature analysis is useful in auditing data collected by general non-destructive testing (NDT) consultants. The evaluation can detect irregularities that weaken a splice, as well as detecting signature changes that can be indicative of adhesion loss. The evaluation can be applied to any NDT data available from a variety of commercial sources, which means that independent review of critical splice data is possible.

Jan 1, 1996

By W. Petruk

Mineral liberations that would be obtained by grinding an ore to a specific size can be predicted by analyzing unbroken ore pieces, and mineral liberations in ground ores and mill products can be determined directly by image analysis. Predictions of mineral liberations are made by measuring size distributions and textures of mineral grains by image analysis and using liberation models. Ground ores and mill products are analyzed to determine the proportion of mineral that is liberated, and the data are used to evaluate mineral behavior during mineral beneficiation. The liberation data for minerals in a suite of mill products from a circuit are processed by a materials balancing technique to calculate recoveries of minerals in different types of particles throughout the circuit. The liberation-materials balance data define mineral recoveries; define the behavior of an ore in a concentrator, pilot plant or bench test: and indicate whether recovery improvements are possible and/or feasible.

Jan 1, 1992

By Tony Treasure, Ian Ewart

The EMEW® cell has been developed to overcome a number of inherent limitations in conventional electrowinning technology, particularly the high cost and restricted process windows characteristic of conventional hardware. The EMEW technology has been widely demonstrated to achieve high performance for various metals under chemical conditions well outside the limits required for efficient operation of conventional cells. In particular application of the EMEW cell for recovery of silver offers significant operating and capital cost advantages over conventional Merrill Crowe technology used for cyanide based solutions. The cell also offers process advantages for direct silver recovery from nitric acid solutions. The performance of the EMEW® cell on silver cyanide solutions, producing high grade silver metal in a single step, is accomplished by providing a physical mechanism which presents metal ions to the cathode on a highly efficient and continuous basis. The simplicity of design and operation of the EMEW cell offers the following advantages for silver recovery from cyanide or nitrate based solutions: • High grade product in a single step. • Selective for silver over other metals in the electrolyte. • Wide operating concentration range (100,000 - 5ppm). • Ability of the cell to operated in a variety of acid or alkaline electrolytes. (Cyanide, Nitrate). • Simple liquor reticulation. • No pretreatment required - Clarification, deaeration or zinc dust. • High cmTent density and current efficiency compared to conventional electrowinning cell. • Modular design allows for flexible operation and production rate. • Pilot plant results using full scale cell result in accurate scale up design. • Easy/fast installation - cell banks are delivered pre configured with piping and wiring. • Enclosed cell minimizes corrosive vapor and liquid losses in the circuit.

Jan 1, 2000

By R. Lee Wooten, Marco D. Boscardin, James M. Taylor

An earth pressure balance (EPB) tunnel boring machine (TBM) and pipe jacking were used to construct a 430-meter-long segment of sanitary sewer force main. The force main was constructed by first jacking a 2045-mm-outside-diameter, reinforced concrete cylinder pipe (RCCP) casing through alluvial sands and gravels. Later, a 1220-mm-diameter, ductile iron carrier pipe was installed within the casing pipe. The main concern affecting the construction method selection was the elimination of the need for dewatering, which could cause groundwater flow from deeper, contaminated sands up across a silt aquitard into cleaner, shallower sands. In addition, the method selected reduced the volume of soil to be handled and, consequentially, the potential amount of contaminated soil to be managed. Items discussed in the paper include provisions for handling boulders and controlling ground movements as excavation and jacking occurred approximately 300 mm beneath an active,4800 kPa, 254-mm-diameter natural gas transmission pipeline.

Jan 1, 1997

In the screening process, used to prepare particles for many applications, shape is known to have a significant effect. The degree of flakiness of construction aggregates has been considered particularly important. The objective of this research was to find values of operating parameters that optimize the separation of flaky from non-flaky particles by slotted screens. Thus an investigation was conducted to experimentally determine the influence of the particle size and thickness on the screening process. The Response surface method was employed for modelling and analysis of the data. Experiments employing a central composite design were performed on a pilot-scale, rectangular-aperture, vibrating screen to examine the effects of the screening variables the mass recovery of flaky and non-flaky particles to the oversize product. The SAS statistics package was used to fit a second-order model to each response and to analyze the fitted surface to determine the optimum levels. The optimization associated with a dual response system was then considered. The results of this study should provide a basis for optimizing screening conditions to obtain maximum recovery of non-flaky particles to the screen oversize while minimizing the recovery of flaky particles, which should be of interest to the aggregate industries.

Jan 1, 1999

By T. van Sandwijk, G. Van Weert, E. Molleman

This paper reports on test work that explored the dissolution/precipitation reaction: ZnS + 2HCl - ZnC12 + H2S, which is part of a process used in the production of pure ZnS. The research focused on the influence of proton activity on the dissolution of zinc concentrates obtained from the Brunswick Mine No. 12 in Canada (Brunswick Mining & Smelting); the Red Dog deposit in Alaska (Cominco Ltd.); and the Tara deposit in Ireland (Outukumpu Zinc). A comparison between the results of the experimental dissolution as a function of pH and the dissolution predicted by thermodynamics suggest that the three concentrates contained sig¬nificant amounts of the more reactive mineral wurtzite, although XRD analysis showed mainly the presence of the mineral sphalerite.

Jan 1, 1999

By Shahid A. Pirzada, Milton Manrique, Patrick R. Taylor

Microsilica or silica fume is a waste material generated from silicon or silicon-containing alloys producing electric furnaces. One of its usage is as an additive in the concrete production. This investigation describes a process to use microsilica as a feed material to produce fine silicon carbide. A thermal plasma reactor is used to convert this waste material into a value added ceramic. Details of the theoretical considerations, experimental work, and characterization are presented in this work

Jan 1, 1995

By A. C. Lyons

The presentation describes the history, preliminary report, site investigation, including examination of old records, design of tunnel including choice of levels, alternative linings and working sites, the preliminary contract involving shaft sinking on the site of the Tower Block; design modifications, the main contract, including shaft sinking, ground treatment, compressed air installation, machine tunnelling, tunnelling enlargements for chambers, waterproofing and equipment.

Jan 1, 1981

By O. A. Bascur

An expert process operation advisor system can increase plant efficiency, even in a complex, natural environment where not all elements of the production process can be measured directly. This system, develaped and tested in a Frasch process sulphur mine, monitors key process variables with extended qualitative pattern processing and provides on-line advise to the operators of sulphur production wells. An expert system framework captured common sense rules generated from years of experience obtained in the operation of a sulphur well monitoring system. The existent operating procedures were enhanced by process analysis using a qualitative modeling approach which provided extended rules for on-line classification of a well operational status and an expert alarm system. The methodology for development and implementation of the process advisor is presented in this report. Qualitative process modeling, statistical process control and heuristics were incorpomted into the process advisor resulting in a more efficient use of heat, an extended well operational life and the resulting cost savings. The computer process advisor also allowed the operator to concentrate his attention on the weak wells or wells in trouble. A process management system improved plant operation by automatically storing well data into a commercial database for operator validation. The enhanced relational data base system provided valuable and timely information for planning and decision making. The synergistic combination of on-line process analysis tools, expert control systems and database technology is shown to facilitate the flow of materials, energy and infomation in a modern plant.

Jan 1, 1990

By Joseph W. Siefke

The Kramer borate deposit is located in the western Mojave Desert at Boron, California, about 100 miles northeast of Los Angeles (Figure 1). The deposit derives its name from the district in which it lies. Borax (Na2 B407.10H2O) is being mined from the Boron open pit to serve a major portion of the United States and world borate markets. This paper deals primarily with those geologic factors which affect slope stability in the overburden at the Boron open pit. Discussion includes slope failure history, slope monitoring techniques and the results of a dipmeter survey of overburden structure. Open pit mining was begun at Boron in 1957. The initial pit was successfully excavated at the recommended 1.5:1 (horizontal to vertical) slope in the overburden. During pit expansion in 1962, excavation of the overburden exposed beds dipping into the pit at +15 degrees and numerous high angle fractures associated with two intersecting fracture systems, the West Jenifer and Portal fault zones. Ensuing south and east wall failures indicated the need for more structural information in the arkose to establish better wall design criteria. Barnard and Kistler (1963) recognized that the many facies changes, faults and other variables in the Boron overburden make it extremely difficult to reduce prediction of slides to a simple arithmetical formula. Despite the difficulties and uncertain¬ties, special programs such as surface resistivity, refraction seismic and core drilling were conducted in an attempt to predict slope stability conditions and to gather geologic information. These early efforts while helpful, did not provide the necessary details of bedding orientations and fault locations which are of paramount importance in our slope stability program. A dipmeter survey in 1974 successfully measured these variables and data from that survey are instrumental in the design of slopes currently being excavated.

Jan 1, 1976

By Gabriel Babut, Ion Matei, Roland Moraru

Several controlled recirculation systems are in operation wor1dwide. As an unconventional technique of ventilation the implementation of such a system requires particular safety conditions and a well-founded set of feasibility factors and parameters. On the other hand, many mines in Romania are facing problemms in meeting the growing ventilation demands, so that controlled air recirculation could give an answer. The present paper presents the results of the work in this field, based on a detailed theoretical approach. Parameters wich must to be taken into account were identified and analysed, numerical simulation are carried out and an experimental test-scale model is presented.

Jan 1, 1997

By Bruce B. Redpath

Single-charge cratering tests can provide a direct measure of the powder factor necessary for achieving a desired effect in conventional blasting. If a desired blast effect, such as fragmentation or mound velocity, is produced by a single point-charge at a particular scaled depth of burial, then the cube of the reciprocal of that scaled depth is the appropriate powder factor for duplicating the effect in a conventional array of blast holes. Scaling formulas are presented that provide a link between point-, line- and plane-charge geometries, and which can be Apparent crater used for blast design. Mound and burden velocities from several sources are compared and several examples of blast design are given.

Jan 1, 1977

By J. P. Savely

This paper describes the development of a trim blast design to improve the stability of a final pit wall. Description is given of the effects of rock characteristics, rock type, and pit plans on the blast design. Currently, six benches have been mined with trim blasting. A more stable final wall has resulted and the successful program has reduced mining costs over an extended time period. Low-cost blast monitoring and field observation were used to determine peak particle velocity and blast damage. Using criteria developed from this relationship, trim blasts were designed and evaluated.

Jan 1, 1987

By N. S. Kim

Economically favored Cr and Cu leaching out process from spent power plant fly ash (PPFA) had been investigated. PPFA, bearing of C, S, V, Ni, Cu and Cr, has been widely used as an assistant fuel in cement industry. Recent environmental regulation in S. Korea prohibits using PPFA as a fuel. Many researchers have also studied on extraction V and Ni from PPFA. Due to low concentration of V and Ni, 2% and 1%, respectively, economical and environmental friendly process could not be found. In this study, Cu and Cr have been removed in an economical way and which satisfied with KS Extraction Test. The rest unburned carbon, V2O5 and NiO2 in residue were found to be applicable for indoor and outdoor colored bricks or deodorant panel. Various parameters such as pH, lixiviates and time on leaching behavior were investigated in order to leach Cr and Cu remaining C, V and Ni. Keywords: Fly ash; Selective extraction; Ammonia; Deodorant panel

Jan 1, 2009

By F. K. Letowski

Leaching of zinc sulphide concentrate by nitric acid which is simultaneously regenerated by oxygen in the reactive froth has been investigated. The reactive froth was formed by a recycled zinc sulphate electrolyte containing nitric acid, a mixture of gaseous 02 and NOx, entrapped in the foam and particles of the zinc concentrate suspended in the foam. In the reactive froth the multiple regeneration of nitric acid proceeded owing to the encapsulated oxygen and amount of nitric acid used can be considerably lower than in the continuous liquid phase. 93 to 97% of zinc was extracted to a solution containing 30 to 409/1 HNO, during 40 to 60 min of leaching in a batch reactor without regeneration of nitric acid. 50 to 100% of the consumed nitric acid was regenerated during continuous leaching in froth carried out in the ‘flotation column’-type reactor at 80 to 90°C and under pressure of 100 to 200kPa. The rate of HNO, regeneration in the froth was proportional to oxygen pressure and inversely proportional to nitric acid concentration in the froth. A two-stage process flowsheet is proposed. In the first, the reduction stage, removal of nitric acid from the leach solution directed to standard purification and electrolysis is carried out by its reduction to nitric oxide using fresh concentrate in the froth. In the second, the oxidation stage, nitric acid is continuously regenerated by oxygen in the froth.

Jan 1, 1995

By Steve McIntosh

Restoration of a wetland which was initially disturbed at the turn­of-the-century will be undertaken to compensate for the temporary loss of wetlands associated with future mining operations. The proposed mitigation area exhibits xeric conditions as a result of past dredging and gravel mining operations which had the effect of lowering the flood plain surface and wasting the fine surface sediments. Together these mining activities resulted in complete alteration of the surface and subsurface water systems. Water which had inundated the soil profile, now flows on the basalt bedrock, surfacing only for a relatively short time during high flow periods. The conventional approach to wetland restoration in this type of area is to remove surface material in an attempt to bring the surface nearer to the underground water. These operations would require the removal and redistribution of large quantities of gravel, cobbles and boulders and the attendant destruction of existing wetland areas. Rather than lowering the surface elevation to the water level, the mitigation plan conceptualized for this project involves forcing the water to the surface by creating subsurface ponds behind four impermeable barriers. The barriers will extend vertically from the bedrock to the surface. Surface berms will be constructed along the length of each groundwater barrier to enhance sediment deposition and encourage the development of wetland vegetation. This is the least expensive and least invasive method of creating a wetland which will remain saturated to the requisite degree and for the amount of time required for classification as a wetland as defined by the 1989 Federal Manual for Identifying and Delineating Jurisdictional Wetlands.

Jan 1, 1993

By V. Ramirez, M. Mankosa, G. Luttrell, E. Wasmund

"The performance of column flotation is strongly influenced by the effectiveness of the gas sparging system. Unfortunately, field studies suggest that gas injector systems used for column sparging are not always optimized. This unfavorable condition can create a number of issues within the concentrator including lower recoveries, poorer metallurgical upgrading, decreased capacities, increased circulating loads, higher reagent consumption and inefficient energy usage. To help overcome these problems, techniques have been developed that can be adopted by plant operators to improve sparger performance. These techniques include (i) design modifications to sparger components such as nozzles, distributors and internal parts and (ii) operational improvements such as proper balancing of gas/water flows, elimination of unnecessary pressure drops, and staged injection of frothing agents. This article reviews the important criteria that govern sparger operation and provides data showing how simple low-cost improvements can positively impact column performance. INTRODUCTION Column flotation cells have become the most popular machine design for industrial applications that require high purity concentrates. The superior metallurgical performance of column cells can be largely attributed to their unique geometry, which readily accommodates the use of froth washing systems. The wash water minimizes the nonselective entrainment of ultrafine gangue minerals that would otherwise be hydraulically carried in the water reporting to the froth concentrate. The larger height-to-diameter ratio of columns allows a deep froth to be maintained, which is essential to achieve even water distribution. Due to these unique features, column cells can provide impressive levels of metallurgical performance closely approaching the ultimate separation curve predicted using the flotation release analysis method (Kohmuench et al., 2007). Another very important feature of column cells is the design of the gas sparging system. One popular choice in the minerals processing industry is the Eriez SlamJet® sparger. As shown in Figure 1, this type of sparger operates by passing compressed gas through a small discharge nozzle. Fluid turbulence created by the exiting gas disperses and distributes small bubbles into the flotation pulp. The sparger is equipped with an internal moveable rod that is attached to a pressure diaphragm in the back housing of the sparger. The internal rod automatically moves back/forward and opens/closes the nozzle outlet when the compressed gas is switched on/off. This patented design effectively eliminates the accidental backflow of flotation pulp into the injection tube during shutdowns. The sparger can be operated as a gas-only injector or with the introduction of a small amount of high-pressure sparger water (Kohmuench et al., 2010)."

Jan 1, 2016

By M. Yekeler

The critical surface tension of wetting values (Ye) of realgar (AsS), talc [Mg3si401o (OH) 2]' stibnite (Sb2S3), and sulfur (S) were determined by flotation in the absence of conventional flotation collectors as 38.7, 38.0, 35.5, and 30.0 dyne/cm, respectively. The surface tensions of flotation media were arranged by methanol. Separation of binary mixtures of these minerals was performed exploiting their Ye differences-which form the basis of the "ganuna flotation process". One step flotation test showed that sulfur floats preferentially from its mixtures with realgar and stibnite at recoveries of 73.6 and 70.7 % and grades of 81.7 and 91.2 %, respectively. The separation of stibnite from realgar gave a recovery of 4.1 % and a grade of 41.2 % for stibnite, indicate that a minimal Ye difference of 3.6±0.2 dyne/cm is essential for such separation when conventional flotation reagents are not used. This paper presents data and describes the approach employed in these separations.

Jan 1, 1994

By P. Moyo, S. Dixon, R. Norcross

The separation and recovery of copper from cyanide solution has been investigated since the early 1900s. The precipitation of copper using sulfide ion was patented in 1911 by Williamson, published by Leaver & Woolf of the USBM in 1931 and Cyanamid in 1960s. The current practice of sulfide precipitation is used in various processes such as “SART" for cyanide regeneration and copper recovery. The precipitation of copper sulfide requires the pH of the clear solution to be in the range of 4-6. The precipitated copper sulfide can be sold to smelters. Alternatively, copper cyanide can be precipitated from clear solutions in the pH range of 2-3. However, selling copper cyanide is challenging because of its cyanide content. Past work has focused on the use of boiling sulfuric acid to convert copper cyanide to copper sulfate as published by Seracini in 1991. This paper describes a simple process to convert copper cyanide to copper oxide using sodium hydroxide at ambient temperatures. The cuprite can be sold to smelters or used as a feed to an electrowinning circuit to produce copper cathodes. The process provides an effective method to recover copper from cyanide solutions with a lower capital requirement.

Mar 2, 2022