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By Andrew Griffiths

The emphasis in the title of this paper should be placed on the world "Total", since the detoxification of cyanide in its free and weakly-complexed form with H202 has already found application in many areas, including the treatment of mining effluents. One of the most common forms of cyanide found in gold-mill effluents is hexacyanoferrate (usually ferrocyanide), which is included in measurements of total cyanide but is too stable to be oxidized by H202 or any other conventional oxidizing agent. This has led to the view that H202 cannot be used to detoxify effluents containing hexacyanoferrates, when a limit has been set on total cyanide. A process is described in this paper which does meet this requirement, and which has already been demonstated in two Canadian gold mills. Before describing the new process, the terms "free", "total" and "weakly-complexed" cyanide will be defined as they are used in this paper.

Jan 1, 1998

By Alvin W. Schillinger

Drilling was not entirely satisfactory in the search for native copper in the Osceola amygdaloid footwall as mining showed oreshoots to be more continuous than drilling indicated. The Geophysics Department of Michigan Technological University developed a portable induced polarization drill hole probe with a 3 electrode configuration and a sampling radius of 5'± A 20 ma current of alternately reversed polarity is pulsed at 3.5 sec. intervals and readings are taken every two feet. Potential is read during the "on" cycle for resistivity determinations. During the "off" cycle, after 10 ms delay, the I.P. potential is sampled for 10 ms and recorded. Resistivity (ohm-feet) and "S" values (mv/v) are plotted on semi-log paper. A lithologic log is plotted based on resistivity and anomalous "S" values noted. The low resistivity amygdaloid contains sills of high resistivity basaltic trap. Verified by core logs, amygdaloid-trap contacts could be picked to ±.5' from resistivity alone. Lithologic logs of long steel holes, based' on resistivity, now replaced sludge logging. An "S" value of 30 mv/v was established as the lower limit of diagnostic I.P. effects in mineralized amygdaloid and 50 mv/v as a threshold value for ore. Of 914 footwall zones drilled, 315 were probed yielding 203 anomalies. Success increased from 34% for drilling to 72% for drilling and probing. As checked by mining, 46 probe results were 78% correct. Failures were due to the instrument not detecting copper or to the misinterpretation of an anomaly. No false anomalies were found.

Jan 1, 1964

By C. H. Sampaio

The effectiveness of modem spirals in the processing of fines from Brazilian coals is assessed and discussed. Coals representing the four major coalfields in Brazil have been cleaned in Reichert LD 9 spirals in pilot and industrial plants and performance results are here presented. Normalized distribution curves for all equipment and splitters are presented and were modeled using an empirical model. These data have been compared with those for shaking tables and water-only cyclones (WOC), and it has been observed that, in the size interval investigated, spirals have indeed superior accuracy than WOC and comparative performance to tables. By analyzing experimental as well as simulation results it could be observed that although limited by the poor liberation characteristics of most Brazilian coals, significant ash and sulfur removal could be achieved using spirals.

Jan 1, 1995

By K. Getsos

Western Greece is a favorable site for exploration and discovery of oil fields. The most important potential source rocks seem to be all the rocks deposited before middle Jurassic under special circumstances, such as reducing conditions, which allowed preservation and maturation of the organic material. In general all the rocks of middle Jurassic to Paleogene are not favorite source rocks. The porosity type was studied on fifty samples using scanning electron microscopy (SEM). Potential reservoir rocks are the porous Paleogene wackestones-packstones with boring, channel and vuggy porosity type. Finally seal rocks are the impermeable mud-stones and wackestones of Jurassic, Cretaceous and Paleogene age. These rocks consist of micrite and whole sells of foraminiferas and the porosity type is mainly intercrystal/interparticle. A Total Organic Carbon (TOC) analysis, conducted on seventy samples using a wet oxidation method, has revealed an extremely low TOC content (less than 0.05 %). This amount is by far less than the minimum organic content amount, required for source rock characterization and characterizes all the rocks of middle Jurassic to Paleogene age. Additionally, 18O and 13C stable isotope analysis was contacted and the results are given in d values. All the rocks within the studied time interval have much lower d values than petroleum source rocks. Clay mineral content was studied in almost seventy samples. As is indicated by the clay mineral content the studied rocks have reached up to the Middle Diagenesis and the temperature during diagenesis was rather low.

Jan 1, 2006

By Howard L. Hartman

If I told you tonight at the outset that my prognastications for the future of mine ventilation were imparted to me by a palm reader or inspired by a vision, you'd dismiss what I had to say before I said it! If, on the other hand, I told you that my forecasts were the result of an elaborate computer model, derived from a complex algorithm, which in turn relied on finite element analysis -- and the entire projection confirmed by on-site experiments with a turbo hybrid-flow mine fan -- you'd sit up in anticipation and hang on my every word!! All of which places me in a terrible dilemma, because my predictions really lie somewhere in between. My intent is to talk to you out of my background of forty years in mine ventilation, looking ahead to conditions that I expect to prevail in the next fifteen years. You may be curious why I picked an unlikely time span of 55 years for my overview, and my response is that it bridges a career lifetime. "The last forty", of course, corresponds with the period of my professional employment since graduating with a B.S. and M.S. here at Penn State. "The next fifteen" bridges the period I expect (the Lord willing) to remain professionally active -- and coincidently brings us into the beginning of the 21st century. (I must confess to stacking the deck a bit: Since it's infinitely harder to look ahead than to look behind, I purposely minimized the forecast period and maximized the history! Besides, "forty" and "fifteen" have a nice phonetic ring, perfect 20/20 vision sums to "forty", etc., etc.). With these disclaimers, I'll invite you to join me now in a fast 55-year overview of mine ventilation, of necessity limited to a broad-brush treatment of the subject. (After all, this is an after-dinner talk, not a marathon!) In each- segment, I've selected the seven topics that seem to me of paramount importance: in the first part, seven accomplishments in retrospect, and in the last, seven expectations for the future. (The number "seven" needn't confound you, either: In the bible, it signifies "wholeness" or "completeness".))

Jan 1, 1987

By G. Rainville, I. Servi, F. Katrak

Despite the severe drought conditions that reduced farm requirements for industrial mineral products, most industrial minerals markets in 1988 continued their growth or, at worst, remained flat. Earlier projections of output declines did not materialize in most segments. Preliminary estimates of demand in Europe and Asia show strong growth for most industrial minerals. Profitability in industrial minerals in North America was best in those minerals that had a significant export market or were not strongly regional. Growth and price trends in the more regional industrial minerals markets in the US such as sand and gravel, crushed stone, and cement, more closely followed the broadly disparate regional economic conditions. For example, sand and gravel and crushed stone grew strongly in the Pacific Coast and northeastern markets but not as much as in the Southeast. Total growth for sand and gravel in 1988 is projected at about 3% above 1987 levels. Combined production is up about 27 Mt (30 million st) to 2 Gt (2.2 billion st). Following the relentless trend of foreign acquisition of US cement companies (currently about two-thirds are owned by foreign interests), several aggregate operations have been purchased by foreign companies. Notable among these in 1988 was the acquisition of Rinker Materials Corp. by CSR of Australia. The acquisition of this Florida-based aggregate and concrete operation will expand the current holdings of CSR in the southeastern US, with operations consolidated under the Rinker logo. In addition, Pike Industries of New England and J.L. Shiely Co. of Minnesota were significant aggregate producers that were acquired by foreign firms. New England's only cement manufacturer, Dragon Products, was acquired by a subsidiary of Cementes del Norte of Spain. Dravo continued to expand its influence in the lime and limestone markets. It became the major supplier of construction aggregates on the inland river system with its purchase of Cyprus Minerals' limestone aggregate operations in Kentucky, Louisiana, and Texas. Although lime production continued to grow from 14 to 15 Mt (15.7 to 16.7 million st) in 1988, lime imports decreased for the fifth consecutive year to 145 kt (160,000 st). In the more export-oriented industrial minerals markets, performance was generally very good for 1988. Soda ash enjoyed an excellent year, with its price up to $102.50/t ($93 per st). This reflected the tight market situation for soda ash, particularly in late 1988. Soda ash production in 1988 was 8.6 Mt (9.5 million st), reflecting the industry's improved efficiency. Particularly significant was the increase in caustic soda prices that led to increased substitution by soda ash. The export market remained at 2.1 Mt (2.3 million st). Phosphate production recovered to the 42 Mt (46 million st) level, a 12% increase despite a soft export market. The price, however, remained soft throughout the year. W.R. Grace sold its interest in its Florida phosphate mine and its phosphoric acid complex as part of its divestiture of the agrichemicals business. The strengthening of the major producers has continued as lower cost capacity has been idled. Future permitting of phosphoric acid facilities and development of reserves will be necessary to maintain current production levels beyond the mid- to late 1990s. Despite new developments worldwide in the titanium minerals market, strong demand has continued to apply pressure to price, with concentrate and slag prices going up. The demand for high quality slag as feedstock for pigment production has resulted in process improvements in South Africa (Richard's Bay) and in plans by Canada to import high quality ilmenite by 1991 to produce a 90% TiO2 slag. Although growth in industrial silica sand applications was small in 1988, concentration in the industry continued. Unimin continued to acquire silica operations. Unimin is now the nation's leading producer of granular silica. The end users of silica have consolidated further. Owens-Illinois purchased Brockway Inc., a leading container glass producer. Three companies now control 75% of the container glass industry. ECC continued to be an aggressive purchaser of industrial minerals operations throughout the world. It acquired Cyprus Minerals' calcium carbonate business as well as two operations in Italy. In addition, ECC continued its aggressive acquisition of kaolin (Australia) and aggregate producers. 1988 was a good year for industrial minerals markets worldwide. More importantly, though, it was a year that showed continuing consolidations of reserve ownership in the industry around the world. Barite AN. Castelli, Baroid Drilling Fluids Inc. US mine production of barite decreased 9.4% during 1988. Consumption (sold or used by grinding plants) increased by 37.9%. Imports are estimated to have increased by 21.2%. World mine production decreased by 9.8%, according to the US Bureau of Mines. The value of domestically produced barite, fob mine, decreased 4.6%, according to the Bureau. The declared value cif US port of all imported ground barite during the first 10 months of 1988 increased from $37.16/t ($33.71 per st) in 1987 to $37.92/t ($34.40 per st), according to Bureau figures. Nevada continued to be the leading producer of barite with 72% of the total, followed by Georgia and Missouri. The Bureau of Mines estimates 69% of US mine production was used as a weighting agent in drilling fluids. The other 31% was used in barium chemicals, glass, or as a filler. Most of the production from Missouri, Georgia, and Tennessee was used in the non-oilfield sector. Of the total consumption used by grinding plants and chemical manufac-

Jan 1, 1989

By C. Yao, T. M. Yegulalp

The scale effect on rock properties has been discussed and studied since the introduction of the weakest-link idea by Weibull (1939). In this study, the capabilities of a dynamic lattice network model to simulate failure of rock under uniaxial tension is utilized. A number of randomly distributed microcracks that contribute to the development of uneven stressfields are introduced. In addition, each unit element in the model is assigned a random value representing its strength properties. Each application creates a randomly created specimen that is subjected to uniaxial tension. The specimens are grouped into three sets according to their size. The results of the study show that the scale effect is present in a statistical sense, i.e., the observed statistical distributions of strength for each specimen group is distinctly separate, and they follow the expected inverse relationship between strength and size. The observed probability distribution for each group of specimens give rise to the estimation of a different set of parameters. In this paper, the potential relationships among these parameters as a function of specimen size is investigated.

Jan 1, 1999

By Wang Dianzuo, Luo Lin, Hu Yuehua, Qiu Guanzhou

This paper introduces a novel classification approach named the flotation classification approach which works by controlling interactions between particles. It differs considerably from the conventional classification processes operating on mechanical forces. In the present test, the micro-bubble flotation technology is grafted onto hydro-classification. Selective aggregation and dispersion of ultrafine particles are achieved through governing the interactions in the classification process. A series of laboratory classification tests for -44 pm kaolin have been conducted on a classification column. As a result, about 92 percent recovery for minus 2 pm size fraction Kaolin in the final product is obtained. In addition, two criteria for the classification are set up. Finally, a principle of classifying and controlling the interactions between particles is discussed in terms of surface thermodynamics and hydrodynamics.

Jan 1, 1995

By Denise Herzog, Sukumar Bandopadhyay

This paper presents an application of analytical hierarchy pro- cess (AHP) to predict the ranking of three beneficiation methods for a low grade, bulk gold deposit located in the interior Alaska. Seven criteria (attributes) were used for evaluating each beneficiation method. For each criterion a matrix of pairwise comparison between methods was developed. The normalized eigenvector of each matrix scales the beneficiation methods with regards to that criterion. An overall scale is constructed by weighting the scales of all the criteria. Methodology used also indicates a measure of inconsistency. This measure is useful in identifying possible errors in expressing judgments as well as actual inconsistencies in the judgment themselves. The outcome of the pro- cess is the best or optimum beneficiation method, considering all the necessary objectives, criteria, and alternatives in a single integrated framework.

Jan 1, 1996

By Leo Langland

One of the primary functions of the Geotechnical Services-Materials section of the Arizona Department of Transportation (ADOT) is locating, sampling, and evaluating potential aggregate deposits throughout the State. This information is essential in designing, estimating, and bidding highway construction projects. The nature of materials used for aggregate varies greatly within Arizona. The northeastern or plateau section is famous for its scenic sedimentary formations that are, how- ever, too soft to make suitable aggregate. Volcanic materials are widely used in place of more conventional geologic units. In contrast, the southwestern, or Basin-and-Range section, contains a relative abundance of good aggregate, especially a diversity of gravels. The paper will review the off ice, field, and laboratory methods used by the ADOT Materials Section in satisfying its needs for aggregate information in Arizona.

Jan 1, 1987

By Klaus Schönert, Martin Botsch

In common high intensity magnetic separators, the magnetic particles are deposited on ferromagnetic matrices, such as expanded metals, steel balls or grooved plates, inserted into a strong magnetic field. The nonmagnetic material is flushed through the matrix chamber. Discharging the magnetic particles is only possible if the magnetic field is reduced to zero (e.g. high gradient magnetic filtration for the purifying of kaolin) or the matrix chamber is moved out of the field by a rotor (e.g. the Jones Separator). Therefore, these separators perform only in a batch or semicontinuous mode. A real continuous operation requirs transport of the deposited magnetic material to an outlet where it can leave the separation chamber inside the field. One possibility for accomplishing such separation and transport is through the use of a rotating induction body with a certain shape, such as a spiral.

Jan 1, 1995

By P. T. Luckie

More efficient classification with a single hydrocyclone through equipment and/or operating design changes does not appear possible. However, improvement in classification efficiency by increasing the sharpness index and decreasing the apparent by-passing while changing the cut size is possible through proper staging of inefficient hydrocyclones. But feasible multistaging requires achieving the necessary material balances around the units. Because of the interactions among the units, these balances require extensive iterations. The final step before commerical installation should be a laboratory demonstration, in order to define the control algorithm required to maintain stability. However, eventually a sufficient knowledge base should be developed that will permit simulation in place of laboratory testing as well as the incorporation of a feed forward strategy.

Jan 1, 1989

By B. K. Parekh

The International Symposium on Comminution was organized at Camborne School of Mines, Cornwall England. Papers covered the fundamental and practical aspects of comminution in the mineral industry. Although comminution equipment design has not changed fundamentally during the last 50 years, methods of control and optimization have improved considerably. A simulation model for batch ball milling in the rotating mill was developed as a step toward continuous simulation of ball and autogenous milling. New concepts in jaw crusher technology design and the concept of a 1.6- x 2.1-m (66- x 84- in) jaw crusher with open feed throat has resulted in power savings. The use of cone crusher technology in comminution circuits with particular reference to machine design, plant flowsheet and control figuration has been reported by Boliden Allis, of Sweden. The Whiten steady state crusher model form has been used to develop a quantitative model of 2.1-m (7-ft) cone crushers. This was done by incorporating liner age (wear) and liner length as variables on the selection of particles for breakage and thus on the product size distribution. Another paper by Lira and Karetsky discussed the development of a model based on a multisegment ball mill developed by Whiten and Kavetsky. It is capable of simulating the performance of a coarse grinding ball mill of a given diameter, ball size and mill speed.

Jan 1, 1991

By Fathi Habashi

LEACHING IS the process of extracting a soluble constituent from a solid by means of a solvent. In extractive metallurgy it is the process of dissolving a certain mineral (or minerals) from an ore or a concentrate, or dissolving certain constituents from metallurgical products such as calcines, mattes, scrap alloys, anodic slimes, etc. In this respect, either one of two purposes can be achieved: 1) Opening of ores, concentrates, or metallurgical products to recover the metal values. 2) Leaching easily soluble constituents (usually gangue minerals) in an ore or a concentrate in order to have it in a more concentrated form, e.g., the

Jan 1, 1970

By D. Robert Weir, Roman M. G. S. Berezowsky

Pressure oxidation can virtually always render refractory auriferous sulphidic ores and concentrates amenable to cyanidation. Its effectiveness as a pretreatment of refractory gold feedstocks is reflected by the successful startup and operation, over the past four years, of four commercial plants. At least three more are scheduled to come on stream during the next three years. Over the past eight years, a variety of ores and concentrates have been subjected to integrated miniplant testing and process demonstration by Sherritt, and data derived from these studies have been used in the design and construction of several of the commercial facilities. Some factors affecting the selection of pressure oxidation in gold recovery processing are discussed.

Jan 1, 1989

By V. Srajer

Several optimization approaches used by the Canadian mining industry were used to investigate surface coal mining operations in Canada. A computer program was applied to optimize truck/shovel systems and for various analyses. The analyses of eight western Canadian coal mines included investigation of fleet imbalance, under- and over trucking, development of the criteria for automated truck control, comparison study of various haulers and loaders, haulage layout, driving conditions, machine performance, servicing and maintenance policies, etc. Each property investigated supplied background information for the study and cooperated in optimization studies. The truck/shovel system optimization study is demonstrated as a test case to outline procedures and step-by-step instruction for similar applications.

Jan 1, 1989

By Terry A. Ring

Sand bed filters are used to remove large and small particles from liquid streams. The large particles are removed by the straining action of the filter bed and the small particles are removed by particle deposition on the surface of the bed particles. Particle deposition, while being essential for the filtering action of colloidal particles, is not the only process that occurs in the filter bed. Other processes that occur are (1) the substrate becomes filled with particles limiting further deposition, and (2) some deposited particles are resuspended. The sum total of all these processes determine the performance of a filter bed.

Jan 1, 1982

By Guerry H. McCullen, Bruno Despujol

Quartz and phosphate grains from concentrates and ores from Atlantic Coastal Plain sediments often are wholly or partially coated by humates. Coatings were studied in situ using infrared microscopy, by transmission Fourier transform infrared of extracts, and scanning electron microscopy. The 14C age of the coatings is about 20,000 years, much younger than the mineral substrates. Coatings on double flotation concentrates indicate that the conditioning pH may be too low, allowing coated quartz grains to follow phosphate grains through beneficiation. Organic matter from coatings may contribute to processing problems as well as affect final product quality.

Jan 1, 1999

By D. C. Willett

INTRODUCTION The Symposium on the Development of Underground Space, held in Seattle, Washington, from October 1 through 3, 1980, was organized by the "Deep Space" subcommittee of the ASCE's Underground Research Technology Council. The primary objective of the symposium was the exploration of the interfaces between the investigation, design and construction of large underground facilities in "deep space" which, for the purposes of the committee, has been defined as starting at 100m below ground surface. The meeting focussed primarily on tunnels, caverns and shafts in hard rock; the meeting format comprised a number of brief presentations concerned with the technical aspects of investigation, design and construction, followed by an open discussion, and concluded with the assembly of recommendations regarding the interface problem by the symposium participants. The principal considerations brought out during the symposium, and a general review of the conclusions, are briefly presented in the following paragraphs. INVESTIGATION The sessions dealing with "Investigation" were chaired by Dr. H. Pratt. Presentations were made by Dr. D.C. Banks, Dr. W.A. Hustrulid and Dr. Pratt. The extent of the interface of the investigation phase with the other (design and construction) phases of an underground facility will depend in large measure upon the nature of the facility; at one end of the spectrum, the investigation must be in continuous and closely coupled relationship with the design of a radwaste facility. At the other end of the spectrum, for (say) a small mining operation, the interface is largely associated with the initial development, with only minor on-going involvement.

Jan 1, 1981

By Victor F. Hollister

Porphyry-type deposits are characterized by mineralization in, as well as adjacent to, an igneous body, usually a porphyritic stock. One deposit style includes both mineral dissemination and mineralized veinlets, and both porphyry copper and porphyry molybdenum deposits are characterized by dissemination and veinlet control of ore minerals. Those gold deposits that occur in stocks, with gold occur- ring in veinlets and disseminations within the stock, clearly are can- didates for consideration as porphyry gold type. Porphyry copper and porphyry molybdenum deposits are also characterized by potassic, phyllic, argillic, orpropyllitic alteration or some combination of these alteration types. Where two or more alteration zones are present, these are arranged in a sequential outcrop pattern. Gold occurring in dissemination and in veinlets in as well as adjacent to stocks, and which also occur in typical pervasive porphyry alteration suits, constitute a clearly defined class of deposit that fits the definition of a porphyry gold type. Porphyry copper deposits may carry appreciable gold. Porphyry copper-gold deposits are known from all porphyry copper provinces. This chapter is intended to cover porphyry gold occurrences that may have little or no copper or molybdenum as economic concentrations.

Jan 1, 1991